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DIWALI ASSIGNMENT
(SRG - ENTHUSIAST)

[Medium : English]

INDEX
ORGANIC CHEMISTRY

1. Hydrocarbon

2. Halogenderivatives

3. Aldehyde, Ketones & Carboxylic Acid Derivatives

4. Alcohol, Phenol, Ether

5. Biomolecules

6. Amines

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SUBJECT : CHEMISTRY
Topic : HYDROCARBON

1. Which of the following is incorrect about ethyne? 5. Which of the following statement is incorrect?
(1) Ethyne is a linear molecule Anhy. AlCl3 /HCl
n − Hexane −−−−−−−−−−−→ Branched
(1)
(2) In industries, ethyne is prepared by treating chain alkanes
calcium carbide with water 2 3 Cr O or V O
2 5
(2) n - Hexane −−−−−−−−→ Benzene
(3) Electron cloud between two carbon atoms or MO2 O3 , Δ
Ni
of ethyne is cylindrically unsymmetrical (3) CH4 + H2 O −→ CO2 + H2
Δ
about the internuclear axis 773K
(4) C6 H14 −−−→ C4 H8 + C2 H6
(4) Each carbon of ethyne has two unhybridised p-
orbital which are perpendicular to each other. 6. Isopropyl alcohol is obtained by reacting which
2. 2 - Methyl butane on reacting with bromine in of the following alkene with Conc. H2SO4 and
the presence of sunlight gives mainly H2O ?
(1) 1 – Bromo 3 – Methyl butane (1) Ethylene (2) Propylene
(2) 2 – Bromo 3 – Methyl butane (3) 2-Methyl Propene (4) Isoprene
(3) 2 – Bromo 2 – Methyl butane 7.
(4) 1 – Bromo 2 – Methyl butane Product is :-
3. Chlorination of Methane doesn't occur in dark
because
(1) Methane can form free radical in presence (1) (2)
of sunlight only
(2) To get chlorine free radicals from Cl2 molecules
energy is required. It can not happen in dark
(3) Substitution reaction can take place only in (3) (4) Both (1) and (2)
sunlight and not in dark.
(4) Termination Step can not take place in 8.
dark, it requires sunlight
4. Assertion : Iodination of alkanes is reversible. Product will be :
Reason : Iodination is carried out in presence of
HNO3.
(1) Assertion is correct, reason is correct, (1) (2)
reason is a correct explanation for assertion
(2) Assertion is correct, reason is correct, reason
is not a correct explanation for assertion (3) (4)
(3) Assertion is correct, reason is incorrect.
(4) Assertion is incorrect, reason is correct.
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9. Reaction which is used to detect the position of 12.
the double bond in alkene

(1) Oxidation
(1) (2)
(2) Ozonolysis

(3) Electrophilic addition Reaction

(3) (4)
(4) Free radical addition Reaction
10. Which one is correct structure of "A" 13.

Y is :-

(1) (2) (1) (2) Ph3C – OH

(3) (4) Me3C – OH

(3) (4)
14. Find major product (A) & (B) of following reactions,
Hg 2+ /H +
Ethyne + H2 O −−−−−−→ (A) ;
333K

