Term - 3, Paper - 2 - Qa

Term-III (ADVANCED)/PAPER - 1 CRONOS 25
BATCH : CRONOS 25 (ADVANCED) – PAPER - 2
ADVANCED, PAPER - 2
Time: 3 hrs. Beware of Negative Marking Total Marks: 180(PCM)
INSTRUCTIONS
A. General:
1. No additional sheets will be provided for rough work.
2. Blank papers, clipboards, log tables, slide rules, calculators, cellular phones, pagers and electronic gadgets in
any form are not allowed.
3. The answer sheet, a machine-gradable Objective Response Sheet (ORS), is provided separately.
4. Do not Tamper / mutilate the ORS or this booklet.
B. Filling the top-half of the ORS:

5. Write your Exam Roll Number, Name and Father’s Name with pen in appropriate boxes. Do not write these
anywhere else.
6. Darken the appropriate bubbles below your Exam Roll Number with HB Pencil.
C. Question paper format and Marking scheme:
7. The question paper consists of 3 parts (Physics, Chemistry and Mathematics).
8. Section - I (01 – 04) contains 4 multiple choice questions which have only one correct answer. Each
question carries +3 marks for correct answer and – 1 marks for wrong answer.
Section - I (05 – 07) contains 3 multiple choice questions which have one or more than one correct answer.
Each question carries +4 marks for correct answer. There is no negative marking.
Section-II contains 2 Paragraphs. Based upon paragraph, 2, 2 multiple choice questions have to be
answered. Each question has only correct answer and carries +3 marks for correct answer. There is no
negative marking.
Section-III (01 – 06) contains 6 Numerical based questions with single digit integer as answer, ranging from
0 to 9 and each question carries +4 marks for correct answer. There is no negative marking.
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SECTION – I
(Single Correct Choice Type)
This section contains 4 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for
its answer, out of which ONLY ONE is correct.
1. The acceleration due to gravity on the moon is only one sixth that of earth. If the earth and moon are assumed
to have the same density, the ration of the radii of moon and earth will be
1 1 1 1
(a) (b) (c) (d)
6 (6)1/ 3 36 (6)2 / 3
Ans. A
1 gm R2eMm R3eRm
3
R
Sol. = = 2 = 2 3 = m
6 ge RmMe RmRe Re
2. Let T1 and T2 be the time periods of two springs A and B when a mass m is suspended from them separately.
Now both the springs are connected in parallel and same mass m is suspended with them. Now let T be the
time period in this position. Then
T1T2 1 1 1
(a) T = T1 + T2 (b) T = (c) T 2 = T12 + T22 (d) = +
T1 + T2 T 2
T12 T22
Ans. D
Sol.
m 4 2m
T1 = 2 or k1 =
k1 T12
m 4 2m
T2 = 2 or k 2 =
k2 T2
m 4 2m
Now, T = 2 or k=
k T2
In parallel k = k1 + k 2
Substituting the values of k, k1 and k 2 we get.
1 1 1
2
= +
T T12 T22
3. A person is talking in a small room and the sound intensity level is 60 dB everywhere within the room. If there
are eight people talking simultaneously in the room, what is the sound intensity level ?
(a) 96 dB (b) 69 dB (c) 74 dB (d) 81 Db
Ans. B
Sol.
l2 = 8l1
l 
L 2 − L1 = 10 log10  2 
 l1 
or L 2 − 60 = 10 log10 8
 L 2 = 69 dB
4. Two monoatomic ideal gases at temperature T1 and T2 are mixed. There is no loss of energy. If number of
their moles are n1 and n2 respectively. The temperature of the mixture will be
T1 + T2 T1 T2 n2 T1 + n1T2 n1T1 + n2 T2
(a) (b) + (c) (d)
n1 + n2 n1 n2 n1 + n2 n1 + n2
Ans. D
Sol. Since there is no loss of energy, therefore :
U = U1 + U2
f f f
n   RT = n1   RT1 + n2   RT2
 
2  
2 2
But, n = n1 + n2
n1T1 + n2 T2
 T=
n1 + n2
SECTION – I
Multiple Correct Choice Type
This section contains 3 multiple choice questions. Each question has 4 choices (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE is/are correct.
5. Let V and E be the gravitational potential and gravitational field. Then select the correct alternative(s)
(a) The plot of E against r (distance from centre) is discontinuous for a spherical shell
(b) The plot of V against r is continuous for a spherical shell
(c) The plot of E against r is discontinuous for a solid sphere
(d) The plot of V against r is continuous for a solid sphere
Ans. ABD
Sol. E-r and V-r graphs for a spherical shell and a solid sphere are as follows :
6. A constant force F is applied on a spring block system as shown in figure. The mass of the block is m and
spring constant is k. The block is placed over a smooth surface. Initially the spring was unstretched. Choose
the correct alternative(s)
k
F
m
(a) The block will execute SHM.

