Session 2022-23

Cumulative Test - 4
Date: 25-12-2022 M.M.:180

Topic: Solid State & Electrochemistry Time: 80 min.

Batch: Dropper (NEET)

IMPORTANT INSTRUCTIONS
This test consists of 50 questions. The maximum marks are 180.
There are two sections. Section – A has 35 questions and all questions are compulsory, whereas in Section –B there
are 15 questions , out of which only 10 questions you have to attempt.
Each question is allotted 4 (four) marks for correct response and one mark will be deducted for indicated incorrect
response of each question. No deduction from the total score will be made if no response in indicated for an item in the
answer sheet.

Section – A
Q 1. A ferromagnetic substance becomes a permanent magnet when it is placed in a magnetic field because
(A) All the domains get oriented in the direction of magnetic field
(B) All the domains get oriented in the direction opposite to the direction of magnetic field
(C) Domains get oriented randomly
(D) Domains are not affected magnetic field

Q 2. Which of the following is incorrect

(A) The defect is known as schottky defect

(B) Density of compound in the defect decreases
(C) NaCl(s) is example which generally shows this defect
(D) Stoichiometry of compound will change slightly

Q 3. The sharp melting point of crystalline solids is due to

(A) A regular arrangement of constituent particles observed over a short distance in the crystal lattice
(B) A regular arrangement of constituent particles observed over a long distance in the crystal lattice
(C) Same arrangement of constituent particles in different directions
(D) Different arrangement of constituent particles in different directions

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Q 4. A crystal is made of particle X, Y and Z. X forms FCC packing, Y occupies all octahedral voids of X and Z.
Occupies all tetrahedral voids of X, if all the particles along one body diagonal are removed then the formula of
the crystal would be
(A) XYZ2 (B) X2YZ2 (C) X8Y4Z5 (D) X5Y4Z8

Q 5. Predict coordination number of the cation in crystals of the following compounds

1. MgO : rc  0.65Å;ra  1.40Å , 2. MgS : rc  0.65Å;ra  1.84Å

(A) 6, 4 (B) 4, 6 (C) 3, 4 (D) 6, 8

Q 6. The radius of metal atom can be expressed in terms of the length of a unit cell is

(A) It is a/2 for simple cubic lattice (B) It is ( 3a / 4) for b.c.c. lattice

(C) It is (a / 2 2) for f.c.c. lattice (D) All of the above

Q 7. Which of the following solids are not correctly matched with the bonds found between the constituent particles:
(A) Solid CO2 : Vanderwaal's (B) Graphite : Covalent and Vanderwaal

(C) Grey Cast Iron : Ionic (D) Metal alloys : Ions-delocalised electrons

Q 8. Which of the following solids is not an electrical conductor ?

(i) Mg(s) (ii) TiO(s) (iii) I2 (s) (iv) H2O(s)

(A) i only (B) ii only (C) iii and iv (D) i, ii and iii

Q 9. Which of the following is an amorphous solid ?

(A) Graphite (C) (B) Quartz glass (SiO2 )

(C) Chrome alum (D) Silicon carbide (SiC)

Q 10. In a CCP lattice of X and Y, X atoms are present at the comers while Y atoms are at face centres. Then the
formula of the compound would be if one of the X atoms from a corner is replaced by Z atoms (also monovalent)
?

(A) X7 Y24 Z2 (B) X7 Y24 Z (C) X24 Y7 Z (D) XY24Z

Q 11. Which one is called pseudo solid -

(A) CaF2 (B) Glass (C) NaCl (D) All

Q 12. The standard reduction potential of Pb and Zn electrodes are - 0.126 and - 0.763 volts respectively. The e.m.f.

of the cell- Zn / Zn2+ (0.1M) || Pb2+ (1M) / Pb is

(A) 0.637V (B) < 0.637V (C) > 0.637V (D) 0.889

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Q 13. Amorphous solids
(A) Possess sharp melting points
(B) Undergo clean cleavage when cut with knife
(C) Do not undergo clean cleavage when cut with knife
(D) Possess orderly arrangement over long distances

Q 14. If Z is the number of atoms in the unit cell that represents the closest packing sequence ABC ABC …, the
number of tetrahedral voids in the unit cell is equal to

Z Z
(A) Z (B) 2Z (C) (D)
2 4

Q 15. How many unit cells are present in 39 gm of potassium that crystallizes in body centered cubic structures?