dil. H2 SO4
Hg 2+ /H +
11. −−−−−−→ A. Pr opyne + H2 O −−−−−−→ (B)
333K
(1) A → Ethane, B → Propane
correct statement is :- (2) A → Ethanal, B → Propanal
(3) A → Ethane, B → Propene
(1) On dehydration of A, gives alkene (major (4) A → Ethanal, B → Propanone
product) which can show stereoisomerism. 15. Propyne on Polymerisation gives
(2) A is optically active alcohol and contain (1) Mesitylene (2) Benzene
(3) Ethyl benzene (4) Propyl benzene
two chiral carbon.
16. Ammonical silver nitrate solution form a white
(3) On hydrogenation of dehydrated product of precipitate easily with
A gives optical active compound. (1) CH3C ≡ CH (2) CH3C ≡ C – CH3
(4) A is optically inactive alcohol. (3) CH3CH = CH2 (4) CH2 = CH2
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17. Assertion : Staggered conformation of ethane is most 21. Assertion : Boiling point of n-pentane is higher
stable while eclipsed conformation is least stable. than 2,2-dimethyl propane.
Reason : Staggered form has the least torsional strain Reason : There is steady increase in boiling point
and the eclipsed form has the maximum torsional
strain with increase in molecular mass.
(1) Assertion is correct, reason is correct, (1) Assertion is correct, reason is correct,
reason is a correct explanation for assertion reason is a correct explanation for assertion
(2) Assertion is correct, reason is correct, reasion (2) Assertion is correct, reason is correct, reason
is not a correct explanation for assertion
is not a correct explanation for assertion
(3) Assertion is correct, reason is incorrect.
(4) Assertion is incorrect, reason is correct. (3) Assertion is correct, reason is incorrect.
18. The difference in potential energy of ethane in (4) Assertion is incorrect, reason is correct.
between eclipsed and staggered form of ethane-
22.
(1) 4 kJ/mol (2) 12.5 kJ/mol ; Z is :-
(3) 2 kJ/mol (4) 44 kJ/mol
19. Select the correct Statement . (1) (2)
(I) Ortho-and para-directing groups increase electron
density at ortho-and para-positions mainly. (3) (4)
(II) Meta-directing groups increase electron density
at meta-position mainly. V2 O5 ,Al2 O3 CH3 COCl
(III) Meta-directing groups decrease electron density 23. n-Hexane −−−−−−−→ A −−−−−−→ B
Δ AlCl3
at ortho para position mainly. Zn−Hg/Conc.HCl NBS
(IV) Ortho-and para-directing groups decrease −−−−−−−−−−−→ C −−−→ D
electron density at meta-position. Identify D :-
(1) (I) & (II) (2) (I) & (III)
(3) (III) & (IV) (4) (II) & (IV) (1) (2)

20.

The possible compound A is. (3) (4)

24. Arrange the following compounds in the order of

(1)
decreasing reactivity towards electrophilic
substitution reaction.

(2)

(3) (1) IV > I > II > III (2) I > II > IV > III
(3) I > II > III > IV (4) I > III > IV > II
(4) Both (2) and (3)
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Topic : HALOGENDERIVATIVES

25. Assertion : 1-bromobutane on reaction with sodium 28. Correct order of rate of given reaction is :
ethoxide in ethanol gives 1-butene as a major product.
Reason : 1-butene is more stable than 2-butene
(1) Both assertion and reason are true and reason
is the correct explanation of assertion.
(2) Both assertion and reason are true but reason
is not the correct explanation of assertion.
(3) Assertion is true but reason is false.
(4) Both assertion and reason are false.
26. Which of the following reaction produces most
stable alkene.
(1) r3 > r2 > r1 (2) r1 > r2 > r3
(1) (3) r2 > r1 > r3 (4) r1 > r3 > r2

29. Which has highest melting point

(2)

(1)
(3)

(2)
(4)

27. In given reaction which complex is not formed-

(3)

(4) All have same melting point.

30.
(1) (2)

A and B are :
(3) (4) (1) Diasteromers (2) Enantiomers
(3) Identical (4) Position isomers

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31. A hydrocarbon C5H10 does not reacts with Cl2 in 34. Column-A Column B
dark but in presence of sunlight it gives one Finkelstein
monochloro product. Structure of hydrocarbon is. (A) C2H6 −Cl−−
2 UV light
−−−−−→ C2H5Cl (p) reaction
/

(1) + −
CuCl Photo
(B) C6 H5 N2 Cl −−−→ C6 H5 Cl (q)
HCl halogenation
(2) Swarts
(C) (r)
reaction
Sandmeyer's
(3) (D) (s)
reaction

(1) A-(q),B-(s),C-(p),D-(r)
(4)
(2) A-(q),B-(r),C-(p),D-(s)
32. (3) A-(r),B-(p),C-(s),D-(q)
H⊕
−−
→ product, (4) A-(s),B-(r),C-(p),D-(q)
35.
Major product is.

(1) (2) D is :-

(1) (2)

(3) (4)
(3) (4)

33. Among given compounds how many show

36. Which of the following is correct reaction-
positive iodoform test :-
(1)

(2)

(3)

(4)
(1) 3 (2) 4 (3) 5 (4) 6
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37. 40. H3 O ⊕
N2 O5 Cl2 /F e
H O CaC2 −−−→ P −F−e−tube
−→ Q −−−
→ R −−−−→ W , W is :
Q −−2→ R, R is : Δ
283 K

(1)
(1) (2)

(2)
(3) (4)

38.

(3)

is :
(1)
(4)
(2)

(3) 41. Which is incorrect about Freon ?

