CHM202 2017

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Question
Type  Question  A  B  C  D  Answer  Remark 

eExam
FBQ Random error Indeterminate
type of error cannot be error
avoided.

eExam
FBQ Treatment of Preparation of
help in eliminating the sample sample
possible sources of
contamination and sample
degradation that could lead
to sample destruction, and
ensure the homogeneity of
samples.

eExam
FBQ Observing sudden colour Titration
change in the indicator is reaction
one of the methods of
detecting completion of a

eExam
FBQ The decrease in power of Concentration
the beam of a
monochromatic radiation
when it passes through
absorbing specie depends
upon the

of the absorber and the


length of the path
transverse by the beam.

eExam
FBQ The device in which Electrochemical
electrolysis of solution cell
takes place is known as

eExam
FBQ In redox titration Potentiometer

measures in voltage the


concentration of species in
solution.

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eExam
FBQ The part of the component Monochromator
of a spectrometer that
selects a narrow band of
wavelength from the source
spectrum is called

__.

eExam
FBQ Concentration
reduce the water content of
a sample material

eExam
FBQ In redox titration, half-cell Electrode
reaction occur at each

_.

eExam
FBQ Indicator
is a compound with a
physical property (colour)
which changes abruptly
near the equivalence end
point.

eExam
FBQ Random error Indeterminate
type of error are indicated error
by small differences in
successive measurements
made by the same analyst
under almost identical
experimental conditions.

eExam
FBQ Stratified
is a method of sampling sampling
employed when population
is heterogeneous with
respect to the variables
(parameters) under study.

eExam
FBQ A typical electrolytic cell is Electrolyte
made up of electrodes, salt
bridge and

_.

eExam
FBQ The process by which Peptization
precipitates revert to the
colloidal state is called

_.

eExam
FBQ Buffer capacity
is defined as the maximum
amount of an acid or base
that can be added to a
buffer system without
causing a change or
appreciable change in pH
of a system.

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eExam
FBQ The process by which a Digestion of Digestion
precipitate is allowed to precipitate
stand in the solution from
which it was precipitated is
known as

eExam
FBQ pH of 7.0 means the Neutral
solution is

__.

eExam
FBQ In volatilization gravimetric Gas
analysis, the substance to
be determined is separated
in a

form from the reminder of


the sample.

eExam
FBQ On the pH scale acidity 0.0, 6.00 0.0, 6.00
increases from

TO

eExam
FBQ Round off 9.43 to two 9.4
significant figures

eExam
FBQ Errors Error
affect the precision and
accuracy of a measured
quantity thereby raising
questions on the integrity of
the reported values.

eExam
FBQ Standardisation
is a process by which the
precise concentration of a
solution is determined.

eExam
FBQ Dissolution
involves converting sample
material in solid form to
solution.

eExam
FBQ The potential of hydrogen in pH
a system is known as

_.

eExam
FBQ Sampling
can be described as the
operations involved in
procuring a laboratory size
that is a true representative
of “a whole lot” for a
particular analytical
exercise.

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eExam
FBQ Precipitates are treated to Drying heating
have it in a form suitable for
weighing by

_.

eExam
FBQ Composite
types of sample provide samples
more representative
sampling of heterogeneous
matrices in which the
composition of the analyte
of interest may vary over a
period of time and or space.

eExam
FBQ Standard
measures how closely the deviation
data cluster about the
mean.

eExam
FBQ Buffer solution
is a solution that resists
changes in pH when small
amount of acid or base is
added or when dilution
occurs.

eExam
FBQ Dry ashing Ashing
involves heating the
materials at high
temperature $$\left(400 –
700^{o)c\right)$$ In a
muffle furnace until it is
turned to ashes.

eExam
FBQ Precision
is defined as the degree of
agreement between
replicate measurements of
the same quantity.

eExam
FBQ At elevated/high High
temperature in a fluid
system the pH turns out to
be

__.

eExam
FBQ pH of 5.4 means the Acidic
solution is

__.

eExam
FBQ Precipitates are washed Coprecipitate Impurities
after filtration so as to impurities
remove any

_.

