SRI CHAITANYA EDUCATIONAL INSTITUTIONS,

INSTITUTIONS,INDIA.
INDIA.
A.P,TELANGANA,KARNATAKA,TAMILNADU,MAHARASHTRA,DELHI,
OUTGOING SR AIIMS S60 & NEET MPL DATE : 05-07-2021
CHEMISTRY
ELECTRON MIGRATION EFFECTS

1. Which of the following is weakest acid?

OH OH
(1) (2) (3) Ph – OH (4) CH 3OH
2. The –I effect shown by is
1) -COOH 2) −CH 3 3) −CH 2 − CH 3 4) −CHR2
3. Shifting of electrons of a multiple bond under the influence of a reagent is called
1) I-effect 2) M-effect 3) E-effect 4) Resonance effect
4. Which of the is the correct order of stability?

I) II) III)
1) I > II > III 2) III > II > I 3) II > III > I 4) II > I > III

5.
1) Resonating structures B) Tautomes
3) Geometrical isomers 4) Optical isomers
6. Cyano hydrin formation is an example of
1) –E.E 2) +E.E 3) +I.E 4) –I.E

CH3 CH2
7. I)

CH3 CH2 CH2

II)

(CH3)2CH CH2
III)
Stabilty order of these benzyl carboncations is
1) I > II > III 2) III > II > I 3) II > III > I 4) III > I > II
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8. Which of the following acids has the smallest dissociation constant
1) CH 3CHFCOOH 2) FCH 2CH 2COOH

3) BrCH 2CH 2COOH 4) CH 3CHBrCOOH

9. The most stable carbanion among the following is
CH2 CH2
CH2 CH2 CH2

1) 2) 3) OCH3 4) NO2

10. Decreasing –I effect of given groups is

a) CN b) NO2 c) NH 2 d) F

1) c > b > a > d 2) b > c > d > a 3) c > b > d > a 4) b > a > d > c
O
H2 N−NH−C−NH2
I II III
11. Which one of the Nitrogen atoms in is the most nucleophillic?
1) III 2) I 3) II
4) All three Nitrogen atoms are equally strong nucleophillic centre
⊕
12. The deactivating nature of NH 3 group when attached to benzene ring is explained by
1) +I effect 2) –I effect 3) +M effect 4) –M effect
13. Electromeric effect is not observed in
1) Ethers 2) Aldehydes 3) Alkenes 4) Ketones
14. The decreasing order of the basic character at a, b, c, d in the compound
a b
NH2 NH2
Me
d
H2N
Me
Me
c
H2N
1) a > c > b > d 2) d > c > b > a 3) c > b > d > a 4) b > c > d > a
15. Which among the following carbocations is most stable
⊕
⊕ ⊕ CH 3 − C − CH 3
1) (C6 H 5 )3 C 2) C6 H 5 − CH 2 ⊕
3) C H − CH 4)
6 5 − C6 H 5 |
CH3

16. Positive inductive effect is shown by all except

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 (1) − CH 2 2) − O − 3) − NH 2 4) − CH 3
17. Which of the following readily gives a white precipitate with AgNO3 ?

Cl Cl
Cl
Cl

1) 2) 3) 4)
18. Most stable carbocation among the following

⊕ ⊕
(1) (2) (3) CH 3 − C H 2 (4) CH ≡ C
19. Correct acidic strength order

I) O 2 N − CH 2 − COOH II) NC − CH 2COOH III) F − CH 2 COOH

1) I > II > III 2) I < II < III 3) II > I > III 4) III > I > II
20. Which is most basic ?
(1) C6 H5 − NH 2 (2) ( C6 H5 )2 − NH (3) C 2 H 5 NH 2 (4) ( C 2 H5 )2 NH