F
(b) Amplitude of oscillation is
2k
m
(c) Time period of oscillation is 2
k
2Fx − k x 2
(d) The maximum speed of block is , (Here, x = F/k)
m
Ans. ACD
Sol. The situation is similar as if a vertical spring and a constant force mg acts downwards. Therefore, in this case
also block will execute SHM with time period
m
T = 2
k
At compression x where,
F=kx
F
x=
k
This is also the amplitude of oscillation. Hence,
F
A=
k
At mean position speed of the block will be maximum. Applying work energy theorem
1 1
F. x = k x 2 + mv 2
2 2
2Fx − k x 2
or v=
m
7. The equation y = 4 + 2 sin (6t – 3x) represents a wave motion with

(a) amplitude 6 units (b) amplitude 2 units
(c) wave speed 2 units (d) wave speed 1/2 units
Ans. BC
Sol. The shape of the equation is as shows : y
From this we can see that amplitude of wave is 2 units.
6
coefficient of t
Wave speed v = 4
coefficient of x
6 2
= = 2 units x
3
SECTION –I
(Paragraph Type)
This section contains 2 paragraphs. Based upon the paragraphs 2, 2 multiple choice questions have to be
answered. Each of these questions has 4 choices (A), (B), (C) and (D) out of which ONLY ONE is correct.
Paragraph for Questions 8 to 9
Two identical blocks P and Q have mass m each. They are attached to two identical spring initially unstretched. Now
A
the left spring (along with P) is compressed by and the right spring (along with Q) is compressed by A . Both the
2
blocks are released simultaneously. They collide perfectly inelastically. Initially time period of both the blocks was T.
A A
2
P Q
A
8. The amplitude of combined mass is given by . Find x.
x
(a) 2 (b) 4 (c) 6 (d) 8
Ans. B
From conservation of linear momentum we can see that velocity of combined mass just after collision is
A
v= .
4
A A
v=
2 A 4
m m  m m
Before collision Just after collision
Since, this is the velocity at mean position.

Hence, v = ’ A’
A
or = ' A '
4
A K 2K
or A' = because  ' = w = or
4 m 2m
1
9. The energy of oscillation of the combined mass is given by kA 2 . Find x.
2x
(a) 2 (b) 4 (c) 6 (d) 8
Ans. D
Sol.
2
1 1  A 
E= (2m)v 2 = (2m)  
2 2  4 
m2 A 2 kA 2  2 k 2k 
= =   = or
16 16  m 2m 
2
1 A kA 2
or E= (2k)   =
2 4 16
A certain amount of ice is supplied heat at a constant rate for 7 min. For the first one minute the temperature rises
uniformly with time. Then it remains constant for the next 4 min and again the temperature rises at uniform rate for
the last 2 min. Given Sice = 0.5cal / g0 C, L f = 80cal / g.
10. The initial temperature of ice is given by −8x 0 C . Find x.
(a) 1 (b) 3 (c) 5 (d) 7

Ans. C
11. Final temperature at the end of 7 min is given by 20x 0 C . Find x.

