Preliminary Examination Secondary Section Subject: Chemistry (Science Paper 2) Std: Std10 Date: 11-02-22 Time: 12 hours MM: 40 Note: Attempt all questions from Section A and any three questions from Section B The intended marks for questions or parts of questions are given in brackets( ). Section A(10 marks) Attempt all questions Question 1 Name the following by choosing the correct answers to the questions from the given options. (Do not copy the question, Write the correct answer only.) [10] i) A hydrocarbon which is greenhouse gas: a)Ethane b) Propane ¢)Methane d) Ethene ii) The tendency of an element to form chains of identical atoms: a) Isomerism b) Substitition c) Addition d) catenation iii) The gas evolved when dilute HCI reacts with metal sulphide: a) Sulphurdioxide b) Hydrogen sulphide c) Sulphite d) Sulphurtrioxide ivyThe hydrogenation of ethene in presence of Nickel forms: a) Ethylene b) Ethyne c) Ethane d) Polythene WChloroform is a product formed due to: a) Oxidation b) substitution c) hydrogenation d) Addition vi)An alloy of aluminium that does not contain copper: a) Duralium b) Magnalium c) Alumina d) bauxite vii) Carbon to carbon double bond is found in: a)Acetic acid b) Ethyl alcohol c) 2- butylene d) Acetaldehydeviii)The formula Al2Os refers to: a)Zine blende b) Corundum c) Cryolite d) Bauxite ix) The gas evolved when copper reacts with concentrated nitric acid: a)Nitrogen dioxide b) Nitric oxide c) Nitrogen d) Oxygen x)Aqua regia is n mixture of : 2)2part HCL and 1 part FINOs b) 3 part cone.HCl and 1 part cone. HNOs c)3 part con HCl and 1 part HINOs d) 3 part cone. HNO3 and 1 part conc:HCl Section B (30 Marks) (Attempt any three question) Question 2 i)Give reasons for the following : @ 1) Methane does not undergo addition reactions buit ethene does. byt is dangerous to burn methane in an insufficient supply of air. ii)State the following = @ a)Product formed when ammonia is burt in exeess of oxygen b)The drying agent used in laboratory preparation of HC! gas ii) With reference to conversion of Alumina to pure aluminium answer the following: @) 2) Give the equation forthe reaction which oceurs atthe eathode during the extraction of aluminium by electrolysis. b) Name the electrolyte used and also give their ratio by weight. ©) Why is layer of powdered coke sprinkled over the electrolytic mixture? iv) Name the gas evolved in each of the following: ® a) Complete oxidation of methane ) Sulphur is oxidized by concentrated nitric acid ) Magnesium nitride reacts with warm water Question 3 )Give a balanced chemical equation for each of the following: @ 2) When concentrated sulphuric acid reacts with glucose b) When silver.nitrate reacts with dilute hydrochloric acid. {i) State one relevant observation for each of the following reactions: @ a) Excess of chlorine gas is reacted with ammonia gas b) Copper sulphide is treated with dilute hydrochloric acid tify Give the IUPAC name for each of the following : “ @ H it a) H-C=0 b) EC oe 9 ve de kh hnG) Equati Sodium nitrate a a Anne Rock salt (more than 300°C) [by Sal Ammonine 2) Question 4 3) In the given equations ident ‘ations identify the role played b: ic aci DES Sees Played by concentrated sulphuric acid, (2) b) SORBED CuSO4 + 5H30 aa ‘action of cthane with chlorine in presence reataed , iii) For the Preparation of hydrochloric acid in the laboratory: @B) 8) Why is direct absorption of hydrogen chloride gas in water not feasible? ‘b) What arrangement is done to dissolve HCI gas in water and why? ©) What do you observe when a gas Jar containing HCI gas is inverted over a jar full of ammonia gas ? iv)Draw the structural formula for each of the following: @) i) Ethanoic acid ii) But-2-yne iii) 1, 1,2,2 tetra chloro pentane Question 5 * i) Identify the term or substance in the following: (2) a)The compound which is added to lower the fusion temperature in extraction of aluminium b) The reaction in which hydrogen of an alkane is replaced by a halogen. {i)Distinguish between the following: @ a)Dilute HCI and dilute nitric acid using silver nitrate solution. b) Dilute HCI and dilute sulphuric acid using lead nitrate solution iti)Write the balanced chemical equations for each of the following reactions: @) a) Action of cold and dilute nitric acid on copper b) Reaction of bromine with ethyne ©) Reaction of ammonia with heated copper oxide iv) With reference to the contact process answer the following: @ a)Give the steps that take place in the absorption tower. Name the catalyst and why is it used? c)Why is the catalyst only initially heated?Question 6 i)Give one word for the following: @ a) Naturally occurring minerals from which metals are extracted. b)Oreanic compounds having same molecular formula but different structural formula. ii) a) Fill in the blanks with the choices given in brackets: 2 32) The absorption tower used for preparation of nitric acid is packed with acid resistant (silica / quartz) ’b Substitution reactions are characteristic reactions of - (alkyne, alkene, alkane) iit) Give a balanced chemical equation for each of the following: @ 2) When methane reacts with oxygen in excess b)Concentrated nitric acid reacts with carbon. ) When concentrated sulphuric acid reacts with copper carbonate iv)With reference to laboratory preparation of nitric acid answer the following: (3) a) How is nitric acid prepared from chile salt petre? b) Why is concentrated sulphuric acid used? c) Why is high temperature above 200°C not preferred? 4) Full apparatus is made of glass. Explain END.