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STUDENT NAME

CLASSROOM CONTACT PROGRAMME

(ACADEMIC SESSION 2023-2024)

Pre-Nurture & Career Foundation Division

CHEMISTRY OLYMPIAD
MOCK TEST # 1 (OPTIONAL)
BATCH - WSNSEC
PLEASE READ THE FOLLOWING INSTRUCTIONS CAREFULLY
1. This question paper contains 60 Questions. The questions appearing in this paper are based on Chemistry.

2. Duration of the test is 120 Minutes. Total Marks are 216.

3. There are 3 Marks for each correct answer and –1 Negative marking for each incorrect answer for single
correct questions (48 Questions) and 6 Marks for correct answer and No negative marking for Multiple
correct questions (12 Questions).

4. Student is not allowed to use calculator while attempting the question paper.

5. Student must abide by the instructions issued during the examination by the invigilators or the centre incharge.

6. Before attempting the question paper ensure that it contains all the pages and that no question is missing.

7. A candidate has to write his / her answers in the OMR sheet by darkening the appropriate bubble with the help
of Blue / Black Ball Point Pen only as the correct answer(s) of the question attempted.

8. Use of Pencil is strictly prohibited.

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Your Hard Work Leads to Strong Foundation

 CHEMISTRY OLYMPIAD TEST # 1

HAVE CONTROL ¾® HAVE PATIENCE ¾® HAVE CONFIDENCE Þ 100% SUCCESS

6. 1 mole of each O2, SO2, Xe and Kr with Vander
section-a waals constants (atm L2 mol–2 ) 1.3, 6.8, 4.2,
and 2.3 respectively is kept separately in four
1. The pair of species having same percentage different vessels of equal volume at identical
(mass) of carbon is: temperature. Their pressures are observed to
P1, P2, P3 and P4 respectively. On the basis of
(1) CH3 COOH and C6H12 O6 this data alone, select the correct option
(2) CH3COOH and C2H5OH (Assuming the effect of 'b' to be same).
(1) P1 < P2 < P3 < P4 (2) P2 < P1 < P3 < P4
(3) HCOOCH3 and C12 H22O11
(3) P2 < P3 < P4 < P1 (4) P3 < P2 < P4 < P1
(4) C6 H12 O6 and C12 H22 O11
2. The number of moles of NaOH required to 7. (
The value of (n2 + n1 ) and n 22 - n12 ) for He+
completely react with 20 ml of 0.1 M NaH2PO3 ion in atomic spectrum are 4 and 8 respectively.
The wavelength of emitted photon when
solution and 40 ml of 0.1 M NaHCO3. electron jump from n2 to n1 is
(1) 8 × 10–3 (2) 2 × 10–3
32 9
(1) RH (2) RH
(3) 4 × 10–3 (4) 6 × 10–3 9 32
3. The ratio of the difference in energy between
9 32
the first and second Bohr orbit to that between (3) 32R (4) 9R
H H
second and third Bohr orbit in He+ ion is
(approx.) 8. A closed rigid empty vessel is maintained at
87°C. By any mechanism, COCl 2 (g) is
introduced in the vessel at 4 bar. If after a long
4 1
(1) (2) time, the total pressure of gases in the vessel
9 3 become 7 bar, then KP for the reaction :
CO(g) + Cl2(g) ƒ COCl2(g)
27 1
(3) (4) 1
5 2 (1) 9 bar (2) bar
9
4. Ammonia at a pressure of 5 atm and H2S gas
1
at a pressure of 10 atm are introduced into an (3) bar -1 (4) 9 bar–1
9
evacuated vessel.
9. In the redox reaction
NH4HS(s) ƒ NH3 (g) + H2S(g), KP = 62.5 atm2 xMnO + yPbO2 + z HNO3 ¾® a HMnO4 + b
The total pressure of gases after long time is: Pb(NO3)2 + c H2O
(1) x = 2, y = 5, z = 10
(1) 15 atm
(2) x = 2, y = 7, z = 8
(2) more than 15 atm (3) x = 2, y = 5, z = 8
(3) less than 15 atm (4) x = 2, y = 5, z = 5
(4) unpredicted 10. Copper metal crystallizes in FCC lattice. Edge
5. Calculate the ratio of rate of effusion of O2 and length of unit cell is 362 pm. The radius of
H2 from a container containing 16gm O2 and largest atom that can fit into the voids of copper
2gm H2 : lattice without disturbing it
(1) 1 : 8 (2) 8 : 1 (1) 53 pm (2) 45 pm
(3) 1 : 4 (4) 4 : 1 (3) 93 pm (4) 60 pm

