SET -I DELHI PUBLIC SCHOOL RUBY PARK, KOLKATA UNIT TEST —1, 2023-24 CLASS- XI ‘Time: 1H. SUBJECT- CHEMISTRY Maximum Marks: 25 General Instructions: There are 12 questions in all Section A consists of 6 multiple choice questions carrying I mark each, Section B consists of 2 short answer questions carrying 2 marks each. Section C consists of 2 short answer questions carrying 3 marks each. Section D consists of 1 case-based questions carrying 4 marks. Section E consists of 1 long answer question carrying 5 marks. SECTION A [1 X 6 =6] 1. Which of the following solution pairs can exhibit minimum boiling 1 azeotrope? (a) Water-HNOs (b) Water-HCI (c) Benzene-toluene (d) CoHsOH-water 2. Vapour pressure of dilute aqueous solution of glucose is 750 mm Hg at 3731 K. If vapour pressure of pure water at 373 K is 760 mm Hg, then the mole fraction of glucose in the solution will be: : Oz as OF Os 3. Which of the following statements is incorrect for the electrolysis of 1 aqueous solution of CuSO, by using platinum electrodes? (a) Copper will deposit at the cathode (b) Oxygen will be released at the anode (©) Electricity is consumed (@ Copper will dissolve at the anode 4. In an electrochemical process, a salt bridge is used 1 (a) as a reducing agent (b) as an oxidizing agent (¢) to complete the cell circuit (d) to act as catalyst 5. The unit of conductivity is 1 (a) ohm™ (b) ohm cm’! (c) ohm cm? (@) ohm? cm mot Class 12/Unit Test 1/Page 1 of 4In the following question a statement of assertion followed by a statement 1 of reason is given. Propose the correct option from the given choices: (@) Both assertion and reason are true and the reason is correct explanation for assertion (b) Both assertion and reason are true and the reason is not correct explanation for assertion (©) Assertion is correct but reason is false (@) Assertion is false but reason is correct Assertion: If standard reduction potential for the reaction Ag’ + ¢ — Ag is 0.80 V, then for 2Ag* + 2e" —+ 2Ag, it will be 1.60 V. Reason: If concentration of Ag” ions increase, its electrode potential also increases. SECTION B [2 X 2= 4] (a) State Henry’s law. 1+1 (b) 20 cm* of liquid X is added to 80 em* of another liquid Y to form a solution whose volume is recorded as 100.05 cm’. Will the value of AsoiH be less or more than zero? (a) What is the charge of 0.1 mole of electrons? 1+1 (b) What are the reactions taking place at anode and cathode in lead storage battery? oR (a) Write two advantages of using fuel cell (b) How many coulombs are required for the oxidation of 1 mole of H20 to On? SECTION C [3 X2=6] Read the passage carefully and answer the following: 142 In 1880 van’t Hoff introduced a factor i, known as the van't Hoff factor, to account for the extent of dissociation or association. The factor j is defined as: __Normal molar mass ‘Abnormal molar mass Observed colligative property Calculated colligative property (Total number of moles of particles after association dissociation) (Number of moles of particles before associagtion /dissociation) (@) What is the approximate value of van’t Hoff factor, i for a dilute solution of potassium ferrocyanide in water? (b) Calculate the freezing point of a solution when 3 g of CaCl: (M= 111 mol") was dissolved in 100 g of water assuming that CaCl undergoes complete ionization. (Ks for water = 1.86 K kg mol") Class 12/Unit Test 1/Page 2 of 410, 1. 12, (2) The standard reduction potential values of three metalic cations XYZ 1+2 aera 2:03: “1.18 V respectively. What will be the increasing order of reducing power of corresponding metals? ~(b) Calculate AG? for the following reaction at 298 K: 2AL (8) + 3 Cu?* (aq) + 2AF* (aq) + 3Cu (5) Given, Baia = -1.66 V; EB’, = 40.34 V SECTION D [4X 1 =4] "Read the Passage carefully and answer the following questions: 4142 Molar conductivity of an electrolyte is the conductance of all the ions produced by one gram mole ofthe electrolyte in solution and is denoted as os ee 1000 Here, wis the specific conductance while cis the molar concentration of the clectrolyte, The molar conductance of the strong electrolytes at infimts filution (An®) can be obtained graphically by extrapolation while the same {for weak electrolytes cannot be obtained graphically. It can be ealeulacat theoretically with the help of Kohlrausch’s Law. It can be mathematically represented as, Aim? (AsBy) = x Dex? (AY) + y An? (B*) (a) i 3 Ee 8 0. qyhat will be your judgement about the nature of electrolytes A and B? 6) Will molar conductivity increase five times if | M KCI's diluted five times? Justify your answer with correct explanation, (© Molar conductivities at infinite dilution at 298 K of NHiCl, NaOH and NaCl are 129.8, 217.4 and 108.9 ohm" cm? mot" respectively. Ifthe molar conductivity of a centimolar solution of NHsOH is 9.33 ohm" cm? mot", what is the percentage dissociation of NHOH at this concentration? SECTION E [5 X 1= 5] (@) The density of 2.0 M solution of acetic acid (Molar mass = 60) in water 1x5 is 1.02 g/mL. Calculate the molality of the solution, (©) 0.5 M aqueous solution of sodium chloride shows higher oiling point than 0.5 M glucose solution at the same temperature. Justify the sttconny (©) What do you mean by reverse osmosis? Class 12/Unit Test 1/Page 3 of 4a) Gas Solvent Ku Fa ‘Water 7118 CO2 ‘Water 1.67 CHa Water 41.85 Arrange the above gases in order to decreasing solubility in water. (c) Cutting onions taken from refrigerator is relatively more comfortable than that lying at room temperature. Explain. OR (a) Gases nearly always tend to be less soluble in liquids as the temperature” is raised. Justify the statement, (b) Two solutes X and ¥ in equal amounts are dissolved separately in 10 moles of solvent C. If X molecules are heavier than Y molecule, which solution will have larger relative lowering of vapour pressure? (©) Define: ebullioscopic constant. (4) What does ‘X represent in the graph given below? 3 x 5 1 3) 1 = 1 —> Temperature (@) What happens when red blood corpuscles are placed in 1% NaCl solution? Class 12/Unit Test 1/Page 4 of 4