MEERUT PUBLIC SCHOOL

MID TERM EXAMINATION (2023-24)

CHEMISTRY ANSWER KEY
CLASS 11TH

SECTION A T = 400 K
1. (c) ∆G° = ?
2. (d) ∵ ∆G° = −2.303 RT log K
3. (b) = −2.303 × 8.314 × 400 × log 2
4. (b) = −2.303 × 8.314 × 400 × 0.3010
5. (a) = −2305.31 J mol−1
6. (c) = −2.05 kJ mol−1
7. (a) 19. Lewis acid is any acid which is an
8. (c) electron pair acceptor.
9. (d) Lewis Base: Lewis base is any
10. (a) base which is an electron pair
11. (b) donor.
12. (a) Lewis acid : BF3
13. (d) Lewis base : OH- , F- , NH2-
14. (a)
15. (c) 20. Electron gain enthalpy is the
16. (a) tendency of an isolated gaseous
atom to accept an additional
SECTION B electron to form a negative ion.
Electronegativity is the tendency of
17. CaCO3 + H2SO4 → CaSO4 + H2O + the atom of an element in a
CO2 chemical compound to attract a
100 g CaCO3 require 98 g H2SO4 shared pair of electrons towards it
∴ 20 g CaCO3 will require (98/100) x in a covalent bond.
20
= 19.6 g H2SO4 21. The structure of CIF3 is shown as
(i)CaCO3 is the limiting reagent.
100 g CaCO3 require 98 g H2SO4
20 g CaCO3 will produce (136 /100) x
20
=27.2 g CaSO4 below:
(ii) 27.2 g CaSO4 will be formed. Due to Ip-lp repulsion, CIF3 is T-
shaped.
18. △G=△H−T△S
So, for △G=0 The structure of BF3 is shown as
we have △H−T△S=0
or △H=T△S
T=△H△S
=−95.4×1000 J−198.3 JK−1 below:
=481 K
B has 3 valence electrons. All of
OR
these, three electrons are used to
Given, K = 2
form bonds with three F-atoms. So, it
R = 8.314 JK−1 mol−1
contains three bps and zero lp. As
there is no lp in BF3, so it is planar.

SECTION C

22. (a) As number of electrons in (n-1)

d subshell and valence shell is
equal to 12 i.e. 10 + 2 = 12. So, it
belongs to group 12
(b) It belongs to d - block as last
electron enters in the d subshell. = -(log 3.75 - 2 log 10)
(c) The name and symbol of the = (2 - log 3.75)
element with atomic number 112 = (2 - 0.574)
are Ununbium and Uub = 1.426
pH = 14 - pOH = 14 - 1.426
23. = 12.574

25. (a) In Mg, its valence orbital 3s is

full and to remove one electron, it
will require more energy. So, we
can say that the first ionization
potential of Al is less than the first
ionization potential of Mg.
(b) Zinc is not considered a transition
element because it has completely filled
24. Molarity of HCl d-orbitals in its ground state and oxidized
= (3.2/ 36.5) x 1 0.089 M state. Transition metals form stable ions
with incompletely filled d-orbitals
= 8.9 x 10-2
(c) After adding one electron to the
Since HCl is completely ionized, oxygen atom, it becomes a uni-negative
[H+] = 8.9 x 10-2 mol L-1 ion. Due to this, the size of oxygen atom
pH = - [log H+] increases and the nuclear force of
= -[log 8.9 x 10-2] attraction on the electrons decreases.
= -[-2 + 0.7762] Also, the new incoming electron
= 1.2238 experiences repulsion. So, energy has to
pH of 0.3g of NaOH in 200 mL of be supplied to add the second electron.
solution Hence, the second electron gain enthalpy
for oxygen is positive.

26.
27. (a) In NF3, N is less electronegative
as compared to F but in NH3, it is
more electronegative than H. And in
case of same central atom, as the
electronegativity of other atoms
increases, bond angle decreases.
(b)