Narayana IIT Academy

CHEMISTRY
PRESENTWEEK (80%):
d-Block elements : General Characteristics,
electronic configuration, atomic & ionic size,
density, ionisation enthalpy, melting points,
enthalpy of atomization, Oxidation states,
Electrode potentials, Chemical reactivity and
E0 values, Nature of oxides

CHEMISTRY MAX.MARKS: 66
SECTION – 1 (Maximum Marks: 18)
This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONLY ONE of these four option is the correct answer.
For each question, choose the correct option corresponding to the correct answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If only the correct option is chosen.
Zero Marks: 0 If none of the option is chosen.(i.e the question is un answered)
Negative Marks: -1 In all other cases.

19. The loss of exchange energy is not observed in

A) Ti   3d 2 4s1 to 3d3  B) V   3d 3 4s1 to 3d 4 

C) Mn   3d5 4s1 to 3d 6  D) Fe   3d 6 4s1 to 3d 7 

20. Metallic radii of some transition elements are given below. Which of these elements will
have highest density?
Element Fe Co Ni Cu
Metallic 126 125 125 128
Radii / pm
A) Fe B) Fe & Co have same density
C) Co D) Cu

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21. Four successive members of the first row transition elements are listed below with their
atomic numbers. Which one of them is expected to have highest third ionization
enthalpy?
A) Vanadium (Z=23) B) Chromium (Z=24)
C) Manganese (Z=25) D) Iron (Z=26)
22. Which of the following is INCORRECT statement
A) In the elements of 3d series, the 3d electrons shield the 4s electrons from the
increasing nuclear charge somewhat less effectively than the outer shell electron can
shield the other
B) The orbitals with high ‘l’(azimuthal quantum number) values, such as d and f orbitals
are much less penetrating and are far poorer at shielding.
C) The oxidising power order is VO 2  Cr2 O72  MnO 4 / H  is due to the increasing stability
of lower species to which above species are going to be reduced.
D) Ti and V are passive to dilute non-oxidising acids at room temperature
23. Which amino acid stabilises the tertiary structure of protein through formation of di-
sulphide bond
A) Tyrosine B) Alanine C) Cysteine D) Valine
24. Three elements chromium, manganese and iron have heat of atomization’s 281kJ, 397kJ
and 416kJ per 1 mole of metal but not respectively. Arrange the values in the order for
chromium, manganese and iron in KJ/mol
A) 416, 397, 281 B) 397, 281, 416 C) 281, 397, 416 D) 416, 281, 397

SECTION - 2 (Maximum Marks : 24)

This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks: -2 In all other cases.

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Narayana IIT Academy
25. Correct statement(s) is / are

A) V2O5 reacts with alkali’s to give VO43 and VO2

B) V2O5 reacts with acids to give VO43 and VO2

C) Mn2O7 is a covalent green oil

D) V2O3 is more basic than V2O4

26. Which of the following is correct statement(s)

A) Lower oxidation states are favored by higher members of P- block due to inert pair

effect

B) In 3d transition series, lower oxidation states of FeII ,III , or Ni II or Co II , III are stable and

higher oxidation states of Cr VI and Mn VII are stable, due to maximum oxidation states of

reasonable stability correspond in value to the sum of the s and d electrons up to Mn

followed by rather abrupt decrease in stability of higher oxidation states of later

( Fe, Ni, Co ).

C) MoVI is more stable than CrVI and W VI is more stable then CrVI

D) Lower oxidation states are found in Ni  CO 4 and Fe  CO 5 due to  acceptor

character in addition to  bonding

27. Which of the following are the correct statement(s)

A) In the case of CoF3 , the ability of fluorine to stabilise the highest oxidation state is

due to higher lattice energy

B) In the case of CrF6 , the ability of fluorine to stabilise the higher oxidation state is due

to higher bond enthalpy

C) MnO3 F is known in which Mn exhibits +7 state

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Narayana IIT Academy
D) CuI 2 is not known because Cu 2  Oxidises I  to I 2

28. Identify the FALSE statement(s) among the following

A) Sucrose is also called invert sugar

B) The correct structure of   D      Fructofuranose is

O
HOCH 2 CH2 OH

H HO

H OH

OH H

C) The correct structure of   D      Glucopyranose is

HOCH2

O OH
H
H
OH H

HO H

H HO

D) During denaturation of protein the primary structure gets destroyed but the

secondary, tertiary structures remains intact.

29. Which of the following statements are correct

A) Glycogen structure is similar to amylopectin with highly branched

B) Sucrose is a non reducing sugar

C) The glycosidic linkage present in Lactose is in between C1 - of Glucose and C4 - of

Galactose

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Narayana IIT Academy
D) Amylopectin is water soluble and constitutes about 15- 20 % of starch

30. The E0 vale of Mn 3 / Mn 2  couple is much more positive than that of Cr3 / Cr 2 or

Fe3 / Fe 2 couple.

Mn 3 / Mn 2 E0 = 1.57 v ;

Cr 3 / Cr 2 E0 = -0.41v;

Fe3 / Fe2 E0 = 0.77v

This is because

A) The 3d5 configuration of Mn2+ is stable than 3d4 configuration of Mn3+

B) 3d3 configuration of Cr3+ is stable due to half- filled t2g3 configuration than 3d4

configuration of Cr2+ having t2g3 eg1 configuration

C) 3d5 configuration of Fe3+ is stable than 3d6 configuration of Fe2+

D) Sum of the three ionization energies (I1+I2+I3) for chromium is very high compared

than those of Mn and Fe

SECTION - 3 (Maximum Marks : 24)

This section contains SIX (06) questions. The answer to each question is a NUMERICAL VALUE
For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual
numeric keypad in the place designated to enter answer. If the numerical value has more than two decimal
places truncate/round- off the value to TWO decimal places.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.

