QUESTION BANK

JRCHEMISTRY
ATOMIC STRUCTURE
LONG ANSWER QUESTIONSs
the postulates
What areinportance ofBor's model ofkydrogen atom? (Mar-19)
ofthis model to explain various series oflinc spectra in hydroga atom?
Di
u 3 NMan01.03.0-4.05./06,08,09,11,12,13,15,17,18,20,23),Ts-Mar-17,18,20,May-22,23
How are the quantum numbersn, Iand ms arrived at? Explain the significance ofthese quantunm
numbers.? (Jun-02,04,06,May-07,Sep-08,Mar-02,09,10,14),Ts-Mar-15,17,19
03.*
Define atomic orbital Explain the shapes of's, pand dorbitas with the help ofdigrams.?
04*
sa) Explain the ditterence between emission and bsorption spectra.?T-May-22 Mar-15)
6) Explan ()Aufbau Principle (i) Hund's Rule (ii) Pauli's Principle? (Mar-19)
(a) Explain the dual behavior ofnatter. Discuss its significance to microscopic piarticles like
clete
clectrons
s Explain brietly the Planck's qumtum theory?
06* al Show that the circumference of the Bohr orbit for the lydrogen atom is an integral multiple of
the de Brogliewavelength associated with the electron revolving around the orbit?
b) Explain photoclectric effeet?
Advantages and Linitations of Bohr'stheory (Mar-13,15)
(d) What will be the wavelength ofa ball ofmass 0. 1kgmoving with avelocity of 1Oms' (Mar-l)
074. a) Explain Heisenberg'_ Uncertainty principle?
b)A golfball has a massof40g, and aspeed of45m's, Ifspeed can be measured with in accuracy of
296, calculate the uncertainty in the position.
c) Explain the difference between line spectrun and bund spectrum
CLASSIFICATION OF ELEMENTS AND PERIODICITY IN PROPERTIES
LONG ANSWER QUESTIONS
X ) * Define lE, and /E,. Why is IE, >IE, fora given atom? Discuss the factors that effect IE ofan
clement?
(Sep,Mar-2000,04,Jun-04,06,08,09,May-09,22, Mar-12,13),Ts-Mar-17,19,22,23
What isa periodic property? How the following properties varyin agroup and in aperiod ?Explain
(a) Atomic radius (b) IE (C)EN (d) Electron gain enthalpy or electron affinity
(e) Nature ofoxides
(Jul-01,May-07, 12 Jun-05,06,Sep-08,Mar-03,07,11,14,15,18), Ts-Mar-5,18.20
Write an essay on s.p.d and f- block elements. (Jun-11,Mar-05,17,19,20,23)
SHORTANSWER QUESTIONS
94.**s Give anyfour characteristic properties oftransition elements
05.* Electron afinity ofchlorine is morethan that offuorine - explain
What is lanthanide contraction ? What are its consequences? T-May-22
07. Explain (0) Electronegativity (i) Elkctron atfinity?
08, Write anote on () Atomicradius () Metallic radius (im) Covalent radius
89, Give the outer orbit general electronic configuration of
a. Noble gases b. Representative elements
C. Transition clenents d. Inner transition clements

NARAYANA Page.No.84
IRCHEMINTRY QUESTON RENK
I%,efNa le than that of Mgbt /, orNawhgher thnthtof Myespln
Whahelt of t e r hs the hte xplain the vara of th per
Wt digoal relatknh Cve apr ofcets hav ng oatetkthe Why hey
show thix relatko
Lhch cch pale of cleeots has a wre eetroe galn ethas t Epla
CHEMICAL BONDING
LOYG ANSTWEROUESOYS
at cdo you ounxkrstanst bv vtlatkplain tere types ofhytt mhgd
ortitals
iive anaount ofVSEPR Theoe, arst tx aylktkns (Sep-200e,Ntay-7,Mar0asao7
Give the Mokvular Obaal Eeoy Dgrans of(a) A, (IMatOY (hO, Cake e
regvte stoe Write the ngNt INture of N, asi O, kves (Mae09,14TMa1s
Expln the tos fvoble vr the kvnof lonk o bP o
SHORTAVSIWEROUESTIONS ar-di,as

Elain the hybvitatininvohat in C, nolcule May-22(Marl2.20TMa ISIK3005

0 Eplanthe hytrilicationinvohd n SE mokule TsINE AR-19,2May-12,Mal41LQ
os *** What isiytrktiration" Explin the structure ofCH, op (he basis oftiybralatin (MaIS)
Explain Fajan srules and give sutable examyian(May-22,MtarIS1LAQz)
(Mar 2e)
Define Diole moment. Write its applicatios
a) NH, has ahigher dipole noent compared to haya 906as
b) dipole moment observed for NE, and not BE whay ? (Mar2017)
What is Hydrogen bond Explain the ditlerent iypes oftydogen bonswth euanpke
(Mar17,I8), I-Mar-|8May-22
12.** Expainthestructure of ethylenet C,H,)and acetyken C,H,) (Maris)
13. Explin the fomation ofCoordinate covalent bond with one example Mar-23
14 Explain valence bond theory with example.
15. Predict the shape ofthe following molecules by using VSEPR theory (Marl)
a) XeF b) BrF ) CIE
16. What isionic bond?Explain with one example (TSMAR-20)

