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Rose Flavour Natural - SDS
Rose Flavour Natural - SDS
Rose Flavour Natural - SDS
The Product Makers (Australia) Pty Ltd Chemwatch Hazard Alert Code: 3
Version No: 1.1 Issue Date: 30/04/2019
Safety Data Sheet according to WHS and ADG requirements Print Date: 30/04/2019
S.GHS.AUS.EN
Product Identifier
Product name: 003478 ROSE FLAVOUR NATURAL
Proper shipping name: EXTRACTS, FLAVOURING, LIQUID
Other means of identification: Not Available
Relevant identified uses of the substance or mixture and uses advised against
Relevant identified uses: Use according to manufacturer's directions.
Details of the supplier of the safety data sheet Emergency telephone number
Registered company name The Product Makers (Australia) Pty Ltd Association / Organisation Not Available
Address 50 - 60 Popes Road Keysborough 3173 Australia Emergency telephone numbers 61 3 9771 0300
Telephone 61 3 9771 0300 Other emergency telephone numbers Not Available
Fax 61 3 9771 0301
Website www.theproductmakers.com
Email Not Available
HAZARDOUS CHEMICAL. DANGEROUS GOODS. According to the WHS Regulations and the ADG Code.
ChemWatch Hazard Ratings
Flammability 3
Toxicity 1 0 = Minimum
1 = Low
Body Contact 2 2 = Moderate
Reactivity 2 3 = High
Chronic 2 4 = Extreme
Label elements
Hazard pictogram(s)
Hazard statement(s)
H319: Causes serious eye irritation.
H225: Highly flammable liquid and vapour.
H317: May cause an allergic skin reaction.
H412: Harmful to aquatic life with long lasting effects.
H401: Toxic to aquatic life.
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003478 ROSE FLAVOUR NATURAL
Substances
See section below for composition of Mixtures
Mixtures
CAS No %[weight] Name
64-17-5 90-99 ethanol
8000-46-2 1-10 geranium oil
106-24-1 <1 geraniol
60-12-8 <1 phenethyl alcohol
Skin Contact
If skin contact occurs:
- Immediately remove all contaminated clothing, including footwear.
- Flush skin and hair with running water (and soap if available).
- Seek medical attention in event of irritation.
Inhalation
- If fumes, aerosols or combustion products are inhaled remove from contaminated area.
- Other measures are usually unnecessary.
Ingestion
- If swallowed do NOT induce vomiting.
- If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration.
- Observe the patient carefully.
- Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious.
- Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink.
- Seek medical advice.
Extinguishing media
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003478 ROSE FLAVOUR NATURAL
Fire/Explosion Hazard
- Liquid and vapour are highly flammable.
Combustion products include:
carbon dioxide (CO2)
other pyrolysis products typical of burning organic material.
HAZCHEM
3Y
Environmental precautions
See section 12
Major Spills
- Clear area of personnel and move upwind.
Other information
Store tightly closed under cool dry conditions in an approved storage area. Avoid exposure to light.
Shelf Life : 12 monthsaccording to the specified storage conditions
Storage incompatibility
- Avoid oxidising agents, acids, acid chlorides, acid anhydrides, chloroformates.
- Avoid strong bases.
*
Terpenoids and terpenes, are generally unsaturated, are thermolabile, are often volatile and may be easily oxidised or hydrolysed depending on their respective structure.
·The interaction of alkenes and alkynes with nitrogen oxides and oxygen may produce explosive addition products; these may form at very low temperatures and explode on heating to
higher temperatures (the addition products from 1,3-butadiene and cyclopentadiene form rapidly at -150 C and ignite or explode on warming to -35 to -15 C).
Control parameters
Exposure controls
Appropriate engineering controls
Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard.
Personal protection
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003478 ROSE FLAVOUR NATURAL
Skin protection
See Hand protection below
Hands/feet protection
- Wear chemical protective gloves, e.g. PVC.
NOTE:
- The material may produce skin sensitisation in predisposed individuals.
