MH-Board +t MHT-CETHJER-Physies — ‘SThive particles, each hi a o eles, each having a charge of 10 iC (A) 17.06 108d - re ph 7 at 7 comers of an equilateral (C) 954 10°F ) 87 we . of side 10 em, The electrostatic vio enn, ssieheae figure, The area of the triangle {cre gta asim’) = lev aw WW) rer (BR) Ae 27) (bp) 1000 c Vv 33Th bringing an electron towards another cloctton, the electrostatic potential energy of He system gal don} —eptectyctite Q -aft Ssame doge 174 “ases (BY inereases (A) deere: | (C) remains same (D) becomes zero. Conductors 34. (AY the free charge tends to be in its miniumum potential energy state. — (B) the free charge tends to be in its minimum Kinetic energy state (©) the free charge tends to be in its maximum potential energy state. (D) the free charge tends to be in its maximum kinetic energy state. Capapitanee, Energy Stored in Capacitor 35 Eight drops of mercury of equal radii possessing equal charges combine to form a big drop. Then the capacitance of bigger drop compared to each individual small drop is (A) 8 times (B) 4 times Times (D) 32 times If the potential difference across a capacitor is increased from 10 V to 30 V, then the energy stored with the capacitor (A) increases to 3 times its initial value. Aacreases to 9 times its initial value. (C) increases to 27 times its initial value. (D) decreases to 1/3 times its initial value ‘A condenser has a capacity 2HF and is charged to a voltage of 50 V. The energy stored is (A) 25 * 1055 (B) 254 (C) 25* 10erg (DF 25 * 10° erg (5 700 uF capacitor is charged by 50 V battery. The electrostatic energy stored by it's (A) electric field between the plates (B) electric flux between the plates (C) grergy density : 40. At the charge on a capacitor is increased by 2 coulomb, the energy stored in it increases by 21%, The original charge on the capacitor is, (AOC (BYE (C)30C_ (D)40C Spherieal Capacitor, Cylindrical Capacitor and Paphitel plate Capacitor / two concentric conducting spheres are of radii +, and r,, The outer sphere is given a charge q ‘The charge q’ on the inner sphere will be (inner sphere is grounded) : XS, Aya (B)- me (D) Zero r plate capacitor has plate area A and 4% A parallel a potentia! separation d. It is charged 10 : difference V,, The charging battery 5 disconnected and the plates are pulled apart 0 three times the initial separation. The work required to separate the plates is 3e,AVi eeAVS (A) =~ (B) 2d AV? eyAVe © 7 (D) “1 Scanned with CamScannera Energy per unit volume for 8 capacitor having, area A and separation d kept at_potential difference V is given by wt s «ny Loy: (©) Sev we If the distan between the plate: Plate capacitor of capacity. 10 then new capacity will be (A) Su (8) 20pF (C) 10. (D) 15aF The energy required to ch condenser of plate s of a parallel F is doubled, ange a parallel plate ‘Separation d and plate area of ‘Stoss-section A such ‘that the uniform el cctric Field between the plates is Eis a (a) bee yaa (C) &EAd (B) &E? / Ad () de,btAd Ths outer sphere ofa spherical air capacitor i canted. For increasing is eapacitance, (A) vacuum is created between two spheres (B) dielectric material i s filled between the two spheres (C) the space between two spheres is increased (D) the earthing of the outer sphere is removed Combination of Capacitor The capacitance between t the following circuit is ‘ of >= te 4 (A)3.5 uF (B)3 uF (C)2 uF (0) He the points P and Q in Four condensers are joined as shown in the adjoining figure. The capacity of each is 8 . The equivalent capacity between the points A and B will be 49, 50, 52, 53. i. -naeiior