THE NARANA GRO

NARAYANA
Page. Na 8s
 JR CHEMISTRY QUESTION BANK
VERYSHORT ANSWER QUESTIONS
17. What is Octet rule? TS-May-22
18 Which ofthe two ions caor Zy is more stable and why? TS-May-22
19. CT ion is more stable than CI atom-Why? Po NOO
20. Why argon does not fom Ar, molecule?c o6 O 2
21.
IfA and B are two different atoms when does AB molecule become Covalent? 40
22 Why H.O has higher BP thanHF Lo Jun-09,May-09,Mar-03,May-12)
what type ofbonds are present in NH,CI? Write its structure(Mar-04,May-12)
24 Define bodangle and bond enthalpy ?3 W39
Define bond lengthand bond order?
26 What is mnent by bcalized orbitals?
27. How many sigma and pi bonds are present in a) C,H, b) C,H, TS-May-22
CHEMICAL EQUILIBRIUMAND ACIDS &BASES
LAOS
e1* what is Lechatlier's principle? Discuss brietly the factors which can influence the equilibrium.-y 300
* Discussthe applicationofLechaterlier's principle for the industrial synthesis ofAnmonia and surhur
trioxide. (Mar-10,12,13), Ts-Mar-15
6** Explain the concept ofBronsted acids and Bronsted bases, Ilustrate the answer with suitable
examples. (Ts-Mar-17,20)
09*** Explain Lewis acid-base theory with suitable example. Classify the following species into Lewis
acids and Lewis bases and show these act as Lewis acid / base.
(a) OH (b) F (©) H* (d) BCI,
SHORTANSWER QUESTIONS
S** Derivethe relation between K and K, for equilibrium reaction (Mar-13,15) TS-MAR-19
wO 180 a) N +3H, 2NH,u b) 250, +O, 250,sMay-22.23
03)** What is Lechaterlier's principle?Discuss th <pplication ofLechaterlier's principle for the industrial
synthesis ofAmmonia by Haber's process May-22 Mar-18,23,Ts-Mar-18
a) What is aconjugate acid-base pair? Illustrate with examples. (Mar-14,19)
b) Write conjugated acid and bases for following species (Mar-20)
i)H,0(Mar-18-VSAQ) i) NH, i) HCO, ,OH (May-22-vsaq) iv) HSO, (Mar-18-vsaq) v) H,0,
Define pH. What is buffier solution? Derive Henderson- Hasselbalch equation for Calculating the
pH ofan acid buffer solution. Pa 905
09,** How does the value ofequilibriumconstant predict the extent ofreaction?
10.** Explainthe term "Hydrolysis ofsalts"with examples. Discuss the pH ofthe following types of salt
solutions.
() Salts ofweak acid and strong base. () Salts of strong acid and weak base.
What are electron deficient compound. Explain why BF, acts alewis acid (May-14)

NARAYANA Page.No.86
JR CHEMISTRY
QUESTION BANK
12,* What is solubility product? Explain the common ion effect on
13.* Write notes on solubility ofionic salts.
() common ion effect
() The relation between K and solubility(STofasparingly
soluble salt BaSO,
Define lonic product ofwater. What is its
15.* Explain the Arrhenius concept of acids value at roomtemperature. (Mar-17),Ts-Mar-17
and bases. Ts-May-22
16. VERYSHORTANSWER QUESTIONS
What is homogeneous equilitbrium? Write two homogeneous reactios.
17. (Mar-14,17),T-Mar-17
What is heterogeneous equilibrium? Write two heterogeneous reactions (Mar-17)
18. Define equilbrium constant
19. Write the relation between K and K with example
20. Give two chemical equilibrium reactions for which K =Ke
21. What is conjugate Acid- Base pair? Give example
22. What is the value of K, ? what are its units?
23. All bronsted bases are Lewis bases. Explain
24. AllLewis acids are not Bronsted acids .Why?
25
Ts-Mar-23
Give two examples ofsalts whose aqueous solutions are basic
26 Give two examples of salts whose aqueous solutions are acidic
27. Calculate the pH of0.05M NaOH solution oL24 (Mar-13)
28. Calculate the pH of0.0SM H,SO, solution (Ts-Mar-15)
29 Find the pH of0.05 M Ba(OH), aqueous solution (Mar-13)
30. Calculate the PH ofO. IM HClsolution? (Mar-14)
31. Calculate the PH of 10% MHCI solution?
32 Calculate the PH of 10*M NaOH solution? 9 4
33 What is degree ofionization. (Ts-Mar-18)
34 What are Lewis acid & base ? Give suitable example Ts May-22 (Mar-15,23)
35 The concentration ofhydrogen ion in asample ofsoft drink is 3.8x10 M What is its pl
36 What is Bronsted base? Give an example (TS-MAR-2019)
37 What is the effect ofpressure on a gaseous chemical equilibriumn (MAR-19)
38. Calculate the chemical equilibrium reaction for which K, >Ke (MAR-20)
39. What is dynamic equilibrium.(TS-Mar-20)
40. Why does BF, behave as Lewis acid? May-22

