VANOO (SHANGHAI) CO.

,LTD

VANOO (SHANGHAI) Machinery Equipment CO.,LTD

Company name VANOO(SHANGHAI) CO.,LTD

VANOO(SHANGHAI) MACHINERY EQUIPMENT CO.,LTD
Email : antonia@vanoo.net
Address: NO. 585 , Jinbi Road , Jinhui Town , Fengxian district , Shanghai China
Tel : 86 -021-3178 1287
Fax: 86-021-5195 1564
Website : https://www.vanoo.net
https://www.vanoo.cc
Contact person : ( Miss ) Antonia
( 00 86 186 1650 4539)

Project proposal

Date : 2024-05-29
NO.VNOSLO -02-2000

Responsibility & Co-ordination

Website : https://www.vanoo.net email : antonia@vanoo.net

 VANOO (SHANGHAI) CO.,LTD

Production of Monoammonium phosphate

Process line
Ammonia neutralization method
1. Specification and dosage of chemical raw materials
1 The temperature of ammonia entering the neutralization reactor is 30 ℃, the
temperature of phosphoric acid is 60 ℃, and the temperature of the slurry is 82 ℃.
2 The fresh steam pressure is 0.30MPa (gauge pressure), and according to the steam
gauge, the saturated steam temperature is 143 ℃.
3 The vacuum degree of the second effect is -0.05MPa, and the pressure of the first
effect flash chamber is 0.05MPa (gauge pressure).
4 The water content of the second effect slurry is 43%, and the water content of the first
effect slurry is 25%.
5 The neutralization degree is 1.05.
6 The complete analysis of phosphoric acid is as follows:

P2O5－20%；MgO－1.65%；SO3－2.3%；Fe2O3－1.2%；Al2O3－0.8%；F－1.65%

2. Properties of ammonium phosphate system

2.1. Physical and chemical properties of solid ammonium phosphate

The main properties of ammonium phosphate orthophosphate are shown in Table 3-1

Table 3-1 Properties of ammonium phosphate salts

Responsibility & Co-ordination

Website : https://www.vanoo.net email : antonia@vanoo.net

 VANOO (SHANGHAI) CO.,LTD
Project NH4H2PO4 (NH4)2HPO4 (NH4)3PO4
Crystalline morphology Orthorhombic Monoclinic crystal Orthorhombic
crystal system system
N% contains 12.2 21.2 28.6
P2O5% Contains 61.8 53.8 48.3

N：P2O5 1:5.1 1:2.5 1:1.7

Density (19℃),kg/m3 1803 1619 —
Heat capacity (25℃)，kJ/mol·K 0.1424 0.1821 0.2301
Melting temperature ，℃ 190.5 decompose decompose
Heat of formation ，kJ/mol 1451 1574 1673
Heat of fusion，kJ/mol 35.6 — —
critical relative Humidity，%(30℃) 91.6 82.5 —
0.1mol/L Solution pH value 4.4 8.0 9.0

Monoammonium phosphate :

Ammonium phosphate has good thermal stability and is not easily hygroscopic. It has a
high solubility in water and is a fertilizer with excellent physical properties. Even if
monoammonium is heated to 100 ℃, it is difficult to detect the release of ammonia. It takes
about 200 ℃ for NH3 and H2O gases to be released:

The equilibrium pressure of ammonia and water vapor for solid ammonium phosphate is
shown in Table 3-2. From the data in the table, it can be seen that when drying ammonium
below 125 ℃, the ammonia loss is very small.

Table 3-2 Ammonia and Water Vapor Equilibrium Pressure of Solid Monoammonium
Phosphate

Responsibility & Co-ordination

Website : https://www.vanoo.net email : antonia@vanoo.net

 VANOO (SHANGHAI) CO.,LTD

Temp./℃ NH3/Pa H2O/Pa Temp./℃ NH3/Pa H2O/Pa

125.1 9.5 60.0 179.1 1823 9093
4
135.0 15.7 537 199.0 5517 2.05×10
4
144.9 40.2 617 219.5 6803 1.93×10
4 4
150.9 99.3 1000 199.5 1.82×10 1.79×10
4 4
160.7 164 1023 349.4 2.09×10 2.37×10
170.0 1350 5138

3. Calculation of the amount of producing one ton of

monoammonium phosphate

2NH3 P2O5 3H2O 2NH4H2PO4

2×17 142 2×115

x7 141.47 y7

Ammonia consumption in the production of monoammonium phosphate：

Ammonia consumption including ammonium sulfate and other ammonium salts:

14.70+37.44=52.14kg NH3
It is known that 1% ammonia is lost during the neutralization and concentration process,
but the actual total amount of ammonia required is 52.14/99%=52.67kg NH3
Among them, NH3 loss during neutralization process is 0.7%: 52.67 × 0.7%=0.3687 kg
NH3 loss during concentration process: 0.3%: 52.67 × 0.3%=0.1580 kg
Total feeding amount: 1000+52.67=1052.67 kg

