TAUTOMERISM

1. How many enolisable hydrogens are there in the following compound?

a) 4 b) 5 c) 6 d) 7

2. How many tautomers can you draw for the following ketone?

a) 1 b) 2 c) 3 d) 4

3. How many tautomers can you draw for the following ketone?

a) 1 b) 2 c) 3 d) 4

4. Which of the following is a tautomer of phenol?

a) b) c) d)

5. Which of the following compound exhibit tautomerism?

a) I b) II c) I and II d) Neither I nor II

6. What is the stability order for the following compounds?

a) I > II > III b) II > I > III c) III > II > I d) I > III > II
7. What is the stability order for the following compounds?

a) I > II > III b) II > I > III c) III > II > I d) I > III > II
8. Which of the following structure can show tautomerism?

a) I b) II c) III d) I and III

9. Identify the compound that exhibits tautomerism:-

(1) 2-Pentanone (2) Phenol (3) 2-Butene (4) Lactic acid

10. Tautomerism is not exhibited by:

A. (Me3CCO)3CH B. C. D.

11.Ketoenol tautomerism is not observed inThis question has multiple correct options)
A. phenol B. glycerol C. HCN D. benzophenone
12. Tautomerism will be exhibited by:
A. (CH3)3CNO B.(CH3)2NH C.R3CNO2 D.R−CH2−NO2

13.Which of the following compound shows tautomerism?(This question has multiple correct options)

A.CH3−CN B. CH3−NO2 C. CH3−CHO D. CH3−COOH

14. Which will show tautomerism?

A B C D

15. Which of the following show stable or major form of tautomerism?

A B C D

16. Which of the following compounds are showing tautomerism?(This question has multiple correct)

options

A B C D
17. ASSERTION: Higher enol content of the given compound is found in benzene (solvent) than ketone.

REASON: In a polar protic solvent like water, the lone pairs will be involved in hydrogen bonding with
the solvent, making them less available to hydrogen bond with the enol form.
18. Which of the following compound has highest enol content?

19. Which of the following has highest enol content.

A. B. C.
20. Arrange the following compounds in order of increasing enol content:
21. Which of the following has highest % enol content in the liquid?A

A. B. C.C D

22. Among the following, the compound having the highest enol content is :
A. acetone B. acetophenone C. acetyl acetone D. acetic acid

23. Which of the following compounds have higher enol content than keto content?

A. BB. C.C D.DDDD.

24. Which of the following compound has higher enol content?A

A. B.B C.C D.D

25. How many of the following will show tautomerism?