(a) 2 (b) 4 (c) 6 (d) 8
Ans. A
Sol. Let m be the mass of ice and q the rate by which heat is supplied. Then,
q  1 = m  0.5  ( −i )
q  4 = m  80
q  2 = m  1 i
Solving these three equations, we get
f = 400 C
and i = −400 C
SECTION–III
(Integer Type)
This section contains 6 questions. The answer to each question is a single-digit integer, ranging from 0 to 9. The
correct digit below the question number in the ORS is to be bubbled.
1. Pertaining to two planets, the ratio of escape velocities form respectively surfaces is 1 : 2, the ratio of the time
period of the same simple pendulum at their respective surfaces is 2 : 1 (n same order). Then the ratio of their
average densities is 1 : n. Find value of n.
Ans. 4
Sol.
l
T = 2
g
1
or T
g
T1 g2 2
= =
T2 g1 1
g2
 =4
g1
v e = 2gR
or v e  gR
v e1 g1 R1
= . = 1.2
v e2 g2 R2
1 R1 1
  =
4 R2 2
R1
 =1
R2
Further,
GM
g=
R2
4 
G  R3  
=  3 
R2
or g  R
g1 R1 1
 = .
g2 R2 2
 1 1
or  4  = (1) 
  2
1 1
or =
2 4
2. A particle under the acting of a SHM has a period of 3 s and under the effect of another it has a period 4 s. Its
time period under the combined action of both the SHM’s in the same direction is (0.4x) second. find value of
x?
Ans. 6
m 1
Sol. T = 2 or T 
k k
4 9
T has increased times. Hence, k ' = k
3 16
When both are combined,
25 25
k net = k + k ' = k or times
16 16
3. A cubical block of mass M vibrates horizontally with amplitude of 4.0 cm and a frequency of 2.0 Hz. A small
block of mass m is placed on the bigger block. In order that the smaller block does not slide on the bigger
block, the minimum value of the coefficient of static friction between the two blocks is (0.16x). Find value of x.
( Take  2
= 10 and g = 10 m / s2 )
Ans. 4
Sol. g >maximum acceleration in SHM > 2 A
2 A

g
4. A person speaking normally produces a sound intensity of 40 dB at a distance of 1 m. If the threshold intensity
for reasonable audibility is 20 dB, the maximum distance at which person can be heard clearly is (2x) meter.
Find the value of x.
Ans. 5
Sol.
 I 
L = 10 log10   ; where l0 = 10 −12 Wm−2
 I0 
l 
Since 40 = 10 log10  1 
 l0 
l1
 = 104
l0
l 
Also 20 = 10 log10  2 
 l0 
l2
 = 102 .......(2)
l0
l2 r2
 = 10 −2 = 12  r22 = 100 r12
l1 r2
 r2 = 10m ( r1 = 1m)
5. A train of sound waves is propagated along a wide pipe and it is reflected from an open end. If the amplitude
of the waves is 0.002 cm, the frequency 1000 Hz and the wavelength 40 cm, the amplitude of vibration at a
point 10 cm from open end inside the pipe will be (0.0x) cm. find value of x.
Ans. 0

Sol. At 10 cm distance from open end or at distance from the open end there should be a node.
4
6. The internal energy of a gas is given by U = 2pV. It expands from v 0 to 2v 0 against a constant pressure
p0 . The heat absorbed by the gas in the process is xp0 V0 . Find value of x.
Ans. 3
Sol.
Q = W + U
= p0 (2v 0 − v 0 ) +  4p0 v 0 − 2p0 v 0 
= 3p0 v 0
Space for Rough Work
SECTION – I
1. In the following sequence of reactions, identify the product (D).
HBr HBr alc. KOH NaNH 2

CH  CH ⎯⎯⎯→ (A) ⎯⎯⎯→ (B) ⎯⎯ ⎯⎯→ (C) ⎯⎯ ⎯⎯→ (D)
(a) Ethanol (b) Ethyne (c) Ethanal (d) Ethene

Ans: (b)
Sol:
H Br
HBr HBr
CH CH CH CH CH CH
H Br H Br
(A) (B)
alc. KOH
H
NaNH2
CH CH CH CH
(D) Br
(C)
2. The one giving maximum number of isomeric alkenes on dehydrohalogenation reaction is (excluding
rearrangement)
(a) 1-bromo-2-methylbutane (b) 2-bromopentane
(c) 2-bromo-3,3-dimethylpentane (d) 2-bromopropane

Ans: (b)
Sol:
 Br 2
 Alc. KOH
CH3 CH2 CH2 CH CH3 CH3 CH2 CH2 CH CH3
From 1
Pent-2-ene(Major) (Saytzeff product)(A)
Alc. KOH
from 2
CH3 CH2 CH2 CH CH2

Pent-1-ene(Minor) (Hofmann product)(B)
In the given structure, 2-different -carbons are available. Hence, three different alkenes would be formed in
which one, Cis-A, trans-A and B.
Hence, 2-bromopentane (option b) gives maximum number of isomeric alkenes after dehydrohalogenation
(excluding rearrangement).
3. Which of the following compound has the highest pKa value?
OH OH OH OH
Cl NO2 CH3 OCH3
(a) (b) (c) (d)
Ans: (d)
Sol: pka highest i.e. ka lowest
i.e. weak acid
OH
OCH3
 EDG ( +R group )
4. CH2
NO2+BF4–
(X). What is the possible product(s) (X) in the reaction?
O2N
NO2
NO2
(a) (b)
CH2 CH2
O2N O2N
(c) (d) both (b) and (c)

CH2 NO2
O2N
Ans: (d)
Sol:
NO2
NO2BF4
CH2 CH2 +
NO2 NO2
Activating group and

ortho-para directing group
Deactivating group CH2 NO2
NO2
SECTION – I
5. Which of the following reagents are used in the following chemical reaction?
O O
|| ||
CH3 − C  C − CH2 – CH3 ⎯
⎯→ CH3 − C − C − CH2CH3
(a) Reductive ozonolysis. (b) 1% HgSO4, dil H2SO4.