31. A) Among the species VO43 , CrO42  , MnO43 , MnO42  , MnO4 , the number of tetrahedral species
are ‘x’
B) Among the following the number of 3d series metals with CCP structure are ‘y’ and
BCC structure are ‘z’.
V, Nb, Ta, Mo, W, Co, Rh, Ir, Ni, Pd, Pt, Cu, Ag, Au

Then
 y  z  value is ____
x

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Narayana IIT Academy
32. The ratio of oxidation state of Fe in Ferrites & ferrates is
33. How many of the following iodides exists
TiI3 , FeI3 , CrCl5 , CrBr5 , MnCl3 , MnBr3 , CoI3 , MnI3 , Ni 2O3 , Co2O3

34. How many of the following atom(s) have 18 e in their outer most orbit
Ne, Ar, Kr, Xe, Cu  , Ag  , Au  , Pd , Zn2 , Cd 2 , Hg 2
35. The number of elements with ns1 ground state configuration of 3d series, 4d series and
6d series are a, b & c, respectively, then b   a  c   value is ___

36. Number of moles of per-iodic acid required to oxidise one mole of Glucose is (x). and
No.of moles of Formic acid formed when one mole of Fructose gets oxides by enough
periodic acid is (y)
Find the value of  x  y 

CHEMISTRY
19 C 20 D 21 C 22 A 23 C
24 B 25 CD 26 ABCD 27 ABCD 28 ABCD
29 AB 30 ABC 31 1 32 0.5 33 1
34 1 35 2 36 2

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Narayana IIT Academy
1
  500 L  15
500C

Solving (i) and (ii) L = 10 mH, C = 100μF

18. Current leads voltage by phase angle

X 1
tan   c   3  
R CR 3
V0 V0 V0
 v  V0 sin t and i  i0 sin(t   3)[ wherei0   
R 2  X C2 R 2  3R 2 2R

Power supplied by the Source

p  vi  V0i0 sin t sin(t   3)

   
 V0 i0  cos .sin 2 t  sin .sin t.cos t 
 3 3 
Vi    
 0 0 cos 1  cos 2t   sin .sin 2t 
2  3 3 
V0 i0   

2  cos 3  cos t (2t  3 
 
V0i0    3 3V02 
pmax   cos  1   V i
0 0  
2  3  4 8R 
V0i0    V0i0 V02 
And Pmax   cos  1      
2  3  4 8R 

Power oscillates with frequency twice that of current and voltage.

CHEMISTRY

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Narayana IIT Academy
21. Mn2 has d 5 configuration

22. Refer NCERT Class XII

23. Refer NCERT text book class – XII ; page - 423
24. Refer NCERT text book
25. Refer NCERT XII Pg- 224
26. Refer NCERT XII Pg- 216
27. Refer NCERT XII Pg- 218 & 219
28. Refer NCERT text book class - XII
29. Refer NCERT text book class – XII
30. Refer NCERT Text Book Class-XII
31. x = 5, y = 3, z = 1
2
32. Fettates  FeO4   6
2
 Fe2O4  3

33. TiI3
34. Consider atoms not ions.
35. a = 2 , b = 6, c = 2
36. 1mole  5HIO4  5 HCOOH  1HCHO
Glu cos e x 5

1mole  5HSO4  2 HCHO  3HCOOH  CO2

Fructose Y 3

19. d 6 configuration

20. On moving left to right along period, metallic radius decreases while mass increases.
Decrease in metallic radius coupled with increase in atomic mass results in increase in
density of metal.
Hence, among the given four choices Cu belongs to right side of Periodic Table in
transition metal, and it has highest density (89 g/ cm 2 )
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Narayana IIT Academy

SUPERCHAINACAMPUS
SR(MODEL-A)_WAT-45_02.07.23_FINAL KEY
S.NO SUB Q.NO GIVEN KEY FINAL KEY REMARKS
5 CHEM 31 1 0.8 x=5, y+z=4
6 CHEM 34 1 1 or 7 wrong framing of question
7 CHEM 35 2 3 b=6, a=2, c=1, b-(a+c)=6-3=3

CHEMISTRY MAX.MARKS: 66
SECTION – 1 (Maximum Marks: 18)
This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONLY ONE of these four option is the correct answer.
For each question, choose the correct option corresponding to the correct answer.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If only the correct option is chosen.
Zero Marks: 0 If none of the option is chosen.(i.e the question is un answered)
Negative Marks: -1 In all other cases.

19. Ionization energies of Ni and Pt in kJ mol1 are given below

(IE)1 + (IE)2 (IE)3 + (IE)4
     

Ni 2.49 8.80
Pt 2.60 6.70
So, (Select the correct statement)
(A) nickel (II) compounds tend to be thermodynamically more stable than platinum (II)
(B) platinum (IV) compounds tend to be more stable than nickel (IV)
(C) (A) and (B) Both
(D) none is correct

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Narayana IIT Academy

20. Which of the following does not represent the correct order of the property indicated
against it?
(A) Ti < V < Cr < Mn increasing order of number of oxidation states
(B) Ti3  V3  Cr3  Mn3 increasing magnetic moment
(C) Ti < V < Cr < Mn increasing melting points
(D) Ti < V < Mn < Cr increasing second ionization enthalpy

21. NH3  CH(R)  CO2 H has its Ka1  107 . The isoelectric point of the  -amino acid occur at
pH  8.2 hence pKa 2 of the conjugate acid of  -amino acid is equal to
(A) 9.4 (B) 1.2 (C) 7.6 (D) 2.4
22. Four statements for Cr and Mn are given below
(P) Cr 2 and Mn3 have the same electronic configuration
(Q) Cr 2 is a reducing agent while Mn3 is an oxidizing agent
(R) Cr 2 is an oxidizing agent while Mn3 is a reducing agent
(S) Both Cr and Mn are oxidizing agent
The correct statements are:
(A) P, R, S (B) P, Q (C) P, Q, S (D) P, S
23. The highest oxidation state is exhibited by the transition metals with configuation:
(A) (n  1)d3ns 2 (B) (n  1)d 5ns1 (C) (n  1)d5ns 2 (D) (n  1)d8ns 2
24. The order of stability of +6 oxidation state for group VI follows the order
(A) Cr > Mo > W (B) Cr < Mo < W (C) Mo > Cr > W (D) W < Cr > Mo

