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Skull Crusher-09
for JEE (Advanced)-(Class XI)
Chemistry
Chapter Name : Some Basic Concepts of Chemistry
Topic Name : Mole concept, Concentration terms, Limiting reagent, Mass percentage
I One or More than One Option Correct Type
1. Consider the following sequential balanced
reactions with given amount of reactants
Reaction 1:
A + B ⎯→ C Yield = x%
4 mol 8 mol
Reaction 2:
C+B → D Yield = y%
Reaction 3:
D + B ⎯→ P Yield = z%
4 mol
Given z > y > x and z < 100. On the basis of this
information and assuming limiting reagent is the
reactant left unreacted in smaller concentration,
select the correct statement(s).
(1) C is limiting reagent in reaction 2
(2) B is limiting reagent in reaction 3
(3) D is limiting reagent in reaction 3
(4) Number of moles of C, D and P formed in
reactions 1, 2 and 3 respectively are in order
of C > D > P
2. Two solutions of different composition are given
below
Solution I : 500 mL of 2 M H2SO4 having
density = 1.8 g/mL.
Solution II : 500 mL of 10% (w/v) of H2SO4 and
density of solution is 1.4 g/mL.
Both solutions are mixed and volume of final
solution is 1000 mL. Select the correct
statement(s) about the final solution.
(1) Molality is more than molarity
(2) Molality is less than molarity
(3) (w/w)% of H2SO4 is 9.25%
(4) Density of final solution is 1 g/mL
3. A magnesium ribbon was burnt in air and left an
ash containing MgO and Mg3N2. The ash when
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taken into solution was found to react with 60
mmoles of HCl (all nitrogen is converted to
NH4Cl). After that, the solution obtained above
was treated with NaOH (excess) and 4 mmoles of
NH3 was evolved. Then the mass of Mg ribbon
burnt is approximately [Atomic mass of Mg = 24]
(1) 672 mg
(2) 576 mg
(3) 600 mg
(4) 648 mg
II Integer Type
4. Empirical formula of an organic compound (Q) is
CxHyOzBrp. Consider the following information and
find the value of x + y + z + p.
(a) 1.81 g of the compound (Q) on complete
combustion produces 2.64 g of CO2(g) and
1.17 g of H2O(I)
[Assume all C converts into CO2 while all
hydrogen converts into H2O]
(b) Percent mass of oxygen (O) in compound is
8.84%
(c) Atomic mass of H, C, O and Br are 1, 12, 16
and 80 respectively
5. The mole fraction of a solute in a solution is 0.2 and
molality of this solution is equal to molarity of this
solution. Ratio of molar mass of solute to solvent is
2 and density of solution is p g/mL, then value of 10p
is (molarity of the solution 5 M)
III Match the List type
6. List-I contains different oleum sample weighing
100 g, while List-II contains properties associated
with those samples. Select the correct match.
List-I List-II
[1]
Skull Crusher-09 for JEE (Advanced) -(Class XI) Chemistry

P 109% oleum 1. 78.9 g Ca(OH)2 for exact S 20% w/w of 4. 89 g NaOH for exact
neutralization SO3 in oleum neutralization
Q 104.5% oleum 2. Gives 1.135 M H2SO4 5. 80% by weight of H2SO4
when dissolved in water
to form 1 L solution,
assuming density of (1) P → 1, 5; Q → 2, 4; R → 3; S → 2, 4
solution = 1 gm/cc (2) P → 4, 5; Q → 2, 3; R → 1, 5; S → 2, 3
R 50% w/w of 3. 120.3 g of Na2CO3 for (3) P → 4; Q → 1, 3, 5; R → 2, 3; S → 1, 2, 5
SO3 in oleum exact neutralization
(4) P → 4; Q → 1, 5; R → 2, 3; S → 1, 5

❑ ❑ ❑

Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005. Phone : 011-47623456 [2]
Chemistry Skull Crusher-09 for JEE (Advanced) -(Class XI)

Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005. Phone : 011-47623456

Skull Crusher-09
for JEE (Advanced)-(Class XI)
Chemistry

[ANSWERS KEY]
1. Answer (1, 3, 4)
2. Answer (2, 3)
3. Answer (1)
4. Answer (21)
5. Answer (15)
6. Answer (4)

Corporate Office : Aakash Tower, 8, Pusa Road, New Delhi-110005, Phone : 011-47623456 [3]