(c) Cold aq. dilute alkaline KMnO4. (d) Oxidative ozonolysis.
Ans: (a, c)
Sol:
O O
(i) O3
CH3 C C CH2 CH3 CH3 C C CH2 CH3
(ii) Zn / H2O
OH OH
cold aq
CH3 C C CH2 CH3 CH3 C C CH2 CH3
dilute alkaline KMnO4
OH OH
- 2H2O
O O
CH3 C C CH2 CH3
6. Which of the following pairs represents enantiomers?
NH2 H CH3 OH
(a) (b) H OH H3C H
H3C H , HO2C CH3
H Cl , H CH3
CO2H NH2 CH3 Cl
CH3 H NH2 CH3

(c) H OH H3C OH (d) H CO2H CO2H H
H Cl , H3C Cl H OH , HO H
CH3 H CH3 NH2
Ans: (a, c)
Sol:
(1) (4)
NH2 H
CH3 H (4) HOOC CH3 (3) Enantiomers

(3) (2)
COOH NH2
(2) (1)
S- R-
(3) (4)
CH3 H
S- R-
(4) H OH (1) (3) H3C OH (1)
(2) (2) Enantiomers
(4) H Cl (1) (3) H3C Cl (1)
R- S-
CH3 H
(3) (4)
7. Which of the following compound shows +R effect on benzene ring?
O
NH−C−CH3 O−CH3 C(CH3)3 O
(a) (b) (c) (d)
Ans: (a, b, d)
Sol:
O
NH C CH3 O CH3 O
All have lone pair on the atom directly attach to benzene ring therefore they shows +R effect.
SECTION –I
(Paragraph Type)
Homolytic bond fission of a covalent single bond gives rise to free radicals. Owing to the presence of an odd electron,
free radicals are highly reactive. They have planar to pyramidal geometry depending upon the groups attached to the
C−atom having odd electron. Alkyl free radicals are stabilised by hyperconjugation whereas allyl and benzyl free
radicals are stabilised by resonance. They are formed as intermediates in the reaction mixture either in the gaseous
phase or in non-polar solvents. Addition of HBr to alkenes in presence of peroxide, the substitution of allylic or
benzylic hydrogen by ‘Cl’ at high temperature or by ‘Br’ in presence of NBS are examples of reactions involving free
radical intermediates.
Now answer the following questions :
8. 3,5−dimethylcyclopentene reacts with N−bromosuccinimide (NBS) in CCl4 in presence of light or peroxide.

Identify the possible product(s).
CH3 CH3 hv
Expected product
+NBS
CH3 CH3 CH3

CH3
(a) (b)
Br
Br
CH3 CH3 CH3 CH3 CH3 CH3

(c) Br and (d)
Br Br Br
Ans: (c)
Sol:
Me CH3 CH3 CH3

Me Me hv
Br +
NBS
Br
Me Me Me Me
Br Br
Me Me Me Me
Br
Br
9. Arrange the following free radicals in the decreasing order of their stability.
• • • •
CH2 = CH − C H2 ; (CH3 ) 3 C ; CH2 = C H ; C H3
• • • •
(a) (CH3 ) 3 C  CH2 = CH − C H2  CH2 = C H  C H3
• • • •
(b) (CH3 )3 C  CH2 = CH − C H2  C H3  CH2 = C H
• • • •
(c) CH2 = CH − C H2  (CH3 )3 C  C H3  CH2 = C H
• • • •
(d) CH2 = CH − C H 2  (CH3 ) 3 C  CH 2 = C H  C H3
Ans: (c)
Sol:
CH3
CH2 CH CH2 > CH2 C > CH3 > CH2 CH

