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2997 Pa
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Starting Behavior of Gathering Lines and
Pipelines Filled with Gelled Prudhoe Bay Oil
T. K. Perkins, SPE-AIME, Atlantic Richfield Co.
J. B. Turner, SPE-AIME, Atlantic Richfield Co.
Introduction
The discovery of large quantities of oil in arctic the shear resistance along the wall, TDLT, and we
regions has led to a number of unconventional diffi- can calculate a yield strength of the gel.
culties in producing and transporting oil under con-
ditions of low air and soil temperatures. One of the DAp
(1)
problems aggravated by low temperatures is that of ‘AT.’””””””””
gelling of oils. Although this difficulty has already
been encountered during transmission of high-pour- Although the theological study described later will
point oils, it is expected that gelling will be much show that this concept is quite oversimplified, yield
more severe or will be encountered more frequently strengths determined this way can reveal the quali-
as ambient temperatures fall far below zero. tative effects of variables on gel behavior.
This paper describes the study of a particular oil, Using this approach, we have found that the follow-
that from the Sadlerochit zone of the Prudhoe Bay ing factors will significantly affect the yield strength
field. Although the gelling and theological behavior of Prudhoe Bay oil: (1) temperature history, (2) shear,
will be described in detail for this oil alone, we believe (3) aging, and (4) composition. Many of these same
. ,
that much of the material presented here wiii be Iactors nave been repoI~-~ r-- UL1lG1
LCU,uI -*I.=.. V.ls
-:1 h.,
“y ~lu. .V-.
nrr=17in11c
c-- ---~---....xl..-
generally suitable m UIKIGIWWJU15
.-+o+~-
.La ~nh ht.=havinr
“W..u..w. invesdgators.1-6
of gathering lines and pipelines filled with other
gelled oils. Temperature History
To investigate the effect of any variable, it is necessary
first to return the oil to what is thought to be its
Factors Affecting the Yield reservoir condition. For Prudhoe Bay oil this is
Strength of Prudhoe Bay CM acconipiished by i~h~iitkg it to 1W ‘F (approxi-
The concept of a “yield strength” of a gel has often mately the reservoir temperature) and holding for at
proved useful in understanding the behavior of gelled least 1 hour. After this “beneficiation” treatment, the
oils. If it is imagined that a sample of gelled oil in a oil is relatively insensitive to any thermal treatment
tube will exhibit a specific yield strength, then exper- that it receives at temperatures above about 100”F.
imentally the pressure differential across the length of However, at less than 100”F three aspects of its sub-
tube can be increased until the oil just begins to move. sequent thermal history measurably influence yield
The force pushing the gel, 7D2Ap/4, is set equal to strengths. The lowest value of yield strength is ob-
tained by monotonically cooling the oil at less than tained by monotonically cooling the oil at less than
The apparent yield strength O) Prudhoe Bay crude oil is influenced by its composition
and its thermal and shear history. Laboratory studies were conducted with this gelled
crude to determine yield behavior in compressible and essentially incompressible tubes,
and it is concluded that with proper design, the proposed Trans Alaska pipeline can
be restarted without di#iculty.
about 10/rein to the desired testing temperature. We by quiescent heating. Similarly, throttling a sample of
have called such values tne yield strength of “bene- beneticlated oil is more det.nmental than temperature
Iiciated’ oil. The most dramatic effect of thermal cyctig an equivalent amount by quiescent heating.
history is shown by cycling the temperature to an
Aging
intermediate value, back to a higher value (but not
high enough to beneficiate the oil again) and finally Three aspects of aging are of interest. First, it has
to a low testing temperature. Such temperature cycling been found that samples of oil subjected to shear or
can lead to appreciable increase in yield strength. temperature cycling will change with respect to time
A second important aspect of thermal history is when stored at room temperature. Measurement of
the level of the testing temperature. As the testing yield strength shows that an equihbrium condition is
temperature decreases, the apparent yield srength in- apparently reached after about 48 hours. Hence, for
creases. Samples of Prudhoe Bay oil of different yield consistency of results, we believe that samples sub-
strengths have been prepared by subjecting them to jected to extreme thermal or shear histories should
various temperature cycles and then testing them at be stabilized at some convenient, warm temperature
dillerent temperatures. The results are shown on Fig. for about 48 hours before testing.
1 to illustrate the potential effects of thermal cycling Second, tests of stabilized oil have shown that gel
and temperature level. strengths may increase for 8 to 12 hours after reach-
A third important aspect of thermal history is that ing the testing temperature; hence it is necessary to
of cooling rate. We have seen little effect of cooling age the gel attesting temperature for at least 12 hours.
rates less than a few degrees per minute. However, Finally, in a hater section of this paper it is shown
if small tubes containing warm, beneficiated oil are that the gel behavior is thixotropic. Partially degraded
plunged into baths of cold liquid so that the cooling gels have been shown to rebuild gel strength upon
rate of the oil is tens or even hundreds of degrees per quiescent aging at testing temperature for a number
minute, substantial increasesq III
‘- ~IQ,
=’:-ld st.rengttis can be of hours.
observed even though the history has been one of
Composition
monotonic cooling.
