MONODENTATE LIGAND BIDENTATE LIGAND CHELATE LIGAND GEOMETRICAL ISOMERISM OPTICAL ISOMERISM

COO- 1 M(AA)
X-- Halido 1) Oxalato 1) EDTA4-, en, ox 1) [Ma2b2] - 2 (cis + trans) 3
Anionic

COO-
OH- - Hydroxo
2 Optical isomers (d cis + l cis)
2) greater Stability
NO2- - Nitrito
2) Ethane-1,2-diamine[en] 2) [Ma2 bc] - 2 (cis + trans)
H2N-CH2-CH2-NH2 2 M(AA) B2
2
SO42- -Sulphato
WERNER’S THEORY 3) [Mabcd] - 3
Total 3 Stereoisomer (d cis + l cis + trans)
O2-- Oxo(Oxido)
S2-- Sulphido POLYDENTATE LIGAND 1) 1 Valency - O.N
0
4) [Ma4b2] / [Ma4bc]- 2 (cis + trans) VBT
1) Trien,N(CH2CH2NH2)3- Tetradentate 2) 20 Valency - C.N SPECTROCHEMICAL SERIES
5) [Ma3b3]- fac & mer
Neutral

H2O- Aqua 2) Ethylene Diamine Tetra Acetato [EDTA] I-<Br-<SCN-<Cl-<F-<C2O42- <H2O

<NCS- < EDTA4-<NH3<en <NO2-<CN-<CO
NO- Nitrosyl -
OOCCH2 CH2COO-
C.N=6 6) [Ma2b2c2]- 5 dsp2 Square planar
NH3 - Ammine
CO -Carbonyl - CH2COO-
[Pt(NH3)5Cl]Cl3 [ML4]
OOCCH2 7) [Mabcdef]- 15 sp3 Tetrahedral
4O Atoms 1) 1 Valency - O.N = 4
0
sp3d
Donor -
2N Atoms 2) 20 Valency - C.N = 6 8) [M(en)2b2] or [M(en)2bc]-2
}
Cationic

3) AgCl Formed per mole of [ML5] Trigonal bipyramidal

dsp 3
complex 3
NO2+- Nitronium AMBIDENTATE LIGAND sp3d2

}
4) Total ions per mole of complex - 4
NO+- Nitrosonium
1) NO2- 2)SCN- [ML6] Octahedral

d2sp3

PHYSICS
COORDINATION COMPOUNDS WALLAH
APPLICATION OF
UNPAIRED ELECTRONS - PARAMAGNETIC CFT CFSE= a x -(0.6 t) + b x(0.4 t ) + np
PAIRED ELECTRONS - DIAMAGNETIC 1) Octahedral - Ligand approaches
along the axis (eg> t2g)
here a,b are number of electrons in low
energy and high energy d-orbitals OMC ORGANO METALLIC COMPOUNDS
1) Ziegler Natta Catalyst is used in
= n(n+2) 1) σ bonded - RMgX(Grignard reagent) polymerisation of alkene
eg HIGH SPIN COMPLEX LOW SPIN COMLEX

1=1.73 BM +
3∆
0
∆ 0
< Pairing Energy ∆ > Pairing Energy
0
- R2SiCl2 TiCl4 + AlEt3
∆0
π bonded - Ferrocene
5
2=2.84 BM 2) 2) Wilkinson’s Catalyst is used in
3=3.87 BM 2 For calculation of n, Crystal field stabilisation energy
− ∆
hydrogenation
3) σ & π bonded- Metal Carbonyls
Average energy of 5 0 consider newly formed pairing only
4=4.90 BM d-orbitals
t 2g
5=5.92 BM Mononuclear- [Fe(CO)6] [{(C6H5)3P}3Rh]Cl
CFSE
Splitting of d-orbitals in
octahedral crystal field.
[NiCl4]2- - sp3,Tetrahedral n=2 [Mn(CO)6]+ < [Cr(CO)6] < [V(CO)6]- APPLICATION OF
[NiCO4] - sp3,Tetrahedral n=0
CFSE= a x (- 0.4 0 )+ b x(0.6 0) + np
1) Stability ∝ CFSE B.O. B.L. B.O. B.L. COORDINATION COMPOUNDS
[Ni(CN)4]2- - dsp2,Sq. planar n=0 -4
2) ∆0 > ∆t , ∆t = ∆ (w.r.to C-O bond)
9 0 1) Cisplatin ([Pt(NH3)2Cl2]) is used as an
H2O act as SFL with Co3+
2)Tetrahedral -Ligand approaches 3) [Fe(CN)6]4- < [Fe(CO)6] Back bonding anticancerous agent
b/w the axis (t2> e) 2) EDTA is used in Lead poisoning
4) Jahn Teller distortion by - d4, d7,d9 π∗
Cr -
3+ forms d sp2 3
( π 3) Copper and iron poisoning-
n= stability constant) π
t2
4d and 5d metals with all ligands
n
penicillamine & deferoxamine
6) Color of d-d transition, E∝ π
act as SFL
2
∆
5 t ∆t =
-4
∆ λ m C≡O 4) Vitamin B-12 - Cobalt
9 0

[Pt(CN)4 ] [Pt(Cl)4 ] [Pd(Cl)4 ] =dsp (diamagnetic)

2- 2- 2- 2
3
[Co(en)3] < [Co(NH3)6] < [Co(H2O)6]
3+ 3+ 3+
5) Chlorophyll - Magnesium
Average energy of − ∆ π
d-orbitals
5 t
E λ (E = energy of d-d transition) E λ 6) Carboxy peptidase- Zinc
C2O42- act as SFL with Co3+ e Synergic Bonding
d-orbitals free ion
F- act as SFL with Ni4+ Splitting of d-orbitals in
tetrahedral crystal field.