DLHHT - 2306646-6648 - SUW - Sept 2023

CERTIFICATE OF ANALYSIS
COA No :
Report To:
Dinas Lingkungan Hidup Kabupaten Halmahera Tengah

Jl. Kilo 40 Kecamatan Wedana Kab. Halmahera Tengah Ternate , Kelurahan Marikurubu,
Kecamatan Kota Ternate Tengah, Propinsi Maluku Utara
Attention:
Mr. Amrul Daga, SKM
Project Name:
Water Samples 2023
PT. WLN Indonesia
Arief Rakhmadi
Business Manager
Page 1 of 10
REPORT REMARKS & DESCRIPTION

REMARKS
APHA : American Public Health Association

USEPA : United State Environmental Protection Agency
mg/L : Milligram per litre
UoM : Unit of Measurement
DL : Detection Limit
GRL : Government Regulation Limit
Rem Q : Remarks of KAN Accredited parameters
< : Less than Detection Limit indicated
n/a : Not available
COC : Chains of Custody
CRM : Certified Reference Material
SRM : Standard Reference Material
DESCRIPTIONS
Blank : Blank or also known as Reagent Blank performed during analysis to determine contribution
reagents and preparative analytical steps to error in the measurement. Blank result acceptance are below
detection limit stated on the report (APHA,2012)
% Recovery CRM/SRM : CRM/SRM performed during analysis is a reagent water samples to which a
known concentration of the analytes of interest has been added. It is use to evaluate laboratory
performance (APHA,2012)
Detection Limit : Smallest amount that can be detected above the noise in a procedure and within stated
confidence level. The confidence level are set so that the probabilities of errors are acceptably small
(APHA,2012)
Manado, September 2023

Reviewed by:
Maria Mawu Aprilia Repi

Quality Manager Technical Manager
Page 2 of 10
PROJECT INFORMATION
Contract No. : - WLN PQ No. : PQ2309025-R1

PO reff : - WLN COC No. : 2309081
WLN Project No. : 23P0387 WLN WO No. : -
SAMPLE INFORMATION
Number of sample : 3
No Customer sample ID WLN Lab ID Sample Matrix Sampling Date Registration Date
1 Pintu Satu Boki Maruru 2306646 Surface Water 9/13/2023 9/15/2023
2 Spot Boki Maruru 2306647 Surface Water 9/13/2023 9/15/2023
3 BUMDES 2306648 Surface Water 9/13/2023 9/15/2023

Page 3 of 10
SURFACE WATER ANALYSIS RESULTS

Customer sample ID : Pintu Satu Boki Maruru WLN Lab ID : 2306646

Sample Matrix : Surface Water Reg. Date : 9/15/2023
Sampling By : Customer Coordinates : -
Sampling Date : 9/13/2023
Government Regulation Limit Peraturan Pemerintah RI No. 22 Tahun 2021 Lampiran VI

:
(GRL) (Baku Mutu Air Sungai & Sejenisnya - Kelas II)
No Test Description UoM Result GRL Method Reference Rem Q
1 Temperature in situ (Water)* °C 24.4 Deviasi 3 n/a
2 Colour TCU < 5 50 APHA-2120-C(2017) Q
3 Garbage* n/a Negative Negative n/a
APHA-2540-C(2017) and
4 Total Dissolved Solids mg/L 173 1000 WI-(ID)-[EHS]-LA-020 Q
(konduktifitas method)
5 Total Suspended Solids mg/L < 1 50 APHA-2540-D(2017) Q
6 pH in situ n/a 7.60 6-9 n/a

WI-(ID)-[EHS]-LA-011
7 Free Chlorine in lab mg/L < 0.02 n/a Q
(HACH)
8 Chloride mg/L 4.8 300 Q
(Spektofotometri)
9 Fluoride mg/L 0.08 1.5 APHA-4500F--C(2017) Q
10 Sulphate mg/L < 5 300 APHA-4500SO42--E(2017) Q
11 Unionized Sulfide (H2S) mg/L < 0.002 0.002 APHA-4500S2--H(2017)
12 Ammonia (N-NH3) mg/L 0.03 0.2 WI-(ID)-[EHS]-LA-064 (FIA) Q
13 Nitrate (N-NO3) mg/L 0.179 10 APHA-4500-NO3-E(2017) Q
14 Nitrite (N-NO2) mg/L < 0.001 0.06 APHA-4500-NO2-B(2017) Q
15 Total-Phosphate (P-PO4) mg/L < 0.005 0.2 WI-(ID)-[EHS]-LA-063 (FIA) Q
16 Total Nitrogen mg/L 1.0 15 WI-(ID)-[EHS]-LA-064 (FIA)
17 Cyanide (Total) mg/L < 0.005 0.02 WI-(ID)-[EHS]-LA-041 (FIA) Q
18 Arsenic-Dissolved (As) mg/L < 0.005 0.05 APHA-3120-B(2017) Q
19 Barium-Dissolved (Ba) mg/L < 0.005 n/a APHA-3120-B(2017) Q
20 Cadmium-Dissolved (Cd) mg/L < 0.0001 0.01 APHA-3120-B(2017) Q
Remarks : The Report of test result applies only to the samples tested, PT. WLN Indonesia is not responsible for the sampling process
*Measured by customer
Page 4 of 10

