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جلسه یازدهم- کایرالیته
جلسه یازدهم- کایرالیته
شیمی مواد
سپیده امجد
Structural Isomers
Same molecular formula
Different connectivity
Different properties
Example:
Structural isomers of C6H14
Bond
Geometrical
cycle
Stereoisomers
Optical
enantiomer
chiral
Optical activity
R,S Cofiguration
I>Br>Cl>F>O>N>C>D>H -1
-2
(CH3)3C−>(CH3)2CH−>CH3CH2−>CH3− -
-3
- HC≡C−>CH2=CH−>CH3CH2
Ex:
CH3CHBrCH3
1-boromo-2choloro-propane
CH3CH2CHBrCH3
1,2 di choloro pentane
Alkane properties
Non polar
London
Mw high, straight chain
:::bp and mp high
Paraffins (little affinity)
Delta H formation
C-C , C-H (348,412)kj/mol
C=O, C-F, C-O (743,
484,360)kj/mol
Alkane reactions
1-Combustion
2- substitution reaction
1- Initiation
2- Propagation
3- Termination