(1) Freon-12 (CCl2F2) is one of the most
(4)
common Freon in industrial use
39. Which of the following reaction represent correct (2) The Chlorofluorocarbon compounds of
major product. methane and ethane are collectively called
Freon.
(1) (3) They are extremely unstable.
(4) Freon-12 is manufactured from
tetrachloromethane by Swarts reaction.
(2)
42.

most suitable reagent for above canversion is-

(3) (1) I2 + NaOH, Δ then H3O ⊕
(2) KMnO4/H ⊕
Θ
Re d hot F e (3) Hot KMnO4/ O H
(4) H – C ≡ C – H −−−−−−−→
or Cu tube
(4) LiA ℓ H4
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43. The decreasing order of boiling points of alkyl 46. Arrange the following compounds :
halides is :
(1) RF > RCl > RBr > RI
(2) RBr > RCl > RI > RF
(3) RI > RBr > RCl > RF
(4) RCl > RF > RI > RBr
44. Match the compounds given in Column I with suitable
uses given in Column II : in decreasing order of their boiling points :
(1) I > III > II (2) II > I > III
Column-I Column II
(3) I > II > III (4) III > I > II
(Compound) (Uses)
47. Assertion : SN2 reaction of an optically active alkyl
(A) lodoform (1) Fire extinguisher halide with an aqueous solution of KOH always
(B) Carbon tetra chloride (2) Insecticide gives an alcohol with opposite sign of rotation.
Reason : SN2 reactions always proceed with
(C) CFC (3) Antiseptic inversion of configuration.
(D) DDT (4) Refrigerant (1) Assertion is correct, reason is correct;
reason is a correct explanation for assertion.
(1) A → 2 B → 4 C → 1 D → 3
(2) Assertion is correct, reason is correct; reason
(2) A → 3 B → 2 C → 4 D → 1 is not a correct explanation for assertion
(3) A → 1 B → 2 C → 3 D → 4 (3) Assertion is correct, reason is incorrect
(4) A → 3 B → 1 C → 4 D → 2 (4) Assertion is incorrect, reason is correct.
45. Assertion : Exposure of ultraviolet rays to human 48. Which of the following reaction proceeds with
causes the skin cancer, disorder and disrupt the SN2 mechanism.
immune system.
(1)
Reason : Carbon tetrachloride is released into air
it rises to atmosphere and depletes the ozone
layer.
(2)
(1) Assertion is correct, reason is correct;
reason is a correct explanation for assertion.
(2) Assertion is correct, reason is correct; reason (3)
is not a correct explanation for assertion
(3) Assertion is correct, reason is incorrect
(4)
(4) Assertion is incorrect, reason is correct.
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Topic : ALDEHYDE, KETONES & CARBOXYLIC ACID DERIVATIVES

49. For the reaction: 52. Identify A, B and C

Br2 /Red P KCN H O⊕
CH3COOH −−−−−−→ A −−−→ B −−3−→ C
H2 O Δ
(1) A = CH3COBr, B = CH3COCN, C = CH3COOH
The major product is:
(2) A = BrCH2COOH, B =