Electrostatics and Capacito' (A)32 pF (BY RE (CYS HE eu A capacitor of eapacity 4 jtF charged to a is connected parallel to another capacitor o} 2 charged to 100, with plates of like charges connected together. What is the total energy before and after connection respectively? (A) 1.33 © 10" Sand 1.5% 1025 (B) 1.5 «10? Sand 1.33 + lores (C) 3.0 * 10° Sand 2.67 » ey (D) 2.67 «10? Jand 3.0 * 1025 Six capacitors, each of capacitance of 2uF, are Connected as shown in the figure. The effective capacitance between A and B is (A) 12 nF (By Su (©) 3pF (D) Gur Thre parallel plate air capacitors are connected '® parallel Each capacitor has plate area ® and the separation between the Fespectively, The combination is («, Plates is d, 2d and 34 equivalent capacity of = absolute permittivity of free space) eA By) SA ON Isa ‘The difference in the effective capacity of two similar capacitors when joine ‘din series and then in parallel is 6 yl. The capacity of each capacitor is (A) 2 ue (B) 4 ye (C) 8 uF (D) 16 pF In the given figure, three capacitors each of ‘Capacitance 6 PF are connected in series. The ‘otal capacitance of the combination becomes ooo alee 243 Scanned with CamScannerMUH-Board + MHT-CET4JEE-Physies (A) 2.2610" F (C) 6x 108 F (B) 3s 10" P (D) 9x 100 The equivalent capacitance between the points Nand B in the given diagram is: * at n te} 8 3 (A) Sn (B) 6pF (uF (D) Fuk Three capacitors, each of capacitance 2 are connected as shown in the figure. The capacitance between X and Y will be Hv PB ate HF i+ zor 3. (A)3 nF (B) Suk (C) SuF (Dy Oar 56. The resultant capacitance of given circuit is =I——r 2: src ak aa? « ‘0 (AIC (B)2C GCM) ¢ 57. A number of capacitors, each of capacitance ‘HF and each one of which gets punctured iff a Potential difference just exceeding 500 volt ig applied, are provided. Then an arrangement Suitable for giving a capacitor of capacitance 2HF across which 2000 volt may be applied requires at least: (A) 4 component capacitors {B) 12 component capacitors {C) 48 component capacitors {D) 16 component capacitors 58. A circuits has a section AB as shown in the figure with E=10V,C,=1.0,F,¢. Our and the potential difference V, -Va=5V. The voltage across C, is: 244, 60. Effect of Di 61. 62, 63. r e149 ac cq 8B (A) zero (C)1oVv In the circ (B)3V (D) SV diaram shown all the capacitors are in mE, The equivalent capacitance between points A & B is (in mF): hh (A) 14/5 (C37 (B75 (D) None of these A capacitor of capacity C, charged upto a voltage V and then connected to an uncharged capacitor of capacity C,, Then final potential difference across each will be: Cw cy By ere BE (a) 1 FC, Cc CQ 7) IV 1- vo e(rEy o(-§) eetric Slab and Sharing of Cha A big hollow ges metal sphere A is charged to 100 volts and another smaller hollow sphere B is charged to $0 volts. If B is Joined with a metallic wire, th charge low = put inside A and len the direction of (A)is from A to B (B) is from B to A (C) no charge Nows (D) depends on the radii of spheres Two metallic spheres of radii | em and 3 em are given charges of -1 x 102 @ a respectively, If conducting wire, sphere is : (A)4 x 10°C (C)2* 10° nd Sx 10°C these are connected by a the final charge on the bigger (B)1<10°¢ (D)3* 107¢ A parallel plate capacitor is ef Potential difference, A slab is inserted between the necessary to ji harged to a certain of thickness 3 mm. plates and it becomes crease the distance between the Scanned with CamScanneriii. ? charge per unit surface area (Surface char, € 4 density)! Fy Electric Faks=Edseos0 ii, constant of a me¢ Dielectric f==— Electric intensity: Electric intensity at a point outside a charged spherical conductor: q oR* -—4L_ = 5 > R) motu “Anker Keo! Egeuin “Gee (r>R) ne, where,o wd ” 2 (aa (D)A WwW tn 4 \ wy, ira=[%" Pland adja = Aart >? 