SECTION - 2 (Maximum Marks : 24)

This section contains SIX (06) questions.
Each question has FOUR options for correct answer(s). ONE OR MORE THAN ONE of these four option(s) is
(are) correct option(s).
For each question, choose the correct option(s) to answer the question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +4 If only (all) the correct option(s) is (are) chosen.
Partial Marks: +3 If all the four options are correct but ONLY three options are chosen.
Partial Marks: +2 If three or more options are correct but ONLY two options are chosen, both of which are
correct options.
Partial Marks : +1 If two or more options are correct but ONLY one option is chosen and it is a correct
option.
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered).
Negative Marks: -2 In all other cases.

25. Identify the correct statement(s)?

(A) Co > Mn > Fe > Cr: decreasing M3 / M 2 value

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Narayana IIT Academy
(B) Cr 2 is oxidizing and Mn3 is reducing even though both have d 4 configuration
(C) VO 2  Cr2O 72   MnO 4 : oxidizing property
(D) Cr2O3 , V2O5 , Mn 2O 7 and ZnO are all amphotric oxides
26. Which is not correct about monosaccharides?
(A) Optically active polyhydroxy carbonyl compounds
(B) Fructose and glucose cannot be distinguish by Br2 / H 2O .
(C) Glucose and mannose are anomers
(D) Fructose and glucose can be distinguish by Fehling solution
27. A comparative study of E 0 (M 3 | M 2 ) values show varying trends. Choose the correct
trends (along with possible reason) among the following.
(A) Low value for Sc reflects the stability of Sc3 which has a noble gas configuration
(B) Zn has the highest value due to stability of d10 configuration
(C) Comparatively high value for Mn and low value for Fe shows extra stability of
Mn 2 (d 5 ) and Fe3 (d 5 ) .

(D) Comparatively low value for V is related to the stability of half-filled t 2g in V2

28. Choose the correct statement(s)

(A) Successive enthalpies of transition elements do not increase as steeply as in the main
group elements.
(B) The magnitude of the increase in the second and third ionization enthalpies for the
successive elements of transition series, in general, is much higher
(C) The lowest common oxidation state of transition metals is +2
(D) The second ionization enthalpy of Cr and Cu are usually high
29. An element of 3d-transition series shows two oxidation states ‘x’ and ‘y’, differing by
two units. Then
(A) compounds in oxidation state ‘x’ are ionic if x > y
(B) compounds in oxidation state ‘x’ are ionic if x < y
(C) compounds in oxidation state ‘y’ are covalent if x < y
(D) compounds in oxidation state ‘y’ are covalent if y < x
30. Amphoteric oxide(s) of Mn is/are
(A) MnO2 (B) Mn 3O 4 (C) Mn 2O7 (D) MnO
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Narayana IIT Academy

SECTION - 3 (Maximum Marks : 24)

This section contains SIX (06) questions. The answer to each question is a NUMERICAL VALUE
For each question, enter the correct numerical value of the answer using the mouse and the on-screen virtual
numeric keypad in the place designated to enter answer. If the numerical value has more than two decimal
places truncate/round- off the value to TWO decimal places.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks: +4 If ONLY the correct numerical value is entered as answer.
Zero Marks: 0 In all other cases.

31. A decapeptide (relative molar mass 796) on complete hydrolysis gives glycine (relative
molar mass 75), alanine and phenylalanine. Glycine constitutes 47.0% of the total mass
of the hydrolysed products. The number of glycine units present in the decapeptide is
_______
32. How many reducing saccharides are there in following list?
(i) -D- methylglycopyranose (ii) -D- glycopyrancose
(iii) Cellulose (iv) Maltose (v) Sucrose (vi) D-fructose
(vii) Starch (viii) -D- fructofuranose
33. Identify the number of amphoteric species amongst the following:
Mn 2O7 , CrO3 , V2 O5 , V2 O4 , V2 O3 , CrO, Fe 2O3

34. Find the number of mixed oxides among the following:

Mn 3O 4 , Fe3O 4 , Co3O 4 , Mn 2O3 , MnO2 , Fe 2O3 , NiO, CrO2 , CrO3

35. The number of halides that do not exist among the following:
CuF2 , CuCl 2 , CuBr2 , CuI2 , CuCl, CuBr, Cu 2 I 2 , CuF

36. Select the number of correct matches for the outermost electronic configuration for d-
block elements
Nb-5s1 4d 4 (group-5) W-6s 2 5d 4 (group-6)

Tc-5s1 4d 6 (group-7) Ru-5s1 4d 7 (group-8)

Rh-5s1 4d 8 (group-9) Pd-5s0 4d10 (group-10)

Pt-6s15d9 (group-10) V-4s2 3d3 (group-5)

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Narayana IIT Academy

CHEMISTRY
19 C 20 C 21 A 22 B 23 C

24 B 25 AC 26 BCD 27 ABCD 28 ABCD

29 BC 30 AB 31 6 32 4 33 1
34 3 35 2 36 8

18.
emax  NBA  0.6V
19. Conceptual
20. Mn has low melting point
21. pKa1  7 , pKa 2  ? , P.I = 8.2
7  pKa 2
8.2 =
2
22. Cr and Mn 2 are more stable
3

23. (n  1)d5 ns 2 can exhibit +7 oxidation state

24. Down the gp in d-block elements stabilities of higher oxidation state increases.
25. Conceptual
26. Conceptual
27. Conceptual
28. Conceptual
29. Conceptual
30. Conceptual

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Narayana IIT Academy

31. (6)
Decapeptide(Mol.wt.796)

