EN THAN KY 11H CHUN DOLTUYEN DU THT TSG GX ANT SMO PHONG GD & DT VEN THAN! NAM HOC 2021-2922 Mon thi: HOA HOC (ving 2) Fl (Thoi gian: 150 phidt Khong ké thoi gian ‘giao niin dé) tirhai chat trong : chat sau: C, Cu, O,, S, H,S, Fes, iy viet ee phurong trinh hod ge digu ché SO, (ghi rd diéu kign phiin tng), Cau Il. (20 dim): Chat X vita tie dung véi dung dich NaOH, via tie dung véi dung dich NaFISO, iy vit phvong trinh phn img xiy ra khi X las 1) Kim logis 2) Osis 3) Hidroxit; 4) Mubi Chu IH, (45 did 1) Mt hin hop rin adm Al, Cu ya AlOn. Hay trinh bay phuong phiip héa hoe dé tich time chit ra ‘hoi hin hop ma khong tam thay 48% khOi Itong ott ching, a 4 2) Chi duge ding them dung dich HCI, Hay trinh bay phuong phip hoa hoe dé Ba £1.06 Io mit eaen bilo dye én bit mt dung dh sau: Nat1COs, NaQH, MaChs, NisCO,, BaCl, NHC, Cin tv. (40 Ant dune dich Nn hep chia (22 mol K:CO, vi 0,18 mol KHCO, vio V tit dung dich Her 05M, sau phan ae hoan toa is tings eae ‘vil Vj lit khi CO, thoat ra (a dktc), Cho dung dich BuOH), dir vio dung dich A thu durge 34,475 gam ket tua. Tinh V,V, va kh ltong méi mudi trong A, REC; 3) ff tan dtm gain KBn hop gdm Fe va mt onit sit (Fe,0)) tone 800 ml dung dich HCI 1M (vir 40) thu dug static X va ae Th (do 6 dite) Cho dung dich X tée dung véi dung dich i Ah duge 132,08 gam kat tia, Xée djnh eOng thie hon hoc ota oxit sit vi tis, Bid tri Cita py, iy ra phan ing gitta Fe véi dung djch mudi sit) Se diém): hop €0j, H;S04, Nass e9 eam chit rin, {oiin, ce khi do & dkte, Nop X dm 2oxit cia 2 kim Jogi thy, tlch nude ¥6) rong dur thu duege 1,5 gam ket ta, ‘lang dc 1580 10% (vir tn] vs dang dich midi o6 nda ap ra i cn a 0.96 pam eh et Rng tate {it hal ont, bit rg ede ph dng ea fot, Ch Hy, O1 COp, HCL, itu ch rong ph a ony nh og vcKY THI CHON HQC SINH GIOI CAP. TINK j 0 NAM HOC 2021 - 2022 s6 rho DUC ae m ? ‘THANE Mén thi: HOA HOC - THCS pb CHINE THUC Negay thi: 26/12/2021 Thdi gian lam bai: 150 phitt, khong ké thoi gian giao aé (Bé thi cé 02 trang) kim logi A va B 1A 142. Trong d6 s6 hat mang dién nhiéu hon s6 iw 1.2.0) i es ie n tir B nhiéu hon nguyén tit A lA 12. Xa¢ nae dign cia nguye ‘1 diga 1d 42. S6 hat mang di a br eee tA va nguyén tir B. ; te eye go gam héa hop Zn va Mg vio 800 ml dung dich HICL IM. 2 minh ring sau phan img edn dr axit. ‘ mY coats ling tgo think 4,48 lit khi (dtc), tinh khOi Iurong mi kim loai cé trong hén hgp bandiu, Cin 2, (2,0 diém) Tim cfc chat 48 thay cho céc chit c4i tir Aj, Ao,..., Az, sau d6 hoan thanh cdc phuong trinh héa ‘hoc sau, ghi 6 diéu kign phin img (néu 6). Ai+Ch— KCI + Ag KCl+H,0 > Ay +Ch +H As+Ch—> Ay+KC1+H,0 Ai>KCl+As +A, AG>KCI+Ag As + Ch» KCl +Ay+ 1,0 Bidt A, a hop chit gm hai newe2s cchita 31,83673506 hai nguyén t0, trong 46 c6 chia 32,773 r Cau day) EIU; Aside kh oid oer a 1% K theo khéi lung; Ayes. 1. Trong mt binh kin chia hén Dinh mgt thi gian kai Bin bop kt R gbm S02, 09.66 thkhéi-en os 47.3 bingsn, ATES mit chs ts Yaoi doe i gk biog 24. Dun ning i f i So véi Hy 6 thé tao o6 i ate theo Phong hp ay mage ca ‘dtimy nite on hay” as a ES WOE he ge KMno,idm) . Hi 1 iit. Hay ang dich KOH 66 néng 46 lan hugt fa 1M, 2M, 3M. M6i dung dich Se é fn ofc dung dich nay 48 thu durge dung djch KOH cé nding 40 1,8M vA of th waich bn hop Y ria tan hod oan ma (BA) hin hop X gdm hai kim logi Na va. Ca v80 dung a ee ree NaCO, v8 0.4 mal CAC thu dave 7 em vet tia va 0,896 lit . sid cba 0 diém) . A Ct? 28 ths 3 phn bing nha, Co ph | vie One nen uF dung djch mudi A thu durge iét tia Ay. Cho phin 2 vio dng nghi¢m chia lung ss ae - aa ese B thu duge két tha B; va cho phiin 3 vio éng nghiém chira lgng dur dung dajeh mubi ese, Bu, Nang B va D; én kh6i lugng khong di thu duge cde chit rin tuomg tg ld Bava Oe t B2 vii D2 roi cho vao mot h nude du thu duge dung djch E chira 2 chat tan. Suc khi CO2,t i ‘vio dung djch E lai xuit hign ket tha By. Biét ring: Aj, B), Dy Jan lugt la oxit bazo, bazo, mudi. Hay hon ege dng dich mubi A, B, D phi hop va viét phurong trinh hod hoe cia cdc phan img xay ra. Chiu 8. (2,0 diém) ae oan toan m (gam) Al vio dung dich loting chim 0,2 mol Has thu duge khi Hp va dung dich X. Cho tir tir dung dich NaOH 2M vao dung dich X durge két qua sau: 6.2 a 63 [The tich dung dich NaOH (ml) 140 240 } [RnGi long Két tia (gam) 2at 1,56 a | Tinh gif ti ela m vie. Cau 9. (2,0 diém) cchay hét mt lugng cacbon trong binh kin chira day khéng khi. Sau phan img thu duge hén hi X ebm 3 chit, Cho X qua 100ml dung dich hén hop gdm NaOH 0,2M va Ba(OH)2 0,1M. ‘thic cdc ‘img thu duge m gam két tia va 3,584 lit (dktc) hén hgp khi Y ¢6 ti i so Voi He