(1) C=

(3) A = BrCH2COOH, B = CH2 < (CN) COOH,

(2) C=
(4) A = Br2CHCOOH, B = Br2 C (CN) COOH,
C = C2H5COOH
(3)
53. Vanillin, salicylaldehyde and cinnamaldehyde
respectively have structures :
(4)
(1)
50. KOH (Conc)
2 HCHO −−−−−−−−→ Products
Δ
Select the correct statements
(a) Reactant does not have ∝ – H (2)
(b) Products formed contain alcohol and
potassium salt of acid.
(c) The reaction is disproportionation reaction (3)
(d) Hybridisation of carbon in reactant and all of
the products is same
(1) a, b, c, d
(4)
(2) Only a and b
(3) Only a, b, d Assertion : Carbonyl carbon is electrophilic and
54.
(4) Only a, b, c carbonyl oxygen is nucleophilic.
Reason : The carbon oxygen bond is polarised due to
51. Mixture of Ph – CHO and H-CHO is treated with higher electronegativity of oxygen relative to carbon.
conc. NaOH, then cannizzaro reaction involves- (1) Both Assertion & Reason are True & the
(1) Oxidation of HCHO Reason is a correct explanation of the Assertion.
(2) Readuction of HCHO (2) Both Assertion & Reason are True but Reason
is not a correct explanation of the Assertion.
(3) Reduction of PhCHO (3) Assertion is True but the Reason is False.
(4) Both (1) and (3) (4) Both Assertion & Reason are False.
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55. During nucleophilic addition reaction, the 60. Gem-dialkoxy compound is
hybridisation of carbonyl carbon changes from: (1) Hemiacetal
(1) sp2 → sp3 (2) sp3 → sp3 d (2) Bisulphite addition compound
(3) sp → sp2 (4) sp3 → sp2 (3) Acetal
56. A Compound (x) with molecular formula (4) Cyanohydrin
C5H10O gives positive 2,4-DNP test but negative
61. Assertion : Aldehyde is more reactive than ketone.
tollen's test. On oxidation, it gives a carboxylic Reason : Two alkyl groups reduce the
acid (y) with molecular formula C3H6O2. electrophilicity of the carbonyl carbon of ketone
Potassium salt of (y) undergoes kolbe's reaction more effectively than in aldehyde.
and gives (z). x, y and z are : (1) Both Assertion & Reason are True & the
(1) Pentan-3-one, propanoic acid, hexane Reason is a correct explanation of the Assertion.
(2) Both Assertion & Reason are True but Reason
(2) Pentanol, Pentanoic acid, octane
is not a correct explanation of the Assertion.
(3) 2-Methyl butanone, butanoic acid, hexane (3) Assertion is True but the Reason is False.
(4) 2,2 Dimethyl propanone, propanoic acid, (4) Both Assertion & Reason are False.
hexane 62. Correct order of reactivity in NAR of the
57. Bisulphite test is given by- following compounds:
(1) aldehyde (1) Ethanal < Propanal < Propanone < Butanone
(2) Aliphatic methyl ketone (2) Ethanal < Propanal < Butanone < Propanone
(3) Glucose (3) Butanone < Propanone < Propanal < Ethanal
(4) Both (1) & (2) (4) Propanone < Butanone < Ethanal < Propanal
58. How many compounds in given below can react 63.
with NaHSO3 + CrO3 + (CH3CO)2O → Q is-

, , , CH3 – CHO
(1) (2)
(1) 4 (2) 3
(3) 1 (4) 2 (3) (4) – O – CH2 – CH3
59.
64.
reagent
−−−−→

A & B are ? Reagent used is

(1) Alkane & amine (2) Alkane & Aldoxime (1) Hg2+, H2SO4 (2) Anhydrous CrO3
(3) Alkene & hydrazone (4) Alkane & Hydrazone (3) DIBAL-H (4) SnCl2 + HCl
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65. Rochelle salt is : 70. C6 H 6
CH3COOH + PCl5 → A −−−−−−−→ B
Anhy AlCl3
(1) CuSO4 C2 H5 MgBr
−−−−−−−→ C
(2) Sodium Potassium tartarate HOH

(3) Ammonical silver nitrate Product 'C' is ?

(4) Ethylene glycol ketal (1) CH3CH (OH) C2H5
66. (a) Aliphatic Aldehydes give reddish brown
ppt with Fehling's reagent. (2) CH3COC6H5
(b) Aromatic aldehydes do not give test with
Fehling's reagent. (3) CH3CH(OH) C6H5
(c) Fehling's solution is ammonical silver nitrate
solution.
Select the set of true statement?
(1) a, b, c (2) a, b (3) a, c (4) b, c (4)
67. Correct order of B.P. is-
(1) C3H7CHO > C4H9OH > C2H5–O–C2H5 > C4H10 71. The major product Z of the following reaction is-
(2) C4H9OH > C2H5–O–C2H5 > C3H7CHO > C4H10
(3) C4H9OH > C3H7CHO > C2H5–O–C2H5 > C4H10 Br2
−−−−−−−→ Z
(4) C4H10 > C4H9OH > C3H7CHO > C2H5–O–C2H5 CH3 COOH

68. Consider the following reaction-

(major)

Product P is ? (1)

(1) (2)

(3) (4) (2)

69. (1) DIBAL−H

−−−−−−−−−→
(2) H2 O

Product (P) 'P' is (3)

(1)

(2)
(4)
(3) CH3 – (CH2)9 – CH2 – OH
(4) CH3 – (CH2)9 – COOH
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Topic : ALCOHOL, PHENOL, ETHER

