Dow Corning (R) 3145 RTV

11119
SAFETYDATASHEET
DOWCORNING(R)3145RTVMIL-A-46146
ADHESIVE/SEALANT-CLEAR
Version RevisionDate: SDSNumber: Dateof last issue:10/17/2016

4.0 03/10/2017 833673-00008 Dateof first issue:11/26/2014
SECTION1. IDENTIFICATION
Productname : DOWCORNING(R)3145RTVMIL-A-46146
Productcode : 000000000001190300
Manufactureror supplier'sdetails
Companynameofsupplier : DowCorningCorporation
Address : SouthSaginawRoad
MidlandMichigan48686
Telephone : (989)496-6000
Emergencytelephone : 24HourEmergencyTelephone: (989)496-5900

CHEMTREC: (800)424-9300
Recommendeduseof thechemicalandrestrictionsonuse
Recommendeduse : Electrical industryandelectronics

Adhesive,bindingagents
SECTION2.HAZARDSIDENTIFICATION
GHSclassificationinaccordancewith29CFR1910.1200
Reproductivetoxicity : Category2
GHSlabelelements
Hazardpictograms :
SignalWord : Warning
HazardStatements : H361fSuspectedofdamagingfertility.
PrecautionaryStatements :
Prevention:
P201Obtainspecial instructionsbeforeuse.
P202Donothandleuntil all safetyprecautionshavebeenread
andunderstood.
P280Wearprotectivegloves/protectiveclothing/eyeprotection/
faceprotection.
Response:
P308+P313IFexposedorconcerned:Getmedicaladvice/
attention.
Storage:
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SAFETYDATASHEET

P405Storelockedup.
Disposal:
P501Disposeofcontents/container toanapprovedwastedis-
posalplant.
Otherhazards
Noneknown.
SECTION3.COMPOSITION/INFORMATIONONINGREDIENTS
Substance/ Mixture : Mixture
Chemicalnature : Siliconeelastomer
Hazardousingredients
Chemicalname CAS-No. Concentration(%w/w)

HexamethyldisilazanereactionwithSilica 68909-20-6 >=19-<=29
Methyltrimethoxysilane 1185-55-3 >=6-<=8
Methanol 67-56-1 >=0.09-<=0.12
Octamethylcyclotetrasiloxane 556-67-2 >=0.09-<=0.12
Dimethyldimethoxysilane 1112-39-6 >=0.09-<=0.12
SECTION4.FIRSTAIDMEASURES
Generaladvice : Inthecaseofaccidentor if youfeelunwell, seekmedical

adviceimmediately.
Whensymptomspersistor inall casesofdoubtseekmedical
advice.
If inhaled : If inhaled, removetofreshair.

Getmedicalattention.
Incaseofskincontact : Incaseofcontact, immediatelyflushskinwithplentyofwater.

Removecontaminatedclothingandshoes.
Washclothingbeforereuse.
Thoroughlycleanshoesbeforereuse.
Incaseofeyecontact : Flusheyeswithwaterasaprecaution.
Getmedicalattentionif irritationdevelopsandpersists.
If swallowed : If swallowed,DONOTinducevomiting.
Rinsemouththoroughlywithwater.
Most importantsymptoms : Suspectedofdamagingfertility.

andeffects,bothacuteand
delayed
Protectionof first-aiders : FirstAidrespondersshouldpayattentiontoself-protection,
2/ 24
SAFETYDATASHEET

andusetherecommendedpersonalprotectiveequipment
whenthepotential forexposureexists.
Notestophysician : Treatsymptomaticallyandsupportively.
SECTION5.FIRE-FIGHTINGMEASURES
Suitableextinguishingmedia : Waterspray
Alcohol-resistant foam
Carbondioxide(CO2)
Drychemical
Unsuitableextinguishing : Noneknown.
media
Specifichazardsduringfire : Exposuretocombustionproductsmaybeahazardtohealth.
fighting
Hazardouscombustionprod- : Carbonoxides
ucts Siliconoxides
Formaldehyde
Nitrogenoxides(NOx)
Specificextinguishingmeth- : Useextinguishingmeasuresthatareappropriatetolocalcir-
ods cumstancesandthesurroundingenvironment.
Usewaterspraytocoolunopenedcontainers.
Removeundamagedcontainersfromfireareaif it issafetodo
so.
Evacuatearea.
Specialprotectiveequipment : Intheeventof fire,wearself-containedbreathingapparatus.

for fire-fighters Usepersonalprotectiveequipment.
SECTION6.ACCIDENTALRELEASEMEASURES
Personalprecautions,protec- : Usepersonalprotectiveequipment.
tiveequipmentandemer- Followsafehandlingadviceandpersonalprotective
gencyprocedures equipment recommendations.
Environmentalprecautions : Dischargeintotheenvironmentmustbeavoided.
Prevent further leakageorspillageif safetodoso.
Retainanddisposeofcontaminatedwashwater.
Localauthoritiesshouldbeadvisedif significantspillages
cannotbecontained.
Methodsandmaterialsfor : Soakupwithinert absorbentmaterial.

containmentandcleaningup Forlargespills,providedikingorotherappropriate
containment tokeepmaterial fromspreading. If dikedmaterial
canbepumped,storerecoveredmaterial inappropriate
container.
Cleanupremainingmaterialsfromspill withsuitable
absorbent.
3/ 24
SAFETYDATASHEET