Ia 14. trim KhOi lugng cia nguyén 6 oxi trong Y la 7,143%. Coi trong kh6ng khi, O2 chiém 20% thé tich khéng Ki, con lai Ia Kh Na, ec phn ting xdy ra hoan ton. 1. Viet cde phuong trinh hod hge xay ra. ‘ 2. Tinh gia trj m. Cfu 10. (2,0 diém) Cho hinh vé m6 ti thi nghiém digu ché Khi X th dung djch A va chit rin B (thi nghiém nay dugc ding diéu ché khi X trong phing thi nghiém @ chuong trinh ie Te 4. Hay viét phuong trinh Amy dibu ché khiX. ance : 72. Hay cho biét cdc héa chét trong cic = fs binh (1), @),@) va chét A,B, Daehit |e E as paso eae ogi ng hlen c—~ trén? —— HET— Cho kx6t leone nexyen ti etc = 24; Al=27; P=31;§ = 32. neuen 6: H= 1, C= 12; N= ches Cin b6 coi ti GEER SEC BS 5 hong gidi thich Thi sinh Khong, i thém. se Pie Rice ie BA 1) 1 roche ol hing nad haan oko 14; O = 16; Na = 23; 56; Cu= 64; Br =80; Ba = 137.UBND THI XA SON TAY pi THI HQC SINH GIOI CAC MON PHONG G) i VAN HOA LOP 9 CAP THTXA Su avaas Be MON: HOA HOC E Nam hge: 2021-2022 [Décuivemtc | Ned this 22/12/2021 ‘Thoi gian: 150 phuit (Khong ké thoi gian phat dé) Cau 1 (5,0 diém) s 2 | 1) Méthén hop X gém cdc chit: KO, KHCOs, NHCl, BaCh, ¢6 s6 mol méi chat bing nhau. Hoa tan hdn hop X vao nude, roi dun nhe thu duge khi Y, dung dich Z va két ta M. Xéc dinh Y, Z, M va viét phuong trinh phan img minh hoa. 2) C6 5 lo khdng nhin dymg 5 dung dich riéng bigt khong mau sau: HCl, NaOH, ‘Na;COs, BaCl, va NaCl. Chi duge ding thém quy tim hay nhan biét cdc lo dug cdc dung dich khéng miu trén, : 3) Hay giai thich vi sao khong nén ding céc dung cu bang nhom dé dung nude voi? Cfu 2 (2,5 diém): Cho 16,8 lit CO, (6 dkte) hdp thy hoan toan vao 600ml dung, dich NaOH 2M thu dugc dung dich A. Tinh khéi lugng cde musi cé trong dung dich A. ‘CAu 3 (3,5 diém): Cho cdc so d6 phan img hod hgc sau day X, +X; — Na,CO;+H,0 EXgegH.@) = Sista phil XG ea, ia | Ki —XtHO" Xg+ CO; + Hh Xp+X; 5 Xz Atuphinatngstty, Xo+ 0 a) Chon ede chat X;, X, Xs Xq Xs, Xs Xs Xs hich hgp va hoan thanh cée phuong trinh hoé hgc ciia cdc phan img trén, b) Em hay dé xudt thém 3 phan img khdc nhau dé tryc tiép diéu ché.X>, ,_ Cau 4 (5,0 diém): C6 15 gam hn hop Al va Mg duge chia lim 2 phan bing nhau. Phan thir nhat cho vao 600ml HCI néng 46 xM thu duge khi A va dung dich B. Cé can dung dich B thu dugc 27,9 gam muéi khan. Phan thir 2 cho vio 800ml dunk dich HCI ndng d6 xM va lam tuong ty thu duge 32,35¢ mudi khan. Piatti Tink thé tich hidro (dktc) thu duge sau khi thye hign xong eéc thi nghiém. ¢) Xéc dinh thanh phn % khéi lrgng méi kim loai mn hop. ¥ Cau 5: (4,0 diém). ven a edi ceding e's nt BSc ge 11SG GIAO DUC VA DAO TAO KY THI HQC SINH GIOI VAN HOA LP 9 THES, QUANG TR} NAM HOC: 2020 - 2021 eee (Risa ngay 25 thing 3nd 2021) [be cninn THC] MON THI: HOA HOC ‘Thai gian lam bai: 150 phit, Khéng ké thdi gian giao dé Caw 1. (5,0 diém) 1 Du doan hign tugmg va viét phuong trinh phan ting xay ra trong cic thi nghigm sau "Y) Suc kh SO2 vio dung djeh mde Bre 1b) Cho NasSO; vio dung dich chira KMnO, va NaHSOs «) Cho FeCl, vao dung dich chia hén hgp dur gém H,S0, loang va KMnO. > 2. Hén hop rin gdm Al, Fe2Os, Cu va AlzO3. Trinh bay phuong phip héa hgc dé tich riéng ede chs khong lam thay di khdi Luong cba mdi chat. Viét cde phurong trinh phin ting xAy ra PAS. Cho hin hop g8m Mg vi Cu the dung v6i dung dich hén hgp chita 0,06 mol AgNOs va 0,05 mol Cu(NOs)o, thu durge dung dich A va chit rin B. Cho dung dich A tic dung voi dung dich NaOH dur, loc ly két tia, nung trong khéng khi dén khéi lugng khong. di, thu duge 6,0 gam hén hop hai oxit. Cho B tie dyng v6i dungidich H:SO« d8e nong, du, thu duge 0,04 mol khi SO, Biét eéc phan img xéy ra hon toan. Viét cde phuomg trinh phan tmg va tinh s6 mol cia Mg va Cu trong hén hop ban du. a 4, Cho FeCOy tée dung vita di v6i dung djch HINOs, thu duge dung dich Ai va 16.2 gam hbn hhof khi CO. vi NO. Cho m gam Cu tan hét trong dung dich A,, thu durge dung dich B1 chiéa ba cht tan c6 ti Ig néng 4 mol la: 1 : 2:3. Viét cdc phuong trinh phan ting va tinh gid tri cua m. Chg. 5 diém) 1. C6 nim chit rin dyng trong $ lo rigng bigt khéng nan la: NayCOs, NaCl, NH«Cl, NaOH, hnthgp NaCl va Na,COs, Hay phan biétchét dung trong mi lo bing phuong php hod hoe va viet cée phuong trinh phan img xay ra. ®. Cho 3,31 gam hén hgp X gbm Al, Fe va Cu tac dung hoan toan v6i dung dich HCI, thu duge 0,635 mol Ho. Mat khéc, néu cho 0,12 mol hén hep X tée dung hoan toan voi Cha du, dun néng, the uge 17,27 gam cht rin Y. Vist cdc phuong trinh phan tmg va tinh s6 mol méi chit trong 3,31 gam X. 3. Cho dung dich chia 19 gam mu6i clorua cia mot kim loai, (héa tr I] tée dung