72. Benzyl alcohol is obtained from benzaldehyde by 77. Which of the following are used to convert
(2) Cannizzaro's RCHO into RCH2OH ?
(1) Fitting reaction
reaction (i) H2/Pd
(3) Kolbe's reaction (4) Wurtz reaction (ii) LiAlH4
73. Assertion : The bond angle in alcohol is slightly (iii) NaBH4
less than the tetrahedral angle. (iv) Reaction with RMgX followed by hydrolysis
Reason : In alcohol, the oxygen of – OH group is (1) (i) and (ii) only
attached to sp3 hybridised carbon atom.
(2) (i), (ii) and (iii) only
(1) Both Assertion & Reason are True & the
Reason is a correct explanation of the Assertion. (3) (ii), (iii) and (iv) only
(2) Both Assertion & Reason are True but Reason (4) (i) and (iii) only
is not a correct explanation of the Assertion. 78. The major product in the following reaction is
(3) Assertion is True but the Reason is False.
(4) Both Assertion & Reason are False.
74. Which one of the following is incorrect ?
(1) CO + 2H2
ZnO−Cr2 O3
−−−−−−−−→ CH3 OH (1) (2)
200−300 atm
573−673K
(2) C12 H22 O11 + H2 O −−−−−−→ C6 H12 O6 + C6 H12 O6
Zymase
Zymase
(3) (4)
(3) C6 H12 O6 −−−−−→ C2 H5 OH + CO2
(4) B.P. of ethanol is 351K 79. Assertion : Dehydration of alcohols with con.
75. Which one does not give dichromate test ? H2SO4 at high temperature give saytzeff alkenes
as a major product.
(1) (2) Reason : Dehydration of alcohols proceeds by
carbanion intermediate.
(3) (4) CH3 – OH
(1) Both Assertion & Reason are True and the
76. Predict the reducing agent in following reaction. Reason is the correct explanation of the
Assertion
(2) Both Assertion & Reason are True but the
Reason is not the correct explanation of the
(1) NaBH4 Assertion
(2) LiAlH4 (3) Assertion is True statement but Reason is
(3) Both (1) and (2) false
(4) H2, Pd, Δ (4) Both Assertion and Reason are False

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80. Which of the following is correct reaction. 84.
(i)NaOH , Δ Br2 CHCl3 Zn−dust
conc. H2 SO4 −−−−−+−−→ P −−−→ Q −−−−→ R −−−−−→
(1) C2H5 – OH −−−−−−−−→ CH2 = CH2 + H2O (ii)H CCl4 KOH
443K

S.
Product S is :
(2)

(1) (2)

(3)
(3) (4)

(4) All of these

85. Column-I Column-II
81. In the given reaction

(A) p. H3PO4/ Δ
Product (Major)

The product will be : (B) q. LiAlH4/H2O

(1) Cis-2-butene (2) Trans-2-butene
(3) 2-butyne (4) Buta-1, 3-diene
82. An industrial method of preparation of methanol is :
(1) Catalytic hydrogenation of carbon monoxide
in presence of ZnO – Cr2O3 catalyst.
(2) By reacting methane with steam at 900°C
with a nickel catalyst
(3) By reduction formaldehyde with LiAlH4
(4) By reacting HCHO with aqueous NaOH
solution
83. The reaction of ethyl iodide with sodium
ethoxide is :
(1) An electrophilic substitution reaction
(2) A nucleophilic addition reaction
(3) A nucleophilic substitution reaction
(4) A free radical substitution reaction
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(C) r. PCC in CH2Cl2
(D) s. SOCl2/Py
(1) A-p; B-q; C-r; D-s (2) A-s; B-r; C-q; D-p
(3) A-q; B-p; C-s; D-r (4) A-r; B-s; C-r; D-p
86. Assertion : Ethyl phenyl ether on reaction with
HBr form phenol and ethyl bromide.
Reason : Cleavage of C – O bond takes place on
ethyl-oxygen bond due to resonance the more
stable phenyl oxygen bond.
(1) Both Assertion & Reason are True & the
Reason is a correct explanation of the Assertion.
(2) Both Assertion & Reason are True but Reason
is not a correct explanation of the Assertion.
(3) Assertion is True but the Reason is False.
(4) Both Assertion & Reason are False.

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87. In the reaction 89.

Heated Product
−−−−→

Which of the following compounds will be Final product of above reaction is :

formed ?