CH3
Resonance stablised Due to Hyperconjugation

−=
Planar monocyclic rings containing (4n + 2) −electrons (where n = 0, 1, 2, 3, and so on), should be aromatic. This is

known as Huckel' s rule for aromaticity. Applying this rule, benzene and its derivatives have six delocalised electrons
and n = 1.
Thus to be aromatic, a molecule must have 2(n = 0), 6(n = 1), 10(n = 2) etc. −electrons in a closed −orbital loop.
Another requirement for aromaticity is planarity of the ring. If the ring is not planar, overlap of p−orbitals is diminished
or prevented, then compound will not be aromatic.
Derivatives of benzene are aromatic as they fulfill both the conditions. Molecules having two or more benzene rings
fused together are called polycyclic benzenoid aromatic hydrocarbons. For example, naphthalene, anthracene etc.
Non−benzenoid aromatic compounds are those which contain a ring that is not six membered. Examples of such
compounds are cyclopentadienyl anion, cyclopropenium cation, tropylium cation etc. Cyclic conjugated compounds,
which possess only 4n electrons, do not satisfy the Huckel rule and are anti−aromatic in nature. In a reaction the reactant
would tend to react with reagents that can result into aromatic products / salts.
10. Which of the following is the correct option regarding the direction of the dipole moment?
(a) (b) (c) (d)
Ans: (b)
Sol:
Aromatic ring
Aromatic ring
11. Which of the following is the correct statement?
(a) gives immediate turbidity with aqueous AgNO3.

Br
(b) Br gives an immediate turbidity with aqueous AgNO3.
(c) Both of them give immediate turbidity with aqueous AgNO 3.

(d) None of them give any turbidity with aqueous AgNO3.
Ans: (c)
Sol:
AgNO3
+ AgBr
Br (Turbidity)
(Aromatic)
AgNO3
Br + AgBr
(Aromatic) (Turbidity)
SECTION–III
(Integer Type)
1. Identify the number of compounds in which positive charge will be delocalized?
CH2 NH3
N N
H H
H
Cl
O
Ans: 5
O O
N N
H H
Cl Cl
CH2 CH2
2. How many of the following compounds is/are aromatic?
(i) N (ii) (iii) (iv)
(v) (vi) (vii) N (viii)

O H
H
(ix) N (x) (xi)

H O
O
Ans: 5
N -
(2e ) O
H - -
(6e ) (6e )
-
(6e )
O O
-
(2e )
3. In the given compounds how many can show geometrical isomerism
CH3
D
(i) (ii) (iii) (iv)
OH
Me Et CH3
Ans: 3
(i)
Me Et Et Me
Me Me
(ii)
Me Me
D D
(iv)
OH OH
4. The total number(s) of stable conformers with non-zero dipole moment for the following compound is/are
Cl
Br CH3
Br Cl
CH3
Ans: 3
Cl Br
Br Cl Br
Br CH3 Br Cl
CH3
Br Cl
CH3 Cl CH3
Cl
CH3 CH3
Eclipse (I) Staggered
CH3 Cl
Br Br Cl
Cl
Br Cl CH3 Br
CH3 CH3
(III) (II)
Staggered Staggered
Staggered conformers are stable conformers.
5. On the following reactions how many reactions are considered as oxidation reaction?
O3
(a)
Ph Ag2O
KMnO4/OH
(b)

(c) LiAlH4
Cl
H2,Ni
(d)

CH3CO3H
(e)
Ans: 3
O3
(a) O + Ph C O
Ag2O
Ph H
KMnO4/OH
(b) CH3 COOH + CO2

CH3 - CO3H
(e) O
6. If 2-chloro-3-methyl pentane is treated with ethanolic KOH solution, how many different alkenes (structural
isomers) would be formed via E- 2 elimination reaction?
Ans: 2
CH3 CH3
alc. KOH
CH3 CH C CH2 CH3 CH2 CH CH Et
E-2
Cl H +
CH3
CH3 CH C Et
SECTION – I
1.. The number of ways of distributing 8 identical balls in 3 distinct boxes so that none of the boxes is empty, is :
(a) 8
C3 (b) 21 (c) 3 8 (d) 5
Ans. B
Sol. We know that the number of ways of distributing n identical items among r persons, when each one of them
n −1
receives at least one item is Cr −1.
8 −1 7! 76
 The required number of ways = C3 −1 = 7 C2 = = = 21
2!5! 2  1
2.. The letters of the word COCHIN are permuted and all the permutations are arranged in an alphabetical orders
as in an English dictionary. The number of words that appear before the word COCHIN is :
(a) 360 (b) 192 (c) 96 (d) 48
Ans. C
Sol. The letter of word COCHIN in alphabetic order are C, C, H, I, N, O.
Fixing first letter C and keeping C at second place, rest 4 can be arranged in 4! ways. Similarly the words
starting with CH, CI, CN are 4! in each case.
Then, fixing first two letters as CO next four places when filled in alphabetic order give the word COCHIN.
Number of words coming before COCHIN are 4  4! = 96
3. The coefficient of t 8 in the expansion of (1 + 2t 2 − t 3 )9 is
(a) 1680 (b) 2140 (c) 2520 (d) 2730

