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Comprehensive Questions
Comprehensive Questions
COMPREHENSIVE OUESTIONS
Na ENH,OH
250cm
H,SO,
A B C
(eCAN)
(eA)
(v) A
IaAAT H,SO, 4g B f A I (RHI)
(eaI)
(CAI)
(vii) 100 mL 5 A DF JAg SIK NaOH IAD AT (Burette Cleansing): efs
1F H,SO, RAF:
br
The Royal Scientific Short Questions-Answer
Publications
H,SO, q ST*9=]x2+32 + 16 x4
=98
W M= 40g
qaT,S= MV(L) V= 100mL =0.1L
S=0.1M
.. w=SMV
=0.1 x 0.1 x40 w=?
= 0.4g
OR, GI|S 9IGA (I I T, 0.4g NaOH *
AA: S5 HNO, 5IF HCI, ù H;SO4, GRoH A O5 fAGA AQT A100 mL SINO ÞA 100
yg*I G 10 M HSO, 43
H,SO, 2H*+ so
.:. (H]=(2 x 10) =20 M
. pH =-log [H]
=- log (20)
=-1.30< 2.5
Na + H,0- NaOH + H,
br&
The Royal Scientific Publications Comprehensive Questions
....
COMPREHENSIVE OUESTIONS
B t4,
V,S, = VS SACAA qAAI, S| =10 mol
nACA NNOR,V= 100 ml.
150 mL 100 mL 25°C GNTqA V,Si
10 (molL) 1, S2V:
10* (molL') MY, 47 y<9 NOA,V)= 150 + 100
100 x 10
Kp = 1,9x 10-33 250
= 250 ml
Y g T, S=?
= 4x10 molL
A-i B
.: fA Y NAA YAIA, 4 x 10 molL-!
) A a s MN, T TT AI
MN, M*+3N
t3, MN, I HIS=S molL
Kgp =(M']x NT
S(3s) GiJO, S = 10 mol L-!
= 27 x
- 27 (10
-2.7 x 10-" mol'+
PN P+ N
0A IaS yCA MN, y I qAAIA, 10 molL-!
Q0, PN GCa Q,0.1M 2A
P rNLA qAA. P|=0.1 M
N INGA qAIAT, N =0.I M
Ias MN,
4, PN GS N
MY, M* +3Y A PN
K,[M'] x [Ny
2.7x 10=Sx(3S+
0.1' [: rs, Kgp =2.7x10')
T,
-Sx(3S)' +3 x(3S)x0.] +3 x3S x(0.1 +(0.11
=S x [27S' + 2.78*+ 0.09S + 0.001]|
0.001S
= 275* + 2.7S' + 0.09S +
x 10-! = 0.001S[.: s, s³. s? Fe + NH,OH Fe(OH),+ NH,.
I, 2.72.7x 10-l (HS)
.: S= 0.00]
mol Ll
= 2.7 x 10
2.7 x 10 moll.-!
yo. MN, ACIA AY GJST, Fe(OH),+ NH,
Fe + NH,OH
x 10* molL-'I
10 mol L' (L*RIA (GI 2.7
Chap
rO
01,32 I
(CA)
hc
(A) AEIN6.626 x10x3x10
486.27 x 10-9
= 4.09 x 10-9
Sclentine Publlcations Comprehensive Questions
The Royol *********************....
COMPREHENSIVE OUESTIONS
A
2 13 14 15 16 17
A B D E X
R
,N’1s² 2s? 2p
O ’ 1s² 2s 2p
(eCuN)
(ea)
(eAr)
(2I)
aN fs afafATCAZ (Be)
f I Be
Be
sB’1s 2s 2p
The Royal Scientific Publications
Comprehensive Questlon
.* * * *t* * *sts.
D-Is2s2p': ITA S8
C(6) - 1s 2s
1
2p
14
sp'*fs
N(7) 1s 2s
2p
11 11
11 1
sp' a f
iv %DAO (C)R DH, GCH, ICH,
NaClo KCI
+4 4R Na
NaCI
****
(Si) RC aFg
sfACS (O) 11R DE,
qEN C0, 014,
28
HÜ
-0-Si-0- Si -0- Si -0
CI
C...H: CI
HF---
The Royal Scientific Publications Comprehensive Questlony
......