9H 2 O

Glycine + Alanine + phenylalanine


Wt = 796+9 18 = 958
47
Wt. of glycine =  958
100
958
No. of glycine unity = .
75
32. (4)
(ii), (iv), (vi), (viii)
33. (1)
V2 O5
34. (3)
Mn 3O 4 , Fe3O 4 , Co3O 4
35. (2)
CuI2 , CuF
36. (8)
All

37. (A)

2
x  x  x  x   0,1
2

1 1 1
  

1 x 2
1 x2
1 x
1 1 1 1
  ln(1  x)  0   
dx   tan 1 x 
0 0
2
1 x

 log e 2  I 
4
38. (D)
 
Since 0 < sin x < 1 and 1 + x > 1 in  0, 
 2
Hence, I3  I2  I1
 I and II are correct  (D).
39. (C)
19
19 sin x 19 | sin x | 19 dx 19 dx  x 7 

10 1  x8 10 1  x8 dx   
10 1  x8 10 x 8  7 
10

1
  197  107 
7
1
 10 7  197   107
7
40. (C)

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Narayana IIT Academy 03-04-22_JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_WAT-46_Q’P
CHEMISTRY Max Marks: 62
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 5 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and –1 in all other cases.
19. The element having maximum 1st IP value in 3d series is

A) Zn B) Cr C) Cu D) V

20. Variable valency of transition element is on account of

A) incomplete p-orbitals B) incomplete d-orbitals

C) completely filled d-orbitals D) incomplete p-orbitals

21. Metallic radii of some transition elements are given below. Which of these elements
will have highest density?

Element: Fe Co Ni Cu

Metallic radii/pm 126 125 125 128

A) Fe B) Ni C) Co D) Cu

22. Which of the following element has lowest atomization energy?

A) V B) Fe C) Mn D) Zn

23. Which of the following is the correct order of second ionization energy?

A) V > Cr > Mn B) V < Cr < Mn C) V < Cr > Mn D) V > Cr < Mn

SECTION – II
(MULTIPLE CORRECT ANSWER TYPE)
This section contains 8 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for all correct options & +1 partial marks, 0 if not attempted and -2 in all wrong
cases
24. The typical acidic oxides are

A) MnO B) Mn2O7 C) CrO D) CrO3

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Narayana IIT Academy 03-04-22_JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_WAT-46_Q’P
25. Which of the following is/are correct statement(s)?
A) MoO3 and WO3 are not stronger oxidizing agents where as Cr2 O72 is strong
oxidizing agent.
B) The ionization enthalpy order of Cu, Ag and Au is Au > Cu > Ag.
C) The high melting points of transition metals are attributed to the involvement of
greater number of electrons from (n–1)d in addition to the ns electrons.
D) Second and third row transition elements have greater enthalpy of atomization than
the corresponding elements of first transition series.
26. Which are the best suitable as coinage metals?

A) Mg B) Cu C) Ag D) Au

27. Which one of the following reactions cannot occur?

A) Cu  ZnSO 4  CuSO 4  Zn  B) Cu  2AgNO3  Cu  NO3 2  2Ag 

C) Cu  FeSO 4  CuSO 4  Fe  D) 3Ag  AuCl3  3AgCl  Au 

28. How many of the following are correct?

A) HF  HI  HBr  HCl  Boiling point 

B) HF  HI  HBr  HCl  Melting point 

C) KHF2  KHCl2  Stability 

D) F2 is more reactive than inter halogen compounds.

29. How many of the following have low bond dissociation energy than H2?

A) F2 B) Cl2 C) Br2 D) I2

30. Which of the following transitional elements show +1 oxidation state?

A) Sc B) Cu C) Cr D) Zn

31. Which of the following characters are attributed to noble character of the metal?

A) High IP. B) Low hydration energy.

C) High hydration. D) High sublimation energy.

Jr.IIT_*CO SC Page No: 12

Narayana IIT Academy 03-04-22_JR.IIT_*CO-SC(MODEL-A)_JEE-ADV_WAT-46_Q’P
SECTION – III
(INTEGER ANSWER TYPE)
This section contains 5 questions. The answer is a single digit integer ranging from 0 to 9 (both inclusive).
Marking scheme +3 for correct answer, 0 if not attempted and 0 in all other cases.
32. How many of the following show variable oxidation states in their compounds?

Cr, Cu, Zn, Fe, Cd, Ti

33. How many of the following are correct about difference between the first row and
other two rows of transition elements?

(i) M-M bonding is quite rare in the first row transition elements. In the second and
third two elements M-M bonds are much more common.

(ii) The (+II) and (+III) states are important for all the first row elements. The higher
oxidation states of the second and third row elements are more important and much
more stable

(iii) Coordination numbers 7 and 8 are uncommon for the first row but are common in
the early members of the second and third rows.

(iv) Zn is having lowest atomization energy in 3d series of elements.

34. How many of the following cannot displace H2 from dil. HCl?

Cu, Zn, Ni, Fe, Ag, Au, Pt, Hg, Cd.

35. How many of the following have greater negative value of standard reduction
potential than Cr 2 /Cr ?

1) Ti 2 /T1 2) Fe2 /Fe 3) V 2 /V 4) Mn 2 /Mn

5) Zn 2 /Zn

36. Number of 90° bond angles in I2Cl6?

Jr.IIT_*CO SC Page No: 13

Sec: JR.IIT_*CO SC(MODEL-A) WAT-46 Date: 03.04.22
Time: 3HRS 2016_P1 Max. Marks: 186
KEY SHEET