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eExam
FBQ The amount of radiation Beer’s
absorbed by a sample is
determined by

law.

eExam
FBQ The region of the Near ultraviolet
electromagnetic spectrum region
that extends from about
200 – 380 nm is known as

__.

eExam
FBQ The statistical tool used Student’s t Test Student’s t Test
most frequently to compare
the mean value from
experimental procedure is
known as

_.

eExam
FBQ Alkalinity increases from 8.0 – 14.0 Eight to
fourteen
on the pH scale.

eExam
FBQ During digestion of a Coprecipitation
precipitate, the process
whereby precipitates carry
down from the solution
other constituent that cause
contamination of the
precipitate is called

_.

eExam
FBQ The type of titration used in Precipitation
determining the titration
concentration of analyte
which precipitate with the
anion or titrant is known as

eExam
FBQ Random
is a method of sampling in sampling
which each item of the
population has equal
chance of being included in
the samples.

eExam
FBQ The tendency to oxidise or Reduction
reduce depends on the potential

of a substance.

eExam
FBQ The actual point when a End point
reaction is observed to be
complete is known as

__.

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eExam
FBQ Complexometric
is an analytical method titration
which is used to determine
larger number metals that
form soluble salt or slightly
dissociated complexes.

eExam
FBQ Gravimetry Gravimetric
is an analytical method that analysis
is based upon the
measurement of the weight
of known composition.

eExam
FBQ The sample container Transparent
which holds the sample to
be analysed by a
spectrometer must be

in the wavelength region


being measured.

eExam
FBQ Ultraviolet region extends 10 to 380 nm
from

__.

eExam
FBQ The end point of a Redox titration Oxidation-
reduction
can be determined by the titration
use of electrode to measure
potential, or use of self
indicator or use of starch
indicator.

eExam
FBQ The difference between the Titration error
equivalence point and end
point is known as

__.

eExam
FBQ Primary
is the purest form of standard
reagent which is used to
prepare a standard
solution.

eExam
FBQ In titration reaction, the end Equivalence
point should coincide with point
the

eExam
FBQ Volumetric
is an analytical technique analysis
that deals with reactions
between measured
volumes of a reagent
against the test substance
called analyte in a
stoichiometric manner

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eExam
FBQ Sample Samples
brought to the laboratory
require further treatment
before analysis
commences.

eExam
FBQ Samples composed of Integrated
mixture of grab samples samples
collected from different
points simultaneously or as
nearly so as possible is
known as

__.

eExam
FBQ The nature of a Sample

must be the same with that


of the population and must
remain so throughout the
analytical exercise.

eExam
FBQ Errors inherent in the Methodic error
analytical method or
procedure used is known
as

_.

eExam
FBQ Mathematical error in the Operative error
calculation of
measurements or prejudice
in estimating measurement
is known as

__.

eExam
FBQ Instrumental
occurs when faulty error
equipment, weight as well
as glassware used are not
well calibrated or wrongly
calibrated.

eExam
FBQ Errors that can be Systematic error
determined and corrected
are known as

__.

eExam
FBQ Error
is termed controllable and
uncontrollable variations
observed when comparing
the measured values to the
true value.

eExam
MCQ Molecules can absorb Molecular Spectroscopic Vibrational Excitation C
radiation by transition transition transition transition
_______________.

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eExam
MCQ The amount of radiation Related Transmitted None of the All of the above B
absorbed by a sample can quantitatively to without above
be _________. the absorption
concentration of
analyte in
solution

eExam
MCQ When atoms or molecules The atoms or There will be The atoms or The atoms or C
absorb radiation, molecules change in state molecules molecules
____________ . moves to lower in the number of moves to higher remains in the
internal energy the atoms or internal energy same energy
level molecules level level

eExam
MCQ ___________ is an Methyl orange Erichrome black Starch Ferroin B
example of a metal-ion T
indicator.

eExam
MCQ Upon absorbing a photon of Loss back the Moves to the Moves to the Moves to higher D
energy from radiation, photon transit state lowest electronic
atoms or molecules electronic energy state
__________. energy state

eExam
MCQ EDTA is hexaprotic The number of The number of The number of The number of A
$$H_{6}Y^{2+}$$ because acidic hydrogen carboxyl lost ammonium lost nitrogen atom
_________. atom lost upon upon complete upon complete lost upon
complete metal metal complex metal complex complete metal
complex formation is six formation is six complex
formation is six formation is six

eExam
MCQ ____________ is a form of Precipitation Complexometric Acid-base Oxidation- B
volumetric analysis in which titration titration titration reduction
the formation of a coloured titration
complex is used to indicate
the end point of the titration.

eExam
MCQ Which of the following Read out, Sample, source, Source, Monochromator, C
options below shows the detector, monochromator, monochromator, source, sample,
correct arrangement of a sample, detector and sample, detector and
spectrometer? monochromator read-out. detector and read-out.
and source. read-out.

eExam
MCQ The region of the Macrowave Visible region Ultraviolet Infrared region B
electromagnetic spectrum region region
that extends from 380 nm
to about 780 nm is called
__________.

eExam
MCQ In the titration of a strong The pH is The pH is The pH is The pH is A
acid against strong bases, determined by determined by determined by determined by
before equivalence point the excess of dissociation of the excess H+ equilibrium
__________. OH in the water. in the solution. between OH
solution. and H+.

eExam
MCQ Good solvent for many Aqueous Water Weak mineral Strong mineral D
organics is _______. solutions acids acids

eExam
MCQ _____________ law states Rutherford’s Schroedinger’s Beer’s Hess C
that “when a
monochromatic radiation
passes through absorbing
specie, the power of the
beam is progressively
decreased as more energy
is absorbed by the particle”.