vita da voi dung dich chira 22 gam mubi sunfua, thu duge 11,6 gam ket tia. Viet eée phrong trinh phin img vi ‘xéc dinh cng thite hai mudi. Chu 3. (4,5 diém) 1. Cho lin lugt cdc chat rin gdm FeS;, NaCl, NaBr va ‘Nall phan tg voi dung dich axit H,SOs a Baap epee prong i ph, mg xay ra. 4 a “Tron lin,cée 8p ‘chifa trong dung dich riéng bigt:natri cacbonat, amoni hidrosunfet, a, bari dlorua, natri tdroxit. Viét cdc phuong trinh phan img xdy ra, om gam hn hop Y gbm Fe,0, Cu va CuO te dung vi dung dich HCI, két thie phi ig, thu i (eh chia musi) va cdn ll 3,2 gam kim log Chia dung dich Z dunt bai phn bing nas. "Yaa dil v6i 500 ml dung dich NaOH 0,5M, Phin 2 tée dung hit v6i dung dich AgNOs du, "kb ta, Vide ede phuong tinh phin tg vi tin sb mol mBi nguyén trong Y ‘rinh phan img theo so 48 chuyén héa sau: Y¥ > ZT Cao suBuna, ; ‘m gim chat A (CyH,O,) cdn ding vira di mot khdi lugng O2 bing “thu duyge mCOp : mH,0 = 22: 9. Biét A dom chite va tée dung voi Na, ‘dio phurong trinh phan ting xdy ra. cee ‘vi el axetat thinh be phn. Phin 1 tic ira dil véi 500 ml dung dich NaOH 0,4M, “v6i NaHCOs, thu duge 0,12 mol COp,Chinh phuc hda hocChinh phuc héa hocJEP IENU TRA CHON HOE SINE GtOH 132 Loe, ell muy Gn, niin hve OE cuts pEtie 8 Mili 1.8 didn) 4 chr Ke whe cho ching 2 Tid bah eh ion oa! DO hia fy A ho tae Vo ni VO ci i jot omnis CUCL, NaHCO, Hael ISO fiat me nude: Ure CO(NTT Heh00: ti feta ge (RS pn ch ia Stiper phogphat (phi hoe eta emt hily iba bet phn dn, (TM SO, 1 fu coe duis dich 41. Tinh Wo) hag de thi eb tan 6 to, Cha ton b§ dung sich A thie dusoe 6 Ur2n tae enn a This fue tanh hy 4, 0.0 i i | Baie Tak V. 2 Tinh kbd Iuome ker wath dre (G5: (2.0 diém} Din Vink dune ich NaOH 1M vio fom mult cha V ld ket sia thu due ing dicls HyS0q 1M n): Frum hist V img Tia gi Linh id tr} nbd nhkt etn V dd Ket ia thu duge len (255 didn): Ha tan hon roan 20 gam hin hep % prim 3,61 ld mol i 2 mur tone bin bp Ta 1:3) ae ding Vek dung dish BCA Tinhtios 4,48 A hi dkic) Noo 15M 1 Tim cfing thite hie hoe eax mudi ACO), 2. Toisas bo keh sinh ta stem hap th: Tih koi lung: mudi thu dupe. 1,5 diem): HOn harp A gdm kien hs Ray 11,2 pany hin herp A hea tat, Bet re tse ite) Mat Khe Bly 11.2 gam din hop A de tifa ba tan trong dun fh dvge 6,72 lit Kehi (dite) Tim rin im Logi M Ci 8: (2,0 dién): ‘Cho libs hyp X yen 3 kim lool Al, Fe, Ce. Lay L Woidung diel HC) ae At thie pin try ti dune £96 is at Cektc) nt eh XM tetren thi tic dang view. dix veel ZK wom keh Cly Tinh plvin trim theo b foi trang tin hop % (Ghia NTK citar Al~s CI=35,5¢ K=39; Na=23) O-12, O= 16, H=1, iM fan ton, van 20 ng dung. fe HCT a, bi line ot fy Fe=302 Ci Ls Gilt thi 2: Ap va 2 th shes sso Girth Ve i ayHUYEN PHONG GIAO DUC VA PAO TAO KY THI CHON HOC SINH GIOLLOP 9 CAP NAM HQC 2018-2019 MON: HOA HOC pb CHiN THUC Neay thi: 09/12/2018 (Dé gdm cé 02 rang) Thevi Bian Jam bai: 150 phat (khdng, ke di gian phat ae) HUYEN LAP VO éi cia cde nguyen t6:Cau IV. (2,5 diém) 1. Bang phan img hoa hoe, hay ching minh ring 46 hoat dng cdc kim gidim dan trong day sau: Na> Zn > Cus Ag. __ 2. Cho m6t mau vat bing di €6 khéi lugng 6 gam vao trong 250 gam « dich bac nitrat 6%. Sau mét thoi gian lay vat ra thay kh lugng bac dich giam 17%. Xe dinh khéi Iugng ciia vat sau phan img. 2 Cau V. (3,0 diém) ; 3 Tien hanh phan img nbi Ki quyén tro) 30 gam hn hop gm Al va FexOs, thu duge 6 khoi long khac nhau. dich NaOH du, thu duge 0,2 mol khi hidro va edn lat han 2 cho tac dung véi dung dich HCI du tha diego V (Vit) khi p X gm KaCOs va K2S03 cho tée dung véi dung dich HCI dtr thu Hi Y 06 ti kh6i hoi so véi khi hidro la 28. Cho 0,448 lit khi Y (akte) ich Ba(OH).. Sau thi nghiém phai ding 60 ml dung dich HC10.2M ich Ba(OH)) du. eeiets86 GIAO DYC VA DAO TAO TINHBONG THAP KY THI CHON HQC SINH GIOL L6P 9 CAP TINH NAM HQC 2020 - 2021 Mon: HOA HOC Ney thi: 28/3/2021 Thai gian lam bai: 150 phi, khéng ké thoi gian phat dé pe CHiNH THUG (Bé gim cé 02 trang) 12; N=14; O=16; Na=23, 27; $=32; Cl=35,5; K=39; Ca=40; Cu=64; Ag=108; Ba=137; Br=80) 2am Cau 1. (2,0 diém) 4 1, Nguyén t6 R 6 cong thite oxit cao nhit 1 RO2- ‘rong hop chit khi voi hidro, R chiém 75% ve khoi lugng. Xie dinh nguyén t6 im CC 2. Cho ede chit sau: CaHs02Na, Nan) NusCa0x, GH:NOz. Rath § F557 a) Chit nao la chat hiru co? i pf ) Chit nio khi d5t chéy hoan toan tron oxi chi thu duuge Khi cacbonic, hoi nude, natri cacbonat? Spitz hea a 0, Ne Nag ‘Cfu 2. (3,0 diém) 1. Viét phuong trinh héa hoe thy hign so dd bién héa sau (ghi r0 diéu kign phan img iu 6) 2), 3 neu c f yy FeCl. Fe(NOs) ee Fe. recy Fato Fa “o i alee Cho efe Lo ki khong