Ba loH), gat
RAYAROUP
NARAYANA Page.No.E
 JR CHEMISTRY
OUESTION BANK
ORGANIC CHEMISTRY
LAQS
Desribe two methods ofprepuration ofetliylene. Give equation for thereaction ofethylene wilhih.
following
(a) Ozone (Mar-19 SAQ)
(Mar-02,04,11,14,23),T-Mar-18
(b) Hypolalous acid
(c) Cold and dil.alk. KA fnO, (Mar19 SAQ) () Heated with O, at high pressure
' Give two methods of preparation ofacetylene. How does it react with a)water b) Ozone an
c)hydrogen bromide? write cquations-(T-mar-20) (Mar-20)
How does eact with the following reagents? Gve the correSpondmg cquations and name
acctyctions
the product formed in t
(b) Water
Ty-Mar-23
(Mar-17)
(Sep-2000,Jun
(c) Hydrogen
(a) Acetic acid (d) Halogens
(e)Hydrogen halide (D Ammonical AgNO, and Cu,Cl,
04,** a),Whut is Geometrical isomerism"Draw cis and trans isomers of the following compounds
iCHCI =CHCI i)C,H,cCH, =CCH,C,H, (May-22)
b)Deseribe any two methods of preparation ofbenzene ?Explain the halogenation, alkylation
acylation, nitration and sulpbonation ofbenzene.TS-Mar-19(May-09,22, Mar-01,12.14.15.18)
0s Explinthe following equations
PaND231 ) Wurtz reaction (May-22-vsaq)(Mar-17),1T-Mar-15,17
b)jdecarboxylationc) kolbe'sclectrolytic method (Ts-Mar-15)
tg oo46as9 Ao 222YSHORTANSWER QUESTIONS
96:** Complete the folowngréaction and name the product AB and C. P9 NO Bux lz)
CaC, e 4 itmadate ,B ACaCC yc (Mar-04,05),Ts-Mar-15
07.*** Nane the products A.B and Cformed in the following reactions. Give the equations forthe ractions
Ethylene BCC AkKOMB hyC (Mar-09), Ts-Mar-15 PA D33l2)
08,** What is substitution reaction? Explain anytwo substitution reactions ofbenzene. (Mar-07 Sep-08)
69,** Which type ofcompounds react with Ozone? Explan with one exmpe.tr,03,)3
10,** Give two examples cach for position and fiunctional isomerism.TS-May-22
1,*** What do you understand about Geometrical isomerism? Explainthe Geometircal isomers of
2-butene. (Mar-07,May-07)
306t4
12,** Explain () Inductive effect (i) Mesomeric effect (ii) Resonance effect with examplbs
13,** Explain the method of writing E-Z configurations for Geometrical isomers taking CHCI =CFB
as your example (Mar-06)
14,** Discuss Markownikov's rule and Kharash effect.
15. What carcinogenicity? Explain with two examples.
16.* Explain a) Dumas method b) KJeldhal method
17.* What is polymerization?explain withone example. (Ts-Mar-17)
18. Describe anytwo methods of preparation of Ethane. Give any three reactions of Ethane.
Mar-19 Ts-May-22

VERY SHORTANSWER QUESTIONS

19. Write thereagentsrequired for conversionofbenzene to methyl benzene
20 How is nitrobenzene prepared (Mar-17)

NARAYANA Page.No.88
JR CHEMISTRY
QUESTION BANK
21
Write the conformations of ethnefa wo Mar-2
Write the structuresof: Trichkoroethanoic acid, Neopentane, P
24
Discuss Lassaigne's test Pg N0 30 nitrobenzalkdehydeIMay-22
Explain the principle
25 Explain the following ofchroinatograp1y PgN030
(a) Crystallistion(b) Distillationc) Stream bDistillation d) Distillation under
26 How is ethylene prepared form ethyl aleohot? Write the renction. Pa No 24
reduced pressre Pa o b
5
27 What is the produet fromed when sodiunn propinoate is heated with soda lime, 32
28
What is deydrohalogenation? Write the cquation for the formationofalkene from alkylhalide o/3
29 Write the IUPAC names of

(a) CH, -CH, -CH, -CH = CH, (I-Mar-18,23) (b) (Ts-Mar-18)

CH, -C-CH,

CH, CH,
CH,-CHl -CH, -CH, -CH,
C CH,-C-CH,-C-CH, D) (I-Mar-15)
OH
CH, CH,

E) (Mar-18)Ts-Mar-23 F) (Mar-20)

CHO

(TS-Mar-19) (Mar-18) H)