NA NA 3NA
(A) NA (B) (C) (D)
4 2 4

Q 16. An element occurring in the BCC structure has 12.08 x 1023 unit cells. The total number of atoms of the element
in these cell will be-

(A) 24.16 x 1023 (B) 36.18 x 1023 (C) 6.04 x 1023 (D) 12.08 x 1023

Q 17. 0.1905 gram of copper is deposited on the cathode by a current of 32 milliamperes passing for 5 hours through
a solution of copper sulphate. Determine the current efficiency
(A) 89% (B) 78% (C) 69% (D) 100%

Q 18. The standard reduction potential for two half cell reaction are given below :

Cd2 (aq)  2e  Cd(s)E  0.4V

Ag (aq)  e  Ag(s)E  0.80V

The standard free energy change for the reaction 2Ag (aq)  Cd(s)  Ag(s)  Cd2 (aq) is given by

(A) 115.8 kJ (B) -115.8 kJ (C) -223.2 kJ (D) -231.6 kJ

Q 19. S1 : When a cleaned strip of zinc metal is placed in a solutoin of CuSO4 , the copper metal starts depositing on
either zinc plate or settles down to the vessel.

S2 : In the electrolysis of aqueous NaBr using Pt electrodes then Br2 gas is evolved at the anode

S3 : The electrode potential of SHE is zero only at 25°C and not on other temperature.

(A) FTF (B) TTF (C) FTT (D) FTT

Q 20. How much time is required for complete decomposition of 4 moles of water using 4 ampere ?

(A) 3.86  105 sec (B) 1.93  105 sec (C) 96500 sec (D) 48250 sec

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Q 21. Consider the following cell reaction : 2Fe(s)  O2 (g)  4H (aq)  2Fe2 (aq)  2H2O(l),E  1.67V

At [Fe2 ]  103 M, P(O2 )  0.1atm and pH = 3, the cell potential at 25°C is

(A) 1.47 V (B) 1.77 V (C) 1.87 V (D) 1.57 V

Q 22. The reaction occurring at anode when the electrolysis of an aqueous solution containing Na2SO4 and CuSO4

is done using Pt electrode is

(A) Cu Cu2  2e (B) 2SO24  2H2O  2H2SO4  4e  O2

(C) 2H2O  O2  4H  4e (D) 2Cl  Cl2  2e

Q 23. Standard electrode potentials are

Fe2 / Fe, E  0.44V

Fe3 / Fe2 , E  0.77V

Fe2 ,Fe3 and Fe blocks are kept together, then

(A) Fe3 increases (B) Fe3 decreases

(C) Fe2 / Fe3 remains unchanged (D) Fe2 decreases

Q 24. A 4.0 molar aqueous solution of NaCl is prepared and 500 mL of this solution is electrolysed. This leads to the
evolution of chlorine gas at one of the electrodes. The total number of moles of chlorine gas evolved is
(A) 0.5 (B) 1.0 (C) 2.0 (D) 3.0

Q 25. When aluminium oxide (Al2O3 ) is electrolysed for the production of aluminium metal. For a given quantity of

electricity, the number of moles of aluminium obtained if the volume of O2 gas obtained is 201.6 litre measured

at NTP is
(A) 9 (B) 6 (C) 12 (D) 4.5

Q 26. On passing electricity through dilute H2SO4 solution the amount of substance liberated at the cathode and

anode are in the ratio

(A) 1 : 8 (B) 8 : 1 (C) 16 : 1 (D) 1 : 16

Q 27. The value of the reaction quotient, Q, for the cell Zn(s)|Zn2+(0.01 M)||Ag+(1.25 M)|Ag(s) is -