Ans. C
Sol.
We have [(1 + 2t 2 ) − t 3 ]9 = 9C0 (1 + 2t 2 )9 − 9C1(1 + 2t 2 )8  t 3 + 9C2 (1 + 2t 2 )7  t 6 − 9C3 (1 + 2t 2 )6  t9 + ..... − 9 C9 (t 3 )9
 Coefficient of t 8 in the expansion of (1 + 2t 2 − t 3 )9
= 9 C0 [coefficient of t 8 in(1 + 2t 2 )9 ] − 9 C1[coefficient of t 5 in (1 + 2t 2 )8 ] + 9 C2 [coefficient of t3 in(1 + 2t 2 )]

9876 98
= 9 C0  9 C4  24  0 + 9 C2  7 C1  2 =  16 + 72
4  3  2 1 2 1
= 9  8  7  5 = 2520
4.. sec −1(sin x) is real, if
(a) x  ( −,  ) (b) x  [ −1, 1]

(c) x  (2n + 1) , n   (d) x = n, n  
2
As. C
Sol. Use basic concept of domain of sec −1
SECTION – I
5. Let 20! = 2 35    (where  is not divisible by 2 or 3 or 5) then :
(a)  = 18 (b)  = 10 (c)  +  = 26 (d)  +  -  = 22

Ans. ACD
Sol.
 20   20   20   20 
Exponent of 2 in(20)! is   +  2  +  3  +  4 
 2  2  2  2 
= 10 + 5 + 2 + 1 = 18
 20   20 
Exponent of 3 in (20)! Is   +  2 
 3  3 
=6+2=8
 20 
Exponent of 5 in (20)! is  1  = 4
5 
1 1 1 1 1 2a
6. If + + + + = (where a and b are positive: e integers), then :
1!9! 3!7! 5!5! 7!3! 9!1! b!
(a) a + b = 19 (b) a2 + b2 = 181 (c) a + b = 17 (d) a2 + b2 = 149

Ans. AB
Sol.
1  10! 10! 10! 10! 10! 
+ + + +
10!  1!9! 3!7! 5!5! 7!3! 9!1! 
1 10 29
= ( C1 + 10
C3 + 10
C5 + 10
C7 + 10 C9 ) =
10! 10!
 a = 9, b = 10
7.. Which of the following is a rational number ?
 1  3
(a) sin  tan−1 3 + tan−1  (b) cos  − sin−1 
 3 2 4
 1 63   1 5
(c) log2 sin  sin−1  (d) tan  cos−1 
  4 8   2
 3 
Ans. ABC
Sol.
 1 
(a) sin  tan−1 3 + tan−1  = sin = 1
 3  2
 3  3 3
(b) cos  − sin−1  = cos  cos−1  =
2 4  4 4
1 63 
(c) sin  sin−1 
4 8 

63
Let sin−1 =
8
63 1
so, sin  = , if cos  =
8 8
 1 + cos  3
we have, cos = =
2 2 4

1 − cos
 2 = 1
sin =
4 2 2 2
1 63  1 3
Now, log2 sin  sin−1  = log2 =−
4 8  2
 2 2
1  5  3 − 5
(d) tan  cos−1  =
2  3   2
  
SECTION –I
(Paragraph Type)
Let a n denotes the number the number of all n-digit positive integers formed by the digits 0, 1, or both such that no
consecutive digits in them are 0. Let b n = the number of such n-digit integers ending with digit 1 and c n = the number
of such n-digit integers ending with digit 0.
8. The values of b 6 is :
(a) 7 (b) 8 (c) 9 (d) 11

Ans. B
9. Which of the following is correct ?

(a) a17 = a16 + a15 (b) c17  c16 + c15 (c) b17  b16 + b16 (d) a17 = c17 + b16
Ans. A
Sol. For a n
The first digit should be 1.