CHEMISTRY
19 A 20 B 21 D 22 D 23 C

24 BD 25 ABCD 26 BCD 27 AC 28 ACD

29 ABCD 30 BC 31 ABCD 32 4 33 4

34 5 35 3 36 0

CHEMISTRY
19. Ionization energy increases from left to right
20. Conceptual
21. On moving left to right along period, metallic radius decreases while mass increases. Decrease in
metallic radius coupled with increase in atomic mass results in increase in density of metal. Hence,
among the given four choices Cu belongs to right side of Periodic Table in transition metal and it has
highest density (89 g/cm3)
22. Conceptual
23. Conceptual
24. Highest oxidation state. Oxides are acidic.
25. Conceptual
26. Conceptual
Cu cannot displace as it has higher E SRP  ve  value.
0
27.
28. Conceptual
29. Conceptual
30. Conceptual
31. Conceptual
32. Conceptual
33. Conceptual
34. Conceptual
35. Conceptual
36. Conceptual
Narayana IIT Academy 03-04-22_JR.IIT_*CO-SC(MODEL-B)_JEE-ADV_WAT-46_Q’P
CHEMISTRY Max Marks: 62
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 5 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONLY ONE option can be correct.
Marking scheme: +3 for correct answer, 0 if not attempted and –1 in all other cases.
19. The basic character of the transition metal monoxides follows the order

A) CrO  VO  FeO  TiO B) TiO  FeO  VO  CrO

C) TiO  VO  CrO  FeO D) VO  CrO  TiO  FeO

20. Among the following outermost configurations of transition metals, which one shows
the probable configuration of the element of highest oxidation state?

A)  n  1 d 5 ns 2 B)  n  1 d 5 ns1 C)  n  1 d 6 ns 2 D)  n  1 d 8 ns 2

21. The melting point of zinc in lower as compared to those of the other elements of 3d-

series because:

A)size of zinc atom is smaller

B)the d-orbitals are partially filled

C)it is the last member of 3d-series

D) d-electrons do not participate in metallic bonding

22. The correct order of decreasing second ionisation enthalpy of Ti,V , Cr and Mn is:

A) Mn  Cr  Ti  V B) Ti  V  Cr  Mn

C) Cr  Mn  V  Ti D) V  Mn  Cr  Ti

23. Which of the following ions has smallest radius?

A) Mn2 B) Ni 2 C) Ti 2 D) V 2

Jr.IIT_*CO SC Page No: 9

Narayana IIT Academy 03-04-22_JR.IIT_*CO-SC(MODEL-B)_JEE-ADV_WAT-46_Q’P
SECTION – II
(MULTIPLE CORRECT ANSWER TYPE)
This section contains 8 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for all correct options & +1 partial marks, 0 if not attempted and -2 in all wrong
cases
24. Which of the following arrangements represent the correct order of the property stated
against it?

A) Sc  Ti  Cr  Mn : number of oxidation states

B) V 2  Cr 2  Mn2  Fe2 : number of unpaired electrons

C) Ni 2  Co2  Fe2  Mn2 : ionic size

D) Co3  Fe3  Cr 3  Sc3 : stability in aqueous solution

25. Which of the following statements is / are correct?

A) Transition metals exhibit the higher enthalpies of atomization

B) Ni (II) compounds are more stable than Pt(II) whereas Pt (IV) compounds are more
stable than Ni (IV)

C) The element which gives the higher number of oxidation states does not occur in
the near the middle of the series

D) IE2 of V  Cr  Mn

26. The correct statement regarding transition metals among the following is:

A) 4s-electrons penetrate towards the nucleus more than 3d-electrons

B) Atomic radii of transition metals increase rapidly with increase in atomic number
because of poor shielding of nuclear charge by (n – 1)d electrons

C) Second and third transition series elements have nearly same size in vertical
groups.

D) Their densities are high and densities of the 5d-series elements are higher than
those 4d series elements

Jr.IIT_*CO SC Page No: 10

Narayana IIT Academy 03-04-22_JR.IIT_*CO-SC(MODEL-B)_JEE-ADV_WAT-46_Q’P
27. The incorrect order of increasing oxidising power in the following series is:

A) VO2  Cr2O72  MnO4 B) Cr2O72  VO2  MnO4

C) Cr2O72  MnO4  VO2 D) MnO4  Cr2O72  VO2

28. Which of the following is/are amphoteric oxide/oxides?

A) Mn2O7 B) CrO C) V2O4 D) Cr2O3

29. The property of halogen acids, that indicated correct is:

A) HCl  HBr  HI  HF : volatility

B) HI  HBr  HCl  HF : reducing strength

C) HI  HBr  HCl  HF : bond length

D) HF  HCl  HBr  HI : thermal stability

30. Which one of them is expected to have the highest EMo 3

M 2
value?

A) Co B) Cr C) Mn D) Fe

31. Which of the following represents the correct sequence of property indicated?

A) Sc3  Cr 3  Fe3  Mn3 : Stability of +3 ions

B) Sc  Ti  Cr  Mn : Number of oxidation states

C) Mn2  Ni 2  Co2  Fe2 : Number of valency electcrons

D) FeO  CoO  NiO  CuO : Basic nature

SECTION – III
(INTEGER ANSWER TYPE)
This section contains 5 questions. The answer is a single digit integer ranging from 0 to 9 (both inclusive).
Marking scheme +3 for correct answer, 0 if not attempted and 0 in all other cases.
32. Sum of atomic numbers of the metal ions present in insulin, haemoglobin and vitamin
B12 is xy , then the value of  x  y  is __

Jr.IIT_*CO SC Page No: 11

Narayana IIT Academy 03-04-22_JR.IIT_*CO-SC(MODEL-B)_JEE-ADV_WAT-46_Q’P
33. Reaction of Br2 with Na2CO3 aqueous solution gives sodium bromide and sodium
bromate with evolution of CO2 gas. The number of sodium bromate molecules
involved in the balance equation is___

34. How many of the following arrangements are correct against to the property indicated

A) Cl2  Br2  I 2  F2 : Bond dissociation energy

B) F2  Cl2  Br2  I 2 : Electronegativity

C) F2  Cl2  Br2  I 2 : Oxidising nature

D) Cl  F  Br  I : Electron gain enthalpy

E) F2  Cl2  Br2  I 2 : Boiling point

F) F  Cl  I  Br : Ionisaton enthalphy

G) I 2  Br2  Cl2  F2 : Density

35. 10g of bleaching powder  CaOCl2  H 2O  on reaction with KI required 50 ml of 2N hypo

