Electrochemistry conductance Cal

b- f- Kia {
0hm -108
Nernst Eq = =

Siemens
Mhtthero → M dilution increases
on as larger
number of ions produced
EMetali-FMetae-0.org#lg1-mn+,
are

specific conductance or conducts

• electrode potential qceee vine
K
f- Gila } 0hm -1cm -1
=
08

aAtbB # ✗ ✗ + yy
"
Decreases as no
.

of ions per
[✗ THY]
Eceee Feed -0%591-19 c. m3 decreases
-

_
.

ÑBb Molar conductivity ( nm )

ra To calculate equilibrium constant
Am -
KXV A- I c. m2
{
-

At equilibrium ,
t-cell -0
Mol l -

or

Peele
005¥ lngkc at 298K or
=
KX
looms smzm.it
=

• cell potential $ Gibbs free Energy increases with dilution due

AG°=-nfEÉeee in
Aci -2.303 RT large increase
to V
;
Iogkc
=

Limiting Molar conductivity Kohlrausch Law

cone
molar conductivity when .

or infinite Ain electrolyte = dilation

approaches to zero

dilution Ami or Anis + ii. Anion

Application
•

Degree of dissociation
-
_
And
(a) rim
↑ strong ( KU "

electrolyte ◦
Am Dissociation ( Kc )
¥3
=

weak
electrolyte CCHZCOOU ) constant

V7 →
 CHEMICAL KINETICS factors influencing Rate

R→P •
Concentration ↑ Reo R ↑ -

Rateqrxn
Aenr÷= -1^-19+1
-

Physical
-

save
-

•
state
↑ R OR ↑
Temperature
•
.

→ ,

Average Instantaneous
Generally ↑ R' ◦R
Rate
Rate
◦
Catalyst ,
↳
large time ↳ particular •
surface Area ↑ , R . OR ↑
interval
instant
of time presence Photochemical
light
•

of →

-1^11
^t?-
Ran
-

]
=

dearly + dep
-

Activation R' QR ↓
.

It
•

At
↑,
energy
Raleqrxn .
_
1- ×
Rate of atbearance Elementary Rxu → takes place in one Steb
coefficient / disappearance complex Rxn → takes blace in more than

i one siteb
Rate law .

0¥
! is bsotaojtionae of power acc.to
of reaction
rate sum

rate law expression

.

to
product of :( one term of reactant
-

Order = ✗+ B
raise to the power their actual used concept
→ experimental
term
conc fractional
.

2
→
can 0,1, or
.

be
aA+bB → Product

✗ [ A)
✗ B Mñ4 of reacting
sum
Rate [B)
B species molecularity atb =

# CAN (B)
.

→
can it be zero → can't be
rate constant/ Velocity constant
' ' *" "◦ "&
→
theoretical concept
Unit
of K :
Knoll -
1) " n Sec -1

first Order
zero order rate depends upon one
cone . term of reactant
rate is independent Rate
2.3¥ Inger
'
✗ [A ] t -

reactant
-

of conc .

of
°
"
then)t Kt + In [ A.)
Rate KCA ]
-
=
:

+42--0%93 Unit l
s
Kt -1CA)
-
=

(A) + = -
◦

t=R◦

tyz-R.IE Unit - mull-151