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eExam
MCQ _________ consist of a Buffer solution Double salt Acidic salt or None of the A
mixture of a weak acid and basic salt above
its salt, or a weak base and
its salt.

eExam
MCQ The pH of most solution is 0.0 – 0.7 0.0 -14.0 0.7 – 14.0 8.0 – 0.0 B
in the range of
____________.

eExam
MCQ When a precipitate is It is completely It decomposes It is ashed A constant D
heated, it is continued until dry weight is
___________. achieved

eExam
MCQ Filterability of a precipitate Exist in solid Is devoid of Is soluble Contain larger D
obtained from gravimetric form impurities crystals
analysis is enhanced if the
precipitate ____________.

eExam
MCQ What happens when the The precipitate Larger crystals Smaller crystals The quantity of B
precipitate obtain from dissolves grow at the grow at the precipitate
gravimetric analysis is expense of expense of obtained
allowed to stand? small crystals larger crystals increases

eExam
MCQ Which of the following is not Drying Precipitation Extraction Washing C
a step of gravimetric
analysis?

eExam
MCQ Peptization of a precipitate Washing the Heating the Filtering the Washing the D
can occur by obtained precipitate precipitate precipitate with
____________. precipitate with water
an electrolyte

eExam
MCQ In gravimetry, precipitation Supersaturation, Crystal growth, Nucleation, Supersaturation, D
occurs through crystal growth nucleation and supersaturation, nucleation and
___________. and nucleation supersaturation and crystal crystal growth
growth

eExam
MCQ The commonest way of Dissolution Introducing Dissolution Heating the B
removing interferences in reagent that sample to
gravimetry is by selectively mask remove
__________. the interfering interfering
substances substances that
are volatile

eExam
MCQ The product obtained from Solubility Quantity None of the All of the above A
gravimetric analysis is of above
limited ____________.

eExam
MCQ Gravimetry is a Qualitative Quantitative Qualitative and Spectroscopic B
___________ method of quantitative
analysis.

eExam
MCQ The component of a Detector Read-out Source Monochromator A
spectrometer that converts
radiant energy to electrical
energy is called
____________.

eExam
MCQ The absorption of radiation Qualitative Qualitative or Quantitative Detection of B
can be used either for analysis quantitative analysis atoms or
______________. analysis molecules

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eExam
MCQ The second step of the Absorption of Atomic or Relaxation Transit state C
process of absorption of radiation molecular
electromagnetic radiation transition
by some species is called
____________.

eExam
MCQ The absorption of Four-step Three-step Five-step Two -step D
electromagnetic radiation
by some species is
considered to undergo a
____________ process.

eExam
MCQ The molecules at ordinary Excited state Transit state Lowest Atomic or C
room temperature is electronic molecular state
considered to be at energy state
_____________.

eExam
MCQ There are how many basic Two Three Four One B
processes by which
molecules can absorb
radiation?

eExam
MCQ _________ is converting Sampling Mixing solids Dissolution Sample D
the accessible sample laboratory decomposition
matrices to the form which samples
is accessible to instrument.

eExam
MCQ _________ is a method of Quartering Coning Quartering and Flattening and C
sample selection which coning quartering
involves pouring the sample
so that it takes on a conical
shape, flattening the conical
shape out into a cake, the
cake is then divided into
quarters and two quarters
which face opposite one
another are discarded
whilst the other two are
combined and constitute
the reduced sample.

eExam
MCQ Grinding and crushing of a Reduce the size Mix the samples Convert sample Reduce the A
sample does which of the of particles of in order to material in solid water content of
following? sample ensure random form to solution. a sample
materials and distribution of material.
increase the the components
surface area. in the analytical
sample.

eExam
MCQ In gravimetric analysis, the Extracted with Chemically Dissolved in an Extracted with B
sample to be determined is an organic reacted with a aqueous solvent an inorganic
_______________. solvent to obtain reagent to yield and filtered to solvent to obtain
a precipitate a precipitate obtain the the precipitate
precipitate

eExam
MCQ The _________ can be Frequency Electromagnetic Photon Wave number B
arbitrarily broken down into spectrum
different region according to
wavelength.

