DELHI PUBLIC SCHOOL RUBY PARK, KOLKATA UNIT TEST - I, 2021-22 Class XL ‘Time: 1 Hour ‘Subject: CHEMISTRY Maximum Marks: 25 SECTION- A 1. Read the passage given below and answer the following questions: All the four colligative properties of dilute solutions help in calculating the observed ‘molecular mass of the solute. It may be same as the theoretical molecular mass if the solute behaves normally. In case, it undergoes dissociation (in aqueous solution) or association (in non-polar solvents), the observed molecular mass of the solute changes and so do the colligative properties. The nature of the solute in solution is expressed in terms of Van"t Hoft factor which may be I, more than 1 and less than 1 (i) Choose the correct option from the multiple choices given: Three aqueous solutions of NaCl are labelled as A, Band C with concentrations 0.1 M, 0.01 Mand 0.001 M, respectively. The value of Van't Hoff factor for these solutions will be of the order fain < in < ic (dyin > in > ic (ia = ip = ic (dix < in > ic In the following questions (i and ii), a statement of assertion followed by a statement of reason is given. Choose the correct answer out of the following choices. 4) Assertion and reason both are correet statements and reason is correct explanation for assertion. by) Assertion and reason both are correct statements but reason is not correct explanation for assertion ¢) Assertion is correct statement but reason is wrong statement, 4d) Assertion is wrong statement but reason is correct statement. (ii) Assertion: Van't Hoff factor for benzoic acid is less than | in benzene. Reason: Benzoie acid associates in benzene. (ii lolecular mass of KCI ealeulated on the basis of colligative properties will be al molecular mass, Reason: Experimentally determined molecular mass is always lesser than the actual molecular mass. 2, By X~ray studies, the packing of atoms in a erystal of gold is found to be in layers such that 1x2=2 starting from any layer, every fourth layer is found to be exactly identical, Choose the correct, options from the following questions: (i) The coordination number of gold atom in the crystal is, (8 (b) 4 (©) 6 (@ 12 (ii) ‘The percentage packing efficiency of gold atoms in the erystal is: (a) 52% (b) 68% (©) 74% (d) 84%6, SECTION- B ‘The following questions are multiple choice questions. Choose the most appropriate answe ‘When two liquids Acetone and Chloroform are mixed, the solution will show: {a) positive deviation from Raoult’s Law (b) negative deviation from Raoult’s Law (c) no deviation from Raoult’s Law (@) slightly inerease in volume. Increasing the temperature of an aqueous solution will cause: {a) decrease in mola (b) decrease in molarity (c) decrease in mole fraction (d) decrease in % (w/w) Which of the following doping will produce p-type semiconductor? (a) Silicon doped with arsenic (b) Germanium doped with phosphorous, {c) Germanium doped with aluminium —_(<) Silicon doped with phosphorus. In the following questions (6 and 7), a statement of assertion followed by a statement of reason is given, Choose the correct answer out of the following choices. a) Assertion and reason both are correct statements and reason is correct explanation for assertion. b) Assertion and reason both are correct statements but reason is not correct jon for assert mn is correct statement but reason is wrong statement. d) Assertion is wrong statement but reason is correct statement. Assertion: Metals are generally good conductors of electricity Reason: The electrical conductivity of metals increases with rise in temperature. Assertion: The vapour pressure of a liquid decreases if some non-volatile solute is dissolved in it Reason: The relative lowering of vapour pressure is a colligative property. SECTION-C Pome (A) Pisaon 13) i sew oe are ae Conceetniiod Feesh water sodium cht (Ay soln ein 118) {a)With respect to the above diagram mention what change would occur ifa pressure greater than Osmotic Pressure is applied on piston (B). (b) Two liquids A and B boil at 145°C and 190°C respectively. Which of them has higher vapour pressure at 80°C 1x3-3 1x2=29, 10, ul (a) State Henry’s law. (b) Aquatic animals are more comfortable in cold water than in warm water. Explain SECTION- D 3x26 (a). Define the term-Ferrimagnetism. (b), Refractive index ofa solid is observed to have the same value along all the directions. Comment on the nature of the solid. (c) What is the formula of a compound in which the element ¥ forms cep lattice and atoms X occupy 2/3" of octaliedral voids? (a)Ethylene glycol (molar mass = 62.g mol") is a common automobile antifreeze, Calculate the freezing point of solution containing 12.4 g of this substance in 100 g of water. (Kr for water = 1.86 K kg mot") (b) Measurement of osmotic pressure method is preferred over other methods for the determination of molar masses of macromolecules. Explain. SECTION -E SXxI=5 (a)What are F — centres? (b) A metal crystallises in a body centred cubic structure. What is the relation between the edge length of its unit cell and the radius of the sphere? (c) What change occurs when AgCI is doped with CdCl? (d) An element having atomic mass 60 u has face centred cubic unit cells. The edge length of the unit cell is 400 pm, Calculate the density of the element.