X
solution thus the percentage of bleaching powder is X, then the value of is___
8
(Nearest Integer)

36. 3.55g of bleaching powder  CaOCl2  H 2O  when treated with acetic acid and excess KI
liberated iodine which required 60ml of 0.5Nsodium thiosulphate solution. The
X
percentage of available chlorine is X, then the value of is__
5

19 C 20 C 21 D 22 C 23 B

24 ACD 25 ABD 26 ACD 27 BCD 28 CD

29 ABCD 30 A 31 ABD 32 5 33 1

34 4 35 9 36 6

Jr.IIT_*CO SC Page No: 12

Narayana IIT Academy 03-04-22_JR.IIT_*COSC(MODEL-B) _WAT-46_Key&Sol’s

CHEMISTRY
19. Basic nature of oxides of the elements decreases in a period.
20. Highest oxidation state shown by transition elements is +8
21. Filled d-orbital electrons not involved in metallic bonding
22. I.E increases in a period
23. Ionic size decreases in a period
24. Small ion is more stabilised in its aqueous solution due to its high hydration energy
25. Conceptual
26. Conceptual
27. As oxidation number increases, oxidising power increases
28. V2O4 and Cr2O3 are amphoteric
29. Conceptual
30. Conceptual
31. Conceptual
32. Insulin contains Zn , Haemoglobin contains Fe and Vitamin B12 contains Co
33. 3 Na2CO3  3Br2   5 NaBr  NaBrO3  3CO2
34. B, C, D, G are correct
35. geq of Bleaching powder = geq of Hypo
50  2
=  0.1 geq
1000
0.1 145
 weight of Bleaching powder =  7.25
2
7.25  100
% of Bleaching powder =  72.5
10
X 72.5
Now  9
8 8
3.55  mcq of hypo 3.55  60  0.5 X
36. %Cl2    30% , hence 6
mcq of Cl2 3.55 5

JR.IIT_*CO SC Page No: 5

Narayana IIT Academy 04-07-21_INC.SR.IIT_*CO-SC(MODEL-A&B)_JEE-ADV_WAT-49_Q’P
CHEMISTRY Max Marks: 88
SECTION – I
(SINGLE INTEGER ANSWER TYPE)
This section contains 8 questions. The answer is a single digit integer ranging from 0 to 9 (both inclusive).
Marking scheme +4 for correct answer, 0 if not attempted and 0 in all other cases.
21.

What is the net charge of the above given compound at pH = 8?

22. Number of outer most ‘d’ electrons in Rhodium.

23. The sum of ns and (n–1)d electrons in Tc are___

24. How many of the following cannot displace H2 from dil.HCl?

Cu, Zn, Ni, Fe, Ag, Au, Pt, Hg, Cd

25. How many of the following reactions cannot occur?

(1) Fe  2HCl 
 FeCl2  H 2 

(2) Cu  2HCl 
 CuCl2  H 2 

(3) Cu  ZnSO 4 
 CuSO 4  Zn 

 Zn  NO3 2  2Ag 
(4) Zn  2AgNO3 

 Cu  NO3 2  2Ag 
(5) Cu  2AgNO3 

(6) Fe  CuSO 4 
 FeSO 4  Cu 

Jr.IIT_*CO SC Page 12
Narayana IIT Academy 04-07-21_INC.SR.IIT_*CO-SC(MODEL-A&B)_JEE-ADV_WAT-49_Q’P
26. In how many of the following, the second element has a higher density than the first
one?
(1) Ag, Au (2) Hf, Zr (3) Zn, Hg
(4) Na, Cu (5) Ca, Co (6) Ta, Na
27. The magnetic moment of an ion in its +3 oxidation state is 3.85 BM. The number of
unpaired electrons present in the ion is

28. A compound of vanadium has a magnetic moment    of 1.73BM. If the vanadium

ion in the compound is present as V x  then the value of x is?

SECTION – II
(ONE OR MORE CORRECT ANSWER TYPE)
This section contains 10 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its
answer, out of which ONE OR MORE than ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -2 in all other cases.
29. Correct statements about the trend in oxidation states of d-block elements is/are.

A) There exists a general trend of lesser number of oxidation states at each end of the
series and a higher number in the middle.

B) There is reduced tendency of higher oxidation states towards the end of the series.

C) The stability of the higher oxidation states decreases going down the group.

D) The highest oxidation states are often stabilized in the oxides and fluoride
compounds.

30. Reduction potential values for the couples

Cr 3 /Cr 2 and Mn 3 /Mn 2 are  0.41 and +1.51 volts respectively. Considering these
values select the INCORRECT options from the following statements.
A) Cr 2 acts as a reducing agent and Mn 3 acts as an oxidizing agent in their aqueous
solutions.
B) Cr 2  aq. is more stable than Cr 3  aq.

C) Mn 3  aq. is more stable than Mn 2  aq.

D) Cr 2 and Cr 3 are equally stable

Jr.IIT_*CO SC Page 13
Narayana IIT Academy 04-07-21_INC.SR.IIT_*CO-SC(MODEL-A&B)_JEE-ADV_WAT-49_Q’P
31. Aq. copper(I) cation undergoes disproportion as
2Cu   aq  
 Cu 2  aq   Cu, because

A) Cu  has d10 configuration

B) Cu 2 has d10 configuration

C) hydration energy of Cu 2 is higher than that of Cu  which components second

ionization energy of Cu.
D) size of Cu   Cu 2
32. Transition elements from binary compounds with halogens. Which of the following
elements will form MF3 type compounds?