Localornational regulationsmayapplytoreleasesand
disposalof thismaterial, aswell asthosematerialsanditems
employedinthecleanupof releases.Youwill needto
determinewhichregulationsareapplicable.
Sections13and15of thisSDSprovideinformationregarding
certainlocalornational requirements.
SECTION7.HANDLINGANDSTORAGE
Technicalmeasures : SeeEngineeringmeasuresunderEXPOSURE
CONTROLS/PERSONALPROTECTIONsection.
Local/Totalventilation : Useonlywithadequateventilation.
Adviceonsafehandling : Donotgetonskinorclothing.
Donotswallow.
Avoidcontactwitheyes.
Handleinaccordancewithgoodindustrialhygieneandsafety
practice.
Keepawayfromwater.
Protect frommoisture.
Takecaretopreventspills,wasteandminimizereleasetothe
environment.
Conditionsforsafestorage : Keepinproperlylabeledcontainers.
Storeinaccordancewiththeparticularnational regulations.
Materialstoavoid : Donotstorewiththefollowingproduct types:

Strongoxidizingagents
SECTION8.EXPOSURECONTROLS/PERSONALPROTECTION
Ingredientswithworkplacecontrolparameters
Ingredients CAS-No. Valuetype Controlparame- Basis

(Formof ters/ Permissible
exposure) concentration
Hexamethyldisilazanereaction 68909-20-6 TWA(Dust) 20Million OSHAZ-3
withSilica particlespercubic
foot
(Silica)
TWA(Dust) 80mg/m3 OSHAZ-3
/%SiO2
(Silica)
Methyltrimethoxysilane 1185-55-3 TWA 7.5ppm DCCOEL
Methanol 67-56-1 TWA 200ppm ACGIH
STEL 250ppm ACGIH
TWA 200ppm NIOSHREL
260mg/m³
ST 250ppm NIOSHREL
325mg/m³
TWA 200ppm OSHAZ-1
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SAFETYDATASHEET

260mg/m³
Octamethylcyclotetrasiloxane 556-67-2 TWA 10ppm USWEEL
Hazardouscomponentswithoutworkplacecontrolparameters
Ingredients CAS-No.
Dimethyldimethoxysilane 1112-39-6
Thesesubstance(s) areinextricablyboundintheproduct andthereforedonot contribute

toadust inhalationhazard.
HexamethyldisilazanereactionwithSilica
Occupationalexposurelimitsofdecompositionproducts
Ingredients CAS-No. Valuetype Controlparame- Basis

(Formof ters/ Permissible
exposure) concentration
Methanol 67-56-1 TWA 200ppm ACGIH
STEL 250ppm ACGIH
TWA 200ppm NIOSHREL
260mg/m³
ST 250ppm NIOSHREL
325mg/m³
TWA 200ppm OSHAZ-1
260mg/m³
Biologicaloccupationalexposurelimits
Ingredients CAS-No. Control Biological Sam- Permissible Basis

parameters specimen pling concentra-
time tion
Methanol 67-56-1 Methanol Urine Endof 15mg/l ACGIH
shift (As BEI
soonas
possible
after
exposure
ceases)
Engineeringmeasures : Processingmayformhazardouscompounds(seesection
10).
Ensureadequateventilation,especiallyinconfinedareas.
Minimizeworkplaceexposureconcentrations.
Personalprotectiveequipment
Respiratoryprotection : Generalandlocalexhaustventilationisrecommendedto
maintainvaporexposuresbelowrecommendedlimits.Where
concentrationsareaboverecommendedlimitsorare
unknown,appropriaterespiratoryprotectionshouldbeworn.
FollowOSHArespirator regulations(29CFR1910.134)and
useNIOSH/MSHAapprovedrespirators.Protectionprovided
byair purifyingrespiratorsagainstexposuretoany
hazardouschemical islimited.Useapositivepressureair
suppliedrespiratorif thereisanypotential foruncontrolled
release,exposurelevelsareunknown,oranyother
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SAFETYDATASHEET

circumstancewhereair purifyingrespiratorsmaynotprovide
adequateprotection.
Handprotection
Material : Chemical-resistantgloves
Remarks : Chooseglovestoprotecthandsagainstchemicalsdepending
ontheconcentrationspecifictoplaceofwork.Breakthrough
timeisnotdeterminedfortheproduct. Changeglovesoften!
Forspecialapplications,werecommendclarifyingthe
resistancetochemicalsof theaforementionedprotective
gloveswiththeglovemanufacturer.Washhandsbefore
breaksandat theendofworkday.
Eyeprotection : Wearthefollowingpersonalprotectiveequipment:
Safetyglasses
Skinandbodyprotection : Selectappropriateprotectiveclothingbasedonchemical
resistancedataandanassessmentof thelocalexposure
potential.
Skincontactmustbeavoidedbyusingimperviousprotective
clothing(gloves,aprons,boots,etc).
Hygienemeasures : Ensurethateyeflushingsystemsandsafetyshowersare
locatedclosetotheworkingplace.
Whenusingdonoteat, drinkorsmoke.
Washcontaminatedclothingbeforere-use.
Theseprecautionsareforroomtemperaturehandling.Useat
elevatedtemperatureoraerosol/sprayapplicationsmay
requireaddedprecautions.
SECTION9.PHYSICALANDCHEMICALPROPERTIES
Appearance : paste
Color : white, translucent
Odor : slight
OdorThreshold : Nodataavailable
pH : Notapplicable
Meltingpoint/freezingpoint : Nodataavailable
Initialboilingpointandboiling : Notapplicable
range
Flashpoint : Notapplicable
Evaporationrate : Notapplicable
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SAFETYDATASHEET