NO,

HENARAANAOUP
NARAYANA Page.No.89
JR CHEMISTRY
QUESTION BANK
CH, - C= CH -CH,
(Ts-Mar-19)
J)
CHO

C (Mar-19)
K,D(CH,), C(C,H,), I)CH, - CH_- CH - CH, -CH-CH, -CHs
ca-cny
30 Write the structural formula ofthe given compounds - (Mar-14)

(a) 3,4,4,5 -Tetramethyl heptane (b) 2-Methyl -1-butene

31 Write the structures offollowing compounds

(a) 2,4 dimethylpentane (b) 3-Ethyl-4,4-dimethylheptane

32 Write a short notes on a) Wurtzreaction (Mar-17) b)Fridel craft alkylation (Ts-Mar-17)

c)Fridel craft acylation
33. What is the type of hybridization of each carbon in the following compound? (Mar-17)
HC= C-CH =CH,

34 Writethe following reaction with equation ?Polymerization ofethylene ? (Mar-17)

35 Write the functional isomers oforganic compound C,H,0. (Ts-Mar-17)

36 Write chain isomer structures ofcorboncompund CHo. (TS-MAR-20)

THENARANA GROUP
NARAYANA Page.No.90
 JR CHEMISTRY
QUESTION BANK
STATES OF MATTER
SHORTANSWERQUESTIONS
(O*** Write the postulates of KineticMolecular Theory ofGases.
-Mar-17,18 ,May-
6.08.12.13).1olhon'
(July-01Jun-11.Mlar-02,04,06.
(0)***Deduce (a) Boyle's law and (5) Charle's law (CGraham's law
Energy from Kinetic gas equntion. Pa No Q1
s law (e) Kinete
-22

AP,TS-May-22 (Mtac03,05,07.08,11,12.15, 19,20,23)Ts-Mar-15,20,23)

(Mar-17)
6.** State and explain Graham's(Jun-02,04,05,06,Mar-03,11),
law of Difusion? Problems T-Mar-18-VSAO
State and explain Dalton's law of partial pressures.? Problens (Jun-10,Mar-01,03,07)
Define (a) RMS (b) average and (e) most probable speeds of gas molecules. Give their
inter relationship.
86,* Find the RMS, most probable and average speeds of SO, at 27° C
07.5+ Find the RMS, average and most probable speeds aof O, at 27 C
Derive ldeal gas equation. TS-Mar-19 (Mar-07)
09. Explain the plhysical significance of VanderWaals parameters.
10. 360 cm' ofCH, gas diffliused through a porous memnbrane in 15 minutes, Under similar
conditions, l120em' ofanother gas diffusedin 10 minutes. Find the molar mass ofthe gas.
(Mar-18)
11. Ancon-dioxygen mixture contains 70.6 gdioxygen and 167.5 gneon. Ifpressure of themicture of
gases in the cylinder is 25 bar:. What is the partialpressure ofdioxygen and neon in the mixture ?
12, What is vapour pressure of liquid?How the vapour pressure ofliquid is related to its boiling pont?
VERY SHORTANSWER QUESTIONS
13. What are Isotherms?
14 What are STP conditions?
15. What is gram molar volume?
16. Why the gas constant "R' is called universal gas constant
Which ofthe gases diffiuses faster among N,,0, and CH, Why?
Mar-02,May-09, Ts-Mar-15,May-22
18. How many times methane diffuses faster than sulphurdioxide? (May-22)
19 Give the relation bctween the partial pressure ofa gas and its mole fraction
20 tension?
What
21. What iss t econstant? Give its value (Mar-12)
22 What is RMS speed
23
24

25
What is compressibility factor?
What is Boyle Temperarure? VAN
Why pressure cooker is used for cooking food on hills? CROUP
TS-Mar-23

26 What is critical Temperarure? Give its value for CO,

27 What is surface tension?

(Mar-18)

NARAYANA Page.No.91
 JR CHEMISTRY QUEST1ON BANK
28 What is coetticient ofviscosity ? Give its units
Calculate Kinetic energy of5 moles of nitrogen at 27"C? (Mar-13, 15),Ts-Mar-17

30
State Boyles law: Give its mathematical Expression
31. What are Isochores

32. What is Laminar flow ofa liquid

33. Find the RMS speed of N, at 27°C?

34. Write the effect oftemperature on surface tension and viscosity. Give reason to that. (Mar-17)
35 Caleulte the kinetic engery of4 moles ofmethane at- 73 C (TS-Mar-19)
36. Caleulte the ratio ofkinetic energies of3g of H, and 4g of o, at agiven tenperature.
Ts-Mar-20(Mar-19)

37.0nWhatashipwillsailinginpacific ocean where temperature is 23.4°C, aballoon is filled with 2L air.

be the volume of the balloon when the ship reaches Indian ocean, where
temperature is 26.1°C? (Mar-20)
38. What is an Ideal gas. Ts-May-22