2 . L3 2 AA= AAT the {1 9] Vy Sa +0 is equal to (MUT- CET 29 wl | wy |? (As (By (OB O. vu sol x 1 lp | 22 20. 1 al} 4 and A = Av! then x. Jeon sine IN WAS] Jet find c satisfying, sina eset oe IMIIT - CET 2014 (A) 0 (B) 4 (C)2 (D)1 21, If A is non-singu Oxas Sy when AHAT=VJ21 Jar matrix such tha (A — 21) (A — 41) = 0 then A + 8a-!. cue IMHT - CET 2019 wt wi oF (w= ra sing pai and (kl 2 22. If A is non-singular matrix and (A +1) 14, If A and B are wo square matrices such that (A=) =OthenA+A-! = A@B= BA and(AB)" = A*B". Then, k is. [MHT - (Murr CET 2022) (A) 2A (B) 0(C) F(D) 31 (A) 1001 (B) 1023 (‘7 i | f + where 23. I A (C) 1042 then A(adj A) . [MHT - CET 2019) where At is, transpose of A (MIT CET — 2022) CET 2019) (D) None of these cose. siner 1s, wra-[ , | «then the matrix A is [-sina cosa (MHT CET — 2022) (A) -2b (B) 21 (C) SE (Dp) at (A) Symmetric matrix 123 (B) Skew-symmetric matrix 24. tf A=|-1 1 2], then (A? - say At (C) ldentity matrix 124 (D) Orthogonal matrix IMHT - CET 20181 Y6. For an invertible matrix, AL it ] 200 Ala AY=\ yg] then al (MET - CET 2021) 20 200 1) 200, ar n. any As ent yy | then 4451 is 123 : where Lis aunt matny, (MINE = CET 2021) 25. Matrix A=/1 S|, then the value ® (A) Nall matriy 247 (B) Skew symmettic mat : : i trig agpA31 #03232 + 233A33 i8 (C) Symmetric Matrix aimai © mah vanrr- cer 20181 (D) None of the above ‘ay io rot ; > D)-13 z cthen At is (c)-1 c 18, A | ; | (MIT - CET 2020) 2 —# ct Scanned with CamScanner27. 28, 29, 30, 1 The inverse of the matrix | 5 Ss 2 a Ththe inverse of the matrix ]2 03 | 623 does not exist, then the value of ais IME T-CET 2017) (At (B) 1 (C)o (D) ~ lo WA=|2 1 5 Mea WAL HO,An ta,A 24 is equal to (MHT- CET 2016) (Ay (B)0 ©-1 22 0-1 wal? ae-[) 0 (B" ')" is equal to 2 7) | ; ~) 3 oF matrix 4. {i 3 such that AX = 1, then X is equal to (A) = i; 3) Dn 32, 35, Matrices cao s_fab A -! apie VT nen whieh one OF the following is notte? EE ain 2020) = (BY Osa? yp cy ) a? 4? =! ising and 02 the matri As © {sa sfies AMA‘ + 31) = 21, then the value of K is, WEE Main 2021) (a) 4 (Cyt (wy -4 wt WavBry=2n, then the system of equations HEE Main 2024] X + (cosy +(cos)z=0 {087)x ++ (cosayz =0 (CosPIx + (cosy (A) no solution (B) infinitely many solution (C) exactly two solutions (D) a unique sotution Let A bea 3% 3 matrix with det(A) denote the i" row of A. If Obtained by performing the operation Re>2Rs + SRy on 2A, then det(B) is equal to [JEE Main 2021) (A)64 (BIG (CVI {000 ‘The number of 3 x 3 matrices A whose enn are either 0 or | and for which the syst +2=0 has 7 Scanned with CamScannerw al QUESTIONNAIRE Solutions 4 EXERCISE -! wnt ggtucose is present in 1000 of solvent, wise Fe je sation 188 nid to be (8) 0.1 motar jay molar (D) 0.1 molat ps molar oe grate action of C\HLCOH), (glycerine) in a Bana of 30 BOE 46 g of glycerine is: joo (B) 0.36 020 (Dy 0.40 nich ofthe following statement is true = (a) Marty is the no, of moles of solute dissolved per litre of solvent. ip) The molarity and aoemality of a solution of sodium carbonate are same, 4) Molafty (m) ofa solution is defined as the number of moles of solute dissolved is 1000 gm of solution (a) The ratio of mole fraction of soluteand solvent isin the ratio of there respective moles. (Byawd (D) Only d (wake (b&e 4. Themolarity ofa solution of sodium chloride (mol. 5) in water containg 5.85 gm of sodium ie chloride in $00 ml of solution is (B) 2.0 (D) 0.2 44) 0.25 C10 ‘hs solution of 7.8 benzene (C,HH,) and 46.08 6 The molarity af? by wt H80,¢d= 18 amb) i (yom (ny kM com (Dy aM 7. For preparing 0.1 M solution of H,SO, inane I tre, we need H,SO, (A) 0.98 1 (yao (C) 49.08 (Dy 9Ke 7 eutralize 8, 25 ml D NaOH solution will exactly nets which of the following solution (A) 25 mi & KOU solution ) 25m 10 (B) 25 mI N H1,SO, solution (C)25 m1 x HCI solution N 2.5 ml > HN or (D) 2.5 ml 7 HINO, solution be ay How much water should be added to 200 ce of seminormal solution of NaOH to make it exactly 2 “eeinorrpal NWO NING Vo= (0007 200 “a = YOO CC A) 1000 ce (B) 400 ce AEP ay 7 100 ml of 0.3 N HCI solu (D) 600 ce jon is mixed with WW the 200 ml of 0.6 N H,SO, solution what ue aN h formality ofthe resultant solution, Ny Vy #835 NiMitNaV> blue (C,11,CH,), the mole fraction of henzene is (ayo (B) 06 May 2 at (C) 04 4D) 0. NG ®t o 5 11, How many grams of dibasic acid (mol wt. 200). ol mt Should be present in 100 ml. of the aqueous solution. (3 to give 0.1 normality ? tn 133 Scanned with CamScannerMH Board ¢ MUT-CET + JEE-Chemistry 14. 16. 17. 19. (10g in) 204 (2 Die aM (0) LB ney 1 mil. of concentrated sulphuric weid (18 molar) is diluted t9 10 titre, The approximate strength of thea Me pent be y= V5 (Ay oats NESTE ay 0.030 N (CVOION ay, 7, {OY 00 N il would be Ne: 0.0% M sodium thiosulphate, meulate the The density of a (Na,8,0,) solution is 1.28 g/ml percentage by weight of soutiuim thiosulphate (73.928 (BY 65.84 (ins (b) 375 A certain aqueous solution of FeCl, (Formula mass = 162) has a density of 1.1 g/ml and contains 20.0% FeCl,. Molar concentration of this solution is ~ (A) 0.028 (B) 0.163 (ct (D) LAT Number of moles of hydroxide (OH) ion in 0.3 litre of 0.005 M solution of Ba(OH), is (A) 0.0075 (B) 0.0015 (C) 0.0030 (D) 0.0050 solution of CaCl, of chloride ions in 500 ml. will be— (A) 0.25 (B) 0.50 (C) 0.75 (D) 1.00. Amount of ferrous ammonium sulphate needed to prepare 100 ml of 0.1 N solution is ~ (A) 39.2 g (B) 3.92 ¢ (©) 19.62, (D) 1.96 g Which of the following solutions has the highest mol/itre, then the moles normality ~ (A) 8 gms of KOH per litre (B) N-Phosphoric acid (©) 6 gms of NaOH per 100 ml (D) 0.5 MH,S0, How much water should be added to 200 ce of semi normal solution of NaOH to make it exactly decinormal - (A) 1000 ce (B) 400 ce (C) 800 ce (D) 600 ce 20, Normality of 0.3 M phosphorous (A015 anyon «p09 (D) 04 Henry's Law constant fora moti atm at 250°C, Whi 0,164 (A) 0.01 (B) 0,164 mol Lt (€)0.026M (D)0,.042M 22, Henry's law constant for dissolution of ey, 1298 K is 24 10%mm OF He. Tho, solubility of CH, in benzene at 298 K (in jern, of mole fraction) under 760 mm of Hg iss benzene (A) 1.2% 10% (B) 3.8107 ©) 4x107 (D) b Teak (C) Nitrie Acid ~ Water (D) Chloroform ~ Benzene “The azeotropic mixture of water(B.P 100°C) and HCL (BP. 85°C) boils at 108.8°C. When this mixture is distilled, itis, possible to obtain: (A) Pare HCI (B) Pure water (C) Pare water 3 (p) Neither HCI 1s well as HCI ‘nor H,O in their pure states | Scanned with CamScannerMH Boara , Mur. Bw / —— CET + JEE-Chemistey The weet benzene toluene shows Cy ett dation fm Rau Negative deviation fram Raoult's lave (C) Positive deviation from Raoult’ haw (D) Practically no deviation from Raoul’s law N solution that obeys Raoul's law is (A) Normal (B) Mol: (C) Ideal () Among the followi does no form an solution is - (A) C,H, and CyH,CH, (BYCCI and CHOI? akohe} (©) C, HCl and C,H,Br D) C,H,Br and CHL Which condition is not satisfied by an ideal solu- tion (A) AH mixing =0 (B) AV mixing =0 Simixing=0 (D) Obeyance of Raoull’s law S on beo 40. Anazeotropic solution of two liquids has boiling 41. 