miu: melan, ti Sac sing puns sto ‘hoc, em hily trinh bay edch phd bit time | khf trén, Viét phuong trinh phin img xy re. Cau 3. (10 did a hanh th nghigm nhwhinh vé bén 1. Trong phong thi nghigm, hinh vé ben o6 th ding 48 dida ché ning chit khi mio trong s6 cde Ki sau: ic, Call, Ha. 5 Fee ee omg inh Won hoe id ci bit ht én tir rin X tuwong (mg. , Cand. B.0 ty ys: dstd -Ofvho dung dich HCL 10% (vira di) thu duge dung 6 12,037% va 2,24 lit khi CO; (dkte), Xe dinh Ong thire mudi va tinh gid tri a. dich 0a oo, B ob cng kit lugng Date oa bing. Cho stm mt, ban AN ‘con mii d6 nia.PHONG GIAO DUC VvADAO TAO THANH PHO SA DEC i DE THI CHON HOCSINH GIO! ‘Lop 9 CAP THAN pHO NAM HQC: 2020-2021 ‘pe CHINH THUC ‘Mon: HOA HOC Ngiay thi: 13/12/2020 yd z “phai gian: 150 plait khdng Ke tho? (Ba thi gam 02 trang) gian phat dé) Cau I (4,0 dim) 1) (2,0 diém) Din khi Hh due di qua hon hop A gdm Fe20s, AlOs, MgO nung néng, sau phan img thu duge hin hgp rin B. Cho hdn hop B ‘yao dung dich NaOH du, sau phn img hoan toan thu duge dupe dich C va ran D. Sue kht COz dur vao dung dich C thi duge két tia E. Cho rin D vio dung dich H,S0, dae, nong dif thi duce khi F mbt hhc. Viét cde phuong trinh hoa hoe xay ta va xe = inh phan A, B, C, D,E,F. ~ ‘ (2,0 aim) Tox 6 hat p, n, € trong hai nguyen. tic 2 nguyén to X va (100 trong 46 téng 6 hat mang dign ‘nhiéu hon tong so hat khong, ‘mang dién 1a 32. 56 hat mang dign ca nguyén 18 Y nhiéu bon ca nguyen +6 X la 14 hat, s6 het khong mang dign nguyén 16 ¥ nhiéu hon 96 hat khong mang ¢ign X a6 rl i z het. A © 2 a) Tinh sé hat p, ny ¢ trong at nguyen tir cba 2 nguyen 10 X,Y b) Xéc dinh tén 2 nguyen 6X, Y. e Cau HI (3,0 diém) 1) 2,0 diém) Viét phuzong, trinh héa hoe dé thye hign so dB chuyén hoa sau: +4CMOF,+H0 -H,08HC e Bet Vai oS C5 Dr, o ° > © ° 6 i” piét trong hap chat oxit, nguyén 8 A oo chiém 5: Hop chat nay 14 thank phan chinh cia quing boxit, =~ 19¢ minh hoa 4 cach khée nhau dé A 9,94% ve khéi luong. 2) (1,0 diém) ‘Viét phuong trinh héa hi ta0 FeCh. ey Caw III (3,0 aiém) 1) (2,0 diem) Lfy x g tinh thé CuSOx. thu duge 500g dd CuSOs 8% . Tinh, ¥. CalsstOue 2) (1,0 diém) Mot loai phin supephotphat kép 6 chita 70,1 % musi canxi _dihidrophotphat, ‘con ai gdm céc chat khéng chia photpho. Dé dinh dung cita ‘phan fan nay 1a bao nhieu? _- Vi sao NH,HCO; va (NH,):COs kchi nhiét phan déu cho OQ, va H,0 nhung ngudi ta chi ding NH,HCO; lam bot no? SH.O cho vio y g dd CuSO. 4% dé a sll.UBND THANH PHO CAOLANH —- DE THI CHON HQC SINH LIU Lury PHONG GIAO DYC VADAOTAO CAP THANH PHO, NAM HQC 2020-2021 re Mon: Héa hoc Théi gian kam bai: 150 phat (Khong ké thei gian phat dé) Nedy thi: 13/12/2020 4; Na=23; Ca=40; C= 12; N= 14; S fic kh do diéu kign tiéu , Dé chinh thire (Dé thi gém cé 02 trang) Cho: Fe = $6; Al = 27; Cl = 35,5; H = 1; O = 16; Mg = 2: = 32; K = 39; Ba= 137; Ag = 108; Cu = 64; No = 6,02.10' ‘i b) Cho mau nhé kim loai Na vao dung dich CuSO,. oe eee di ngiin, €) Suc khi CO, te N 1.2. Kim logi Fe tae dung véi clo va lin theo hi duge x gam két tia va 2.3, Cho 0,08 mol khi CO2 vio dang dich chita 0,05 mol Ca(OH), tha dng dich B), cho dung dich NaOH 0,1M vao dung djoh (B), a@ thu i cnt thidu td V ml dung dich NaOH. Viét ec phin img xiy ra vi tinh gid rs Cau 3: (4,0 did) Be ae chit v6 co tir X dén Xy) va viét phuong trinh héa hoe eta ede phan Ung sau: Fe eth eette ay Fell, MO eile a) jar ft Xe (2) Xs +X5—9 Kot Rieck ox 4+ Xaee> Kivi FCs 4) Xo > XutX¥ yo ()Xit Xo Xi + Xp 0 ON, F Fez05 + Bids Xylt ihudi sit IT eldrua (céng thite la FeCl) 1 = OF. a Cho hdn hop X gém Fe (2x mol), FeO (1,5x mol) va FeCOs (x mol). Hoa tan hét m ‘Sim X trong dung dich HI, thu dirge 1,568 lit hén hop gdm hai khi ¢6 ti khoi so v6i Hs bang 10 va dung dich Y chi chira mudi clorua. 3.2.0 Tinh gid trj m. 3.2.b Viét phirong trinh hoa hoe ea cdc phan img xay ra. 10 ¥ tc dung hoan toa véi lung dung dich AgNOs du, thu duge p gam két tha. Tinh gid trj cla p? Sb P35 Chiu 4: (4,0 diém) 4.1. Diin m6t ludng khi CO dw di qua hdn hop m gam céc oxit: CaO (x mol), CuO (x mol), Fes (2x mol), Al,O; (x mol) nung néng, Sau khi phin img xéy ra hoan toan thu duge hén hop khi (A) va hén hgp rin (B). Cho hén hgp (B) vao nuée dur thu dirge dung dich (C) va hn hop rin (D). Cho (D) vio dung dich H2SO, lofing (du) thu duge 0,08 mol khi Hz. Sye hén hgp khi (A) vio dung dich (C) durge dung dich (G) va két tia (H). Vé so dé phan img tao thanh cdc chat (A), B), (C), (D), (Ey, (G), (A) * Tinh khOi Itong (B); khOi lung (D); khOi lvgng (H) vi gid tri m (Khong ef imgxiy ra). 