A) Cr B) Co C) Cu D) Ni

33. Identify the correct statement(s)?

A) Co  Mn  Fe  Cr : decreasing M 3 /M 2 values

B) Cr 2 is oxidising and Mn 3 is reducing even both have d4 configuration.

C) VO 2  Cr2 O72  MnO 4 : oxidizing property
D) Cr2O3, V2O5, Mn2O7 and ZnO are all amphoteric oxides.
34. Which are the true statements regarding ionization energy of d-series elements?
A) Ionization energy of Mn is greater than Cr
B) Ionization energy of Pd > Rh and Pd > Ag
C) Ionization energy decreases from 3d to 4d transition series but it increases from 4d
to 5d series
D) Ionization energy of Mo is greater than W
35. Transition elements act as good catalysts because
A) Presence of partially filled ‘d’ orbitals.
B) Form hydrogen bonding easily.
C) Transition elements show variable oxidation state.
D) Easy inter convertibility of oxidation states due to low oxidation and reduction
potential.

Jr.IIT_*CO SC Page 14
Narayana IIT Academy 04-07-21_INC.SR.IIT_*CO-SC(MODEL-A&B)_JEE-ADV_WAT-49_Q’P
36. The aqueous solution of transition metal salt changes colour from pink to blue, when
concentrated HCl is added to it. The change in colour is due to

A) evolution of hydrogen that changes the oxidation state of the metal ion.

B) change in the coordination number of the metal ion from 6 to 4 and formation of
new species in solution.

C) inability of formation of a coordination complex of the metal ion with HCl acid.

D) protonation of the metal ion.

37. Which of the following are correct about difference between the first row and other
two rows of transition elements?

A) M-M bonding is quite rare in the first row transition elements. In the second and
third two elements M-M bonds are much more common.

B) The (+II) and (+III) states are important for all the first row elements. The higher
oxidation states of the second and third row elements are more important and much
more stable.

C) Coordination numbers 7 and 8 are uncommon for the first row but are common in
the early members of the second and third rows.

D) Second and third row transitions elements form complexes with high coordination
number.

38. The transition metals exhibit higher enthalpies of atomization due to

A) their ability to show variable oxidation states.

B) the presence of incompletely filled d-subshell.

C) their ability to exist in the solid state with unpaired electrons.

D) strong interatomic interactions arise because of having large number of unpaired

electrons in their atoms.

Jr.IIT_*CO SC Page 15
Narayana IIT Academy 04-07-21_INC.SR.IIT_*CO-SC(MODEL-A&B)_JEE-ADV_WAT-49_Q’P
SECTION - III
(MATRIX MATCHINGANSWER TYPE)
This section contains 2 questions. Each question has four statements (A, B, C and D) given in Column I and four
statements (P, Q, Rand S) in Column II. Any given statement in Column I can have correct matching with ONE
or MORE statement(s) given in Column II. For example, if for a given question, statement B matches with the
statements given in Q and R, then for the particular question darken the bubbles corresponding to Q and R in
the OMR sheet. For each correct matching will be awarded +2 marks ONLY and 0 if not attempted and
-1 in all other cases.
39. Match the following.
Column - I Column - II
(Pair of Compounds) (Stereo-chemical relationship)
(A) D-Erythrose and L-threose (P) Enantiomers

(B) D-Glucose and D-Mannose (Q) Diastereomers

(C)  -D-Glucose and  -D-glucose (R) Epimers

(D)  -D-Glucose and  -L-glucose (S) Anomers

40. Match the following.

Column-I Column-II

(A) Maltose (P) Does not react with Fehiling’s solution

(B) Lactose (Q) Contains a  -glycosidic linkage

(C) Sucrose (R) Contains an  -glycosidic linkage

(D) Cellobiose (S) Undergoes mutarotaion

21 0 22 8 23 7 24 5 25 2
26 4 27 3 28 4 29 ABD 30 BCD
31 C 32 AB 33 AC 34 ABC 35 ACD
A-QR, A-RS,
B-QR, B-QS,
36 B 37 ABCD 38 D 39 40
C-QS, C-PQR,
D-P D-QS

Jr.IIT_*CO SC Page 16
Narayana IIT Academy 04-07-21_INC.SR.IIT_*CO-SC(MODEL-A&B)_JEE-ADV_WAT-49_KEY&SOL
CHEMISTRY
21. Conceptual
22. Conceptual
23. Conceptual
24. Conceptual

25. Conceptual
26. Third row transition elements having higher density than second row elements.
d-block elements have higher density than group IA and IIA elements. Note that atomic size
decreases or remains almost same and atomic weight increases and so show higher density.
27. Conceptual
28. Conceptual
29. Conceptual
30. Conceptual
31. Conceptual
32. Conceptual
33. Conceptual
34. Conceptual
35. Conceptual
36. Conceptual
37. Conceptual
38. Conceptual

JR.IIT_*CO SC Page 3
Narayana IIT Academy 07-06-20_Incoming.Sr.IIT_CO SC_JEE-Adv_WAT-47_Q’P
CHEMISTRY Max Marks : 60
SECTION-I
(One or More options Correct Type)
This section contains 10 multiple choice equations. Each question has four choices (A) (B)(C) and (D) out of
which ONE or MORE are correct
21. In which compound does vanadium have on oxidation number of +4?

A) NH 4VO2 B) K 4 V  CN 6  C) VSO4 D) VOSO4

22. Which is/are correct

A) Cr(VI) is more stable then Mo((VI) and W(VI)

B) Sc does not exhibit variable oxidation states.

C) The transition metal ions containing empty d-orbital’s e.g Sc 3 and Ti 4 ions  or

completely filled d-orbital’s e.g Cu  , Ag  , Zn 2 , Cd 2 , Hg 2 etc  in dry state are colourless

0
D) ECu 2
/ Cu
is +ve among EM0 2
/M
of 3d series elements as energy required to transform

Cu  s   cu 2  g  is not balanced by hydration enthalply.