Flammability(solid,gas) : Notclassifiedasaflammabilityhazard
Self-ignition : Thesubstanceormixtureisnotclassifiedaspyrophoric.The
substanceormixtureisnotclassifiedasself heating.
Upperexplosionlimit / Upper : Nodataavailable

flammabilitylimit
Lowerexplosionlimit / Lower : Nodataavailable

flammabilitylimit
Vaporpressure : Notapplicable
Relativevapordensity : Nodataavailable
Relativedensity : 1.12
Solubility(ies)
Watersolubility : Nodataavailable
Partitioncoefficient: n- : Nodataavailable
octanol/water
Autoignitiontemperature : Nodataavailable
Decompositiontemperature : Nodataavailable
Viscosity
Viscosity,dynamic : Notapplicable
Explosiveproperties : Notexplosive
Oxidizingproperties : Thesubstanceormixtureisnotclassifiedasoxidizing.
Molecularweight : Nodataavailable
Particlesize : Nodataavailable
SECTION10.STABILITYANDREACTIVITY
Reactivity : Notclassifiedasareactivityhazard.
Chemicalstability : Stableundernormalconditions.
Possibilityofhazardousreac- : Useatelevatedtemperaturesmayformhighlyhazardous
tions compounds.
Canreactwithstrongoxidizingagents.
Whenheatedtotemperaturesabove180°C(356°F) inthe
presenceofair, tracequantitiesof formaldehydemaybere-
leased.
Adequateventilationisrequired.
SeeOSHAformaldehydestandard,29CFR1910.1048
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SAFETYDATASHEET

Hazardousdecompositionproductswill beformeduponcon-
tactwithwaterorhumidair.
Hazardousdecompositionproductswill beformedatelevated
temperatures.
Conditionstoavoid : Exposuretomoisture.
Incompatiblematerials : Oxidizingagents
Water
Hazardousdecompositionproducts
Contactwithwaterorhumid : Methanol
air
Thermaldecomposition : Formaldehyde
SECTION11.TOXICOLOGICALINFORMATION
Informationonlikelyroutesofexposure
Skincontact
Ingestion
Eyecontact
Acutetoxicity
Notclassifiedbasedonavailableinformation.
Product:
Acuteoral toxicity : Acutetoxicityestimate: >5,000mg/kg

Method:Calculationmethod
Acuteinhalationtoxicity : Acutetoxicityestimate: >200mg/l

Exposuretime: 4h
Testatmosphere:vapor
Method:Calculationmethod
Acutedermal toxicity : LD50(Rabbit): >2,000mg/kg

Assessment: Thesubstanceormixturehasnoacutedermal
toxicity
Remarks:Onbasisof testdata.
Ingredients:
HexamethyldisilazanereactionwithSilica:
Acuteoral toxicity : LD50(Rat): >5,000mg/kg

Assessment: Thesubstanceormixturehasnoacuteoral tox-
icity
Remarks:Basedondatafromsimilarmaterials
Methyltrimethoxysilane:
Acuteoral toxicity : LD50(Rat): 12.3ml/kg

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SAFETYDATASHEET

icity
Remarks: Informationtakenfromreferenceworksandthe
literature.
Acuteinhalationtoxicity : LC50(Rat): >42.1mg/l

Exposuretime: 6h
Assessment: Thesubstanceormixturehasnoacuteinhala-
tiontoxicity
Acutedermal toxicity : LD50(Rabbit): >9,500mg/kg

toxicity
Methanol:
Acuteoral toxicity : Acutetoxicityestimate(Humans): 300mg/kg

Method:Expert judgment
Acuteinhalationtoxicity : Acutetoxicityestimate: 3mg/l

Exposuretime: 4h
Remarks:BasedonharmonisedclassificationinEUregulation
1272/2008,AnnexVI
Acutedermal toxicity : Acutetoxicityestimate(Humans): 300mg/kg

Octamethylcyclotetrasiloxane:
Acuteoral toxicity : LD50(Rat): >4,800mg/kg

icity
Acuteinhalationtoxicity : LC50(Rat): 2975ppm

Exposuretime: 4h
tiontoxicity
Acutedermal toxicity : LD50(Rabbit): >2.5ml/kg

toxicity
Dimethyldimethoxysilane:
Acuteoral toxicity : LD50(Rat): >2,000-5,000mg/kg

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SAFETYDATASHEET

Acuteinhalationtoxicity : LC50(Rat): >4.7mg/l

Exposuretime: 4h
tiontoxicity
Skincorrosion/irritation
Product:
Species:Rabbit
Result: Mildskinirritation
Ingredients:
Assessment: Repeatedexposuremaycauseskindrynessorcracking.
Species:Rabbit
Result: Noskinirritation
Methanol:
Species:Rabbit
Species:Rabbit
Species:Rabbit
Seriouseyedamage/eyeirritation
Product:
Species:Rabbit
Result: Noeyeirritation
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SAFETYDATASHEET