7/56 oor 2/496 4.2. Néu hign tugng va viét phan img xy ra. Khi cho dung djch sau: )BaCl, — b) MgCO;, ©) NaOH, 4.3. Vid ce phiong tinh hoa hge the hign cdc chuyén di 1 phuong trinh héa hoc) Cy 5: (4,0 diém) 24,5% | Hoa tan a gam oxit cia mot kim logi M. fairimate Gree coe S.tb, DunPHONG GIAO DUC VA DAO TAO KY TH chon HUYEN LAI VUNG NAM HO ee GIOLLOP 9 out 2018-2019 pi CHINH THU [ MON THI: HOA HOC Thoi gian tam bai: 150 phi Ngay thi: 20/01/2019 Ho va tén thi sin S6 bao danh:, Chit ky cia gidm thi 1: bi ky cia giam thj 2.... NOI DUNG BE THT (Bé thi cb 0 rare gdm 7 céiu) Cho: Zn=65; Fe=56; Ca=40; ‘Mg=24; Br=80; C1=35,5; C12; 4, Cu 1 (3,0 diém) Neuyén tir cia nguyén t6 X e6 tong s6 hat 14 82. Trong dd, téng s6 hat mang dién nhiéu hon tong s6 hat khéng mang dign 1a 22 hat. Biét nguyén tir khéi cla X ¢6 gid trj bang tong s6 hat trong hat nhan nguyén tir. _a) X4c dinh tén cia X. te ry Néu coi nguyén tir X c6 dang hinh cau voi thé tich xp xi biing 8,74.107 cm’ va trong tinh thé X c6 74% thé tich bj chiém boi cae nguyén tir, cdn lai la khe trong. Tinh khéi long riéng ctia tinh thé X (Biét s6 Avogadro: N = 6,02.10°), ©) Viét cde phuong trinh phan img xay ra khi cho X lan lugt tac dung voi: +Khi Ch. + Dung dich HC. + Dung dich CuSO,, + Dung dich FeCl. Clu 2 (2,0 diém) Aon 1) Tinh khéi lugng KBr 06 #hé hi tan trong 100 gam dung dich KBr bio i din néng len 100°C: tet ring ning 45 dung dich bio ha 6 20°C 12 39,5% va & 100°C 1a 51%. Trong ci hai trudmg hop bé qua sy béc hoi née. 2) Tinh ti 1¢ thé tich dung dich HCI 18,25% (D = 1,2 g/ml) va thé tich dung dich HCl 13% (D = 1,123 g/ml) 48 pha thanh dung dich HCI 4,5M. 3) D6 tan ciia mudi n (NaCl) 6 20°C 14 36 gam. Xéc trim cia dung dich bao hoa 6 nhiét 45 trén, Chu 3 (3,0 diém) Viet cde phurong trinh phan mg hoan thanh chudi bién aéi sau (ghi rd digu ign, néu 08): nong 6 phan1) Canxi cacbonat —°+ canki oxit 5 canxi cacbua — axetilen —> benzen. 2)Fe —O FeS —?+ HLS Se, go, , so, ©, H)SO, —2> HC! —25 Cl —® > Nude Gia-ven, ‘Cau 4 (2,0 diém) truc tigp tir ancol etylic, ngoai ra cd mé) trude khi néu.UAN NIU DAN QUAN PHONG LIAO BYC VADAO FSO ON WEI ct amt ae TH Bans 90 pb sing Ad Chin ty (2 oak) Db tding dna vb + Ko te, ins aroma, lie fpeydn whi phd bide bin cho dit troy tnd ee cake corti kibas aber cara Soe hrgloghengeea iets (a hati, ighidn). WOl won ghip ol tgo dt chisa vira gilip De chl che vi minh via pay h rp vis kiln thi bak he 83 ge vb rin Li doge vii tnd, hy tech & Thé nde Ih da chua? Néa nguyéa the vi-cich lim 8 phar hign ea dle Ung. gill thich cho cach lam dh Vi sao ot tring bj chs? TB V1 sao vide abv Ba po tpo dit bi hua? Clie 2 3 aides) Hook tm 25 gam CuSO, SHO vo: ears elt 2 duge dung dich CuSO, co ‘Nhtig mit dla ct vlo dung dich, san mit thir gian miu dung dich Lat tiga Hay che bid life tof nghigm miu kém dume bi vio obe A hay ede i? Gil thick. Clu 4: (3 itm) Cho 14,6 yar mbt hla hyp tin vi xt vie 300 ml Gung dich 1:80, 12M, Sau : thet rent chlt kit uy ef Wht, mba Ete, Kol buon a A aa hon tog khih lugmg eie chit cham pla phn ong 486.5 yam. Tinb bog ot dung dich us sau phir ding. (Chu $3 didn Cho 12 gam fidin hyp sit vi dling the dung BEL thu dupe yao dy “Tin 96 V8 HBO! Bugg nb Ki gt 68 trong Bin opChe 6 C8 didn That hy Uh inh veo A fi ehorusk CAE oT bd th peau (anise C1) mang i Didi Ihde hats cx bars by, Treg phan toto bt dom. The ra Ngaydn ti motri (Wa) Nuyda fir nates shuimg: | electron cho nguetn ts ‘vilion eloewa (anion CT) Cation Na" Aaion CF Cia 7: (3 iden) Hinh Bn ti sob sein cut chide, bay cho bids: i a. Neuyéa liga: phm 6 nhOng chit nio? San phien hu duise gh of nhiberg ‘cht nv? Baby ls scr dB ssh oct cha 1? tb. Widt phurong trink hod pe cla pain ‘ang, ghi rb cbe dieu kin. seoceecees HET Cho; He |, (C= 12, O= 16, Na= 23, Zn= 68, 5~ 32, Cle 35,8, Cam 40, Po = 56, Cu 64 Thi ait hing hae: sak ahem balm tints tan vib bing Jt tg ues eee gt nok pe. Trang |2PHONG GIAO DUC YA DAO TAO MO CAY BAC be CHIN aim) ‘Viet ic phamg cis planing nc) DAs A> BG a Vid ede phuomg tah pt ting sy rahi ing me Kin gg su yr ey a SO; Ch, HS. Ciuk: 4 den) Masi rn Dung dich Cust ing thug lim thude digt In bly cach pa ché 200 gam dung dich CuSO12% tt 1 3:_ (4 dism) Tron 100 ml dung dich FeCl 2M y6i 150) ung dich A (D=1,|2eml) va ket tia B, nung néag E «Gén khoi lugng khng 654 thu duge'm gam chitin C a) Tinh m 'b) Tinh ning 49 phi trim eta dung dich A: Caw 4: G4 dim) 1. _ Cho 6,45 gam hBa hyp hal kim fog hog a 11 H,S0, loding de, Sau phn img xong thu dirge 1,12 Leong etn ny te ding vi iw 200 mil du cic kim losi A,B (bigtA dimg tnade B trong dl 2. Hoi tan 0,78 gam hn hop (Mg, Al) bi lugng dung dich ting thém 0,7 gam: hhgp ban