For bn 1...........1
(n− 2 places)
Last digit is 1, so b n is equal to number of ways of an−1 [i.e., remaining (n – 1) places]
bn = an−1
For cn
Last digit is 0 so second last digit must be 1.
so c n = an−2
bn + c n = an
so an = an−1 + an−2
Similarly bn = bn−1 + bn−2
(i) a1 = 1, a2 = 2
so a3 = 3, a 4 = 5, a5 = 8
 b 6 = a5 = 8
(ii) an = an−1 + an−2
Put n = 17
a17 = a16 + a15 (A iscorrect)
c n = c n−1 + c n−2
so put n = 17
c17 = c16 + c15 (B in incorrect)
bn = bn−1 + bn−2
Put n = 17
b17 = b16 + b15 (C is incorrect)
a17 = a16 + a15
While(D) says a17 = c17 + b16 (D is incorrect)

Given that, f(x) = sin cot −1 ( x + 1) − cos tan−1 x ( )
a = cos tan−1 sin cot −1 x
b = cos(2cos−1 x + sin−1 x)
10. The value of x for which f(x) = 0 is

1 1
(a) − (b) 0 (c) (d) 1
2 2
Ans. A
11. If f(x) = 0, then a 2 is equal to

1 2 5 9
(a) (b) (c)
2 3 9 5
Ans. C
Sol.
f(x) = 0  sin {cot −1(x + 1)} = cos(tan −1 x)
1 1
 sin sin−1 = cos cos −1
1 + (x + 1) 2
1 + x2
1 1
 =
1 + (x + 1) 2
1 + x2
 1 + x 2 = 2 + x 2 + 2x
1 1
 x = − ,so f(x) = 0 for x = −
2 2
Now consider,
a = cos tan−1 sin cot −1 x = cos tan−1 sin  [where, x = cot ]

1 1
 a = cos tan−1 = cos  [where, tan  = ]
1+ x 2
1 + x2
1 x2 + 1 x2 + 1 5
= =  a2 = =
1 x +22
x +2 2 9
1+
1 + x2
1
for x = −
2
SECTION–III
(Integer Type)
1. Let Tn denotes the number of triangles which can be formed using the vertices of a regular polygon of n sides.
If Tn+1 − Tn = 21, then n equals :
Ans. 7
Sol. Key concept : A regular polygon of n sides has n vertices, no more than two of which are collinear. Out of
these n points n
C3  ' s can be formed.
n +1
 Tn = nC3 ; Tn+1 = C3
As per question,
Tn+1 − Tn = 21
n +1
 C3 − nC3 = 21
(n + 1) n(n − 1) n(n − 1)(n − 2)
− = 21
3  2 1 3  2 1
 n − (n − 1)(n + 1 − n + 2) = 126
 n(n − 1) = 42
 n(n − 1) = 7  6
 n=7
2. Let n  2 be an integer. Take n distinct points on a circle and join each pair of points by a line segment. Colour
the line segment joining every pair of adjacent points by blue and the rest by red. If the number of red and
blue line segments are equal, then the value of n is :
Ans. 5
Sol. Number of red line segment = n

C2 − n
Number of blue line segment = n
 n
C2 − n = n
n(n − 1)
= 2n  n=5
2
1 10 102 103 102n

3. The value of − . 2n
C1 + . 2nC2 − . 2n
C3 + ..... is :
81n 81n 81n 81n 81n
Ans. 1
Sol. Given expansion can be written as
1
= [1 − 10  2n
C1 + 102  2n
C2 − 103  2n
C3 + ..... + 102n ]
81n
1
= n
[ 2n
C0 − 10  2n
C1 + 102  2n
C2 − 103  2n
C3 + ..... + 102n  2n
C2n ]
81
1 1 1
= n
[1 − 10]2n = n
( −9)2n = n
 81n = 1
81 81 81
4. The number of real solutions for x, y, if y = sin x and y = sin−1(sin x), where x  [ −2, 2] is _____.
Ans. 5
Sol. From the figure, it I clear that number of solutions is 5.
Y