Ingredients:
Species:Rabbit
Species:Rabbit
Methanol:
Species:Rabbit
Species:Rabbit
Species:Rabbit
Respiratoryor skinsensitization
Skinsensitization
Respiratorysensitization
Product:
Assessment: Doesnotcauseskinsensitization.
TestType:BuehlerTest
Species:Guineapig
Result: negative
Ingredients:
Assessment: Probabilityorevidenceof lowtomoderateskinsensitizationrateinhumans
TestType:BuehlerTest
Species:Guineapig
Result: positive
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SAFETYDATASHEET

Methanol:
TestType:MaximizationTest
Routesofexposure:Skincontact
Species:Guineapig
Result: negative
Assessment: Doesnotcauseskinsensitization.
TestType:MaximizationTest
Species:Guineapig
Result: negative
Germcell mutagenicity
Product:
Genotoxicityinvitro : TestType:Bacterial reversemutationassay(AMES)

Result: negative
Ingredients:

Result: negative

Result: negative
: TestType:Mutagenicity(invitromammaliancytogenetictest)
Result: positive
: TestType:Chromosomeaberrationtest invitro
Result: positive
Genotoxicityinvivo : TestType:Mammalianerythrocytemicronucleustest (invivo

cytogeneticassay)
Species:Mouse
ApplicationRoute: Ingestion
Result: negative
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SAFETYDATASHEET

Germcell mutagenicity- : Animal testingdidnotshowanymutageniceffects.

Assessment
Methanol:

Method:OECDTestGuideline471
Result: negative
: TestType: Invitromammaliancell genemutationtest

Result: negative

cytogeneticassay)
Species:Mouse
ApplicationRoute: Intraperitoneal injection
Result: negative

Result: negative
: TestType:Mutagenicity(invitromammaliancytogenetictest)
Result: negative
: TestType:Chromosomeaberrationtest invitro
Result: negative
: TestType: Invitrosisterchromatidexchangeassayinmam-
maliancells
Result: negative
: TestType:DNAdamageandrepair, unscheduledDNAsyn-
thesisinmammaliancells(invitro)
Result: negative

cytogeneticassay)
Species:Rat
ApplicationRoute: inhalation(vapor)
Result: negative
TestType:Rodentdominant lethal test (germcell) (invivo)

Species:Rat
Result: negative
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SAFETYDATASHEET

Germcell mutagenicity- : Animal testingdidnotshowanymutageniceffects.

Assessment
Genotoxicityinvitro : TestType:Chromosomeaberrationtest invitro

Result: negative
Carcinogenicity
Ingredients:
Methanol:
Species:Mouse
Exposuretime:18Months
Result: negative
IARC Noingredientof thisproductpresentat levelsgreater thanor

equal to0.1%isidentifiedasprobable,possibleorconfirmed
humancarcinogenbyIARC.
OSHA Nocomponentof thisproductpresentat levelsgreater thanor

equal to0.1%isonOSHA’slistof regulatedcarcinogens.
NTP Noingredientof thisproductpresentat levelsgreater thanor

equal to0.1%isidentifiedasaknownoranticipatedcarcinogen
byNTP.
Reproductivetoxicity
Suspectedofdamagingfertility.
Ingredients:
Effectsonfertility : TestType:Combinedrepeateddosetoxicitystudywiththe
reproduction/developmental toxicityscreeningtest
Species:Rat, maleandfemale
Symptoms:Noeffectsonfertility.
Effectsonfetaldevelopment : TestType:Combinedrepeateddosetoxicitystudywiththe
Symptoms:Noeffectsonfetaldevelopment.
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SAFETYDATASHEET

Reproductivetoxicity-As- : Noevidenceofadverseeffectsonsexual functionandfertility,

sessment orondevelopment, basedonanimalexperiments.
Methanol:
Effectsonfertility : TestType:Fertility/earlyembryonicdevelopment
Species:Mouse
Result: negative
Effectsonfetaldevelopment : TestType:Embryo-fetaldevelopment
Species:Mouse
Result: positive
Remarks:Theeffectswereseenonlyatmaternallytoxicdos-
es.
Effectsonfertility : TestType:Two-generationreproductiontoxicitystudy
Symptoms:Effectsonfertility.
Effectsonfetaldevelopment : TestType:Prenataldevelopment toxicitystudy(teratogenicity)

Species:Rabbit
Symptoms:Noeffectsonfetaldevelopment.
Reproductivetoxicity-As- : Someevidenceofadverseeffectsonsexual functionand

sessment fertility,basedonanimalexperiments.
Effectsonfertility : TestType:Combinedrepeateddosetoxicitystudywiththe
Symptoms:Effectsonfertility.
Reproductivetoxicity-As- : Someevidenceofadverseeffectsonsexual functionand

sessment fertility,basedonanimalexperiments.
STOT-singleexposure
Ingredients:
Methanol:
TargetOrgans:Eyes,Centralnervoussystem
Assessment: Causesdamagetoorgans.
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SAFETYDATASHEET