(1) (2)
(1)

(2)
(3) (4)

(3)
90. Column-I Column-II

(4) (a) (P) Nitration

88. Match the columns : Dow's

Column-I Column-II (b) (Q)
process

(A) p. Resorcinol Kolbe

(c) (R)
reaction

Reimer
(B) q. Catechol (d) (S)
Tiemann

(1) a → P, b → Q , c → R, d → S
(2) a → S, b → Q , c → R, d → P
(C) r. Phenetole (3) a → S, b → R , c → Q, d → P
(4) a → Q, b → S , c → R, d → P
91. Arrange the following compounds in decreasing
order of their acidic strength :
Hydroquinone or 4 – Methylphenol 2,4,6 – trinitrophenol
(D) s.
Quinol I II
3 – Nitrophenol 3,5 – dinitrophenol
III IV
(1) A-p; B-q; C-r; D-s (2) A-q; B-p; C-s; D-r
(1) II > III > IV > I (2) II > III > IV > I
(3) A-s; B-p; C-q; D-r (4) A-r; B-q; C-r; D-s
(3) II > I > IV > III (4) II > IV > III > I
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92. In which reactions salicylic acid is formed as the
major product. 95. In the given reaction

CHCl3 H3 O ⊕

(I) −−−−→ −−−→ A is

NaOH

CCl4 H3 O ⊕

(II) −−−−→ −−−→ (1) (2)

NaOH

CO2 +NaOH H3 O ⊕

(III) −−−−−−−−→ −−−→

NaOH H3 O ⊕

(IV) −−−−→ −−−→ (3) (4)

(1) II, III (2) II, III, IV

(3) III, IV (4) I, IV, III 96. Match the column
93. Which of the following is not true in case of Column-I Column-II
reaction with heated copper at 300°C ?
A. o-nitro phenol p. pKa = 10.2
(1) Phenol → Benzyl alcohol
B. m-nitro phenol q. pKa = 10.0
(2) Secondary alcohol → Ketone
(3) Primary alcohol → Aldehyde C. p-nitro phenol r. pKa = 7.1
(4) Tertiary alcohol → olefin D. phenol s. pKa = 8.3
94. In which reaction given product is correct : E. o-cresol t. pKa = 7.2
(1) (1) A-p; B-q; C-r; D-s; E-t
(2) A-q; B-p; C-s; D-r; E-t
(2) (3) A-t; B-s; C-r; D-q; E-p
(4) A-s; B-q; C-t; D-r; E-p
97. Which of the following compounds shows
intramolecular hydrogen bonding ?
(3)
(1) p-Nitrophenol
(2) Ethanol
(4) (3) o-Nitrophenol
(4) Methanamine

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Topic : BIOMOLECULES

98. Which of the following is not true about amino 102. Which of the following is correct about invert
acids ? sugar ?
(1) They all are constituents of proteins. (1) Glucose contains a pyranose ring and
(2) Alanine having one amino and one carboxylic fructose contains a furanose ring.
group. (2) Fructose contains a pyranose ring and
(3) Most naturally occurring amino acids have glucose contains a furanose ring
D-configuration. (3) Both glucose and fructose contains
(4) Glycine is the only naturally occurring pyranose ring
amino acid which is optically inactive. (4) Both glucose and fructose contains
99. Proteins are found to have two different types of furanose ring
secondary structure. Then α -Helix and β -pleated 103. Which one of the following statements is not
sheet structure α -Helix structure of protein is true regarding (+) lactose?
stabilised by :
(1) on hydrolysis (+) lactose gives equal
(1) Peptide bonds
amount of D(+) glucose and D(+)
(2) Vander waals forces
galactose.
(3) Hydrogen bonds
(2) (+) lactose is a β -glucoside formed by the
(4) Diple-dipole interaction
union of a molecule of D(+) glucose and a
100. In zwitter ionic form, amino acids shows which molecule of D(+) galactose.
of the following behaviour?
(3) (+) lactose is a reducing sugar and does not
(1) Acidic (2) Basic
exhibit mutarotation.
(3) Amphoteric (4) None of the above
(4) (+) lactose, C12H22O11 contains 8-OH
101. Study the structure of α -D-(+) glucopyranose groups.
and β -D-(+) glucopyranose and mark the correct
104. Read the following statements and choose the
statement:
correct option?
(i) Starch is a polymer of α -Glucose.
(ii) Starch consists of amylose and amylopectin.
(iii) Amylose is insoluble in water.
(iv) Amylopectin is soluble in water.
(1) structures I and II are enantiomers
(1) i, iii and iv
(2) structures I and II are anomers
(2) i, ii and iv
(3) the two structures I and II differ in the
configuration of C1 and C4 (3) i and ii
(4) both the structure I and II give 2, 4 – DNP test (4) ii, iii and iv
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105. Match the name of vitamins in column-I with 106. Match the columns:
their sources in column-II and mark the
Column-I Column-II
appropriate choice:
Column-I Column-II (a) Vitamin B6 (p) Fat soluble
Vitamin Milk, Yeast, Green (b) Vitamin K (q) Xerophthalmia
(A) (i)
B1 vegetables, Cereals
(c) Vitamin D (r) Convulsions
Vitamin
(B) (ii) Meat, Fish, Egg
B12 (d) Vitamin A (s) Delayed blood clotting
Vitamin (1) a – p,q; b – p,s; c-p; d – r
(C) (iii) Carrots, Butter, Milk
A
(2) a – r; b – p,s; c-p; d – p,q
Vitamin Citrus, Fruits, Amla,
(D) (iv) (3) a – p,s; b – r; c-p; d – p,q
C Green leafy vegetables
(1) (A)→(iii), (B)→(iv), (C)→(i), (D)→(ii) (4) a – r; b – p,s; c-p,q; d – p