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 PRE-NURTURE & CAREER FOUNDATION DIVISION TEST # 1
11. A solid crystallises as cubic close packing of 16. Consider the following reactions:
O2– ions. Ax+ ions occupy 25% of the tetrahedral IO3– + 6H+ + 6e– ® I– + 3H2O ; E º = + 0.907 V
voids and B y+ ions occupy 50% of the IO3– + 3H2O + 6e– ® I– + 6OH– ; E º = + 0.260 V
octahedral voids. The suitable values of 'x' and Predict where does IO3– acts as a better oxidant?
'y' are
(1) In acidic medium
(1) x= 1, y = 3 (2) x = 2, y = 1
(2) In basic medium
(3) x = 3, y = 2 (4) x = 1, y = 2
(3) In pure water
12. At a certain temperature the following data were
collected for the reaction (4) Equally effective in both acidic and basic
2ICI + H2 ® I2 + 2HCI mediums
O
Initial Initial Rate of H \ ||
17. C=O CH3–C–H
Concentrations formation of I2 (Ms–1) H

\
I II
[ICI] (M) [H ]2
0.10 0.10 0.0015 O O
|| ||
0.20 0.10 0.0030 CH3–C–CH3 Ph–C–Ph
0.10 0.05 0.00075
III IV
Determine overall order of reaction
Which of the following order is correct for
(1) 0 (2) 1
nucleophilic addition on these substrates?
(3) 2 (4) 3
13. Benzene burns according to the following (1) I > II > III > IV (2) III > II > I > IV
equation (3) II > I > III > IV (4) IV > III > II > I
2C6H6(l) + 15 O2(g) ¾® 12CO2(g) + 6H2O(l) 18. Use of a strong base in b-dehydrohologenetion
DH° = –6542 kJ reactions prefers
What is DE° for the combustion of 1.5 mole of (1) E1 pathway (2) E2 pathway
benzene (3) Both (1) and (2) (4) SN1 pathway
(1) –3271 kJ (2) –9813 kJ
(3) –4906.5 kJ (4) None of these 19. O
14. Which of the following do(es) not represent
N N N N
DH formation of the product
H H H
1
(I) H (g) + (aq) ¾® H+ (aq) I II III IV
2 2
2 Which of the following order is correct for the
(II) O (g) ¾® O2 (g)
3 3 basic strength of these compounds?
(III) NH4+(g) + Cl– (g) ¾® NH4Cl(s) (1) II > I > IV > III (2) III > IV > II > I
(IV) P4(black) + 5O2(g) ¾® P4O10(s) (3) I > II > III > IV (4) IV > III > I > II
(V) Reaction representing DHcomb of C (graphite). 20. Among these nucleophite, nucleophilicity
(1) I, IV, V order is?
(2) II, IV !
NH2, OH!, NH3, F!
(3) II, III, IV
(1) NH!2 > OH! > F ! > NH3
(4) II, III, IV, V !
(2) NH2 > OH! > NH3 > F!
15. What is the pKb of a weak base whose 0.1M
!
solution has pH = 9.5? (3) NH2 > NH 3 > OH! > F !
(1) 7.5 (2) 8 !
(4) F! > OH ! > NH 2 > NH 3
(3) 9 (4) 10

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 CHEMISTRY OLYMPIAD TEST # 1
21. The number of groups showing +R effect = X.
The number of groups showing –R effect = Y.
(3) 1, 4 – dimethyl cyclo butene
Find value X – Y
(i) –CH=O (ii) –CONH2
Cl Cl
O
||
(iii) –NH– C –OH (iv) –NO2
1– Bromo – 3, 3- dichloro
O (4) cyclopentane
||
(v) –O– C –R (vi) –NH2
Å Br
(vii) –O–N=0 (viii) – C H2
(ix) –OH (x) –O! 26. Which of the following is unstable at room
temperature?
(1) 1 (2) 2
(3) 3 (4) 4 H

22. CH3 – Cl + CH3 – CH2 – Cl ¾¾¾¾Na

Dry Ether
® major
product is
(1) (2)
(1) CH4
(2) CH3 – CH3
(3) CH3 – CH2 – CH3 H
(4) CH3 – CH – CH – CH3
O
23. Number of chiral centre in the given molecule.
H Cl (3) (4)

O
27. Which of the following can show geometrical
Isomerism
Br
(1) 5 (2) 3 (3) 2 (4) 4
(1) (2)
24. Total no. of monochloro derivative product for
the following compound

(3) (4)
(1) 3 (2) 4 (3) 5 (4) 6
25. Which of the following represent correct 28. Which of the following alkene given same
IUPAC name? product with HBr and HBr/H2O2
Br

(1) 3 – Bromo – 2 – Chloro butane (1) (2)