39. Give the values of gas constant Rin different units. Mar-23

THENARAAROUP
NARAYANA Page.No.92
JRCHEMISTRY
QUEST1ON BANK

STOICHIOMETRY_-SAQS
O. Slince the lollowing redox equation by ion- eleetron method taking place in acidic medium.
A) CrO, +NO, ’G4 NO, (Mar-04.05,May-07)
B) AMO,+so,’ M SO, (Jun-06,Sep-08,Mur-09,11)
)H,SO, +HBr- SO,+ Br
D) MnO,+CO- Mn+Co,
E) Cro,+SO, ’C+SO, (Mar-18)
F) MnO, +SO,’ Mn + HSO, (T-Mar-I5,23,May-22)
G) Fe +CrO ’ Fe'+C (Mar-15), Ts-Mar-18
02,*** Detenination ofEnpirical fornula and molecular fornula (Jun-04,11,Mar-11)
(a) Acarbon compound contains 12,8%carbon, 2. 1%hydrogen, 85.1% bromine. The
molecukr weight ofthe compound is 187.9. Caleulate the molecular formula. May-22 (Mar-17)
(b) Chemical analysisofa carbon compound gave the following percentage composition by
weight ofthe clements present, carbon- 10,06%, Ihydrogen=0.84% chlorine-89. 10%,
calculate the empirical formula ofthe compound. Mar-23 (Is-Mar-20)
(c) Calculate the empirical formua ofthe compound having percentage composition potassium
(K)-26.57, chromium(Cr)=35.36, oxygen(O)-38.07 (Given the atomicweights of
K, Cr, Oas 39,52 and 16 respectively]
D) Acompound having 4,079% hydrogen, 24.27% carbon and 71.65% chlorine its molecular
weight is 98,96 what are its emperical formula and molecular formula (T-Mar-17,19)
03,**
Balance the following redox equation by ion-electron method taking place in basic medium.
(a) MnO, +’MnO, + 1, (Mar-l4, 19)
(b) PoPH, +H,PO, () Cr(o#), +10; Cro; +1
(d).
PPH,+H, PO,
(e) Mno Ao t Br ’Mno aw, + BrO, cey (MAR-20)
04. Calculate the amount of90% H-SO, required for the preparation of420kg HCI
2NaCl +H, S0, ’ Na, SO, +2HCI
0S. When 50gm ofa sample ofsulphur was burnt in air 4% ofthe sample left over. Calculate the
volume ofair required at STP containing 21% oxygen by volume.
06, Calculate the volume of0.IN H,SO, required to neutralize 200ml of0.2N NaOH solution.
07. Calculate the volume of0.1M KMnO, required to react with 100ml of0.IM H.C,0,2H,0
solution in presence of H,SO,
08. Explainthe different types ofredox reactions.

NARAYANA Page.No.93
 JRCHEMISTRY QUESTION BANK
09. Assign oxidation nunber to the underlined elements in each ofthe following species.
a) Co, d) FeO,
b) H,PO, e)H,S,0, e) Cao,
) NaBH, 2) H,S,0, h) KAI(SO), 12H,0 DKMnO,
k) H,0, L) 0,F (Mar-15), Ts-Mar-15
10,
Caleulate the Gram Equivalent weights of KMno, with different conditions.
11,*
12,"
The densityof3M solution of NaCI is 1.25g.mL, Caleulate molality ofthe solution.
Calculate the mass ofNa,CO, required to prepare 250ml of0.5N solution.
13. How much minimum volumc ofCO at STP is needed to react completely with 0.112LofO. at
pressure and 127 to give CO,
14, Balance ofthe following cquation by the oxidation number method?
MnO +Cl, ’ MnO, +CI
15,. Define normality.(May-22) 6.3 gms ofoxalic acid is present in 500 ml of solution its
normalty is.
16. VERYSHORTANSWER QUESTIONS
How many number ofmoles ofglucose are present in 540 gms
ofglucosc? Mar-23
17
18
Calculate the weight of0. 1 mole ofsodium carbonate.
(TS-Mar-20)
Calculate the number ofmolecules present in 1.12x10 cce ofa gas at
(Jun-10)
STP
(C.c,-cubic centimneters=cm
19 What is a redox concept ? Give an example
20 What do you mean by significant figures?
21. The empirical formula ofcompound is CH,0 .Its molecular weight is 90.
Calculate the
molecular formula ofthe compound. TS-May-22,23 (Mar-13)
22. What are the disproportionation reactions? Give
examples.
23. What are comproportionation reactions? Give examples
24. What volume of CO, is obtained at STP by heating 4g of CaCO.! (Jur
25 How many (Jun-09,Mar-12)
significant figures are present in the following?
(a) 0.0025 (b) 208 (c) 5005 (d) 126.000 (c) 500.0 ()2.0034
26. Round up the following up to three significant figures.
(a) 34.216 (b) 10.4107 (c) 0.04597 (d) 2808
27. What volume ofH, at STP is required to reduce 0.795gm of Cuo to give Cu and
H,0?
28 Calculate the volume of O, at STP required to completely burm 100ml of acetylene.
29 Calculatethe cquivalent weights of CrO inAcid medium.
30 Calculate the oxidation number to the under lined elements.
(a) H,SO, (b) H,S,0, (c) CrO, (d) BrO, (e) KMnO, () Nallj PO,