(2) (A)→(ii), (B)→(iii), (C)→(iv), (D)→(i)

(3) (A)→(iv), (B)→(iii), (C)→(ii), (D)→(i)

(4) (A)→(i), (B)→(ii), (C)→(iii), (D)→(iv)

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Topic : AMINES

107. The correct order of basic strength of alkyl 111. The method by which aniline would be prepared
substituted amines in aqueous solution :
is/are
(1) (C2H5)2NH > C2H5NH2 > (C2H5)3NH > NH3
(A) Reduction of nitriles
(2) (CH3)2NH > (CH3)3N > CH3NH2 > NH3
(3) (C2H5)2NH > NH3 > C2H5NH2 > (C2H5)3N (B) Gabriel phthalimide synthesis reaction

(4) (CH3)2NH > CH3NH2 > (CH3)3N > NH3 (C) Reduction of amides
108. In the given set of reactions (D) Hoffmann bromamide degradation reaction
Ethanolic NaCN H2 /Ni
C6 H5 − CH2 − Cl −−−−−−−−−−−→ A −−−−→ B (1) Only A and C (2) Only B and C
The IUPAC name of product B is : (3) Only B and D (4) Only D
(1) 2 – phenyl propanamine
112. Find (A) and (B)
(2) 2 – phenyl ethanamine
(3) 1 – phenyl ethanamine
(4) None of the above
109. Choose the incorrect statement about acylation
reaction of amine :-
(1) Acylation is a nucleophilic substitution
reaction
(2) Acylation reaction carried out in the (1)
presence of a base weaker than amide
(3) Reaction of amine with benzoylchloride is
called benzoylation
(4) In acylation reaction hydrogen atom of (2)
amine is replaced by acyl agroup.
110. An organic compound A on reduction gives
compound B, which on reaction with CHCl3 and
KOH form C. The compound C on catalytic (3)
reduction gives N-methyl benzenamine, the
compound A is :
(1) Nitrobenzene
(2) Nitromethane
(4)
(3) Methanamine
(4) Benzenamine
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113. Statement-I : Bond angle of trimethyl amine is 116. Match the column
108°. Column-I Column-II
Statement-II : In trimethylamine N is (Compound) (B.P./K)
sp3 hybridised and shape is tetrahedral.
(a) n-C4H9NH2 (i) 390.3
(1) Both Statement-I and Statement-II are
(b) (C2H5)2NH (ii) 350.8
incorrect
(c) C2H5N(CH3)2 (iii) 310.5
(2) Statement-I is correct but Statement-II is
incorrect (d) n-C4H9OH (iv) 329.3
(3) Statement-I incorrect and Statement-II is Choose the correct answer
correct (1) (a) – i, (b) – iv, (c) – iii, (d) – ii
(4) Both Statement-I and Statement-II are (2) (a) – i, (b) – ii, (c) – iii, (d) – iv
correct (3) (a) – ii, (b) – iii, (c) – iv, (d) – i
114.
(4) (a) – ii, (b) – iv, (c) – iii, (d) – i
Statement-I: is ortho toluidine. 117. Which of the following is correct order of k in
b

Statement-II : IUPAC name of aquous phase.

