Practice Assignment Euilibrium

Equilibrium

Answer Key
1. (Kc = 1.8)
18. (a) 2NO2  aq.  2H2 O I  HNO 2  aq.
2. (a) Moles of O2 = 0.1
 H3 O  aq.  NO3–  aq
(b) Moles of O2 = 0.4
(b) NO2   4.5  10
– 4
3. ( PH2S =0.387 atm)
pH = 1.17
4. (KP = 5.1 × 1011)
5. (Above 1078.5 K, value of K will (c)   4.95atm

be greater than 1) (d) w CaO  0.924 g

6. (Overall stability order :
B > C > A) 19. (pH = 7.81)
20. (d)
CH3 CH2 CH  C  CH2  21. (b)
22. (Yes)
  CH3 CH2 C  C — CH3 
23. (1.47 × 10–2)
7. (KP = 6.14 atm)
24. (61.3%)
8. (T = 1167.26 K or 894.26°C)
25. ( PH2O  7.92 mm Hg )
9. K C1  0.11 and K C2  0.142
26. (0.03 & 18.45)
10. (P = 0.126 atm)
27. (10.83)
11. (1)
28. (–142.7 kJ/mol & –371.5 kJ/mol)
12. (d)
29. (Negligibly small)
13. (CaseI : OH   NH2C2H4NH3 
 
30. (b)
31. (d)
= 3.57  103 M )
32. [H+] = 3.2 × 10–5 M
Case II : NH3C2H4NH3 
2
33. (AgI, 10–6)
34. (MnS will not ppt.
8
= 2.7  10 M  K b2 CuS will ppt
14. (Ka = 1.2 × 10–5) % CuS an precipitated = 3.28 × 10–14%
15. [I–] = 8.5 × 10–16 M At (H+) = 10–7 M, MnS will ppt)
% of Ag precipitated = 99.83% 35. [H+] < 1.1 × 10–2
16. KSP(BaCO3) = 4.9 × 10–10 pH < 2
17. (CdS will be precipitated first.)

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 Euilibrium Practice Assignment

36. (a) MnS will not ppt 51. (a, b, c)

(b) [CH3COONa] = 1.7 M 52. (b)
37. (0.044 M) 53. (c)

38. pH 1.55 54. (d)

39. pH = 7.86 55. (a)

56. (c)
40. (b)
57. (c)
41. (a)
42. (a) 58. (c)

43. (b) 59. (b)

44. (c) 60. (c)

45. (b) 61. (a)

62. (b)
46. (b)
63. (a)
47. (a)
64. (b)
48. (d)
65. (d)
49. (c)
66. (a, c)
50. (a)
67. (4)

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