........bs*e**
*****************.,.
3d
n 4H
P (n- 1) d ns f f S CN gU
(n - 1) d ns 3c 4
R )d ns'
(n - ) ns
() Fe d'sp*IA
4p
(i) [Q(CN)I SUIfDE sJQCN),URUNCAv, 3d 4s
4p
(Fe(CN)J’1| 1 11|
CN CN CN CN CN CN
(T)
3d 4s
4p
(AI)
3d 4%
4p
Fe ’
(eKA)
d'sp'ER
P, O. R, S bIsOs TJUKAG }HH 3d 4s 4p
feUP RSA(n-1 d' ns, (n - l)d° ns, (n - l)d° ns', (Fe(CN).J1|1|: :
CN CN CN CN CN!
fReJ E - 3d' 45. 3d'4s 3d°4s'. 3d°4s* d'sp'*rNa
q8R P, Q, R, S MSISÍD 21 RA- SJRNIA
er-3) O
(Sc), ISK (Fe), S(Cu) GR fRS (Zn) I
$g (Cu) g P AT-G 21
iii 4AA R Gafo
1Sc ’ [Ar] 3d'4s* Sc’[Ar] 3d° 4s°
26Fe ’ (Ar] 3d°4s Fe ’[Ar] 3d 4s°
Cu ’ (Ar) 3d° 4s 2Cu’ Is' 2s² 2p°3s? 3p 3d'°4s'
29Cu -’ [Ar] 3d°4s'
3oZn ’ [Ar] 3d'4s Zn ’[Ar] 3d 4s 21Sc ’ ls' 2s' 2p° 3s' 3p" 3d' 4s
Cu' ’ 1s 2s 2p°3s² 3p 3d
Se’ 1s 2s 2p° 3s²3p 3d
Waf4GM, 4p
11 Cu AM19 aItGJO A (8 foA) 4s
cu1|11 1---< AE
3d
Non-Degenerate
4 4p 4d
3d
Cu’
4s 4d
3d
sp'd
H,N: :NH,
Cu
H,N: :NH,
Chapter
2sFe ’ 1s 2s' 2p° 3s3p°3d° 4s viG A O(3d°4s) cafo q r (Fe) 4R S
(3d" 4s')
1 1 1
Fe(26)- [Ar] 3d'= 1 1
R Zn g MIT.fHUA:
Zn (30) ’ [Ar] 3d=111 1 1 1
R aft
COMPREHENSIVE OUESTIONS
K, aifM afTE
AX(g) +Xlg), AH=+ (ve) ffera: AX(g) AX,(g) + X{g)
AXMg) 0
sn/ BTjatqR 15 atm btc AX, 4T25%f<U
|-x X
1-x X X
(ear)
-x)
AX; AX, + X,
0
|-x X
:. K,=
PAx, XPs
(eUI) PANE
(0.25 0.25
(.25P2sP)
0.75
1.2P
AX(g) AX,(g) +Xg) (0.25) O
Chapter-4
1.25 x 0.7 XP
0
·|-x X X
0.0625
GAG QAI: |-x+x+ x=|+X 0.9375
x 15
I-x X = | atm
|+x
|+X
I-x X
1+x*P T+xXxP 1+**P K, = K, (RT)h
[ ,CAIÜ T = P] 1, K, = K, x RT
R=0.0821 L atm molk
PAX, xPx; I,KRT BNIAT, T=30°C
PAXs 0.0821 x 303 An =2-|=|
= 303k
) 0.0402
|- X
P .:. K,=0.0402 mol L'
P AX; AX, + X,
(|+x)(I-x) |-0.25
0
0.25 0.25
=0.75 0.25 0.25
80
The Royal Scientific Publicotions
0.75
2
0.25 0.25
2 2
log K, -( -AH
Compr* * * *e*hens* * * * * *iv* *e Quevl
=0.375 0.125 0.125
.:. Ke [AX] x[XI
[AX<]
0.125 x0.125
0.375 log K,
=0.04 16
HOR, f R, = 0,0416 mol L
K,
x*P
x
K, =latm
fafaurftbry e
X=0.3
A, x*P =| -x*
A, P
T.P=03
0.3
. P= 10.11 atm
yoR, DUE AID ST 10.1| atm AAB, 4% 30%
AX(g) AX(g) + X(g); AH =+(ve)
AXs = AX, + X,
x*P
K,-1-x
x*x 7.5 ArAKEF, K,=Iatm
1,|=
fafés s19, P' log K,-(-,)+F
A, 7.5x* =|-x
1,7.5x*+x*= 1 -
Ai,8.5x= | =7.5 atm
log K, qAARbufD 24,
8.5
.. X
log Ky
pter-4 O =0.343 mol
100
054 , 100
= 34.3%.
SAR,fJGA NIAS fsrea (34.3 - 25)% = 9.3%
830
Royal Sclentllc Publlcatlons Comprehensive Questions ....