Finally, the mixing of two streams of beneficiated Gel strengths are sensitive to light-ends content.
oils that are at different temperatures can in some Weathering or removal of light ends can lead to sig-
cases lead to a tenfold or even a hundred-fold increase nificant increases in gel strength. Weathering experi-
in yield strength. This increase is thought to be a ments in the presence of air as well as pure nitrogen
result of the temperature cycling effect on the cold have shown that mild contact with air at room tem-
oil stream, with perhaps a contribution of shock cool- perature causes no oxidation effect on gel strength.
ing of the hot oil stream. The presence of only a fraction of 1 percent of
emulsified water had little effect on yield strength,
Shear History but a high percentage led to a decided increase.
Various experiments have shown that subjecting the Finally, the mixing of a small sample of high-yield-
oil to high shear conditions at temperatures below strength oil with a large quantity of beneficiated oil
about 100”F will increase the yield strength of the at the same temperature will create a mixture with a
gel after it is subsequently cooled to a low testing yield strength very nearly like that of the sample.
temperature. For instance, cycling the oil tempera-
ture by imparting shear energy is more detrimental Theological Study
than increasing the temperature of a similar sample Consider now the rheology of gelled Prudhoe Bay oil.
+ y 3/8’’o.D.
l-n
M-
STEEL SHAFT
(PRESS FITIN1O ALUMINUM BOB)
I--2 l/4’’O.D.+
ALUMINU
BOB
/16”
%
\
TEMPERATURE, ‘F BOB BRASS SX.FP
Fig. l—Yield strength of temperature.cycieci Fig, 2—Dimensions of viscometer bobs and cups,
Prudhoe Bay crude.
0.1 -h I ,
I
i 1
0.08 \
(
4
GJ 111~’
i, 1
~ 0,06 I
~ i I
lo,ow
w’
? I I
= 0.04
g -.
o >
e 0.02 %
I :lm
I I i
o1 i I
o 1 2 3 4 5 6 7 1,000Io,ooa
TIME, MINUTES 7#SECONDS-’
Fig. 3—Typical viscometer data. Fig. 4-A typical plot of initial yield strengths showing
change in slope at high shear rates.
I
* 0
9 3---
0
“’*0=:
●
+
+
I
1 1 I 11(111 I t , II-J
LEGEND:
7’ f$$i)
SYMBOL RUN# TEMP. “F SYMBOL RUN# TEMP ‘F
o 1 Q + 6 11
● 2 o
07 0
A 8 0
09 0
x5 ii
V.t
Fig. 5—Correlation of viscometer data at zero shear strain ~ = ~ = 0.
behavior fell on the Newtonian line except at the very We define shear strain for the pipe as
lowest shear rates studied. At these very low shear
rates the behavior was in reasonable agreement with
that predicted by the generalized correlation for an
&value of 2 million. e=
[01
l–zz-
.
Vmax
dv
. . . . . . (13)
Vmax
=l–
() L.....
r~=
. (lo) (or volume injected). Fig. 6, however, shows four un-
knowns: rate of injection, injection pressures, volume
injected and “B”, an exponent relating 7 and y at
Fig. 7 shows the calculated veloci~ profiles for the
two extreme possibilities for Prudhoe Bay crude of any stage of displacement (B is often denoted the
B = 0.162 and B = 1. It is interesting to see that “flow-behavior index”). This problem can be over-
even though mathematically there is no finite gel come by yielding duplicate tubes with all conditions
strength in this fluid, when B is small the flow in a constant except rates of injection, which differ by
pipe will still be essentially “plug” like. twofold to tenfold. If it is assumed that there is some
The shear rate (or velocity gradient) across the average value of “B” that is adequate to describe
pipe will be a maximum near the wall and will in both experiments (at equal values of shear strain),
fact fall to zero at the center of the pipe. Thus, to be then the tube-yielding data can be plotted on Fig. 6
ma~hematicallv. .precise, equations relating flow rate without any prior knowledge of rheo[ogical behavior
and pressure gradient should incorporate the correct m determined in a viscometer. Data of this type have
relationship between ~ and y, between the maximum shown agreement that appeared to be as good as the
value of y (at the wall) and y = O. From a practical original correlation of viscometric data for values of
point of view, however, the velocity profile is insensi- &of about 100 or more.
tive to the relationship between . and y at very low It is now necessary to introduce a new variable —
values of y. Thus, a very useful simplification will be compressibility of the pump system. Any real labora-
to evaluate A and B at the shear rate and shear strain tory pump will have some compressibility resulting
near the pipe wall and then to use the pseudoplastic from compressibility of the fluid it contains, elastic
equations to relate pressure drop and flow rate in the expansion of the pump chamber, elastic flexing of
L -ln.~fi~l nnram~t~.~ .
pipe. Tk r11eu,u51we1~----- for a piape can then the drive system, etc. Therefore, with most “constant-
be approximated as rate” pimp system-~, e!lhent rates are not actually
constant unless the rate of change of pressure is low.