di. Giw 5: (4 diém) Din tir ti: Iubng Khi nung néng, dé ee phan img hoi nude sinh ra cho,TRUONG THCS LUONG THE VINH DE THI CHON HOC SINH GIOI LAN IL (Nam hoc 2021-2022) (Thoi gian: 90 phut) Cau 1: (64) a) Co 5 lo Khong nhan dung cic dung dich sau: NaOH, NH,CI, H>SO,, BaCh »MgCh. Khong ding thém thudc thw khac nhan biét cac dd chat trong mdi lo. Viet phwong trinh hoa hoc. b) Néu trong va ph dung dich NaHCO; Al(NOs)s; ( ‘ © Hon hop khigom CO, , SO) , SOs , CO . Cn ding phan tng hoa hoc nao dé nhan ras ng khi.. Cau 2: 24) Hoan thanh day chuyén hoa sau ( mét mui tén 1A mt phan tng) Res Ax" {tf inh phan rng (néu co) khi cho Bari yao timg X—+Al Noe Cau 3 : (Sd) X la dung dich HCI néng 46 aM, Y 1a dung dich HCI néng 46 bM. Tron Vi lit dung dich X voi V> lit dung dich Y duc V lit dung dich Z. Khj lay 9,66 gam hon hop kim loai A gom Al, Fe, Cu thi tac dung vira di v6i V lit dung dich Z trén, thu duc 2,016 lit Hz (dktc), dung dich B va mt chat ran khong tan. Nung chat ra nay trong oxi (dw) dén phan dng hoan toan thu duge chat ran D. Hoa tan hoan toan P vao dung dich Z thi cing can ding hét V lit trén. a. Tinh khoi Ivgng moi kim loai trong hon hop A. b. Xac dinh a, b. Biét rang : V = V, + V2~ 0,6 ; b= 4a ; V2 lit dung dich Y hoa tan vira hét 1/3 long Fe c6 trong hon hop A. Cai 7s 1. Ala dung dich AIC , B la dung dich NaOH 2M. Thém 150ml dd B vao céc chira —__100m1 dd A, khuay deu thi trong coc tao ra 7.89 két tia. Lai thém tién vao coe 100m)eve! ae = PRIN “crm pes ee ee ‘dung dic a ich_N NaHCO; (NOs)3 ; (NH4)2SO. . Hon hop khigom CO, , SO; > SOs , CO . Can ding phan img héa hoc nao dé nhan mat cua tirng khi . ean 4) Hoan thanh day chuyén hoa sau (m6t mii én la mét phan tng) ee Al—>xx | > VY Cau 3 : (Sd) X 1a dung dich HCI nng d@ aM, Y la dung dich HCI néng 46 DM. Tron Vi lit dung dich X v6i V2 lit dung dich Y duge V lit dung dich Z. Khi lay 9,66 gam hon hop kim loai A gom Al, Fe, Cu thi tac dung vira dit v6i V lit dung dich Z trén, thu dugc 2,016 lit H2 (dktc), dung dich B va m6t chat ran khong tan. Nung chat ram nay trong oxi (dw) dén phan tng hoan toan thu duge chat ran D. Hoa tan hoan toan P yao dung dich Z thi cing can ding hét V lit trén. a. Tinh khéi Igng moi kim loai trong hon hyp A. b. Xac dinh a, b. Biét ran; Vi + V2= 0,6 ; b= 4a ; V2 lit dung dich Y hoa tan vira hét 1/3 lwgng Fe co trong hon hgp A. Cfu 4: (74) 1, Ala dung dich AICL , Bla dung dich NaOH 2M . Thém 150ml dd B yao céc chira 100ml dd A, khuay déu thi trong coc tao ra 7,8g ket tita . Lai thém tiép vio coc 100ml dd B , khuay déu thi long két tia co trong coc Ia 10,92g . Cac phan tng déu xay ra hoan oan . Xac dinh néng d@ (M) ciia dd A 2. Hin hop X gom FeOs, CuO, Al c6 khéi hrong 5,54g cho Iudng t° cao di qua hh X (Hiéu suat phan tng 100%) thu duge chat ran Y. Néu hoa tan Y trong dd HCI de thi rong Fb sinh ra toi da 13441 (DKTC) Néu hoa tan Y trong dd NaOH dw con Iai 2,96g chat ran . Tim % vé WI cae chat co trong X . JHE SESE SEH OEE EEE CO OEE© an su thay S01 (ng hay ¢ D Hot) 2 CONC ny dr dos on aang: CH) + HO OU i ve item om Thang ef tn tod, chi dua v0 O. ; a. Kh pi cia hg khi xy ra pin img Cs hay thu nhige? ‘ang (7) dign ra theo ¢l io’ 7) toa niet 0.25 Can hy cho bit cid thu eO8 PNP J AGS, (kJ/mol) —— S%q (/mol. K) 7 . = hirae Khi A, metan, amoniac jus(Q0dim) dn chi: Khi A, meta ah thoi diém khai sinh sy sng trén Trai dit, thin phan ks oth khong ton tai. DO ee ee soe re rk Khie chiém thank phn chi yu, tong Khi don C 5 xudng, cm lugng chit } rin hod hoe xy ra trong co thé sinh vat ma Iugng chat A bit dau quang hop: i quyén Trai dat do sy Nal nay, chit B chiém lugng tuomg di ton trong khi quyén a aA $i a hinh cia B. Tat ¢@ nhiing Lap chit khi C bio vé Trai, dat khéi tia eye tim Coy), Ha ms done thy hinh 43i nay 3 gép phn thhic day sy da dang sinh hoe tren noo Pinna ies a Dudi nhimg digu kign nbd 4 i thanh cd trong khi quyén nhimg digu kign nhét dinh, hgp cht D c6 thé durge #20 HST chi eb hido vA ox tinh oxi hod lan tinh khut. len. bi sng, Phin tir D chi c6 hidro va oxi, va m6 ¢6 a. Xac dinh cng thie phan tir va goi tén cdc chat A, B,C, D. b. Hoan thanh phuomg trinh img (9), (10), (11), (12): (10 ‘nA + nkzO — nB + (CH20)n Qe) Ds 12) Fe(OH): +B +H: ayy B-C 4 ie ind ¢. Dya vio tinh oxi hod- khir cia D, 4c ban phan tmg va phan tmg tong cho ede phuong trinh phan ting (13), (14): D+KI+H2SO.