⊕ ..−
O − ⊕ . ..
CH 2 − CH = Cl .. (I) O
CH 2 − CH = Cl . (II) CH = CH − Cl .. (III)
21. .. .. 2 .. Increasing order of stability is
1) I < II < III 2) II < I < III 3) I < III < II 4) II < III < I
22. Consider the following alkenes:
H3 C CH3 H CH3
C C C C
H
I) H II) H3C H III) CH3 – CH2 – CH = CH2
Correct order of stability is
1) III > II > I 2) I > III > II 3) II > I > III 4) II > III > I
23. Which of the following carbo cations is least stable
+ +
1) C6 H5 CH 2 2) P − NO 2 − C6 H 4 CH 2
+ +
3) P − CH3O − C6 H 4 CH 2 4) P − Cl − C6 H 4 C H 2
24. Rearrangement occurs in
•
•
1) CH3CH2+CH2 2) CH3 3) CH 3CH 2 C H 2 4) CH 3CH 2 C H 2

25. Which of the following has +R effect (Resonance effect) ?

1) -CN 2) -CHO 3) –NH2 4) –NO2
26. Resonance is possible in
1) CH3 – CO – CH3 2) CH2 = CH – CHO
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 3) CH2 = CH – CH2 – CHO 4) CH2 = CH – CH2 – CH = CH2

27. Which of the following alkene is most stable ?

1) 2) 3) 4)
28. Which of the following shows reverse hyper conjugation ?

1) CF3CH2 2) CH3CH2 3) C6H5CH2 4) C6H5CHCH3

29. Propene , 2, 3-dimethyl-2-butene , ethylene , 2-butene, the decreasing stability order of alkenes on
the basis of hyper conjugation is ________
1) 2, 3-dimethyl-2-butene > 2-butene > propene > ethylene
2) 2-butene > propene > ethylene > 2, 3-dimethyl-2-butene
3) propene > ethylene > 3-dimethyl-2-butene > 2-butene
4) ethylene > 2, 3-dimethyl-2-butene > 2-butene > propene
30. Arrange the following in order of their decreasing acidic strength ?

⊕ ⊕
NH 2 O2 N NH 3
⊕ ⊕
H3C − NH 2 C6 H5 − NH3 H 2 N − C − NH 2
(I) (II) (III) (IV)
1) I > II > III > IV 2) IV > II > I > III 3) IV > III > II > I 4) IV > I > II > III

KEY
1) 2 2) 1 3) 3 4) 4 5) 1 6) 1 7) 1 8) 3 9) 4 10) 4
11) 2 12) 2 13) 1 14) 2 15) 1 16) 3 17) 1 18) 2 19) 1 20) 4
21) 1 22) 3 23) 2 24) 1 25) 3 26) 4 27) 4 28) 1 29) 1 30) 2

SOLUTIONS
1. Greater the ‘+I’ groups lesser the O – H polarity
4. II) – shows + ME
III) – shows – IE
5.

6.
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 O O−
CH3 − C − H + CN− 
→ CH3 − C − H
CN
7. (I) shows more number of hyper conjugative structures
8. In option 3, Br has low EN and far distance from COOH
9. EWG increases stability of carbanion
11. (I) NH 2 is not involved in resonance

⊕
NH 3

12. can form ‘meta’ compounds

13. Due to absence of multiple bonds
14. d → alkyl amine ; c → ERG increases basic character ; b → + ME ; a → due to ortho effect
basic character decreases
15. ( C6 H5 )3 C⊕ forms more number of resonating structures
16. − NH 2 shows – I effect

17. has 2π electrons

18. Option 2 involves in resonance

19. - IE group order NO 2 > CN > F

- IE increases acidic strength
20. Aliphatic amines are more basic than aromatic
21. (III) Neutral molecule is more stable
(I) do not follow Lewis dot formula
22. Stability order : Trans > Cis
23. EWG decreases stability of the carbocation
⊕
24. Only CC involves in rearrangement
25. Due to presence of lone pair of electrons − NH 2 will involve in + ME
26. Due to the conjugated diene
27. Possess more number of hyperconjugation structures
28.
F

F − C − CH 2
F
29. Based on hyperconjugation

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