Cl

OH
(3) (4)
(2) 3 – Hydroxy butane –2– amine
NH2

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 PRE-NURTURE & CAREER FOUNDATION DIVISION TEST # 1
34. Given below are two statements :
29. ¾¾¾
Br2
® major product is
CCl4 Statement-1: H2O2 can act as both oxidisation
Me Me and reducing agent in basic medium.
H Br Br Br Statement-II : In the hydrogen economy, the
(1) (2) energy is transmitted in the form of dihydrogen.
Br H H H
Me Me In the light of the above statements, choose the
Me Me correct answer from the options given below:
(3)
H Br
(4)
Br H (1) Both statement-I and statement-II are false.
H Br H Br
(2) Both statement-I and statement-II are true.
Me Me
(3) Statement-I is true but statement-II is false
30. Which reaction represent incorrect major
product formation (4) Statement-I is false but statement-II is true.
35. X' + CO2 + H2O ® 'Y'
(1) CH3 – CH2 – Cl ¾¾¾
NaCN
® CH3 – CH2 – NC
'Y' + CO2(excess) + H2O ® 'Z'
(2) CH3 – CH2 – Cl ¾¾¾¾®
Moist Ag2O CH3 – CH2 – OH 'Z' + NaCl ® NH4Cl + NaHCO3
In above reaction 'X' is recovered when NH4Cl
(3) CH3 – CH2 – Cl ¾¾¾
KCN
® CH3 – CH2 – CN
treated with -
(4) CH3 – CH2 – I ¾¾¾¾
Alc.KOH
® CH2 = CH2 (1) CaCl2 (2) Na2CO3
OH (3) CaCO3 (4) Ca(OH)2
P
31. ¾¾¾¾¾
Conc.H 2SO 4
D
® 36. Which of the following species does not exist.
Major
(1) SH2 (2) Pl 6–
No. of possible Alkenes. –
(3) SeF6 (4) XeF 3
(1) 2 (2) 3 (3) 1 (4) 4
37. Which of the following are isoelectronic and
O isostructural?
NO-3 , CO 32 - , ClO3- , PO34-
32. In the given reaction, ¾¾¾
1. OH-
® P is
2. Heat (1) PO34- , CO32 -
Major
Product (2) SO 3 , NO 3-
O O (3) ClO3- , CO 32 -
(4) CO 32 - , PO34-
(1) (2) 38. Which of the following is an outer orbital
complex?
(1) [Fe(CN)6 ]4– (2) [Mn(CN)6 ]4–
O
(3) [Cr(NH3 )6 ]3+ (4) [Ni(NH3)6]2+
39. CrO -4 2 ƒ Cr2 O 7-2 equilibrium is established in
(3) (4) a solution whose pH = 4, then correct statement
is
33. How many of the following are correctly (1) CrO-42 pre-dominate (pH > 7)
matched? (2) Cr2 O -7 2 pre-dominate (pH > 7)
Code-1 : [Cu(CN)4]3– - dsp2 hybridisation (3) Both form exists 50% at pH = 10
Code-2 : [Co(H2O)6]3+ - zero electron in eg set (4) Equilibrium does not shift's as pH changes
Code-3 : [Ni(CN)4]4– - tetrahedral geometry
40. Find the group of orbitals in which atleast one
Code-4 : [Fe(ox)3]3– - two geometrical isomers common nodal plane is present :
Let the sum of code corresponding to correct (1) 2px, 3dxy, 4dyz (2) 2py, 3dxy, 4dyz
matches be x. Find (x – 1)
(1) 1 (2) 4 (3) 6 (4) 3 (3) 2pz, 3dxy , 4dyz (4) 4d 2 2 ,5d 2z
x -y

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 CHEMISTRY OLYMPIAD TEST # 1
41. Which of the following is correct set up 46. All possible bond angles in anionic part of PCl5
quantum number(s) for the last electron enters are
in 'Fe'? (1) 109°28'
n l m s (2) 90°, 180°
1 (3) 90°, 120°, 180°
(1) 4 0 0 +
2 (4) 72°, 90°, 180°
1 47. Ore in which same oxidation state of metal
(2) 3 1 0 -
2 isnot present as given in other options:
1 (1) Calamine (2) Haemetite
(3) 3 2 -1 +
2 (3) Malachite green (4) Azurite
1 48. Which of the following statement is correct?
(4) 3 2 -3 +
2 (1) Pig iron is the purest form of iron.
42. Which of the following is INCORRECT? (2) Tin stone is consisting of wolframite as non-
(1) C < N < O (2nd IE) magnetic impurity.
(2) Li+ > Mg2+ > Al3+ (size) (3) During the extraction of Aluminium by the
(3) Diamond is hardest natural substance Hall-Heroult process a graphite lines steel
(4) For A(g) + e– ¾® A–(g) DH must be negative tank serves as cathode and a graphite rod
43. Consider the following our elements, which are acts as an anode
represented according to long form of periodic (4) Lead and tin are extracted from their chief
table. one the carbon reduction and seft
Y
section-b
W X Z
49. Consider the following first order
Here W, Y and Z are left, up and right elements decomposition reaction,
with respect to the element 'X' and 'X' belongs
to 16th group and 3rd period. Then according A4(g) ¾® 4 A (g)
to given information the incorrect statement
Which of the following statements regarding
regarding given elements is:
(1) Maximum electronegativity : Y the reaction are correct?
(2) Maximum catenation property : X
(3) Maximum electron affinity : Z
(4) Y exhibits variable covalency
Concentration