— (13) D+K2Cn07+H2SOs> (14) 4.2, Héa tan hoan toan m gam hén hop CuSO; va NaCl V80 amen nude, thu durge dung dich X. Tién hanh dién phan X voi cde dign eye tro, mang ngin xp, dong dign c6 cuémg d6 khéng 916 48i. Téng sO mol khi thu duge trén ca hai dign cue (n) phy thude véo thii gian dign phan (t) duge mé ta nlur dé thi hinh dé thi gap khtic tai cdc diém M, N). i&t phuong trinh phan tng xay ra 6 méi dién cue trong “°° ae a 5.1. Hoan thanh céc phuong trinh phan tmg sau: (16) FeCl +KMnOs+H2SO; —=> Bt +... (15) KMn0s (is) —> AT +... (18) FeS+HC] —> Df +... (17) FeS +02 “+ Ct + .. (19) NaN +H20 —+ET +... (20) A+D —> CT+ QNB+C—5F | (22) Dis +B —> ...+ 5.2. Cho 3,58 gam hin hop X gim Al, Fe, Cu vio 200 ml dung dich Cu(NOs)2 0,5 M. Khi phan img hon toin dusge dung dich A va chat rin B, Nung B trong khéng khi nhiet 46 eao dn phan img hodn toan thu duge 64 gam chit rin, Cho A tée dung dung dich NHB du, loc két tiia nung trong khong khi dén khéi lugng khong di thu duge 2,62 gam chat rin D. a. Tinh phan tram khoi Iuong mdi chat trong hon hgp X. b. Hoa tan hodn toan 3,38 gam hin hp X vio V mL dung dich HNO; 0,8 M duge dung dich E va 5 ae aa , ; . iung dj fl NO (san phim khir duy nhat). Dung dich E hoa tan t6i da 0,88 gam bot dng, TithV. sn Trang 2/4ell © ene an ota ngudi ta tach duge nde oat ee cong thie phan ir CaHLsO3, ill Tt tgo mai thom che kgo. Tit aud ® iq i GE Sesetle 6 cong thie phin tir CaHsO2. TH qua cay hdi hoang, ngudi t@ Ibenzandehit £6 cong thie A,B bit ergs chkt htu co A, Bcd cing Sone thire phan tit inh cdg tite cfu tgo ot (23) A+ 2NaOH ~ 1 ‘mudi + 1 ancol + H20 (24) B+ 2NaOH 2 mudi + | ancol ue Khi dt chity musi do A tgo ra thi trong sin phim chiy khéng thu duge nude, mot a o ie tpo thinh ti B co Kid fing, phi (6 . ang bi, hi a0 ean ce chht phenol, P-cre7o} (p-metylphenol), do khong 46i, hang 's phin ly Ka cla ca pl al mT a 63. nit yy4,6-rinitrophenol (axit pierio)s 7 7,0. 10%; 4,2,10" i a, Hay vi {cong thite cau tao cdc cl t tren. = tea gi tr Ke vio efi chat phi hep- Giai thich? EY Cau 7 (2,0 diém) ee , Ai wn ehie, mach hi A, By C, Dy F €6 cOn8 thge phan tir khong theo thir tu 18 a | 7A, Nam chat hiru co dor Ganu0, CaHs0, CsHeO2. Trone 46: wT dyng voiNa chi c6 A, E. Te dung v6i dung dich NaOH chi co: D,B,E. UNC, = Cae chét D, A, € quan bé ‘yéi nhau theo so 40: Dee ae tén cia 5 chit A,B, C,D,E- a. Xéc dinh céng thire ‘cdu tao (co gidi thich ngfin gon) va gol F.C chit ling A, B, D, E chita trong 4 Dinh Heng bigt, khong nan. Neu phuoms phap hod hoe phiin bigt 4 chat trén va viet phuong ‘inh phan tng xay Fa. . ie ia 14,2 gam hon hap X gom hai andehit dow ‘hie thanh hai phn bing nhau: = Dot chy hoan 2 va 4,5 gam H20. toan phan 1 thu duge 15,4 gam CO: = Cho phin hai tée dung voi long du dung ‘dich AgNOs trong NHL thu duge 43,2 gam bec. Xiie dinh cng thire cau tao cia hhai andehit tren. Cu 8( 2,0 diem) ea shaocarit X 18 cacbohidrat duge hoe trong choc trinh hoa phd théng, 06 6 1mo:me= 11 :% veh amiy pin 68,4 gam X trong dung dich HS 108 higu sudt la 80%) thu due dung dich ¥ che ba chat htru co khae nhau. Trung hhda dung dich Y bang Iuong via di dung dich NaOH roi thém dung, dich AgNOs trong NFL du, sau phan tg thu dige m gm Ag. a. Tim phan ti cia X. Goi ten X. pb, Viét céc phuong trinh phan img héa hoe da xay ra. Tinh m. 8.2, Hon hop A gom mudi X (CaHlioO4N2) va tripeptit ¥ (durge t20 nen tir cde a-aminoaxit no, mach ho trong phan tr chi cb 1 nhém NH: va 1 nhom COOH). Cho m gam hén hop A tée dung via di véi S00 vadung dich NaOH 1M, dun néng thu die 4,48 It (aktc) hén hop Ki 6 ti Kho aie ‘ait 12 va ae Sich B chi chia mudi, Co can dung dich B thu duge 43,9 gam hin hop mudi khan. . a. Tinh m. b. Xéc dinh X, Y. Viet cde dng phan c6 thé ¢6 ca Y. Cfiu 9: (2 diém) 9.1, Hop chit X c6 cdng thie CaHl1sOs, Tir X thye hign cde phin tmg (theo ating ti 1g mol): (25) X + 2NaOH —> Xi + X2* Ha oe (26) X1 + HzSOs > Xs + Na2SOs (Q27) nXa + nX¢— nilon-6,6 + 2nH20 (28) 2X2 + X3—> Xs + 2H20 ity hoiin than ede phurong trinh phan ting 25), (26), (27), (28) dudi dang céng thite cf vin g tinh phi (26), (27) ang céng thie . 9.2. XY la ai axitcacboxylic du hai chite, mach hé, ké tiép nhau trong day ding fing LAT la hai este thuin chtte (chi chtta m6t loai nhom chite) hon kém nhau 14 avC. Y va Z 1a dong phan aa nhau (Mx < My < Mr). Dét chay het Cy X25 edn dig vin 00 752 i~ 7,28 gam A cin dling song ti mane en a re cig at Mt ta i 42 ecco hn PO \ Cw 10: (2 idem) Tid i thi gig nb hin v= 1 npc a bap KX Wins ¥7 Gidi thich bing eée phuong trinh phn img hod hoc? Pcie gn mg yr binh dg dang dich KMnOs di va éng nghiém? Gi hich? 2 102. Bing abtng kin the héa hoe hy ili thich oe vin 2 sau: ave aie Meat dam amoni hoBe dam ure cing voi vi cho cy ane cho tim gilt? ng lb dé c6 nude ding cho tim gia? i 44. Vi sao khdng bin bh. Vi sao phen chua ge ding dif mudi dpe tang dich st khuan it dung trong phong dich Covid-19, 0 chic 10.3. Dé pha ché 10,0 lit ‘WHO gi6i thigu mot cing thie mb sau: ‘Dung dich etanol (nagu etylic) 96° 3533 mi Dung dich hidro peroxit 3% 417 ml ‘Dung dich glyxerol 98% 145 ml [Niube eft 48 dun 6, 46 ngudi hin con Tai a. Hidy cho bidt vai ro cia etanol, hidro peroxit va glyxerol trong dung dich sat Khuan. 