23. Which of the following are paramagnetic?

A) Cu 2 B) Fe2 C) Fe3 D) Cr 3

24. The correct statements about some of the ions of 3d-series in aqueous solution

A) Cr 2 is better reducing agent than Fe2

B) Co3 is better oxidizing agent than Fe3

C) When Fe3 is used as oxidizing agent, it attains 3d 6 electronic configuration

D) Cu is the only metal in 3d series, which is not having ability to displace hydrogen

as H 2 from acid

25. Transition elements show magnetic moment due to spin and orbital motion of
electrons. Which of the following metallic ions have almost same spin only magnetic
moment?
A) Co2 B) Cr 2 C) Mn2 D) Cr 3
Narayana IIT Academy 07-06-20_Incoming.Sr.IIT_CO SC_JEE-Adv_WAT-47_Q’P
26. In the form of dichromate, Cr(VI) is a strong oxidizing agent in acidic medium but
Mo(VI) in MoO3 and W (VI) in WO3 are not because
A) Cr (VI) is more stable than Mo VI  and W VI  .

B) Mo(VI) and W(VI) are more stable than Cr(VI).

C) Higher oxidation states of heavier members of group-6 of transition series are more
stable.
D) Lower oxidation states of heavier members of group-6 of transition series are more
stable.
27. Transition elements form binary compounds with halogens. Which of the following
elements will forms MF3 type compounds?

A) Cr B) Co C) Cu D) Ni

28. Which of the following will not act as oxidizing agents?

A) CrO3 B) MoO3 C) WO3 D) CrO42

29. Which of the following is/are true?

A) All halogens exist as diatomic gaseous molecules at ordinary temperature

B) Bromine dissolves in chloroform imparting blue colour

C) Chlorine monoxide is evolved when KClO3 is treated with conc. H 2 SO4

D) Chloride ion is confirmed by chromyl chloride test

30. The state of hybridization in the anionic part of solid Cl2O6 is

A) sp 3d 2 B) sp 3d C) sp3 D) sp 2

SECTION-II
(Integer Value Correct Type)
This section contains 10 questions. The answer to each question is a single digit integer, ranging from 0 to 9
(both inclusive).
31. An ion ' M n  ' , (at no:26) has paramagnetic moment of 4.8 BM. Then the value of ‘n’ is

32. How many of the following are pseudohalogens?

Azidocarbondisulphide, Isocyanide ion, Fulminate ion, Tellurocyanante ion,

Oxycyanogen, Selenocyanogen.
Narayana IIT Academy 07-06-20_Incoming.Sr.IIT_CO SC_JEE-Adv_WAT-47_Q’P
33. What is the oxidation number of Cl2 in final product formed due to oxidation in it
when Cl2 reacts with hot and concentratedNaOH?

34. Select the number of correct matches for the outermost electronic configuration for d-
block elements.

Nb  5s1 4d 4 (group-5) W  6s 2 5d 4 (group-6)

V  4s 2 3d 3 (group-5) Ru  5s1 4d 7 (group-8)

Rh  5s1 4d 8 (group-9) Pd  5s 0 4d 10 (group-10)

Pt  6s1 5d 9 (group-10)

35. Given the species: Mn3 , Co3 , Ti 2 ,V 2 , Cr 2 , Fe 2

(a) Number of species which are strong oxidizing agent =X

(b) Number of species which are strong reducing agents and will liberate hydrogen
from dilute acid=Y

Hence, find the value of 3X-Y.

36. Find the number of colourless species among the following:

Sc 3 , Ti 4 ,V 3 , Zn 2 , Mn 2 , Fe3 , Ni 2 , Cu 2 , Cr 3

37. The number of species which are paramagnetic

Ti 3 ,V 3 , Cu  , Sc 3 , Mn 2 , Fe3 , Co 2

38. Number of ions which gives blue colour in aqueous state:

V 4 , Ni 2 , Ti 3 , Co 2 , Fe 3 , Cu 2

39. Find the number of species from the following which has magnetic moment value of
1.73 B.M. Fe2 , Cu 2 , Ni 2 , Sc 2 .

40. How many unpaired electrons are present in Cu  ?

 Sec:Incoming.Sr.IIT _COSC WAT-47 Date: 07-06-20
Time: 3HRS 2014-P1 Max.Marks: 180
KEY SHEET

CHEMISTRY
21 D 22 BCD 23 ABCD 24 ABCD 25 AD

26 BC 27 AB 28 BC 29 D 30 C

31 2 32 3 33 5 34 7 35 2

36 3 37 5 38 2 39 2 40 0

CHEMISTRY
2 2
21. VOSO4  VO  SO 4

So oxidation state of V is +4.

24. 0
ECr 3
/Cr 2
 EFe
0
3
/ Fe2
 ECo
0
3
/Co 2

29. The first statement is false because F2 and Cl2 gases, Br2 is liquid while I 2 is a solid.
Bromine dissolves in chloroform imparting reddish-brown colour. Chlorine dioxide is
evolved when KClO3 is treated with conc. H 2 SO4
30. Fact
32. Azidocarbondisulphide  SCSN3 2 , Oxyeyanogen  OCN 2 and Selenocyanogen  SeCN 2
33. 3Cl2  6NaOH ho
t  5NaCl  NaClO3  3H 2O

35. X  2 : Mn3 ,Co3 37. Ti 3 ,V 3 , Mn 2 , Fe3 ,Co 2

Y  4;Ti 2 ,V 2 ,Cr 2 , Fe 2 38. V 4 ,Cu 2

36. Sc 3 ,Ti 4  d 0  , Zn 2  d 10  . 39. Cu 2 , Fe 2

JR’S(MODEL-A)_WAT-46_03.04.22_FINAL KEY
SNO SUB Q.NO GIVEN.KEY FINALKEY REMARKS
2 CHEM 31 ABCD ABD KEY CHANGE
3 CHEM 33 4 DELETE Option 3 out of syllabus