Table 3-7 Quantity and composition of ammonium phosphate products

produced per ton of wet process phosphoric acid (dry basis)

Responsibility & Co-ordination

Website : https://www.vanoo.net email : antonia@vanoo.net

 VANOO (SHANGHAI) CO.,LTD

Component NH4H2PO4 (NH4)2HPO4 MgHPO 4 ·3H 2 O FePO 4 ·2H 2 O

Quality/kg 229.14 13.85 71.78 28.05

% 53.13 3.21 16.64 6.50

Component AlPO 4 ·2H 2 O (NH4)2SO4 (NH4)2SiF6 Totally

Quality/kg 24.78 37.95 25.76 431.31

% 5.75 8.80 5.97 100

4. Calculation of water content in ammonia slurry (before

vaporization and dehydration)

Total P2O5 content percentage of ammonium phosphate (dry basis):

The percentage of water-soluble P2O5 content in ammonium phosphate

Nitrogen content percentage of ammonium phosphate

5. Heat balance calculation of wet process phosphoric acid

Responsibility & Co-ordination

Website : https://www.vanoo.net email : antonia@vanoo.net

 VANOO (SHANGHAI) CO.,LTD

ammonification process
Table 3-8 Relationship between specific heat capacity and water content of
ammonium phosphate

Water content in slurry % 20 25 30 40 50 60

Specific heat capacity
1.841 1.987 2.134 2.427 2.720 3.192
KJ/ Kg·K

According to the interpolation method, when the water content of the slurry is 59.0%, its
specific heat capacity is 3.150 KJ/Kg · K

Phosphoric acid begins to boil and vaporize from 60 ℃ to 108 ℃

By looking up the table and using interpolation method, the evaporation heat of water in
the slurry at 108 ℃ is 2237.7 KJ/Kg

Table 5-1 Standard generation heat

H3PO4 NH3 H2SO4 NH4H2PO4
Substance
（Liquid） （sir） （liquid） （solid）
¢
△H ，KJ/mol -1279 -46.1 -811 -1451
f

(NH4)2HPO4 (NH4)2SO4 H2SiF6 (NH4)2SiF6

Substance
(Solid) （Solid） （water liquid） （water liquid）
¢
△H ，KJ/mol
f -1574 -1181 -2331 -2602

6. Dry Material Balance Sheet

Feeding Discharge
NO.
NO. Name Quantity（kg） % Name Qua。
（kg） %

1 Concentrated 575.08 100 1 Water 135.06 23.49

Solution evaporation
2 NH3 LOSS 4.313 0.75
2
3 Ammonium 435.71 75.77
phosphate
products
Totally 575.08 100 Totally 575.08 100
Theoretical calculation of consumption quota and product specifications:
Responsibility & Co-ordination

Website : https://www.vanoo.net email : antonia@vanoo.net

 VANOO (SHANGHAI) CO.,LTD
Mainly raw material consumption quota (per ton of ammonium phosphate
product):
wet-process phosphoric acid : （ 20% P2O5 ） 1000/435.71=2.295t H3PO4/t Product gas
ammonia
(100%NH3） 52.67×2.295/1000=0.121t NH3/t Product

Theoretical composition of the product

NO. Name Mass of substances % N（kg） P2O5（kg）

（kg） Contains Contains
1 NH4H2PO4 229.14 52.59 27.90 141.47

2 (NH4)2HPO4 13.85 3.18 2.94 7.45

3 (NH4)2SO4 37.95 8.71 8.05 —

4 (NH4)2SiF6 25.76 5.91 4.05 —

5 FePO 4 ·2H 2 O 28.05 6.44 — 10.65

6 AlPO 4 ·2H 2 O 24.78 5.69 — 11.14

7 MgHPO 4 ·3H 2 O 71.78 16.47 — 29.29

8 Loss -4.313 0.99 — —

9 H2O 8.71 2.00 — —

Totally 435.71 100 42.94 200

Product contains nitrogen:42.94×14/17=35.36kg

The percentage of nitrogen in the product is:42.94/435.71×100%=9.86%
The total amount of P2O5 in the product:200 kg
The percentage of P2O5 in the product is:200/435.71×100%=45.9%
The product specifications are represented as:10—46—0

7. Cost Calculations
The cost required to produce one ton of monoammonium phosphate

1 Phosphoric acid （20%P2O5 at leaste ) ：2.259 tons

2 Gas ammonia: 0.121 ton
3 Steam Consumption ：1 ton Steam /Now we design the evaporation crystallizer with MVR type and
multi-effect for client choice .
4 Power consumption ：150 150 kWh electricity Depends on client use MVR type or Mulit -effect type
5 Cooling water consuption :Depends ( circulation use )
6 Labor, safety, environmental protection, sales costs, and factory construction costs

Responsibility & Co-ordination

Website : https://www.vanoo.net email : antonia@vanoo.net