NARAYANA Page.No.94
 QUESTION BANK
31 Asolution is prepared by adding 2gm ofa
percent of the solute. substance A to 18gm of water. Calculate the mass
32. Calculate the molarity ofNaOH in the solution prepared by dissolving (TS-Mar-19)
4gm in
250ml ofthe solution. enough water to fom
33 Define (Mar-18)
34 Define Mokrity,percentage
Normalit« May-22),
35 Calculate the equivalent weights ofthe molaity and molefraction
following
a) H,SO, c) Na,CO,
b) NaOH d) K,Cr0,
36, How many numbers of CaCO, moles present in 200grams of
CaCO,?(May-14)
37
Calcuate the oxidation number ofCr' in K,Cr,0, .or Cr,0 (Mar-17),Ts-Mar-17
38, Calculate the oxidation number ofMaganese (Mn) in MnO, (T-Mar-18)
39. Calculate the amount ofcarbon dioxide that could be produced when one mole ofcarbon is burnt
in 16 gofdioxygen (Mar-19) 7g No13b
40. Claculate the normality of oxalic acid solutions containing 6.3 g of H,C,0,,2H,0 in 500 ml
of solution.
(Mar-20)
THERMODYNAMICS
SHORTANSWER QQUESTIONS
81. State the first law ofthermodynamics. Explain its mathematical notation.
State and explain the Hess's law ofconstant Heat summation.
(May-22,Mar-23-vsaq) (Mar-12,14,15,17,18,20,Ts-Mar-15,18,19,20,23,May-22
P3,* Explain spontaneity ofa process in terms ofGibbs energy
State the second law ofthermodynamics and explain it.
What is entropy? Explain with examples. May-22 e heat capacity.
What are Chand C,? Show that C-C =R

D8,**
State
What isthe
t third law ofthermodynamics,(Mar- 9.VSAQ) What do you understand byi? (T-Mar-17)
Py ofreaction? Explain the standard enthalpy ofa reaction.
09)* What is the lenthalpy of formation explain wvith example. May-22
Define and explain the standard enthalpy of sublimation.
M.** Define and explain enthalpy of combustion.
12.* Derive the equation of W in isothermal reversible process.

13
VERYSHORTANSWER QUESTIONS
Define a system .Give an example
14 No heat is absorbed by the system fromthe surroundings, but work (w) is done on the
system. What type ofwall does the system have?
15.

16.
State the first law ofthe
thermodynamics.
What are intensiv and extensive properties GR (Ts-Mar-18,May-22)
(Mar-19)
17. Give the equation that gives the relationship between AU and AH
18 Is increase ofentropy the criterion for spontaneity. Why?

NARAYANA Page.No.95
 QUEST1ON BANK

JR CHEMISTRY equilibriumconstant.
Gibbsenergychangeand Calculatethe heat relensel
the
relationshipbetween CO,is-393.5kJ mol".gas Pa l64 (h-Mar-15)
Explain to
19
ofconbustionofcarbonfYom carbonand dioxygen
20. Enthalpy of35.2gofCO, 92.4kJ mol
uponforation 2NIH,AN
Given Nt3H fornation of NH,
gas?
21.
standard enthalpy of following data:
What is the offorntionofCH,OH, from the
enthalpy
22. Caleulatethe standard
AP-726 kJ mol
2H,0,, :
’ Co, t

coi AF393 kJ mol

CtOu ’
H,0,:AJP-286 kJ mol .
’ of AG?
H, ts What will be the value
10.
equilibrium constant for a reaction is
23 The
R=8.314 JK' mol,T-300K.
endothermic reactions? Mar-23
sign conventions forexothermic and
COMPOUNDS
24. What are the AND ITS
HYDROGEN
SHORTANSWERQQUESTIONS
peroxide, Whiek
ofpreparing hydrogen
equations, various methods
Discuss, with relevant chemical D,0,?(Sep-2000,Jun-06,May-07,Mar-02,05,07, l,12)
methods is useful to prepare
ofthese
that hydrogen peroxide can function as an oxidizing as wellas
justify
02* Writethe chemical reactionsto (Mar-03,04,06,08), Ts-Mar-18
reduing agent.
suitable examples (Mar-14,19), Ts-Mar-17,20
Explainthe following
03/* electron-deficient with (b)electron-precise hydrides.
hydrides (Mar-19)
(a) hydrides (Mar-19)
d) lonic
c) electron rich hydrides method and
terms hard water and soft water. Write a note on the () ion -exchange
Explain the
(ii) Calgon method for the removal ofhardness of water.
(May-22 Jun-02,Sep-08,15,Mar-18),Ts-Mar-15,19)
permanent hardness ofwater? Mention which ions causes the hardness of
05*. What is temporary and (May-14,Mar-15)
water.
06, Write a note on heavy water. TS-Mar-23 (Mar-13,17,23)
Wite afew lines onthe utility of hydrogen as afuel. the basis ofits electronic configuration.
08. Discuss the position ofhydrogen in the periodic table on Mar-20
isotopes?
09, Name the isotopes of hydrogen. What is the ratio of masses of these
Ts-May-22
VERYSHORTANSWER QUESTIONS
10 Name the isotopes ofhydrogen. What is the ratio ofthe masses ofthese isotopes?
11 Why is dihydrogen used in weldingofbigh melting metals ?
12 Explain the term "SYNGAS".
13 Whatis meant bycoal gasification ?Explain withrelevant, balanced equation