(A) 156 (B) 125 (C) 1.25 × 10–2 (D) 6.40 × 10–3

Q 28. When aqueous solution of KCl is electrolysed, resultant solution -

(A) has pH > 7 (B) turns red litmus blue (C) is basic in nature (D) all of these

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Q 29. For a cell reaction involving a two-electron change the standard e.m.f. of the cell is found to be 0.295 V at 25ºC.
The equilibrium constant of the reaction at 25º C will be

(A) 10 (B) 1 × 1010 (C) 1 × 10–10 (D) 29.5 × 10–2

Q 30. A metal crystallises in a face centred cubic structure. If the edge length of the unit cell is ' a ', the closest
approach between the two atoms in the metallic crystal will be

a
(A) 2a (B) (C) 2a (D) 2 2a
2

Q 31. The crystal system which contains maximum Bravais lattice is

(A) Cubic (B) Tetragonal (C) Orthorhombic (D) Rhombohedral

Q 32. From the following molar conductivities at infinite dilution.


m for Al2  SO4 3  858 S cm2 mol1


m for NH4OH  238.3Scm2 mol1


m for NH4 2 SO4  238.4 S cm2 mol1


Calculate m for Al(OH)3

(A) 715.2Scm2 mol1 (B) 1575.6 s cm2 mol1

(C) 786.3 Scm2 mol1 (D) 157.56 Scm2 mol1

Q 33. Four faradays of electricity were passed through AgNO3 ( ),CdSO4 ( ) . AlCl3 ( ) and PbCl4 ( ) kept in four

vessels using inert electrodes. The ratio of moles of Ag,Cd,Al and Pb deposited will be

(A) 12: 4: 6: 3 (B) 1: 2: 3: 4

(C) 12: 6: 4: 3 (D) 4: 3: 2: 1

Q 34. Sn2  2e  Sn(s), E  0.16 V

Ni2  2e  Ni(s), E  0.25 V

Cr 3  3e  Cr(s),E  0.74 V

Based on the above data, the reducing power of Pb,Sn,Ni and Cr is in the order

(A) Pb  Sn  Ni  Cr (B) Cr  Ni  Sn  Pb

(C) Cr  Sn  Ni  Pb (D) Sn > Ni  Cr  Pb

Q 35. The specific conductivity of 0.5 N solution is 0.01287ohm1 cm1 . What would be its equivalent conductance (in

ohm1 cm2eq1 )?

(A) 257.4 (B) 2.574 (C) 25.74 (D) 0.2574

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 Section – B
(Attempt any 10 questions out of 15 questions)

Q 36. NH4 and Br  ions have ionic radii of 143pm and 196pm respectively. The coordination number of NH4 ion in

NH4Br is

(A) 6 (B) 2 (C) 8 (D) 4

Q 37. The correct statement regarding defects in crystalline solids is

(A) Frenkel defect is a dislocation defect
(B) Frenkel defect is found in halids of alkaline metals
(C) Schottky defects have no effect on the density of crystalline solids
(D) Frenkel defects decrease the density of crystalline solids

Q 38. Assertion. Size of the cation is larger in tetrahedral hole than in an octahedral hole.
Reason. The cations occupy more space than anions in crystal packing.
(A) If both assertion and reason are true, and reason is the true explanation of the assertion.
(B) If both assertion and reason are true, but reason is not the true explanation of the assertion.
(C) If assertion is true, but reason is false.
(D) If both assertion and reason are false.

Q 39. Assertion. In any ionic solid, [MX], with Schottky defects, the number of positive and negative ions are same.
Reason. Equal number of cation and anion vacancies are present.
(A) If both assertion and reason are true, and reason is the true explanation of the assertion.
(B) If both assertion and reason are true, but reason is not the true explanation of the assertion.
(C) If assertion is true, but reason is false.
(D) If both assertion and reason are false.

