Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI

A right Choice for the Real Aspirant
ICON Central Office - Madhapur – Hyderabad
Sec:Sr.C-120 2022_P2 Date:08-06-2024
Time: 09.30 AM to 12.30 PM WTA-33 Max. Marks:180

KEY SHEET
MATHEMATICS
1 5 2 1 3 3 4 9 5 9 6 3

7 6 8 8 9 AB 10 AB 11 AD 12 AD

13 AC 14 ABCD 15 A 16 C 17 C 18 D

PHYSICS
19 6 20 6 21 3 22 2 23 5 24 5

25 2 26 6 27 BD 28 BC 29 CD 30 ABC

31 AC 32 CD 33 C 34 D 35 A 36 A

CHEMISTRY
37 2 38 4 39 0 40 6 41 3 42 6

43 3 44 6.47 45 ACD 46 BC 47 BC 48 CD

49 BCD 50 AB 51 A 52 D 53 C 54 B
 Sri Chaitanya IIT Academy 08-06-2024_Sr.C-120_Jee-Adv(2022-P2)_WTA-33_Key & Sol’s

SOLUTIONS
MATHEMATICS
1  3P 1  P 1  2 P
1.   1
3 4 2
1
P  ................(1)
3
1  3P 1 P 1  2P
0  1, 0   1, 0  1
3 4 2
1 2 1 1
  P  ,1  P  3,  P  ........(2)
3 3 2 2
1 1
From 1 & 2 P
3 2
2. sum of digits =45
1 1
3. P( A  B)  1 / 6 P  A   P B 
3 2
B 1
6 P    6 P  B   6.  3
 A 2

Lt 2  a x  bx 
4. e x0  1  6  ab  6
x  2 

E  1, 6  ,  2,3 ,  3, 2  ,  6,1

4 1
n  E   4, n  S   62  36 : P( E )  
36 9
5. 10 10  100 ways

x 2  y 2 is divisible by 10 if unit digit of sum of squares of unit digits of x and y is zero.

 unit digits of x,y can be (0,0),(1,3),(3,1),(1,7),(7,1) (2,4)

(4,2)(2,6),(6,2),(3,9),(9,3),(4,8),(8,4),(5,5),(6,8)(8,6),(7,9),(9,7)
18 9
 18 cases are favorable and P=   50 P  9
100 50
a b
6. For unique solution  0 where a, b, c, d  0,1
c d

Total no of cases 16, if ad=1 then bc=0 or ad=0 then bc=1 this can be done in 6 ways
6
 probability   k  8k  3
16
7. n  S   11C2  55

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 Sri Chaitanya IIT Academy 08-06-2024_Sr.C-120_Jee-Adv(2022-P2)_WTA-33_Key & Sol’s
Set of numbers of form 4K is 0, 4,8  A

Set of number of form  4 K  2  is 2, 6,10  B

Sum and difference of the two numbers are both multiples of 4
If both the numbers are taken from either A or B
No.of favorable cases=  3C2  3C2   6
6 x
 Re quired probability   x6
55 55
8. P  A  B   1  P  A  P  B   P  A  B   1

 P  B   1  P ( A)  P  A  B   1  0.6  P  A  B 

 0.4  P  A  B   0.4  0.4

8 K
 P  B   0.8   where k  8
10 10
1
9. P( X ) 
3

X  P X Y  1
P  
Y  P Y  2

Y  P X Y  2
P  
X  PX  5

2
P  X Y  
15
4
P Y  
15
4 2

 X '  P(Y )  P  X  Y  15 15 1
P   
Y  P Y  4 2
15
1 4 2 7 7
P  X Y      
3 15 15 15 15
P  A  B
10. i. Conditional probability, i.e P  A / B  
P  B

ii. P  A  B   P  A  P  B   P  A  B 

iii. Independent event, then P  A  B   P  A .P  B 

1 Y 1
Here, P  X / Y   , P   
2 X 3
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1
and P  X  Y  
6
P X Y 
 P X /Y  
P Y 

1 1/ 6 1
   P Y   .....(i )
2 P Y  3

1 P  X Y  1
P Y / X    
3 P X  3
1 1
  P X 
6 3
1
 P( X )  ...........(ii)
2
P  X  Y   P  X   P Y   P  X  Y 

1 1 1 2
    .............. iii 
2 3 6 3
1 1 1 1
P  X Y   and P  X  .P Y   . 
6 2 3 6
 P  X  Y   P  X  .P Y 

i.e independent events

 P  X ' Y   P  Y   P  X  Y 

11.
11
PE  F   PE  F   ......(i)
25
[i.e only E or only F)

2
Neither of them occurs=
25
2
PE  F   ......(ii )
25

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 Sri Chaitanya IIT Academy 08-06-2024_Sr.C-120_Jee-Adv(2022-P2)_WTA-33_Key & Sol’s
11
From Eq (i) P  E   P  F   2 P  E  F   ......(iii )
25
2
fROM eQ (II) 1  P  E   1  P  F   
25

2
1  P  E   P  F   P( E ) P( F )  ........(iv )
25
From Eqs (iii) and (iv)
7 12
1 P  E   P  F   AND P ( E ) P ( F ) 
5 25

7  12
 P( E )   P( E )  
5  25
2 7 12
  P( E )   P( E )  0
5 25

 3  4
  P( E )    P( E )    0
 5  5
3 4 4 3
 P( E )  or  P ( F )  or
5 5 5 5
P( E  F ) P( E  F )
12. (a) P( E / F )  P( E  F )  
P(E ) P( F )

P( E  F )  P( E  F )

P( F )
P( F )
 1
P( F )

Therefore, Option(a) is correct.