The selection of suitable gloves does not only depend on the material, but also on further marks of quality which vary from manufacturer to manufacturer.
Body protection
See Other protection below
Other protection
- Overalls.
- Some plastic personal protective equipment (PPE) (e.g. gloves, aprons, overshoes) are not recommended as they may produce static electricity.
Ingestion
Accidental ingestion of the material may be damaging to the health of the individual.
Ingestion of ethanol (ethyl alcohol, 'alcohol') may produce nausea, vomiting, bleeding from the digestive tract, abdominal pain, and diarrhoea.
Skin Contact
Skin contact is not thought to have harmful health effects (as classified under EC Directives); the material may still produce health damage following entry through wounds, lesions or abrasions.
Open cuts, abraded or irritated skin should not be exposed to this material
Entry into the blood-stream, through, for example, cuts, abrasions or lesions, may produce systemic injury with harmful effects.
There is some evidence to suggest that the material may cause moderate inflammation of the skin either following direct contact or after a delay of some time.
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003478 ROSE FLAVOUR NATURAL
Eye
Direct contact of the eye with ethanol (alcohol) may cause an immediate stinging and burning sensation, with reflex closure of the lid, and a temporary, tearing injury to the cornea together with
redness of the conjunctiva.
There is evidence that material may produce eye irritation in some persons and produce eye damage 24 hours or more after instillation.
Chronic
Inhaling this product is more likely to cause a sensitisation reaction in some persons compared to the general population.
Skin contact with the material is more likely to cause a sensitisation reaction in some persons compared to the general population.
Ample evidence from experiments exists that there is a suspicion this material directly reduces fertility.
Prolonged exposure to ethanol may cause damage to the liver and cause scarring.
Certain substances, commonly found in perfumes or perfumed products, produce hypersensitivity.
A number of common flavor and fragrance chemicals can form peroxides surprisingly fast in air.
Peroxidisable terpenes and terpenoids should only be used when the level of peroxides is kept to the lowest practicable level, for instance by adding antioxidants at the time of production.
Intolerance to perfumes, by inhalation, may occur if the perfume contains a sensitizing principal.
TOXICITY IRRITATION
003478 ROSE FLAVOUR NATURAL
Not Available Not Available
TOXICITY IRRITATION
[2] Eye (rabbit): 500 mg SEVERE
Inhalation (rat) LC50: 124.7 mg/l/4H
TOXICITY IRRITATION
[2] [1]
Dermal (rabbit) LD50: 2500 mg/kg Eye: adverse effect observed (irritating)
geranium oil Oral (rat) LD50: >5 mg/kg [2] Skin (g.pig): 100% - mild
TOXICITY IRRITATION
[2] [1]
Dermal (rabbit) LD50: >5000 mg/kg Eye: adverse effect observed (irritating)
TOXICITY IRRITATION
[2] Eye (rabbit): 0.75 mg/24h SEVERE
dermal (rat) LD50: >5000 mg/kg
[2] Eye (rabbit): 12000 mg/10m mild
Inhalation (rat) LC50: >4.63 mg/l/4H
phenethyl alcohol
[2] [1]
Oral (rat) LD50: 1500 mg/kg Eye: adverse effect observed (irritating)
Skin (rabbit): 100 mg/24h moderate
[1]
Skin: no adverse effect observed (not irritating)
Legend: 1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2.* Value obtained from manufacturer's SDS. Unless otherwise specified data extracted from RTECS -
Register of Toxic Effect of chemical Substances
GERANIUM OIL
Inhalational exposure of mice and man to linalool caused slight sedative effects but a dose dependent response characteristic could not be determined.
GERANIOL
Geraniol does have sensitising properties, but the response it exhibits tends to be weak and variable.
With few exceptions* (see below), there are no safety concerns regarding certain cyclic and non-cyclic terpene alcohols **, as fragrance ingredients, under present declared levels of use and
exposure, because
- They have low acute toxicity
- No significant toxicity was observed in repeat dose toxicity tests
- They were not found to cause mutations or genetic toxicity
- Substances in this group are processed similarly in the body
- There is no indication of persistent breakdown products causing severe toxicity
- They practically do not irritate the skin
- They have a generally low potential for sensitization
- The margin of safety is more than 100 times the maximum daily exposure.