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eExam
MCQ _________ is a branch of Titrimetry Spectroscopy Redox titration Complexometry B
analytical chemistry that
deals with the study of
concentration of analyte as
a function of amount of
radiation absorbed when
electromagnetic radiation
from appropriate source is
directed at it.

eExam
MCQ The number of Non metals electrodes ions Ligands D
_____________ that
complexes metals depends
on the coordination number
of the metal.

eExam
MCQ _________ are complexing Ligands Electrodes Salt Electrolytes A
agents that bind with metals
to form complexes.

eExam
MCQ Which of the following is not Sample label Sample Assignment of Sample delivery B
among the chain of custody collection sample for to the laboratory
procedure? analysis

eExam
MCQ Which of these statements Precision helps Significant The smaller the Average C
is true? in expressing figure is a standard deviation is a
confidence method of deviation, the method of
interval showing more closely the expressing the
dispersion from data are minimum
central values. clustered. number of digit
of a data.

eExam
MCQ __________ enables Performance of Statistical None of the All of the above B
analytical chemist to accept replicate analytical tools above
conclusions that have high measurements
probability of being correct
and to reject conclusions
that are doubtful.

eExam
MCQ _______ are single Composite Integrated Grab samples Non composite C
samples collected at samples samples samples
specific spot at a site over a
short period of time.

eExam
MCQ ________ is designed to Correlation Coefficient of F-test Variance C
investigate whether there is variation
a significant difference
between two method based
on their standard deviation.

eExam
MCQ __________ cannot be Random error Determinate Systematic error Controllable A
predicted or estimated. error error

eExam
MCQ ________ is a form of Precipitation Complexometric Acid-base Oxidation- D
volumetric analysis which titration titration titration reduction
involves the transfer of titration
electrons from one
substance to another.

eExam
MCQ The magnitude of random Using a well Replication of Exercising Using different B
errors can be reduced by calibrated experiment carefulness analytical
_________. equipment during the methods to
experiment perform the
same
experiment

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eExam
MCQ Co-precipitation with Operative error Methodic error Instrumental Random error B
impurities, incomplete error
reaction, impurities in the
reagents used is an
example of __________.

eExam
MCQ Characteristics of a A method must The reaction of Reaction of the All of the above. D
standard solution include exist for the standard standard
________. detecting the solution with the solution with
equivalence analyte must be analyte should
point between describable by be rapid.
the standard equation.
solution and
analyte.

eExam
MCQ ______ are also known as Random error Systematic error Uncontrollable Controllable A
indeterminate errors. error error

eExam
MCQ Which of the following is Treatment or The chain of All of the above None of the A
true? preparation of custody above
sample converts procedure is not
the sample from helpful in
the nature in identifying the
which it exists at source of
the site of contamination
sampling to the of a sample.
form in which it
can be
analysed.

eExam
MCQ The titrand is The reagent The solvent The solvent The analyte in a D
___________. added from used in making used in diluting conical flask to
burette to the a solution of the the acid. which reagent in
analyte in a base. the burette is
conical flask. added to.

eExam
MCQ Completion of a titration Increase in the Decrease in the Observation of All of the above. C
reaction can be detected by volume of the volume of the marked change
____________. analyte in the reagent in the of pH in the
conical flask. burette titration of an
acid with a
base.

eExam
MCQ Using an incorrectly Random error Variation in Systematic error Uncontrollable C
standardised pH meter in measurement error
an experiment will introduce
________ .

eExam
MCQ Which of these statements In titration In titration Titration Titration C
is not true? reaction, there reaction, there reaction need reaction should
should be no should be not be rapid. be quantitative.
side or parallel known reaction
reaction. pattern between
the analyte and
titrant.

eExam
MCQ The titrant is __________. The reagent The solvent The solvent The analyte in a A
added from used in making used in diluting conical flask to
burette to the a solution of the the acid. which reagent in
analyte in a base. the burette is
conical flask. added to.

eExam
MCQ The likelihood that the true Confidence limit Confidence Confidence Accuracy B
value falls within a range is level interval
called ________.

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eExam
MCQ Write 92500 as 3 significant $$9.25 x $$9.250 x 925 0.925 A
figures. 10^{4}$$ 10^4$$

eExam
MCQ Which of the following is not Analysing Analysing blank Using different By operators of A
a method used for the samples of samples analytical varying
prediction and correction of unknown methods to capabilities in
systematic error. composition measure the different
same quantity laboratories
carrying out the
same analyses.

eExam
MCQ A miniature replica of the Grab sample Composite Gross sample Integrated C
bulk of materials to be sample sample
analysed is called
___________.

eExam
MCQ A good _________ must Raw material Sample Analysis Result B
have the same
characteristic or features
with that of the original
population from where it is
selected.

eExam
MCQ The range within which the Coefficient of Accuracy Confidence limit Confidence D
true value might fall within a variation interval
given probability is known
as?

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