42. ‘The vapour pressure of 136 lower than either of them when it~ (A) Shows as negative deviation from Roult's law (B) Shows no deviation from Raoult's law (C) Shows positive deviation from Raoult’s law (D) Is saturated ‘An ideal solution is that which ~ (A) Shows positive deviation from Raoult’s law (B) Shows negative deviation from Raoults law (C) Has no connection with Raoult’ law (D) Obeys Raoult’s law TOS OLE a solution containing 2 moles of a nonvolatile solute in 2 moles of ‘water (vapour pressure of pure water = 24 mm Hg) is (A) 24. mm Hg (C)48 mm Hg (B) 32 mm Hg, (D) mm Hg, 43. 46. 47. 48. 49. ALL jgative property of a solution is (B) boiling point (D) freezing point The eu (A) vapour pressure (C) osmotic pressure Colligative properties ofthe solution depend upon (A) Nature of the solution (B) Nature of the solvent (C) Number of solute particles (D) Number of moles of solvent 15. Pressure cooker reduces cooking time for food because (A) boiling point of water involved in cooking is increased (By heat is more evenly distributed in the cooking space (C) the higher pressure inside the cooker crushes the food material (D) cooking involves chemical changes helped by arise in temperature. The vapour pressure of pure A is 10 torr and at the same temperature when 1 g of B is dissolved in 20 pmof A, then the vapour pressure of solution is 9 torr. If the molecular mass of A is 200 amu, then the molecular mass of Bis : (A) 100 amu (B) 90 amu (C) 75 amu (D) 120 ama Vapour pressure of solution of 5 g of non-electro- Iyte in 100 g of water ata particular temperature is 2985 N m7, Vapour pressure of pure water at that temperature is 3000 N m*. The molecular weight of the solute is ~ (A) 180 (B) 90 (€)270 (D) 200 Relative lowering of vapour pressure is equal to the mole fraction of the non volatile solute, this statement was given by — (B) Henry (D) Dalton (A) Roult (C) Joule Vapour pressure of a solution having solid as sok ute and liquid as solvent is — (A) Directly proportional to mole fraction of the solvent Scanned with CamScannerSolutions ppp A a$jpams (uy lnversely proportional to mote f ition of the solvent {C)Ditectly proportional to mole fraction of the softs (p)lnversely proportional to mole fraction ofthe solute 4, Vapour pressure of a dilute aqueous solution of Glucose is 750 mm of mercury at 373 K, The mole fraction of solute L 1 50 O ay 1 1 ©) «( (D) 35 451, Ebullioscopic constant is the boiling point elevation when the concentration of solution is (aim IM (C1 %whw {D) 1 mole fraction of solute. .. Molal elevation constant is the ratio of the eleva- tion in boiling point to - (A) Molarity (B) Molatity (C) Mole fraction of solute (D) Mole fraction of solvent 53, Asolution containing 3.3 gof a substance in 125 g of benzene (b.p. 80°C) boils at $0.66°C. IK, for one litre of benzene is 3.28°C, the molecular weight of the substance shall be ~ (A) 127.20 (B) 131.20 (C) 137.12 (D) 142.72 $4. Ifthe solution boils at a temperature T, and the solvent at a temperature T; the elevation of boiling point is given by ~ (AT, +7, (BT, -T, « Obeh (D) None of these When common salt is dissolved in water ~ (A) Melting point of the solution inereases (B) Boiling point of the solution inereases (C) Boiling point of the solution decreases (D) Both melting point and boiling point decreases $6. In calculating osmotic pressure the concentration of solute is expressed in 957, SH, *59, 60. “61. 62. 