Customer sample ID : Pintu Satu Boki Maruru WLN Lab ID : 2306646


:

Chromium Hexavalent- WI-(ID)-[EHS]-LA-025
21 mg/L < 0.005 n/a
Dissolved (Cr-VI) (Spektofotometri)
22 Cobalt-Dissolved (Co) mg/L < 0.001 0.2 APHA-3120-B(2017) Q
23 Copper-Dissolved (Cu) mg/L < 0.005 0.02 APHA-3120-B(2017) Q
24 Nickel-Dissolved (Ni) mg/L 0.006 0.05 APHA-3120-B(2017) Q
25 Lead-Dissolved (Pb) mg/L 0.005 0.03 APHA-3120-B(2017) Q
26 Selenium-Dissolved (Se) mg/L < 0.005 0.05 APHA-3120-B(2017) Q
27 Zinc-Dissolved (Zn) mg/L 0.049 0.05 APHA-3120-B(2017) Q
28 Mercury-Dissolved (Hg) mg/L < 0.00005 0.002 USEPA-245-7(2005) Q
29 Biologycal Oxygen Demand mg/L 6 3 APHA 5210-B(2017) Q
30 Chemical Oxygen Demand mg/L 12 25 APHA 5220-D(2017) Q
31 Dissolved Oxygen in lab mg/L 8.62 n/a APHA-4500O-G(2017) Q
32 Oil & Grease mg/L < 1 1 APHA-5520-B(2017) Q
33 Total Phenol mg/L 0.048 0.005 APHA 5530-C(2017) Q
34 Surfactant mg/L 0.03 0.2 APHA 5540-C(2017) Q

35 Benzene Hexa Chloride (BHC) µg/L 210 Q
< 0.01 (GC-MS)
36 Endrin µg/L < 0.01 4 Q
(GC-MS)
Dichloro Diphenyl WI-(ID)-[EHS]-LA-099
37 µg/L < 0.01 2 Q
Trichloroethane (DDT) (GC-MS)
Page 5 of 10

Customer sample ID : Spot Boki Maruru WLN Lab ID : 2306647

Sampling By : Customer Coordinates :

:
APHA-2540-C(2017) and
5 Total Suspended Solids mg/L 3 50 APHA-2540-D(2017) Q

(HACH)
(Spektofotometri)
10 Sulphate mg/L < 5 300 APHA-4500SO42--E(2017) Q
14 Nitrite (N-NO2) mg/L < 0.001 0.06 APHA-4500-NO2-B(2017) Q
15 Total-Phosphate (P-PO4) mg/L 0.076 0.2 WI-(ID)-[EHS]-LA-063 (FIA) Q
19 Barium-Dissolved (Ba) mg/L 0.008 n/a APHA-3120-B(2017) Q
20 Cadmium-Dissolved (Cd) mg/L < 0.0001 0.01 APHA-3120-B(2017) Q
Page 6 of 10

Customer sample ID : Spot Boki Maruru WLN Lab ID : 2306647


:

21 mg/L < 0.005 n/a
30 Chemical Oxygen Demand mg/L 15 25 APHA 5220-D(2017) Q

< 0.01 (GC-MS)
(GC-MS)
37 µg/L < 0.01 2 Q
Page 7 of 10

Customer sample ID : BUMDES WLN Lab ID : 2306648


:
APHA-2540-C(2017) and
5 Total Suspended Solids mg/L 3 50 APHA-2540-D(2017) Q

(HACH)
(Spektofotometri)
10 Sulphate mg/L 6 300 APHA-4500SO42--E(2017) Q
14 Nitrite (N-NO2) mg/L 0.003 0.06 APHA-4500-NO2-B(2017) Q
15 Total-Phosphate (P-PO4) mg/L 0.084 0.2 WI-(ID)-[EHS]-LA-063 (FIA) Q
19 Barium-Dissolved (Ba) mg/L 0.008 n/a APHA-3120-B(2017) Q
20 Cadmium-Dissolved (Cd) mg/L 0.0001 0.01 APHA-3120-B(2017) Q
Page 8 of 10