STOT-repeatedexposure
Ingredients:
Routesofexposure: inhalation(vapor)
Assessment: Nosignificanthealtheffectsobservedinanimalsatconcentrationsof 1mg/l/6h/dor
less.
Routesofexposure: Ingestion
Assessment: Nosignificanthealtheffectsobservedinanimalsatconcentrationsof100mg/kg
bwor less.
bwor less.
Routesofexposure: inhalation(vapor)
Assessment: Nosignificanthealtheffectsobservedinanimalsatconcentrationsof 1mg/l/6h/dor
less.
Routesofexposure:Skincontact
bwor less.
bwor less.
Repeateddosetoxicity
Ingredients:
Species:Rat
Species:Rat
Methanol:
Species:Rat
NOAEL:1.06mg/l
Exposuretime:90Days
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SAFETYDATASHEET

Species:Rat
Species:Rat
Species:Rabbit
ApplicationRoute:Skincontact
Species:Rat
Aspirationtoxicity
Further information
Ingredients:
Remarks:Resultsfroma2yearrepeatedvapor inhalationexposurestudytoratsofoctamethyl-
cyclotetrasiloxane(D4) indicateeffects(benignuterineadenomas) intheuterusof femaleani-
mals.Thisfindingoccurredat thehighestexposuredose(700ppm)only.Studiestodatehave
notdemonstratedif theseeffectsoccur throughpathwaysthatarerelevant tohumans.Repeated
exposureinratstoD4resultedinprotoporphyrinaccumulationintheliver. Withoutknowledgeof
thespecificmechanismleadingtotheprotoporphyrinaccumulationtherelevanceof thisfinding
tohumansisunknown.
Remarks:Thismaterialcontainsdimethyldimethoxysilane.Repeatedexposureinratstodime-
thyldimethoxysilaneresultedinprotoporphyrinaccumulationintheliver. Withoutknowledgeof
thespecificmechanismleadingtotheprotoporphyrinaccumulationtherelevanceof thisfinding
tohumans
isunknown.
SECTION12.ECOLOGICALINFORMATION
Ecotoxicity
Ingredients:
Toxicitytofish : LC50(Oncorhynchusmykiss(rainbowtrout)): >110mg/l
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SAFETYDATASHEET

Exposuretime:96h
Toxicitytodaphniaandother : EC50(Daphniasp. (Waterflea)): >122mg/l

aquaticinvertebrates Exposuretime:48h
Toxicitytoalgae : ErC50(Pseudokirchneriellasubcapitata(greenalgae)): >120

mg/l
Exposuretime:72h
Toxicitytomicroorganisms : EC50: >100mg/l

Methanol:
Toxicitytofish : LC50(Lepomismacrochirus(Bluegill sunfish)): 15,400mg/l

Exposuretime:96h
Toxicitytodaphniaandother : EC50(Daphniamagna(Water flea)): >10,000mg/l

Toxicitytoalgae : EC50(Pseudokirchneriellasubcapitata(greenalgae)): 22,000

mg/l
Exposuretime:96h
Toxicitytofish(Chronictox- : NOEC(Oryziaslatipes(Orange-redkillifish)): 15,800mg/l

icity) Exposuretime:200h
Toxicitytomicroorganisms : IC50: >1,000mg/l

Exposuretime: 3h
Toxicitytofish : LC50(Cyprinodonvariegatus(sheepsheadminnow)): >

0.0063mg/l
Exposuretime:336h
Remarks:Notoxicityat thelimit ofsolubility.
Toxicitytodaphniaandother : EC50(Mysidopsisbahia(opossumshrimp)): >0.0091mg/l

Toxicitytoalgae : ErC50(Pseudokirchneriellasubcapitata(greenalgae)): >

0.022mg/l
Exposuretime:72h
Toxicitytofish(Chronictox- : NOEC(Oncorhynchusmykiss(rainbowtrout)): >=0.0044mg/l

icity) Remarks:Onbasisof testdata.
Notoxicityat thelimit ofsolubility.
Toxicitytodaphniaandother : NOEC(Daphniamagna(Water flea)): >=0.0079mg/l

aquaticinvertebrates(Chron- Exposuretime:21d
18/ 24
SAFETYDATASHEET

ictoxicity) Remarks:Onbasisof testdata.

Notoxicityat thelimit ofsolubility.
EcotoxicologyAssessment
Chronicaquatictoxicity : Maycauselonglastingharmfuleffectstoaquaticlife.
Toxicitytofish : LC50(Oncorhynchusmykiss(rainbowtrout)): >126mg/l

Exposuretime:96h
Toxicitytodaphniaandother : EC50(Daphniamagna(Water flea)): >119mg/l

Toxicitytoalgae : EC50(Pseudokirchneriellasubcapitata(greenalgae)): >118

mg/l
Exposuretime:72h
Toxicitytomicroorganisms : EC50: >100mg/l

Exposuretime: 3h
Persistenceanddegradability
Ingredients:
Methanol:
Biodegradability : Result: Readilybiodegradable.

Biodegradation: 95%
Exposuretime:20d
Biodegradability : Result: Not readilybiodegradable.