P( E  F ) P( E  F )
b) P( E / F )  P( E / F )  
P( F ) P( F )

P( E  F ) P( E  F )
  1
P(F ) 1  P( F )

Therefore, option(b) is not correct

P( E  F ) P( E  F )
c) P( E / F )  P( E  F )  
P( F ) P( F )

P( E  F ) P ( E  F )
  1
P( F ) 1  P( F )

Therefore , option(C) is not correct.

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 Sri Chaitanya IIT Academy 08-06-2024_Sr.C-120_Jee-Adv(2022-P2)_WTA-33_Key & Sol’s
P( E  F ) P( E  F )
d) P( E / F )  P( E  F )  
P( F ) P( F )

P( E  F )  P( E  F )

P( F )

P( F )
 1
P( F )

Therefore, option(d) is correct.

13. S  1, 2,3, 4, 5, 6

A  1,3,5
B  2, 4, 6
C  4,5,6
D  1, 2

 
14. A  each place can be filled in 2- ways
 
n  S   2  2  2  2  2 4  16 ways

A) A square matrix is invertible if its determinants is non zero, it can zero in following
ways
  1 1  1 0  0 0   0 1   0 1  0 0  
    
 0 0   0 0  1 0   0 0   0 0  1 1 
But  
 1 0  0 1 0 0 1 1 
 1 0  0 1 0 0 1 1 
  

Number of ways det is zero is 10  it is not zero 6 ways

6 3
PE  
16 8
10 5
B) P  E   
16 8
1 
C) trace should be 2    remaining 2 place can be followed in 2X2 =4 ways
 1 
4 1
PE  
16 4
a b 
D) Let   be the symmetric matrix  bc
c d 
Each of a,b, and d can permuted in two ways
2.2.2 1
Therefore P  E   
16 2
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 Sri Chaitanya IIT Academy 08-06-2024_Sr.C-120_Jee-Adv(2022-P2)_WTA-33_Key & Sol’s
15. Train is to be stopped at 4 stations out of 17. Prob(At least two of the 4 stops are
adjacent)
=1- prob( no two of them are adjacent)
 n  r 1Cr 
 1  n  where n=17, r=4
 Cr 

 14C   14.13.12.11  143 197

 1   17 4   1     1 
 C4   17.16.15.14  340 340

No of fav cases 8 1
16. P  
Total No cases 24 2

17. If n things are arranged in a row at random , then the probability that K different things
1
occur in a specified order=
K

18. 0
( q  1)(q  4)  0

q  1, or q  4
The set of possible values of q are

S  10, 9, 8.......0,....8,9,10  n(S )  21

If E is an even the given equation has real roots then
E  10, 9,.......  1, 4,.......10  n( E )  17
17
P( E ) 
21

PHYSICS
f
m
19. f u
sin c  3 / 5 R  6 cm
20.
21. For v1  50 / 7 m, u1  25 m, v2  25 / 3 m, u2  50 m
25 18
Speed of object=   3km h 1
30 3
2 2 2  1
22.  
v u R

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 Sri Chaitanya IIT Academy 08-06-2024_Sr.C-120_Jee-Adv(2022-P2)_WTA-33_Key & Sol’s
7
7 1 1
 4
4v 24 6
7 3 1 2 1
   
4v 24 24 24 12
7 2
 V  21cm
4
21 7 / 4
  OS ''  16
OS '' 4 / 3
 BS ''  2 cm
23. The situation is shown in fig. The radius of curvature of the mirror is r  2 f  20cm . Thus,
the nearer and B of the rod AB is at the center of the curvature and hence, its image will
be formed at B itself. We shall now locate the image of A here u  30cm and f  10cm .
We have
1 1 1 1 1 1
  or  
u v f v f u
1 1
 
10cm 30cm
Or , v  15cm
Thus, the image of A is formed at 125 cm from the pole. The length of the image is,
therefore, 5.0 cm
1 1 1  2
24. p  2    1    
f  R1 R2  R2
p  5D
25. For a plane refracting surface, the lateral magnification is 1. Thus, the image of the coin
will be of the same size as the coin itself
26. When the object is placed at the centre of the glass sphere, the rays from the object fall
normally on the surface of the sphere and emerge undeviated.
27. The image formed will be complete because light rays from all parts of the object will
strike on the lower half. But since the upper half light rays are cut off, the intensity will
reduce.
28. Concave lens and convex mirror are diverging in nature. Therefore, the
refracted/reflected rays do not meet and are produced to make them meet. Therefore, the
image formed is virtual and effect
29. For total internal reflection to take place: angle of incidence i  critical angle,
 1
 c  where sin  c  
 n
1 1 1
Or sin 450  or  or  2 or n  1.414
n 2 n
Therefore, possible values of n can be 1.5 or 1.6 in the given options
30.