Customer sample ID : BUMDES WLN Lab ID : 2306648


:

21 mg/L < 0.005 n/a
30 Chemical Oxygen Demand mg/L < 10 25 APHA 5220-D(2017) Q

< 0.01 (GC-MS)
(GC-MS)
37 µg/L < 0.01 2 Q
Page 9 of 10
LABORATORY QUALITY CONTROL

% Recovery Analysis
No Test Description UoM DL Blank
CRM/SRM Location
1 Temperature in situ (Water) °C n/a n/a n/a By Customer
2 Colour TCU 5 <5 92% Manado
3 Garbage n/a n/a n/a n/a Manado
4 Total Dissolved Solids mg/L 1 <1 102% Manado
5 Total Suspended Solids mg/L 1 <1 106% Manado
6 pH in situ n/a n/a n/a n/a By Customer
7 Free Chlorine in lab mg/L 0.02 < 0.02 n/a Manado
8 Chloride mg/L 0.5 < 0.5 102% Manado
9 Fluoride mg/L 0.02 < 0.02 102% Bogor
10 Sulphate mg/L 5 <5 83% Manado
11 Unionized Sulfide (H2S) mg/L 0.002 < 0.002 109% Manado
12 Ammonia (N-NH3) mg/L 0.02 < 0.02 111% Manado
13 Nitrate (N-NO3) mg/L 0.005 < 0.005 98% Manado
14 Nitrite (N-NO2) mg/L 0.001 < 0.001 98% Manado
15 Total-Phosphate (P-PO4) mg/L 0.005 < 0.005 103% Manado
16 Total Nitrogen mg/L 0.5 < 0.5 n/a Manado
17 Cyanide (Total) mg/L 0.005 < 0.005 100% Manado
18 Arsenic-Dissolved (As) mg/L 0.005 < 0.005 107% Manado
19 Barium-Dissolved (Ba) mg/L 0.005 < 0.005 110% Manado
20 Cadmium-Dissolved (Cd) mg/L 0.0001 < 0.0001 104% Manado

Page 10 of 10
LABORATORY QUALITY CONTROL

% Recovery Analysis
No Test Description UoM DL Blank
CRM/SRM Location
Chromium Hexavalent-Dissolved (Cr-
21 mg/L 0.001 < 0.001 90% Manado
VI)
22 Cobalt-Dissolved (Co) mg/L 0.001 < 0.001 98% Manado
23 Copper-Dissolved (Cu) mg/L 0.005 < 0.005 101% Manado
24 Nickel-Dissolved (Ni) mg/L 0.001 < 0.001 108% Manado
25 Lead-Dissolved (Pb) mg/L 0.001 < 0.001 102% Manado
26 Selenium-Dissolved (Se) mg/L 0.005 < 0.005 102% Manado
27 Zinc-Dissolved (Zn) mg/L 0.005 < 0.005 105% Manado
28 Mercury-Dissolved (Hg) mg/L 0.00005 < 0.00005 93% Manado
29 Biologycal Oxygen Demand mg/L 2 < 2 103% Manado
30 Chemical Oxygen Demand mg/L 10 < 10 111% Manado
31 Dissolved Oxygen in lab mg/L n/a n/a n/a Manado
32 Oil & Grease mg/L 1 <1 102% Manado
33 Total Phenol mg/L 0.001 < 0.001 117% Manado
34 Surfactant mg/L 0.01 < 0.01 98% Manado
35 Benzene Hexa Chloride (BHC) µg/L 0.01 < 0.01 86% Manado
36 Endrin µg/L 0.01 < 0.01 106% Manado

Dichloro Diphenyl Trichloroethane
37 µg/L 0.01 < 0.01 95% Manado
(DDT)

DLHHT - 2306646-6648 - SUW - Sept 2023

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CERTIFICATE OF ANALYSIS

Dinas Lingkungan Hidup Kabupaten Halmahera Tengah

PT. WLN Indonesia

REPORT REMARKS & DESCRIPTION

APHA : American Public Health Association

Manado, September 2023

Maria Mawu Aprilia Repi

Contract No. : - WLN PQ No. : PQ2309025-R1

1 Pintu Satu Boki Maruru 2306646 Surface Water 9/13/2023 9/15/2023

2 Spot Boki Maruru 2306647 Surface Water 9/13/2023 9/15/2023

3 BUMDES 2306648 Surface Water 9/13/2023 9/15/2023

SURFACE WATER ANALYSIS RESULTS

Customer sample ID : Pintu Satu Boki Maruru WLN Lab ID : 2306646

Government Regulation Limit Peraturan Pemerintah RI No. 22 Tahun 2021 Lampiran VI