Biodegradation: 3.7%
Exposuretime:28d
Stabilityinwater : Degradationhalf life:69.3-144h(24.6°C)pH:7

Stabilityinwater : Degradationhalf life: <0.6hpH:7
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SAFETYDATASHEET

Bioaccumulativepotential
Ingredients:
Partitioncoefficient: n- : logPow: -2.36

octanol/water
Methanol:
Bioaccumulation : Species:Leuciscusidus(Goldenorfe)
Bioconcentrationfactor(BCF): <10
Partitioncoefficient: n- : logPow: -0.77

octanol/water
Bioaccumulation : Species:Pimephalespromelas(fatheadminnow)
Bioconcentrationfactor(BCF): 12,400
Partitioncoefficient: n- : logPow:6.48(25.1°C)
octanol/water
Mobilityinsoil
Nodataavailable
Otheradverseeffects
Ingredients:
ResultsofPBTandvPvB : Remarks:Octamethylcyclotetrasiloxane(D4)meetsthecur-
assessment rentREAChAnnexXIII criteriaforPBTandvPvB. InCanada,
D4hasbeenassessedanddeemedtomeet thePiTcriteria.
However, D4doesnotbehavesimilarlytoknownPBT/vPvB
substances.Theweightofscientificevidencefromfieldstud-
iesshowsthatD4isnotbiomagnifyinginaquaticandterres-
trial foodwebs.D4inair will degradebyreactionwithnaturally
occurringhydroxyl radicalsintheatmosphere.AnyD4inair
thatdoesnotdegradebyreactionwithhydroxyl radicalsisnot
expectedtodeposit fromtheair towater, toland,or toliving
organisms.
SECTION13.DISPOSALCONSIDERATIONS
Disposalmethods
ResourceConservationand : ThisproducthasbeenevaluatedforRCRAcharacteristics
RecoveryAct (RCRA) anddoesnotmeet thecriteriaofhazardouswasteif discarded
initspurchasedform.
Wastefromresidues : Disposeof inaccordancewithlocal regulations.
20/ 24
SAFETYDATASHEET

Contaminatedpackaging : Emptycontainersshouldbetakentoanapprovedwaste
handlingsitefor recyclingordisposal.
If nototherwisespecified:Disposeofasunusedproduct.
SECTION14.TRANSPORTINFORMATION
InternationalRegulations
UNRTDG
Not regulatedasadangerousgood
IATA-DGR
IMDG-Code
Transport inbulkaccordingtoAnnexII ofMARPOL73/78andtheIBCCode
Notapplicableforproductassupplied.
Domesticregulation
49CFR
SECTION15.REGULATORYINFORMATION
EPCRA-EmergencyPlanningandCommunityRight-to-Know
CERCLAReportableQuantity
Ingredients CAS-No. ComponentRQ CalculatedproductRQ

(lbs) (lbs)
Methanol 67-56-1 5000 *
*: CalculatedRQexceedsreasonablyattainableupper limit.
SARA304ExtremelyHazardousSubstancesReportableQuantity
Thismaterialdoesnotcontainanycomponentswithasection304EHSRQ.
SARA302ExtremelyHazardousSubstancesThresholdPlanningQuantity
Thismaterialdoesnotcontainanycomponentswithasection302EHSTPQ.
SARA311/312Hazards : ChronicHealthHazard
SARA313 : Thismaterialdoesnotcontainanychemicalcomponentswith
knownCASnumbersthatexceedthethreshold(DeMinimis)
reportinglevelsestablishedbySARATitleIII, Section313.
USStateRegulations
PennsylvaniaRightToKnow
Dimethylsiloxane,hydroxy-terminated 70131-67-8
HexamethyldisilazanereactionwithSilica 68909-20-6
Methyltrimethoxysilane 1185-55-3
Methanol 67-56-1
21/ 24
SAFETYDATASHEET

CaliforniaProp.65
WARNING:ThisproductcontainsachemicalknownintheStateofCaliforniatocausebirthde-
fectsorotherreproductiveharm.
Methanol 67-56-1
Theingredientsof thisproduct arereportedinthefollowinginventories:
NZIoC : All ingredientslistedorexempt.
REACH : ForpurchasesfromDowCorningEUlegalentities,all
ingredientsarecurrentlypre/registeredorexemptunder
REACH.Pleaserefer tosection1for recommendeduses.For
purchasesfromnon-EUDowCorninglegalentitieswiththe
intentiontoexport intoEEApleasecontactyourDC
representative/localoffice.
TSCA : All chemicalsubstancesinthisproductareeither listedonthe

TSCAInventoryorareincompliancewithaTSCAInventory
exemption.
AICS : All ingredientslistedorexempt.
IECSC : All ingredientslistedorexempt.
ENCS/ISHL : All componentsarelistedonENCS/ISHLorexemptedfrom

inventorylisting.
KECI : All ingredientslisted,exemptornotified.
PICCS : All ingredientslistedorexempt.
DSL : All chemicalsubstancesinthisproductcomplywiththeCEPA

1999andNSNRandareonorexempt fromlistingonthe
CanadianDomesticSubstancesList (DSL).
TCSI : All ingredientslistedorexempt.
22/ 24
SAFETYDATASHEET

SECTION16.OTHERINFORMATION
Further information
NFPA: HMIS®IV:
Flammability
HEALTH * 0
1
FLAMMABILITY 1
nI
hta
1 0
s
le
i at
H
ytilb
PHYSICALHAZARD 0
HMIS®ratingsarebasedona0-4rating
Specialhazard. scale,with0representingminimalhaz-
ardsorrisks,and4representingsignifi-
canthazardsor risks.The"*"represents
achronichazard,whilethe"/"represents
theabsenceof achronichazard.
Full text ofotherabbreviations
ACGIH : USA.ACGIHThresholdLimit Values(TLV)

