‫یا حق‬

‫شیمی مواد‬

‫سپیده امجد‬
Structural Isomers
Same molecular formula
Different connectivity
Different properties
Example:
Structural isomers of C6H14
 Bond
Geometrical
cycle
Stereoisomers
Optical

Same molecular formula

Same connectivity
Different stereo structure
Ex: cis 2- pentene, trans-2-pentene
Optical

enantiomer

chiral
Optical activity
R,S Cofiguration

I>Br>Cl>F>O>N>C>D>H -1
-2
(CH3)3C−>(CH3)2CH−>CH3CH2−>CH3− -
-3
- HC≡C−>CH2=CH−>CH3CH2
Ex:

CH3CHBrCH3

1-boromo-2choloro-propane
CH3CH2CHBrCH3
1,2 di choloro pentane
 Alkane properties

Non polar
London
Mw high, straight chain
:::bp and mp high
Paraffins (little affinity)
Delta H formation
C-C , C-H (348,412)kj/mol
C=O, C-F, C-O (743,
484,360)kj/mol
Alkane reactions
1-Combustion

2- substitution reaction
1- Initiation

2- Propagation

3- Termination