44. The hybridisation of the central atom will

change when:
–
(1) C H3 combines with H+
(2) H3BO3 combines with OH– 30 min. Time

(3) NH3 from NH -2 [Given : log 2 = 0.30]

(1) At 30 min., only 20% reaction is complete
(4) H2O combines with H+
45. Identify the specie among the following in (2) t1/2 of reaction is approximately 90min.
which central atom uses d-orbital(s) for (3) Rate of reaction decreases linearly with time.
bonding.
(4) The time for intersection of two curves is
(1) PCl5 (2) SO2
- independent of initial concentration of A 4
(3) ClO 4 (4) All of these

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 PRE-NURTURE & CAREER FOUNDATION DIVISION TEST # 1

50. 1 mol of liquid A and 9 mol of liquid B (molar Me

1. BH3 : THF
53. P
mass of B = 100) are mixed to form a solution. 2. H2O2 /OH
(Major)
Given : PAo = 20 mmHg, PBo = 400 mmHg ‘P’ should be

It is observed that vapour pressure of solution H Me Me H

(1) HO H (2) H OH
is 350 mmHg. The incorrect information(s)
about the solution is/are: OH

(1) the liquid form ideal solution. Me

(3) (4)
(2) DHmix = 0 H

(3) The volume of final solution will be less 54. CH3 CH3
than sum of individual volumes of liquids H OH HO H
mixed. H OH HO H
CH3 CH3
(4) The solute solvent interactions are stronger
(I) (II)
than solvent - solvent or solute - solute
interaction. Which of the following statements is true about
these molecules?
51. For the reaction.
(1) (I) is a meso compound
Cl2 ( g ) + 3F2 ( g ) ƒ 2ClF3(g) DH = – 329 kJ (2) (I) and (II) are identical
(3) (I) and (II) are two different meso compound
Decomposition of ClF3(g) will be favoured by
(4) (I) and (II) are enantiomere
(1) Increasing the temperature
55. Which of the following statements is correct
(2) Increasing the volume of the container about oxymercuration of alkenes?

(3) Adding of F2 (1) It is an electrophilic addition.

(4) Adding of Inert gas at constant pressure
52. An aqueous solution is formed by mixing
0.09 kg glucose in 0.8 kg water. The density
of solution is 1780 kg/m3 .
(1) The molarity of solution is 1.0 M
(2) It follows markovnikov’s rule.
(3) It does not allow carbonion rearrangement.
(4) It does not follow markovnikov rule and it
is an anti addition.
56. Which of the following gives product as
"CH3 – CH3 when react with CH3CH2MgBr.

(2) The molality of solution is 0.625 m. (1) NH3

(2) CH º CH
(3) The normality of solution is 2.0 N, when
glucose converts into gluconic acid.
(3)
(4) The number of g-equivalents of glucose in
200 ml of the same solution is 3.2, when
glucose converts into n-hexane. (4) MeOH

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 CHEMISTRY OLYMPIAD TEST # 1
57. Based on the trends against the metioned 59. Choose the correct order
property, identify the incorrect option(s). (1) Thermal stability Þ LiOH < KOH < RbOH
(2) Bond strength Þ 1S-2S < 1S-2P < 1S-1S <
(1) sp3 < sp2 < sp : Electronegativity of hybrid
2P-2P
orbitals
(3) Bond length Þ HF < HCl < HBr < HI
(2) Hl > HBr < HCl < HF : Increasing acidic (4) Bond angle Þ NH4+ < NH3 < NH2–
strength 60. Which of the following statement(s) is/are
(3) Mg < Al < Si < P < S : Increasing first CORRECT ?
ionization enthalpy (1) In Ostwald process for the preparation of
HNO3, Pt/Rh is used at catalyst.
(4) S –2 > Cl– > K+ > Ca2+ : decreasing ionic
radii (2) In Contact process for the preparation of
H2SO4, V2O5 is used as catalyst.
58. Which of the following having identical bond
(3) In Decan process for the preparation of Cl2,
order?
CuCl2 is used as catalyst.
(1) CN– (2) O2 – (4) In Haber process for the preparation of NH3,
(3) NO + (4) N2 + (iron oxide, Al2O3, K2O) is used as catalyst.

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 PRE-NURTURE & CAREER FOUNDATION DIVISION TEST # 1

SPACE FOR ROUGH WORK

8/8 Your Hard Work Leads to Strong Foundation