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CHE 112 Tutorial Sheet IV 2022 - 2023
CHE 112 Tutorial Sheet IV 2022 - 2023
Q1. The freezing point of a glucose solution (C6H12O6; molar mass= 180.0 g/mole) is -
10.3 °C. The density of the solution is 1.50 g/ml. What is the molarity of the glucose
solution? (Kf for water is1.86 °C.kg/mole).
Q2. Chloroform and methanol form an ideal solution. The solution boils at 22 °C and
0.255 atm. At 22 °C, the vapor pressure of pure methanol is 0.192 atm and the vapor
pressure of pure chloroform is 0.311 atm. What is the mole fraction of chloroform in
the solution?
Q3. What is the normal boiling point of 1.21 M solution of CaI2 that has a density of
1.92 g/ml? (Kb for H2O = 0.512 °C .kg/mole)
Q4. What is the molar mass and molecular formula of a non-dissociating compound
whose empirical formula is C4H2N, if 3.84 g of the compound in 500g benzene give a
freezing point depression of 0.307 °C? (The molal freezing point depression constant
for benzene is 5.12 °C .kg/mole)
Q5. A 0.900 L aqueous solution contains 30.0 g of a protein. The osmotic pressure of
the solution is 12.7 torr at 25 °C. What is the molar mass of the protein?
Q7. CH2F2 has a dipole moment of 1.93 D and a boiling point of –52°C. CH2Cl2 has a
dipole moment of 1.60 D and a boiling point of 40°C. Why is the boiling point of
dichloromethane 92º higher than that of difluoromethane?
Q8. You are provided with the following compounds, arrange the following compounds
in the increasing order of their boiling point. (Justify your placement)
Q9. The graph below shows the boiling points of various compounds of hydrogen and
elements from group 4 to group 7.
(a) Explain why CH4, NH3, HF and H2O show such a characteristic behavior in
relation to boiling points?
(b) Describe the forces that are predominant each of the molecules name above in
(a).
(c) Using intermolecular forces, explain why generally the B.P decreases with
decrease in molecular masses.
Q10. (a) The vapor pressure of a substance is 21mmHg at 200 K. Calculate the
vapor pressure at 310 K if the enthalpy of vaporization is 12 kJ.mol-1.
(b) A liquid has vapour. pressure. of 2.02 x 103 N.m-2 at 293 K and heat of
vaporization 41 kJ.mol-1. What is the boiling point the liquid in (i) Kelvin (ii)
Degrees Celsius?
Q16. Draw a heating curve for water, going from -20ºC to 125ºC on the axis below.
Determine the heat needed to 15 g of ice at -20ºC to 125ºC. Calculate the total
energy involved in the all process. Given that: Five Step Problem for Water
Heat of Fusion = 334 J/g, Heat of Vaporization = 2260 J/g, Cp (solid) = 2.05 J/gºC
Cp liquid) = 4.18 J/gºC, Cp (vapor) = 1.90 J/g.
Q17. The heating curve of a mineral discovered is as shown in the diagram below.