ACGIHBEI : ACGIH-BiologicalExposureIndices(BEI)
DCCOEL : DowCorningGuide
NIOSHREL : USA.NIOSHRecommendedExposureLimits
OSHAZ-1 : USA.OccupationalExposureLimits(OSHA) -TableZ-1Lim-
itsforAir Contaminants
OSHAZ-3 : USA.OccupationalExposureLimits(OSHA) -TableZ-3Min-
eralDusts
USWEEL : USA.WorkplaceEnvironmentalExposureLevels(WEEL)
ACGIH/ TWA : 8-hour, time-weightedaverage
ACGIH/ STEL : Short-termexposurelimit
DCCOEL/ TWA : Timeweightedaverage
NIOSHREL/ TWA : Time-weightedaverageconcentrationforuptoa10-hour
workdayduringa40-hourworkweek
NIOSHREL/ ST : STEL-15-minuteTWAexposurethatshouldnotbeexceeded
atanytimeduringaworkday
OSHAZ-1/ TWA : 8-hourtimeweightedaverage
OSHAZ-3/ TWA : 8-hourtimeweightedaverage
USWEEL/ TWA : Timeweightedaverage
AICS-AustralianInventoryofChemicalSubstances;ASTM-AmericanSocietyfor theTestingof
Materials;bw-Bodyweight; CERCLA-ComprehensiveEnvironmentalResponse,Compensation,
andLiabilityAct; CMR- Carcinogen,MutagenorReproductiveToxicant; DIN- Standardof the
GermanInstituteforStandardisation;DOT- DepartmentofTransportation;DSL- DomesticSub-
stancesList (Canada); ECx-Concentrationassociatedwithx%response;EHS- ExtremelyHaz-
ardousSubstance;ELx-Loadingrateassociatedwithx%response;EmS-EmergencySchedule;
ENCS- ExistingandNewChemicalSubstances(Japan); ErCx- Concentrationassociatedwith
x%growthrateresponse;ERG- EmergencyResponseGuide;GHS- GloballyHarmonizedSys-
tem;GLP- GoodLaboratoryPractice;HMIS- HazardousMaterialsIdentificationSystem; IARC-
23/ 24
SAFETYDATASHEET

InternationalAgencyforResearchonCancer; IATA-InternationalAir Transport Association; IBC

- InternationalCodefor theConstructionandEquipmentofShipscarryingDangerousChemicals
inBulk; IC50-Half maximal inhibitoryconcentration; ICAO-InternationalCivil AviationOrganiza-
tion; IECSC- InventoryofExistingChemicalSubstancesinChina; IMDG- InternationalMaritime
DangerousGoods; IMO-InternationalMaritimeOrganization; ISHL-IndustrialSafetyandHealth
Law(Japan); ISO- InternationalOrganisationforStandardization;KECI -KoreaExistingChemi-
calsInventory;LC50- LethalConcentrationto50%of atestpopulation;LD50- LethalDoseto
50%of atestpopulation(MedianLethalDose); MARPOL- InternationalConventionfor thePre-
ventionofPollutionfromShips;MSHA- MineSafetyandHealthAdministration;n.o.s. -NotOth-
erwiseSpecified;NFPA-NationalFireProtectionAssociation;NO(A)EC-NoObserved(Adverse)
EffectConcentration;NO(A)EL- NoObserved(Adverse)EffectLevel; NOELR- NoObservable
EffectLoadingRate;NTP- National ToxicologyProgram;NZIoC- NewZealand Inventory of
Chemicals;OECD- OrganizationforEconomicCo-operationandDevelopment; OPPTS- Office
ofChemicalSafetyandPollutionPrevention;PBT- Persistent, BioaccumulativeandToxicsub-
stance;PICCS-PhilippinesInventoryofChemicalsandChemicalSubstances; (Q)SAR-(Quanti-
tative) Structure Activity Relationship; RCRA- ResourceConservationandRecovery Act;
REACH-Regulation(EC)No1907/2006of theEuropeanParliamentandof theCouncil concern-
ing theRegistration,Evaluation,AuthorisationandRestrictionofChemicals;RQ- Reportable
Quantity; SADT- Self-AcceleratingDecompositionTemperature; SARA- SuperfundAmend-
mentsandReauthorizationAct; SDS- SafetyDataSheet; TCSI -TaiwanChemicalSubstance
Inventory;TSCA-ToxicSubstancesControlAct (UnitedStates); UN-UnitedNations;UNRTDG-
UnitedNationsRecommendationsontheTransport ofDangerousGoods; vPvB- VeryPersistent
andVeryBioaccumulative
Sourcesofkeydatausedto : Internal technicaldata,datafromrawmaterialSDSs,OECD

compiletheMaterialSafety eChemPortalsearchresultsandEuropeanChemicalsAgen-
DataSheet cy,http://echa.europa.eu/
RevisionDate : 03/10/2017
Itemswherechangeshavebeenmadetothepreviousversionarehighlightedinthebodyof this
documentbytwovertical lines.
The informationprovided in this Safety Data Sheet is correct to thebest of ourknowledge,

informationandbelief at thedate of its publication. The information is designedonly asa
guidanceforsafehandling,use,processing,storage, transportation,disposalandreleaseand
shall notbeconsideredawarrantyorqualityspecificationofanytype.Theinformationprovided
relatesonlytothespecificmaterial identifiedat thetopof thisSDSandmaynotbevalidwhenthe
SDSmaterial isusedincombinationwithanyothermaterialsor inanyprocess,unlessspecified
in the text. Material users shouldreviewthe informationand recommendations in thespecific
context of their intendedmanner of handling, use, processingandstorage, includingan
assessmentof theappropriatenessof theSDSmaterial intheuser’sendproduct, if applicable.
US/ Z8
24/ 24