Current opinion holds that there are no safety concerns regarding the branched chain unsaturated non-cyclic alcohols, as fragrance ingredients, at current declared levels of use and exposure;
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003478 ROSE FLAVOUR NATURAL
however, use of these materials at higher maximum levels of skin or whole-body exposure requires re-evaluation.
The material may cause severe skin irritation after prolonged or repeated exposure and may produce on contact skin redness, swelling, the production of vesicles, scaling and thickening of the
skin.
PHENETHYL ALCOHOL
Fragrance allergens act as haptens, low molecular weight chemicals that cause an immune response only when attached to a carrier protein.
Unlike benzylic alcohols, the beta-hydroxyl group of the members of benzyl alkyl alcohols contributes to break down reactions but do not undergo phase II metabolic activation.
This is a member or analogue of a group of phenethyl, aldehyde, acid and related acetals generally regarded as safe (GRAS), intended for use as flavouring ingredients, based partly on their
self-limiting properties as flavouring substances in food.
The aryl alkyl alcohol (AAA) fragrance ingredients have diverse chemical structures, with similar metabolic and toxicity profiles.
Mutation mouse ascites tumour
003478 ROSE FLAVOUR NATURAL & GERANIUM OIL & GERANIOL & PHENETHYL ALCOHOL
The following information refers to contact allergens as a group and may not be specific to this product.
Legend: – Data either not available or does not fill the criteria for classification
– Data available to make classification
Toxicity
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003478 ROSE FLAVOUR NATURAL
Legend: Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - Aquatic Toxicity 3. EPIWIN Suite V3.12 (QSAR) - Aquatic Toxicity
Data (Estimated) 4. US EPA, Ecotox database - Aquatic Toxicity Data 5. ECETOC Aquatic Hazard Assessment Data 6. NITE (Japan) - Bioconcentration Data 7. METI (Japan) -
Bioconcentration Data 8. Vendor Data
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Do NOT allow product to come in contact with surface waters or to intertidal areas below the mean high water mark.
For Ethanol:
log Kow: -0.31 to -0.32;
Koc 1: Estimated BCF= 3;
Half-life (hr) air: 144;
Half-life (hr) H2O surface water: 144;
Henry's atm m3 /mol: 6.29E-06;
BOD 5 if unstated: 0.93-1.67,63%
COD: 1.99-2.11,97%;
ThOD : 2.1.
For Terpenes such as Limonene and Isoprene:
Atmospheric Fate: Contribute to aerosol and photochemical smog formation.
DO NOT discharge into sewer or waterways.
Bioaccumulative potential
Ingredient Bioaccumulation
ethanol LOW (LogKOW = -0.31)
geraniol LOW (LogKOW = 3.47)
phenethyl alcohol LOW (LogKOW = 1.36)
Mobility in soil
Ingredient Mobility
ethanol HIGH (KOC = 1)
geraniol LOW (KOC = 70.79)
phenethyl alcohol LOW (KOC = 28.89)
Labels Required
Marine Pollutant
NO
Not Applicable
HAZCHEM
3Y
Land transport (ADG) Air transport (ICAO-IATA / DGR) Sea transport (IMDG-Code / GGVSee)
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003478 ROSE FLAVOUR NATURAL
III 220 L
Passenger and Cargo Packing Instructions:
355
Passenger and Cargo Maximum Qty / Pack:
60 L
Passenger and Cargo Limited Quantity Packing Instructions:
Y344
Passenger and Cargo Limited Maximum Qty / Pack:
10 L
Safety, health and environmental regulations / legislation specific for the substance or mixture
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003478 ROSE FLAVOUR NATURAL
Other information
Classification of the preparation and its individual components has drawn on official and authoritative sources as well as independent review by the Chemwatch Classification committee using
available literature references.
The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment.
end of SDS