H2N – CH2 – CH = CH2 is Allylamine. (a) Et2NH > Et3N > EtNH2 > NH3
(1) Both Statement-I and Statement-II are
(b) Me2NH > MeNH2 > Me3N > NH3
incorrect
(2) Statement-I is correct but Statement-II is (c) Et2NH > Et3N > Me2NH > Me3N
incorrect (d) Ee2NH > EtNH2 > MeNH2 > Me3N
(3) Statement-I incorrect and Statement-II is
correct (e)
(4) Both Statement-I and Statement-II are correct
115. Statement-I : Higher amines are essentially (1) a, b only (2) a, b, e only
insoluble in water. (3) c, d only (4) All of these
Statement-II : Butan – 1 – ol is more soluble in
118. Which of the following statement is correct :
water than butan – 1 – amine.
(1) Amine salts are soluble in water but
(1) Both Statement-I and Statement-II are insoluble in organic solvent like ether.
incorrect
(2) The reaction of amines with mineral acids
(2) Statement-I is correct but Statement-II is to form ammonium salts.
incorrect
(3) Amines have an unshared pair of electron
(3) Statement-I incorrect and Statement-II is on nitrogen atom due to which they behave
correct as Lewis base.
(4) Both Statement-I and Statement-II are correct (4) All of these.
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119. Which of the following is correct - 123. Statement-I : In coupling reaction azo product
(a) Aliphatic and Aromatic primary amines on have an extended conjugated system having both
heating with chloroform and ethanolic potassium aromatic ring joined through the – N = N – bond.
hydroxide form isocyanides or carbylamines. Statement-II : The azo product in coupling
(b) Carbylamines are foul smelling substance. reaction are often coloured and are used as dyes.
(c) Secondary and tertiary amine gives positive
(1) Both Statement-I and Statement-II are
carbylamine test.
incorrect
(d) Isocyanide test is used as test for primary
amine. (2) Statement-I is correct but Statement-II is
(e) In carbylamine reaction 3 mole of KOH is incorrect
used (3) Statement-I incorrect and Statement-II is
(1) a, b only (2) a, b, c, only correct
(3) a, b, d, e only (4) c only (4) Both Statement-I and Statement-II are correct
120. Aniline is purified by - 124. In Gabriel phthalimide synthesis the compound
which are not obtain :
(1) Azeotropic distillation
(1) primary amine
(2) Steam distillation
(2) aniline
(3) Fractional distillation
(3) secondary amine
(4) Distillation in presence of mangesium.
(4) Both 2 and 3
121. Statement-I : The yield in sandmayer reaction is
125. Phthalimide −KOH CH3 Br − aquous
found to be better than Gatterman reaction. −−→ (A) −−−−−→ (B) −−−−→ (C)
NaOH
Statement-II : When Benzenediazonium chloride Which of the following is correct :
is treated with KI, then Iodobenzene is formed
(1) Both Statement-I and Statement-II are (1) (2) B = CH3NH2
incorrect
(2) Statement-I is correct but Statement-II is
incorrect (3) (4) None of these
(3) Statement-I incorrect and Statement-II is
correct
(4) Both Statement-I and Statement-II are correct 126.
122.
Final product R is
(1) Aniline
Which of the following is correct (2) Phenol
Θ Θ
(1) A = Ar N⊕2 Cl (2) ⊕
B = Ar N2 BF4
(3) Benzene

(3) C = ArNO2 (4) All are correct (4) Benzene diazonium chloride

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 ANSWER KEY
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Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30
A. 3 3 2 2 3 2 4 3 2 3 3 1 3 4 1 1 1 2 2 4 2 2 2 1 3 1 4 2 3 1
Q. 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60
A. 4 3 3 1 1 3 1 2 2 1 3 1 3 4 2 3 4 2 4 4 4 2 1 1 1 1 4 2 4 3
Q. 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90
A. 1 3 1 2 2 2 3 2 2 4 1 2 2 2 3 4 2 3 3 4 2 1 3 3 1 1 3 2 4 3
Q. 91 92 93 94 95 96 97 98 99 100 101 102 103 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118 119 120
A. 4 1 1 2 2 3 3 3 3 3 2 1 3 3 4 2 4 2 2 1 4 3 2 2 4 4 4 4 3 2
Q. 121 122 123 124 125 126
A. 4 4 4 4 1 1

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