NARAYANA Page.No.9%
JRCHEMISTRY
QUESTION BANK
14
What do you mean by autoprotolysis? Give the equation to represent the
15. Water behaves as an amphoteric substance in the Brosted sense. IHow doautoprotolyis
you explain? of water
16 Mention any three uses ofH,0,?
17 Why H,O has a higher B.P than H,S
18, What is perhydrol and byperol?
19 Calcute the strength of 10 volume solution of H,0, ?
20. How many hydrogen bonded water molecules are associated in CuSO,.5H,0?
21. Define the term hydride ? How they are classified. (May-22)
Alkali and Alkaline earth metals(S-BLOCK ELEMENTS)
SHORTANSWER QUESTIONS
01,*** What do you know about Castner-Kellner process? Write the principle involved in it.

Given an account ofthe biological importance of Na' (IS-Mar-20)arnd k ions.

(Mar-18-VSAQ),T-Mar-17
03)*** Give an account ofthe biological importance of Mg'' and Ca (TS-Mar-20)
04.** Give an account ofthe properties ofwashing soda.
What is Plaster ofParis? Write a short note on it. (May-22) (Mar-17), Ts-Mar-17,20
06.
07. InDiscuss
what ways lithium shows similarities to magnesium in its chemical behaviour?
the variousreactions that occur in the Solvay process.
08. Write a few lines about cement.

09.
VERYSHORTANSWER QUESTIONS
Write completelythe electronic configurationsofK and Rb
10 Lithium reacts with water less vigorously than sodium.Give your reasons
11. (Ts-Mar-18)
Explain the biologicalimportance ofMagnesium &Calcium
12. What happens when magnesium metal is burnt in air?
13. Mar-23,Ts-Mar-15,18,23)
Write abalanced equation for the formation ofammoniated IIAmetal ions from the metals in
liquid ammonia.
14. Deseribe the importance of Plaster of Paris(Mar-18Xor)What is Plaster of Paris? write itsuses
15. Write the average composition ofPortland cement. (Mar-19)
16. Describe the important uses of caustic soda.
17 (Mar-15)
Describe the important uses of sodiumcarbonate TS-Mar-23 (Mar-20)
18 Describe the important uses ofquick lime
19 Why are alkali metals not found in the free state in (Mar-14)
nature (Mar-13,17)
20 Which is called milk ofmagnesia?Give its uses?
(Mar-15)
21. Write the properties of Washing soda.
(Mar-14)

NARAYANA
Page.No
 QUESTION BANK

JR CHEMISTRY
(May-14)
called as alkali metals (Ts-Mar-15,19)
22 Why are IA group elements
Mar-23
23. Why is gypsum added to cement?
strongly heated?
24. What happens, When caleium nitrate is
Give two uses ofi) Lithium ) Sodium
25.
calculate oxdation state ofK ?
26. Whay kO, is paramagnetic and metal hydroxides in water increases down the
group?
ofalkaline earth
27 Whay does the solubility carbonates and sulphates in water decreases dow
ofalkaline carth metal
28 Whay does the solubility
the group ? (Mar-20)
prepared in solvay process? (Mar-19)
29 Whay does potassium carbonate can't be (TS-Mar-19)
metal
30 Write any two uses of Mg
Lithium salts are mostly hydrated. why? (TS-May-22)
31. by the IIA elements? (TS-May-22)
32. What are the characterstic colours imparted May-22
balanced equation.
33. What happens, When Mg(NO,), is heated ?Give the
GROUP-13 ELEMENTS
SHORTANSWERQUESTIONS

Explain the structure ofdiborane.

(Sep-2000,Jun-04,06,May-07,Mar-2000,04,07,11, 15,17,19),Ts-Mar-15,18
02.*** How does diborane react with (May-12)
(a) H,0 (b) CO (c) N(CH,), (d)NH,
03.* Explain the structure ofboric acid.
P9 NO 276
Explain borax beadtest with asuitable example. (TS-Mar-19,20,23) (Mar-13,18,20)
05. Give two metho ds ofpreparation ofdiborane. Mar-23 (Mar-14)
06. What areelectron deficient compounds?Is BCl, an clectron deficient species. Explain.
TS-May-22
VERYSHORTANSWER QUESTIONS
07. How do you explain higher stabilityof TICI than TI CI,
08. Is boric acid a protic acid? Explain.
09 Explain inertpair effect (Mar-19) (Ts-Mar-17)
10 What is the hybridization ofBin diborane and borazine?
11 Givethe formula ofborazine. What is its common name? (Ts-Mar-17)
12 Give the formulae of (a) Borax (b) Colemanite
13. Sketch the structure oforthoboric acid