(aur)
AXg) AX(g) X,\g); AH (ve)
PAxs
[AXIIX] (K) B Ga fAuaa YA1.5% g 3pH A A| (U)
|AX]
PV = nRT
1,P-RT K, =u'c
K, = L8 x [0
..P=CRT 1,a A , (=05M
=CAx, RT
.. PAX, 1.8 10
Px, Cxy RT 1,a 0.5
CAx, RT
PANs .. a =0.006
(CAx,RT) x (C«,RT)
yodR, K, CAxRT (H]=Ca
=0.5 0.006
[AX][X1,x RT 0.003
, Ky [AXJ
:. K,= K,RT :. pH =-log [H]
=- log (0.003)
- 2.52
AXS(g) AXilg) +X{g): AH =+(ve)
K, =K,(RT)M
AB TA 0.3M NaOH faa NaOH
1, 8K, = K, (RT)
1,8= RT
8 K,=8K, NaOH Na -OH
1, TX An =2-|= | mol NaOH =I mnol OH
1,T0.0821
..T=97.44K
R =0.0821 L. atm mol'K
.. pOH =- log [OH]
=03 M
=- log (0.3)
=0.52
:. pH = 14-pOH
= 14-0.52
CH,COOH NaOH = |3.48
30 mL 15 mL A+B Chapter-4
O
0.5 M
0.3 M
K,= 1.8 x 10
A B
(I)
(eAN)
n,
n, =0.0045 mol
s NH,
sfarIfTS NH,OHb
pH pk, + log n, n, =0.0105 mol H ARAT
0.0045
=-kg(1.8 x 10 )+ log0.0105 K, = 1.8 x 105
= 4.38 y4, pH =? NH,OH NH, +OH
CARY TAS pH < 7
NH,CI’ NH, + CI
b 7 C IA CH,COOH qR CH,COONaf A OH ARAII NH,OH
CH,COOH H'+ CH,CO0
CH,COONa Na' + CH,CO0
n, = S,V, a5 yA0,S, =0.5 M
= 0.5 x 0.03 af5 SIWSA, V, = 30 ml.
= 0.015 mol
CH,COOH GeA PAAI
=0,031.
H+ CH;CO0 CH,COOH n, = S, V, 9 A , S, = 0.1
=0.1 x X
= 0.lx
K, = ac
faATSN uI,c = |0%
(0.1) × 0.5 =0.1
|-0.1 yAIAT, C= 0.5 M
=5.5 x,10
.. K, = 5.5 x 10
892
Sclentific Publications Comprehensive Questions
TheRoyal
HCIy49 9 0 J
A
R, UAA AA pH HAg 1L
CH,CO0H fATS F*, 1.5 x 10'g HCI AIS A0 A|
=yl.8x10"x0.5 K,= 18x 10-5
= 0.003 M I.5% NaOH 3AIAIK I00 mL yA I5 g NaOH I
C=0.5 M
(0.003)
=-log
. pH -2.52 1000W
S
MV W= L.5g
1000 × .5 V= 100 mL
10x 0.1 HCOOH 4 furg R$, M= 23 + 16+ |= 40
= 0.004 K, =.8 x 10 40 x 100
(0.004) HCOOH 47 yIAI, =0.375 M
log
. pH=- C=0.1 M
= 2.4
NaOH ’ Na + OH
IH']=(0.003 + 0.004) M : Imol NaOH =| mol OH
= 0.007 M .: 0.375 M NaOH OH WR(AA EAAA=(| x0.375)M
.. pH=-log (0.007) - 0.375 M
=2.15
%pH A IAA pH R RAIS" .. pOH =- log [OH 1
=-log (0.375)
= 0,426
:. pH = 14 - pOH
= 14-0,426
= 13.574
[Saltl
pH =pk, t log (Acid] [Acid] 0.0105
(Salt] 0.0045
[Saltl
,pk, =pH- logAcid] [Salt] 0.0045
0.0045 [Acid] 0.0105 gAA RA S TRILA -84, -393 QR -220 kJ mol
.- logK, = 4.38 - log o 010s
Pa}ATOCA Va BY -1370 kJ mol
I, -logk,=4.74 (2) HCl+ NaOH= NaCl + H.O
I, logk, =-4.,74 (3) CH,COOH + NaOH =CH,COONa +H,0; A|I =-5432 kJ
1, K, = 0474 (4) HF + NaOH = NaF + H,o
.. K, =1.8 x 10
(b60 ) Chapter-4
(iii) (2) R AIK e Bt (3) R AIA
C,H,+30’2CO, + 2H,0
COMPREHENSIVE OUESTIONS
6-10 f
Ugg f f o (25 - 30)°CSITAI3
(eA)
(etui)
(eAI)
CeH,O,| + H,0. 37°C
apter-5 O
7-8% TMI
y08
Publications Comprehensive Questions
Royal.Scientific
The
.....
L-OOH ’L.+HOO.
T¢)
A-H+ L, ’ LH+ A. (fS Y
CH,COOH)
fbu- 4a 15 Rp¢ft fsASA (6-10%
(C,HOs)n nC1H0,
5 g I AQe
pKa 4.74 QSTA 4A pH4
CiH,,0,+ H,0
orChapte
-5