2
X’ 
  3
X
-2 − 3 - − -1 0
2 2
2 2 2
-1
−
2
Y’
1 1 1
5. The positive integer value of n > 3 satisfying the equation = + is........
  2   3 
sin   sin   sin  n 
n  n   
Ans. 7
Sol. Given, n > 3  Integer
1 1 1
and = +
  2   3 
sin   sin   sin  n 
 
n  n   
1 1 1
 − =
 3 2
sin sin sin
n n n
3 
sin − sin
 n n = 1
 3 2
sin  sin sin
n n n
 3
sin  sin
 2   n n
 2cos    sin n =
 n  2 
sin
n
2 2 3
 2 sin  cos = sin
n n n
4 3
 sin = sin
n n
4 3
 = −
n n
7
 =  n=7
n
6. The number of distinct solution of the equation, log1/ 2 sin x = 2 − log1/ 2 cos x in the interval [0, 2], is –
Ans. 8
Sol.
log1/ 2 sin x + log1/ 2 cos x = 2
log1/ 2 sin x cos x = 2
1
sin x cos x =
4
1
sin2x =
2
1
sin2x = 
2
using graph we can say there will be 8 solution

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Term-III (ADVANCED)/PAPER - 1 CRONOS 25

BATCH : CRONOS 25 (ADVANCED) – PAPER - 2

Time: 3 hrs. Beware of Negative Marking Total Marks: 180(PCM)

B. Filling the top-half of the ORS:

C. Question paper format and Marking scheme:

7. The question paper consists of 3 parts (Physics, Chemistry and Mathematics).

Champ ID : ________________________________ Batch________________

Name of the Candidate :___________________________________________

Substituting the values of k, k1 and k 2 we get.

(a) The block will execute SHM.

7. The equation y = 4 + 2 sin (6t – 3x) represents a wave motion with

Paragraph for Questions 8 to 9

Before collision Just after collision

Since, this is the velocity at mean position.

Paragraph for Questions 10 to 11

the last 2 min. Given Sice = 0.5cal / g0 C, L f = 80cal / g.

10. The initial temperature of ice is given by −8x 0 C . Find x.

(a) 1 (b) 3 (c) 5 (d) 7

11. Final temperature at the end of 7 min is given by 20x 0 C . Find x.

Solving these three equations, we get

Sol. g >maximum acceleration in SHM > 2 A

1. In the following sequence of reactions, identify the product (D).

HBr HBr alc. KOH NaNH 2

(a) Ethanol (b) Ethyne (c) Ethanal (d) Ethene

(a) 1-bromo-2-methylbutane (b) 2-bromopentane

(c) 2-bromo-3,3-dimethylpentane (d) 2-bromopropane

CH3 CH2 CH2 CH CH2

3. Which of the following compound has the highest pKa value?

(c) (d) both (b) and (c)

Activating group and

(a) Reductive ozonolysis. (b) 1% HgSO4, dil H2SO4.

6. Which of the following pairs represents enantiomers?

CH3 H NH2 CH3

CH3 H (4) HOOC CH3 (3) Enantiomers

(a) (b) (c) (d)

Paragraph for Questions 8 to 9

Now answer the following questions :

8. 3,5−dimethylcyclopentene reacts with N−bromosuccinimide (NBS) in CCl4 in presence of light or peroxide.

CH3 CH3 CH3

CH3 CH3 CH3 CH3 CH3 CH3

Me CH3 CH3 CH3

CH2 CH CH2 > CH2 C > CH3 > CH2 CH

Resonance stablised Due to Hyperconjugation

Paragraph for Questions 10 to 11

(a) (b) (c) (d)

11. Which of the following is the correct statement?

(a) gives immediate turbidity with aqueous AgNO3.

(b) Br gives an immediate turbidity with aqueous AgNO3.

(c) Both of them give immediate turbidity with aqueous AgNO 3.

1. Identify the number of compounds in which positive charge will be delocalized?

2. How many of the following compounds is/are aromatic?

(i) N (ii) (iii) (iv)

(v) (vi) (vii) N (viii)

(ix) N (x) (xi)

3. The coefficient of t 8 in the expansion of (1 + 2t 2 − t 3 )9 is

(a) 1680 (b) 2140 (c) 2520 (d) 2730

= 9 C0 [coefficient of t 8 in(1 + 2t 2 )9 ] − 9 C1[coefficient of t 5 in (1 + 2t 2 )8 ] + 9 C2 [coefficient of t3 in(1 + 2t 2 )]

4.. sec −1(sin x) is real, if

(a) x  ( −,  ) (b) x  [ −1, 1]

Sol. Use basic concept of domain of sec −1

5. Let 20! = 2 35    (where  is not divisible by 2 or 3 or 5) then :

(a)  = 18 (b)  = 10 (c)  +  = 26 (d)  +  -  = 22

(a) a + b = 19 (b) a2 + b2 = 181 (c) a + b = 17 (d) a2 + b2 = 149

Champ ID : ________________ Batch