DAp Since the yield pressure of a tube is sensitive to the
. (11) effluent rate from the pump, the measured initial yield
‘D=4LTi’ ”””””””
pressure jor a tube filled with gelled oil is then a
y. = (3 -t l/B)q function oj the nominal injection rate as well as the
. . . . . . . (12)
i7r~~X3ri compressibility of the pump system. Fig. 8 shows
1.0 .
0.8 -
—
; 0.6 -
‘E
& 0.4 -
0.2
(—)
r max
some calculated examples together with experimental and yielded. Duplicate runs were made in a copper
results that verify this compressibility effect of the tube (essentially incompressible) of the closest avail-
pump system. able size (ID of 0,311 in.) and with all other condi-
tions the same. Results of a typical pair of runs are
Yielding in a Compressible Pipe shown on Fig. 10. We invariably noted different
ln a large pipeline containing a thixotropic fluid, characteristic shapes of the yield curves, and observed
compressibility will play a measurable role in yield- that the initial yield pressure of the compressible hose
ing behavior. This effect results from the compressi- was lower than for the equivalent run in the incom-
bility of the fluid contained in the pipe as well as the pressible tube even though the nominal shear rate in
expansion of the pipe itself, which gives an effect the hose was slightly greater. Calculations show that
equivalent to greater compressibility. The effective the decrease in initial yield strength could not be
compressibility resulting from expansion of the pipeg accounted for by the slight increase in diameter of
is given by Eq. 15. the compressible hose resulting from the pressure
increase. However, it could be accounted for by
~,= D(l– v’)
(15) including the effect of degradation of the gel resulting
hE ””””””” from the compressibility of the system.
The effect of a compressible systeKmis illustrated
on Fig. 9. Because of compressibility, fluid can be Trans Aiaska l?i@ine Behavior
injected at the inlet with a high pressure gradient, Although the design of the proposed Trans Alaska
and it will not immediately flow out of the pipe exit. pipeline is not yet final, the calculated starting behav-
As fluid continues to be injected, the moving gel near ior of one hypothetical section can be used to illus-
the pipe inlet degrades in yield strength as a result trate the present approach. Consider the 100-mile
of thixotropic behavior. Thus as the pressure wave section nearest Prudhoe Bay. Assume that this section
moves through the pipeline, the “effective” yield contains 22 miles of pipeline arranged in segments of
. .. -1 ..,:11 hm c mewhat ]e$s than if the various lengths, alternating surface and buried pipe-
strength or me gtx W1ll “v .c . . . . . . . .
whole length of gel had to be yielded at one time. iine. H the ~ipelifie IAu.-
~-r- . . . .in for a long period of
C~ut
This effect can be calculated by breaking the pipeline time, then the temperature in surface sec~ions could
into mathematical segments and allowing the gel conceivably fall to about – 200 F during winter
properties to vary along the pipeline as the transient months. If the pipeline had previously been in opera-
pre~~ure wave advances. tion, then the temperature of buried segments would
The effect of a compressible pipe system has been not fall below 32 ‘F for a very long penod of time.
demonstrated in the laborato~. A reinforced rubber If the pipeline were full of oii when shut in, the dii?er-
hose, 50 ft long, with an ID of 0.335 in. and a com- ence in elevation between the first two pump stations
pressibility of about 0.001 psi-’, was wound in the would cause a static oil head of about 500 psi at the
form of a helix, filled with oil, cooled slowly, aged, first pump station. Thus during start-up, a maximum
10
I I
TI I I
9 - ~
CALCULATED POINTS FOR A PUMP SYSTEM OF ZERO COMPRESSIBILITY
z ~-
5 ‘1
3
oYNu
CALCULATED WITH ?’i = 230 ~ .
2
DYNES
XXXK. CALCULATED WITH Yi = 13S
1 ~ -
— EXPERIMENTAL RUNS
0
o 1 2 3 4 5 6 7
TIME, MINUTES
500
40
30 200 -
COMPRESSIBLETUBE
20
100
10 INCOMPRESSIBLETUBE
~ .1.27 S. C:’
o 1 1 I 0
o 5 10 1s 20 0 1 2 3 4 5 6 7 a
TIME, MINUTES TIME, HOURS
Fig. 10-Typical pressure behavior during displacement Fig. n--Calculated starth’tg behavior for a hypothetical
of gelled oil from a compressible and incompressible tube 100-mile section of the proposed Trans Alaska pipeline
of essentially the same size. (oil properties as shown on Fig. 1).