1 1
Using Snell’s law sin 1  sin 1
3 2
Net deviation is 900

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 Sri Chaitanya IIT Academy 08-06-2024_Sr.C-120_Jee-Adv(2022-P2)_WTA-33_Key & Sol’s
1.4 1 1.4  1
31.  
v  R
1.4 0.4 7R
 ;v 
v R 2
1.5 1.4 105  104
Film to glass :  
v' 7R R
2
1.5 0.4 0.1
 
v R R
1.5 0.5
 ; v '  3R  f1  3R
v' R
1.4 1.5 104  1.5
Glass to film: '  
v  R
1.4 0.1

v R
v  14 R
1 1.4 1  1.4
Film to air:  
v ' 14 R R
1 1 0.4
 
v ' 10 R  R
1 0.4 0.1 0.5
  
v' R R R
R
v'  2R  f2  2R
0.5
1 1 1
32.   (mirrorformula ) f  24cm
f v u
33. Since total deviation is to be zero, therefore
1   2  0   1  1 A1   2  1 A2  0

A2 
1.54  1 40  30
1.72  1
1 1 1
34. From mirror formula  
f v u
Differentiating equation(i), we obtain
2
1 1 v
O   2 dv  2 du  dv     du (ii)
v u u
v f
Also from equation  i   (iii)
u u f
2
 f 
From equation(ii) and (iii) we get dv     l
u f 
2
 f 
Therefore size of image is   l 35.
u f 
1 1 1 1 1 1 1 0.25  0.4 0.15 0.15
35. a.           1.5
f f1 f 2 0.4 0.25 0.4 0.25 0.4  0.25 0.4  0.25 0.4  0.25
1
 0.25  0.4  0.15  0.15  1.5  P   1.5 D
f

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 Sri Chaitanya IIT Academy 08-06-2024_Sr.C-120_Jee-Adv(2022-P2)_WTA-33_Key & Sol’s
0
sin 90 1
36. 1
2    for critical angle
sin C sin C
 1 
 C  sin 1   1  (i)
 2 
Applying snell’s law at P, we get
1 sin r ' sin  90  r 
2  
sin i sin r
 i  r ; r ' r  900 
cos r
 21   ii 
sin r
From (i) and (ii), C  sin 1  tan r 
CHEMISTRY
37. The actual composition is Al2O3 .2 H 2O
38. Ag 2 S  4 NaCN  Zn  Ag  Na2 [Zn(CN ) 4 ]  Na2 S Zn has 4 coordination number
39. Ni  CO 4
40. 1. Hydride shift 2. No rearrangement 3. Methyl shift 4. No rearrangement
5. Methyl shift 6. No rearrangement 7. Ring expansion 8. Ring expansion
9. Hydride shift 10. No rearrangement
Number of molecules that undergo rearrangement reaction during S N 1 are 6
O O OH
RMgX
Cl  C  O  C2 H 5  2RMgX  R  C  R 
H OH
R C  R

41. R 30 alcohol
42. 1,3,5,7,10,11 compounds undergo both S N 1 and S N 2
OCH 3
Cl Cl

43. No cine substitution in due to STERIC INHIBITED RESONANCE

44. The reaction can be as follows:
PbS + O2 → Pb + SO2
Moles of Pb = Moles of O2 = 1000 / 32 mol
∴ Mass of Pb = 1000 / 32 × 207 g = 207 / 32 kg = 6.47 kg
45. conceptual
46. conceptual
47. Active metals like Mg , Al, Na ….. etc are extracted by electrolytic process
48.

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 Sri Chaitanya IIT Academy 08-06-2024_Sr.C-120_Jee-Adv(2022-P2)_WTA-33_Key & Sol’s
O O

-
OH + 3I2 + 3 NaOH O Na+
Na+ O-

O O
+ 3 NaI + 3H2O
+ CHI3

O
O

+ 6 I2 + 6NaOH -
O Na+
+ -
Na O

O
O
sodium succinate

+ 6 NaI + 6 H2O

+ 2 CHI3

49.
O
Cl

Oxidation Cl
OH
Decarboxylation

Cl

Oxidation Cl
Decarboxylation
OH

Cl
Cl

O
Cl Cl
Cl Decarboxylation
Oxidation OH

50. Selectivity towards 30 carbon is in the order I 2  Br2  Cl2  % a  %b  %c

51. ZnS forms water soluble complex ZnS + 4 NaCN 4Na+ + [Zn(CN)4]2– + S–2
Water soluble
52. leaching is done in the case of aluminum, gold and silver.
53. For symmetrical molecule with even no. of chiral center total no. of stereoisomer
n
–1
= 2n–1 + 22 where n = no. of chiral center=4
54. Hydride shift is faster than deuterium shift

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