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11119

Version RevisionDate: SDSNumber: Dateof last issue:10/17/2016

Emergencytelephone : 24HourEmergencyTelephone: (989)496-5900

Recommendeduse : Electrical industryandelectronics

Version RevisionDate: SDSNumber: Dateof last issue:10/17/2016

Substance/ Mixture : Mixture

Chemicalname CAS-No. Concentration(%w/w)

Generaladvice : Inthecaseofaccidentor if youfeelunwell, seekmedical

If inhaled : If inhaled, removetofreshair.

Incaseofskincontact : Incaseofcontact, immediatelyflushskinwithplentyofwater.

Most importantsymptoms : Suspectedofdamagingfertility.

Protectionof first-aiders : FirstAidrespondersshouldpayattentiontoself-protection,

Version RevisionDate: SDSNumber: Dateof last issue:10/17/2016

Specialprotectiveequipment : Intheeventof fire,wearself-containedbreathingapparatus.

Methodsandmaterialsfor : Soakupwithinert absorbentmaterial.

Version RevisionDate: SDSNumber: Dateof last issue:10/17/2016

Materialstoavoid : Donotstorewiththefollowingproduct types:

Ingredients CAS-No. Valuetype Controlparame- Basis

Version RevisionDate: SDSNumber: Dateof last issue:10/17/2016

Thesesubstance(s) areinextricablyboundintheproduct andthereforedonot contribute

Ingredients CAS-No. Valuetype Controlparame- Basis

Ingredients CAS-No. Control Biological Sam- Permissible Basis

Version RevisionDate: SDSNumber: Dateof last issue:10/17/2016

Color : white, translucent

Version RevisionDate: SDSNumber: Dateof last issue:10/17/2016

Upperexplosionlimit / Upper : Nodataavailable

Lowerexplosionlimit / Lower : Nodataavailable

Version RevisionDate: SDSNumber: Dateof last issue:10/17/2016

Acuteoral toxicity : Acutetoxicityestimate: >5,000mg/kg

Acuteinhalationtoxicity : Acutetoxicityestimate: >200mg/l

Acutedermal toxicity : LD50(Rabbit): >2,000mg/kg

Acuteoral toxicity : LD50(Rat): >5,000mg/kg

Acuteoral toxicity : LD50(Rat): 12.3ml/kg

Version RevisionDate: SDSNumber: Dateof last issue:10/17/2016

Acuteinhalationtoxicity : LC50(Rat): >42.1mg/l

Acutedermal toxicity : LD50(Rabbit): >9,500mg/kg

Acuteoral toxicity : Acutetoxicityestimate(Humans): 300mg/kg

Acuteinhalationtoxicity : Acutetoxicityestimate: 3mg/l

Acutedermal toxicity : Acutetoxicityestimate(Humans): 300mg/kg

Acuteoral toxicity : LD50(Rat): >4,800mg/kg

Acuteinhalationtoxicity : LC50(Rat): 2975ppm

Acutedermal toxicity : LD50(Rabbit): >2.5ml/kg

Acuteoral toxicity : LD50(Rat): >2,000-5,000mg/kg

Version RevisionDate: SDSNumber: Dateof last issue:10/17/2016

Acuteinhalationtoxicity : LC50(Rat): >4.7mg/l

Version RevisionDate: SDSNumber: Dateof last issue:10/17/2016

Assessment: Probabilityorevidenceof lowtomoderateskinsensitizationrateinhumans

Version RevisionDate: SDSNumber: Dateof last issue:10/17/2016

Genotoxicityinvitro : TestType:Bacterial reversemutationassay(AMES)

Genotoxicityinvitro : TestType:Bacterial reversemutationassay(AMES)

Genotoxicityinvitro : TestType:Bacterial reversemutationassay(AMES)

Genotoxicityinvivo : TestType:Mammalianerythrocytemicronucleustest (invivo

Version RevisionDate: SDSNumber: Dateof last issue:10/17/2016

Germcell mutagenicity- : Animal testingdidnotshowanymutageniceffects.

Genotoxicityinvitro : TestType:Bacterial reversemutationassay(AMES)

: TestType: Invitromammaliancell genemutationtest

Genotoxicityinvivo : TestType:Mammalianerythrocytemicronucleustest (invivo

Genotoxicityinvitro : TestType:Bacterial reversemutationassay(AMES)

Genotoxicityinvivo : TestType:Mammalianerythrocytemicronucleustest (invivo

TestType:Rodentdominant lethal test (germcell) (invivo)

Version RevisionDate: SDSNumber: Dateof last issue:10/17/2016

Germcell mutagenicity- : Animal testingdidnotshowanymutageniceffects.

Genotoxicityinvitro : TestType:Chromosomeaberrationtest invitro