No Test Description UoM Result GRL Method Reference Rem Q

1 Temperature in situ (Water)* °C 24.4 Deviasi 3 n/a

2 Colour TCU < 5 50 APHA-2120-C(2017) Q

3 Garbage* n/a Negative Negative n/a

5 Total Suspended Solids mg/L < 1 50 APHA-2540-D(2017) Q

6 pH in situ n/a 7.60 6-9 n/a

10 Sulphate mg/L < 5 300 APHA-4500SO42--E(2017) Q

11 Unionized Sulfide (H2S) mg/L < 0.002 0.002 APHA-4500S2--H(2017)

12 Ammonia (N-NH3) mg/L 0.03 0.2 WI-(ID)-[EHS]-LA-064 (FIA) Q

13 Nitrate (N-NO3) mg/L 0.179 10 APHA-4500-NO3-E(2017) Q

14 Nitrite (N-NO2) mg/L < 0.001 0.06 APHA-4500-NO2-B(2017) Q

15 Total-Phosphate (P-PO4) mg/L < 0.005 0.2 WI-(ID)-[EHS]-LA-063 (FIA) Q

16 Total Nitrogen mg/L 1.0 15 WI-(ID)-[EHS]-LA-064 (FIA)

17 Cyanide (Total) mg/L < 0.005 0.02 WI-(ID)-[EHS]-LA-041 (FIA) Q

18 Arsenic-Dissolved (As) mg/L < 0.005 0.05 APHA-3120-B(2017) Q

19 Barium-Dissolved (Ba) mg/L < 0.005 n/a APHA-3120-B(2017) Q

20 Cadmium-Dissolved (Cd) mg/L < 0.0001 0.01 APHA-3120-B(2017) Q

SURFACE WATER ANALYSIS RESULTS

Customer sample ID : Pintu Satu Boki Maruru WLN Lab ID : 2306646

Government Regulation Limit Peraturan Pemerintah RI No. 22 Tahun 2021 Lampiran VI

No Test Description UoM Result GRL Method Reference Rem Q

23 Copper-Dissolved (Cu) mg/L < 0.005 0.02 APHA-3120-B(2017) Q

24 Nickel-Dissolved (Ni) mg/L 0.006 0.05 APHA-3120-B(2017) Q

25 Lead-Dissolved (Pb) mg/L 0.005 0.03 APHA-3120-B(2017) Q

26 Selenium-Dissolved (Se) mg/L < 0.005 0.05 APHA-3120-B(2017) Q

27 Zinc-Dissolved (Zn) mg/L 0.049 0.05 APHA-3120-B(2017) Q

28 Mercury-Dissolved (Hg) mg/L < 0.00005 0.002 USEPA-245-7(2005) Q

29 Biologycal Oxygen Demand mg/L 6 3 APHA 5210-B(2017) Q

30 Chemical Oxygen Demand mg/L 12 25 APHA 5220-D(2017) Q

31 Dissolved Oxygen in lab mg/L 8.62 n/a APHA-4500O-G(2017) Q

32 Oil & Grease mg/L < 1 1 APHA-5520-B(2017) Q

33 Total Phenol mg/L 0.048 0.005 APHA 5530-C(2017) Q

34 Surfactant mg/L 0.03 0.2 APHA 5540-C(2017) Q

SURFACE WATER ANALYSIS RESULTS

Customer sample ID : Spot Boki Maruru WLN Lab ID : 2306647

Government Regulation Limit Peraturan Pemerintah RI No. 22 Tahun 2021 Lampiran VI

No Test Description UoM Result GRL Method Reference Rem Q

1 Temperature in situ (Water)* °C 26.7 Deviasi 3 n/a

2 Colour TCU < 5 50 APHA-2120-C(2017) Q

3 Garbage* n/a Negative Negative n/a

5 Total Suspended Solids mg/L 3 50 APHA-2540-D(2017) Q

6 pH in situ n/a 7.20 6-9 n/a

10 Sulphate mg/L < 5 300 APHA-4500SO42--E(2017) Q

11 Unionized Sulfide (H2S) mg/L < 0.002 0.002 APHA-4500S2--H(2017)

12 Ammonia (N-NH3) mg/L 0.03 0.2 WI-(ID)-[EHS]-LA-064 (FIA) Q

13 Nitrate (N-NO3) mg/L 0.920 10 APHA-4500-NO3-E(2017) Q

14 Nitrite (N-NO2) mg/L < 0.001 0.06 APHA-4500-NO2-B(2017) Q

15 Total-Phosphate (P-PO4) mg/L 0.076 0.2 WI-(ID)-[EHS]-LA-063 (FIA) Q

16 Total Nitrogen mg/L 1.5 15 WI-(ID)-[EHS]-LA-064 (FIA)