NARAYANA Page.No.98
 JR CHEMISTRY
QUESTION BANK
14 Write the structure of AlCl, as a dimer
15. Boron is unable to form BF ion-
explain
16. White fumes appear around the bottle ofanhydrous AICI, Give reason ?
17. Al reacts with dil HNO, but not with con HNO, why?
18. Give two uses ofAluminium?
19 Metal borides having gl are used as protective shield why?
20. What happend when boric acid is heated?
21 Explain why atomic radius of Ga is less than that of Al May-22
GROUP-14 ELEMENTS
SHORTANSWERQUESTIONS
Explain the difference in properties ofdiamond and graphite on the basis oftheir structure.
(Jun-04,Mar-07,23),Ts-Mar-17)
62 Why is diamond hard? TS-May-22 (Mar-11),Ts-Mar-15
03,* What are silicones? How are they prepared? Give one example, What are their uses? (Mar-15)
04 Write a note on (a) silicates so )zeolitesaA (c) Fullerenes
0S. What do you understand by Allotropy(Mar-19)) Inert pair effect (Mar-19Xc) Catenation
06.* Explain the structureofsilica. How does it react with (a) NaOH (b) HE

VERYSHORTANSWER QUESTIONS
07. Why is CO poisonous ? (Mar-13,18)
What is allotropy ?((Mar-19)Givethe crystallineallotropes ofcarbon.Mar-13,20 Ts may-22
09. How does graphite function as a lubricant (Jun-11,Mar-17), Ts-Mar-15,19,20
10 Graphite is a good conductor-explain AP,TS-May-22 (Jun-09,Mar-09,10)
11. Diamond has high melting point -explain. May-22,TS-Mar-23
12. Write the use ofZSM-5 (TS-Mar-19,20)
13. C-Cbond length in graphite is shorter than C-C bond length in diamond- explain
14. Diamond is used as precious stone - explain
15. SiF is known while SiCI is not - explain
16. Name any two man made silicates. (Mar-14)
17. How is water gas or blue gas prepared? (Mar-12,Mar-08,18)
18. How is producer gas prepared?
19. What is use ofdry ice? (Mar-15)
20 Give the use of CO, in Photosynthesis. (Mar-14)
21. Writethe hybridisation ofcarboninthefollowing (a) Co, (b) Diamond (c) Graphite
(d) Fullerene (May-14), Ts-Mar-18-SAQ,23
22 CCI, is notdissolved in water, but SiCI, dissolves why? give reason (May-14)

NARAYANA Page.No.99
 JR CHEMISTRY OUESTION BANK
23 Give four uses of CO,
24
What are metal carbonyles?
25 What is the effeet ofwater on tin?
26 Explain the structure of silica ?
27 Sio, is solid while CO, is gasexplain ?
28 Write any four uses of CO, gas.? (Mar-17)
ENVIRONMENTAL CHEMISTRY
VERYSHORTANSWERQUESTIONS
01. What is chemical oxygen demand (COD) ? (T-Mar-17) (Mar-14,23)

02. a) What is Bio chemical oxygendenmand (BOD)? (Mar-14),20,Ts-Mar-18,19,23

b) Give the possiable BOD values for clean water and poluted water.
03 Define Receptor? (Mar-15)
04 Name the najor particulate pollutants present in Troposphere
05 A) What is Green house effecet? It is caused by....nd.gases (Mar-14,20,T-Mar-i5.18.28
b) Mention the harmful effects caused by Gobal warming. (Mar-17)
06. Which bxides cause acid rain ?and what is its p# value? (TS-Mar-19)
07 Name two adverse eflects caused by acid rains (Mar-18),Ts-Mar-15,17
08
a) What is classical smog? and what is its chemical character (Oxidizing reducing)?
b) What is photo chemical smog? and what is its chemical character (Oxidizing reducing)?
09 What is PAN ? What effect is caused by it TS-Mar-23
10. How is ozone formed in the stratosphere?
Give thechenical equations involved in the ozone depletion by CF,CI,
12 What is ozone hole? Where was it first observed ?
13 Name three industrial chemicals that pollute water
What agrochemicals are responsible for water pollution ? (Mar-19)
Define the terms sink ,TLV (TS-Mar-20)& Receptor? (Mar-15,17,18)
16. What is Eutrophication?
17 What is polutant, contaminant, speciation
18 Mention the harmful effects caused due to depletion ofozone layer (Mar-15)
19. What is Bio-amplification?
20
21
25
23.
Define the term Green chemistry?
What are smoke and mist ?
Define the term soil pollution ?
Explain the following terms
AGROUP
) Atmosphere i) Biospherei) Hydrosphere ivy) Lithiosplhere (Mar-19)
Name the common components of photo chemical smog?
v)Troposphere vi) Stratosphere

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