Q 40. In a compound, oxide ions are arranged in cubic close packing arrangement. Cations A occupy one-sixth of the
tetrahedral voids and cations B occupy one-third of the octahedral voids. The formula of the compound is
(A) A2BO3 (B) AB2O3 (C) A2B2O2 (D) ABO3

Q 41. Select the incorrect statement in relation to Schottky defects

(A) Cation and anion should have comparable sizes
(B) Equal number of cations and anions (for an ionic solid MX) are present
(C) Density of crystal decreases
(D) It is a type of extrinsic defect

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Q 42. In an experiment, 0.04 F was passed through 400 mL of a 1 M solution of NaCl. What would be the pH of the
solution after the electrolysis ?
(A) 8 (B) 10 (C) 13 (D) 6

Q 43. Which of the following shaded plane in fcc lattice contains arrangement of atoms as shown by circles

(A) (B) (C) (D)

Q 44. No. of effective tetrahedral and octahedral voids present in FCC unit cell are respectively
(A) 4, 8 (B) 8, 4 (C) 6, 4 (D) 4, 6

Q 45. Which of the following is secondary cell?

(A) Dry cell (B) Mercury cell
(C) Lead storage battery (D) All of these

Q 46. Column A describe nature of bonding and Column B the solid having that type of bonding

A (Nature of bonding) B (Solid)

I. Van der Waals P. Al, Cd

II. Ionic Q. CO2,H2

III. Metallic R. Si, diamond

IV. Covalent S. MgO, NaCl

Correct matching of A and B is in alternate

I II III IV
(A) P Q R S
(B) Q S P R
(C)Q P R S
(D)S P Q R

Q 47. Consider an electrochemical cell in which the following reaction occurs and predict which changes will
decreases the cell voltage :

Fe2 (aq)  Ag (aq)  Ag(s)  Fe3 (aq)

(I) Decrease the [Ag ] (II) Increase in [ Fe3  ] (III) Increase the amount of Ag

(A) I (B) II and III (C) II (D) I and II

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Q 48. Given the listed standard electrode potentials, what is E for the cell :

4BiO (aq)  3N2H5 (aq)  4Bi(s)  3N2 (g)  4H2O(l)  7H (aq)

N2 (g)  5H (aq)  4e N2H5 (aq), E  0.23V

BiO (aq)  2H (aq)  3e  Bi(s)  H2O(l),E  0.32V

(A) +0.55 (B) +0.34 (C) +1.88 (D) +0.09

Q 49. For a galvanic cell, Zn | Zn2 (C1) | Zn2 (C2 ) | Zn . Select the incorrect option.

(A) E0cell  0 (B) Ecell  0 (C) Ecell  0 if C1  C2 (D) Ecell  0 if C2  C1

Q 50. A compound Mp Xq has cubic close packing (ccp) arranpacking (ccp) arran- gement of X . Its unit cell structure

shown below. The empirical formula of the compound is

(A) MX (B) MX2 (C) M2 X (D) M5 X14

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 Session 2022-23

Cumulative Test - 4
Date: 25-12-2022 M.M.:180

Topic: Solid State & Electrochemistry Time: 80 min.

Batch: Dropper (NEET)

ANSWER KEY

1 A 11 B 21 D 31 C 41 D

2 D 12 C 22 C 32 C 42 C

3 B 13 C 23 B 33 C 43 C

4 D 14 B 24 B 34 B 44 B

5 A 15 C 25 C 35 C 45 C

6 D 16 A 26 A 36 A 46 D

7 C 17 D 27 D 37 A 47 D

8 C 18 D 28 D 38 D 48 A

9 B 19 B 29 B 39 A 49 C

10 B 20 B 30 B 40 D 50 B

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