'b. 6 naga cho biét s5 ml rugu etylic nguyén chit (d = 0,8 g/ml) c6 trong 100 ml dung dich rugu. Tinh ‘ii eng etal 6 trong 8333 ml rau 96° (96 d6) 6 trén. y ¢. Niu trong phong thi nghiém khéng sin 6 dung dich etanol 96° ma chi cé sin dung dich etanol 85°. Ems hy tinh thé tich dung dich etanol 85° va nude cat cin dé pha ché 10,0 lit dung dich sat khuan trén, Hb teveeneeeeenneneen nee Hoe sinh duge si dung bang hg théng twin hod ede nguyén 16 hda ge va. méy tinh edm tay theo quy dink cia BG Gio duc va Dao tao Ho vis tén thi sink: oe ssennnenenb bdo danhs (Chie Bb ca ght th ences RIK ia gion th 2:Cau 1 G,5 diém) t . 1. Cho cfc lo trong suét riéng. phenotphtalein; NaxSO«; HCI. Chil dling them (thigt bi cn thiét coi nb ©6 di). ‘Viet céc phwrong. 2, Ha tan hoan toan 10,2 gam m@t oxit ki 80 thu durge dung dich mudi ndng 49 10%. Cau 2G diém) i 1. Phuong phép thu khi (thuéng dun theo hinh I, hinh 2, hinh 3 du6i day 6 CO2, NHs, $02, Ch? Git thich sy Iya ch ‘(hinh 1) a 2. Néu hién tuong, viét cc phuong trinh héa ho a) Cho tir tir dén dur dung dich HCI vac b) Cho phoi hao Mg 4én dur vao dige va viet phuong trinh hoa hoc ea cée phan img xay ra Kh: (O.); vi dung dich KS: io dung dich Fe(SO3)s i vaio dung dich ehtia ZnCl 1 ir hai nguyén t6 c6 cng thie Li AB. Téng s6 hat proton trong mot phn tir nam gia vio m@t s6 phan ting héa hge theo so d8 sau Q)X+¥ 5 2Z+H,0 M ()X+FeCls 3 Z+M+Q Y, Z, TM, Q va viét phuong trinh hoa hoe xéy ra : 8 op X gdm Fes, va Cu tée dung vira dit 160 ml dung dich HCl 2M, sau khi ede phin : i fhu duge dung dich Y va m gam kim logi khOng tan, Dung dich Y phan tng vita dt véi | dich KMnO, 0,1M trong mai trudng axit (SO, lodng, dir). Viét phyong trinh héa hoe ede phan i trj ctia m ya V | nop B gém hai mudi MyCOs va MHCOs, Chia 49,95 gam B thanh ba phan bang nhau: | Phan mot tic dung hoan toan véi dung dich Ba(OH), du, thu duge 39,4 gam ket tia. Phin hai tae dy toan véi dung dich BaCl, du, thu duge 9,85 gam két tia. t6i da véi V ml dung dich NaOH 2,0 M. Tinh gid tri eva V va viet phuong trinh phan tmg xay ra (dang ion) trong time thi nghigm trén, ign tuong va viét phurong trinh ion thu gon trong ede thi nghiém sau: a) Cho NaHS vao dung dich CuCl b) Sue khi SO> vao dung dich nude brom; ©) Cho NaNO; vao dung dich ESO, (loa d) Suc khi CO) vao dung dich natri phenolat 2. Hop chit MX c6 trong mét loai quing phé bién trong ty nhién. Hoa tan MXa trong dung dich HNOs, thu duge dung dich A. Cho dung dich BaCh vao A thu duge két tita triing, cho A the dung v6i dung 1 tia dé nau. Xac dinh céng thire héa hoc MX2 va viét phurong trinh héa hge cia che dac nd dich NH phan tm Van dung kien thie mon héa hoe, hay tra loi cc a) Vi sao khi bon phan dam uré cho dong ru6ng kh b) Vi sao khéng ding khi CO dé dép tit dm chay kim loai Mg? 4. Hoa tan hoan toan 14,8 gam hén hop A gom Fe va Cu vao 100,0 gam HNO; 50,4%, sau khi kim loai tan hét thu duge dung djch X (khéng c6 mudi amoni) va hén hop khi B (g6m cée san phim Khir cia NO;). Cho 500 ml dung dich KOH 1,2M vao dung dich X thu duge két tia Y va dung dich Z. Loe ly Y¥ rbi nung trong khong khi dén khdi Iugng khéng déi thu durge 20,0 gam chat rin. C6 can dung dich Z. duge chat rin T. Nung T dén khoi lung khong doi thu duge 49,55 gam chat rin, Biét ede phan img xay ra hodn tod, tinh ‘trim khdi lugng moi kim loai trong A va ndng 49 C% moi chat tan trong X. p Cau 3. (4,0 diém) E ei 1. Chi duge ding them thudc thir 1& quy tim (cfc thiét bi cin thiét o6 di) hay trinh bay phuong phép hod: hoe dé nhin biét céc chat trong céc dung dich rigng bigt: NaxSO4, KHCOs, NaxCOs, KHSOx, NaOH, BaCh, Viét phurong trinh hoa hoc cua céc phan img xay ra. 4 2, Tién hinh thi nghiém diéu ché etyl axetat nhur sau; cho vio Ong nghiém 1 ml ancol X, 1 mi axit cacboxylic Y nguyén chat va 1 giot axit Z dim die. Lae déu, sau dé dun nhe trén ngon lita dén cn (khong, thu duge -4u hoi sau: nén tron chung v6i voi? duge dun s6i), Lam lanh rdi r6t thém vao éng nghiém 2 ml dung dich NaC! bao hoa. a) Xéc dinh ede chat X, Y, Z va viét phuong trinh héa hoc ota phan ting didu ché etyl axetat. b) Cho biét vai trd cia axit Z va dung dich NaCl bio hoa, ¢) Tai sao khOng duge dun s6i hén hop trong éng nghiém? " Trang 1/2