63. (B) molality (C) mole fraction (D) mass percent Cryoscopic constant depends on (A) nature of solvent (B) nature of solute (C) nature of solution (D) number of solvent molecules Identify the correct statement (A) vapour pressure of solution is that of pure solvent (B) boiling point of solvent solution (C) osmotic that of solvent (D) osmosis isa colligative property. ngcell contains a solution which is isotonic {with 0.3 M sugar solution, What osmotic pressure develops when the cell is placed in 0.1 M KCI solution at body temperature? (A)5.08 atm (B)2.54 atm (©) 492 am (D) 2.46 atm The osmotic pressure of blood is 7.65 atm at 310 K. An aqueous solution of glucose isotonic with blood has the percentage (by volume) {A)SAI% (B)3.54% (©)453% (D) 53.4% Which of the following statement is NOT correct for 0.1 M urea solution and 0.05 M sucrose solution? (A) osmotic pressure exhibited by urea solution is higher than that exhibited by sucrose solution (B) urea solution is hypertonic to sucrose solution (C) they are isotonic solutions (D) sucrose solution is hypotonic to urea solution higher than is lower than that of pressure of solution is lower than Ifa thin slice of sugar beet is placed in concentrated solution of NaCI then (A) Sugar beet will lose water from its cells. (B) Sugar beet will absorb water from solu n (C) Sugar beet will neither absorb nor lose water (D) Sugar beet will dissolve in solution ‘The plant cell will shrink when placed in: (A) Water (B) A hypotonic solution (C) A hypertonic solution 137 Scanned with CamScannerMH Board + MHT-CET «1: 64, 66. 67. (D) An isotonic solution Osmotic pressure of a solution (der contain is lym) 3 got glucose (molecular weight = 180) in 60 g of water at 15°C is (A) 0.34 atm (B) 0.65 atm (D) 5.57 atm Isotonic solution have the same — (A) Density (B) Molar concentrat (C) 6.25 atm (©) Normality (D) None of these Semipermeable membrane is that which permits the passage of - (A) Solute molecules only (8) Solvent molecules only (C) Solute and solvent molecules both (D) Neither solute nor solvent molecules Which inorganic precipitate acts as semipermeable membrane or the chemical composition of semipermeable membrane is (A) Calcium sulphate (B) Barium oxalate (C) Nickel phosphate (D) Copper ferrocyanide NORMAICO! xe Poa 69. 138 Whi (A) 0.1 M BaCl, = h solution will have least vapour pressure Bro. 1 Murea - / (C) 0.1 MNaSO, , (D) 0.1 MNaPO, i 4 ‘The substance A when dissolved in solvent B shows the molecular mass corresponding to A,, The Vant Hof’s factor will be - (A) (C)3 (B)2 (D) 13 70. mh. 72. 73. 14. ™ ALLEY: The ratio of the value of any colligative pro, for KCI solution to that for sugar solutions, for KCI s ea (B) 0.5 (D) 25 (Ayl («2 Which ofthe followingaqucous moll solution, highest freezing point (A) Urea (B) Barium chloride (C) Potassium bromide (D) Aluminium sulphate The value of observed and calcutated moleculy, weight of silver nitrate are 92.64 and 179 issociation of silver respectively, The degree of nitrate is: (A) 60% (B) 83.5% (©) 46. (D) 60.23% Among 0.1 M solutions of urea, Na,PO, and Al(SO,)s - (a) The vapour pressure and freezing point are the lowest for urea (b) The vapour pressure and freezing point are the highest for urea (c) The elevation in boiling pointis the highest for Al(SO)); (d) The depression in freezing poi for Al(SO,), (A) Only a (B) b & c both (C)b, cand d (D)a,b,candd Which one of the following solutions will have highest osmotic pressure? (Assume that all the s the highest salts are equally dissociated) - (A) O.IMAL(SO,), (B) 0.1 M BaCl, (C)0.1MNa,SO, (1D) The solution ob- tained by mixing equal volumes of (B) and (C) Scanned with CamScanner