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College Board AP Chemistry Your notes

6.9 Hess’s Law

Contents
Hess's Law

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Hess's Law
Your notes
Hess's Law
In 1840, the Russian chemist Germain Hess formulated a law which went on to be known as Hess’s Law
This went on to form the basis of one of the laws of thermodynamics
The first law of thermodynamics relates to the Law of Conservation of Energy
This means that in a closed system, the total amount of energy present is always constant
Hess’s law can be used to calculate the standard enthalpy change of a reaction from known standard
enthalpy changes
Hess’s Law tells us that:
If the coefficients of a chemical equation are all multiplied by a constant, the ΔH°r is multiplied by that
same constant
If two or more equations are added together to obtain an overall reaction, the heats of these equations
are also added to give the heat of the overall reaction
This means that whether the reaction takes place in one or two steps, the total enthalpy change of the
reaction will still be the same
The combustion of 1 mole of propane has an enthalpy change of -2044 kJ, and whilst the reverse
reaction is not actually possible, we can deduce that the enthalpy change would be +2044 kJ
ΔH°r forward reaction = – ΔH°r reversereaction
Combustion of Propane

The heat of reaction has the same magnitude for a reaction in both the forward or reverse reaction. In
one direction the enthalpy change will be positive and the other direction the enthalpy change will be
negative

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If 2 moles of propane are burned in oxygen the enthalpy change will also double
2CH3CH2CH3 (g) + 10O2 (g) → 6CO2 (g) + 8H2O (l) ΔH°r = -4088 kJ
Your notes
If 0.5 moles of propane are burned then the enthalpy change will be half
½CH3CH2CH3 (g) + 2½O2 (g) → 3CO2 (g) + 2H2O (l) ΔH°r = -1022 kJ

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Worked example
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Consider the following reactions:
N2 (g) + O2 (g) → 2NO (g) ∆H = +180 kJ
2NO2 (g) → 2NO (g) + O2 (g) ∆H = +112 kJ
What is the ∆H value, in kJ, for the following reaction?
N2 (g) + 2O2 (g) → 2NO2 (g)
Answer:
Step 1: Identify which given equation contains the product you want:
This equation contains the desired product on the left side:
2NO2 (g) → 2NO (g) + O2 (g) ∆H = +112 kJ

Step 2: Adjust the equation if necessary, to give the same product:

If you reverse it, reverse the ΔH value
2NO (g) + O2 (g) → 2NO2 (g) ∆H = -112 kJ

Step 3: Adjust the equation if necessary, to give the same number of moles of product:
The equation contains the same number of moles as in the question, so no need to adjust the
moles
Step 4: Identify which given equation contains your reactant:
N2 (g) + O2 (g) → 2NO (g) ∆H = +180 kJ
Step 5: Adjust the equation if necessary, to give the same reactant. If you reverse it, reverse the ΔH
value:
There is no need to reverse it as the reactant is already on the left side
Step 6: Adjust the equation if necessary, to give the same number of moles of reactant
Step 7: Add the two equations together
N2 (g) + O2 (g) → 2NO (g) ∆H = +180 kJ

2NO (g) + O2 (g) → 2NO2 (g) ∆H = -112 kJ

Step 8: Cancel the common items
N2 (g) + O2 (g) + 2NO (g) + O2 (g) → 2NO (g) + 2NO2 (g)
Step 9: Add the two ΔH values together to get the one you want
N2 (g) + 2O2 (g) → 2NO2 (g) ∆H = +180-112 = +68 kJ

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Worked example
Your notes
Consider the following reactions
C2H4 (g) + 3O2 (g) → 2CO2 (g) + 2H2O (l) ΔH = -1411 kJ
C2H6 (g) + 3.5O2 (g) → 2CO2 (g) + 3H2O (l) ΔH = -1560 kJ
H2 (g) + 0.5O2 (g) → H2O (l) ΔH = –286 kJ
Calculate the enthalpy change, ΔHr, for the conversion of one mole of ethene and one mole of
hydrogen to one mole of ethane.
C2H4 (g) + H2 (g) → C2H6 (g)
Answer:
Step 1: Reverse the second equation to form ethane as a product
C2H4 (g) + 3O2 (g) → 2CO2 (g) + 2H2O (l) ΔH = -1411 kJ
C2H6 (g) + 3.5O2 (g) → 2CO2 (g) + 3H2O (l) ΔH = -1560 kJ
H2 (g) + 0.5O2 (g) → H2O (l) ΔH = –286 kJ
Step 2: Cancel out common items in all the given equations to form the equation for the formation
of one mole of ethane
C2H4 (g) + 3O2 (g) → 2CO2 (g) + 2H2O (l)
2CO2 (g) + 3H2O (l) → C2H6 (g) + 3.5O2 (g)
H2 (g) + 0.5O2 (g) → H2O (l)
Step 3: The enthalpy change, ΔHr, is the sum of the enthalpy changes
ΔHr = (-1411) + 1560 + (-286) = -137 kJ

Exam Tip
Hess’s Law states that the total enthalpy change in a chemical reaction is independent of the route
by which the chemical reaction takes place
Therefore, we can piece together the reactions in order to produce the desired product
You may need to reverse equations to get the reactants and products on the correct side or
multiply the equations in order for them to be balanced
If you reverse an equation, you must also reverse the sign and use this in the calculation

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