JEE

Prayas JEE (2025)

Practice Sheet (Chemistry)
Thermodynamics

Q1 The final temperature in an adiabatic Q5 The entropy change in the fusion of one mole of
expansion is: a solid melting at 27 C
∘
(latent heat of fusion is
(A) Greater than the initial temperature 2930 Jmol
−1
) is:
(B) Same as the initial temperature (A) 10.73 J K −1
mol
−1

(C) Half of the initial temperature (B) 2930 J K−1 mol

−1

(D) Less than the initial temperature. (C) 108.5 J K−1 mol
−1

(D) 9.77 J K−1 mol

−1

Q2 Given that
∘
Q6 Which of the following is not a state function?
C + O2 ⟶ CO2 ; ΔH = −xkJ

∘
(A) G
2CO + O2 ⟶ 2CO2 ; ΔH = −ykJ
(B) U
The enthalpy of formation of CO will be: (C) W
(A) y − 2x (D) H
(B) 2x−y

2 Q7 Which of the following reactions defines ΔHf ?

(C) y−2x

2 (A) C(diamond) + O2( g) ⟶ CO2( g)

(D) 2x − y (B) 1
H2( +
1
F 2( ⟶ HF(g)
g) g)
2 2

Q3 Identify the state function among the following: (C) N2( g) + 3H2( g) ⟶ 2NH3( g)

(A) q (D) CO(g) +

1
O2( g)
⟶ CO2( g)
2

(B) q − W
q
Q8 ∘
(C) W
PbO2 ⟶ PbO; ΔG < O
∘
(D) q + W SnO2 ⟶ SnO; ΔG > O

Q4 The values of ΔG for the following reaction at Most probable oxidation state of Pb and Sn
800 C
∘
are: W) will be:
(A) Pb4+ , Sn4+
S2( g) + 2O2( g) ⟶ 2SO 2( g) ; ΔG = −544 kJ
(B) Pb4+ , Sn2+
2Zn (s) + S2( s) ⟶ 2ZnS(s) ; ΔG = −293 kJ (C) Pb2+ , Sn2+
2Zn (s) + O2( g) ⟶ 2ZnO(s) ; ΔG = −480 kJ (D) Pb2+ , Sn4+

The ΔG for the reaction: Q9 If the bond energies of H − H, Br − Br and

are 433, 192 and
−1
H − Br 364 kJ mol
2ZnS(s) + 3O2( ⟶ 2ZnO(s) + 2SO 2(
g) g)
respectively ΔH for the reaction:
H2( + Br2( ⟶ 2HBr(g) is:
Will be: g) g)

(A) −261 kJ
(A) −731 kJ
(B) +103 kJ
(B) −773 kJ
(C) +261 kJ
(C) −229 kJ
(D) −103 kJ
(D) −357 kJ

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Q10 An ideal gas expands in volume from 10

−3
m
3
(A) -7.42 (B) +3.72
to (C) -3.72 (D) +7.43
10
−2
m
3
at 300 K against a constant pressure
Q15 In which of the following process, the process is
of 10 5
Nm
−2
. The work done is :
always non-feasible.
(A) −900 J
(A) ΔH > 0; ΔS > 0
(B) −900 kJ
(B) ΔH > 0; ΔS < 0
(C) 270 kJ
(C) ΔH < 0; ΔS > 0
(D) 900 kJ
(D) ΔH < 0; ΔS < 0

Q11 For A ⟶ B
−1 −1 −1 Q16 Match Column I with Column II
ΔH = 4kcalmol ; ΔS = 10calK mol

The reaction is spontaneous when temperature

is:
(A) 400 K
(B) 300 K
(C) 500 K
(D) None

Q12 The ΔH
∘
for CO2( g) , CO(g) and H2 O(g) are (A) A − S; B − R; C − P; D − Q
-393.5 , (B) A − S; B − R; C − Q; D − P
-110.5 and −241.8 kJ mol
−1
respectively. The (C) A − S; B − Q; C − R; D − P
standard enthalpy change (in kJ ) for the (D) A − Q; B − S; C − Q; D − P
reaction:
Q17 One mole of an ideal gas at 300 K is
CO2( g) + H2( g) ⟶ CO(g) + H2 O(g) is:
expanded
(A) 542.1 (B) 41.2
isothermally from an initial volume of 1L to 10L.
(C) -262.5 (D) -41.2
The ΔU for this process is....................
Use R
−1 −1
Q13 How much energy is released when 6 moles = 2calK mol

octane is burnt in air? Given: ΔH∘f for

Q18 The number of intensive properties among the
CO2( g) = −490 kJ mol
−1 following is................... Temperature, Volume,
−1 Enthalpy, Density, Entropy, Free energy, Internal
H2 O(g) = −240 kJ mol

−1
energy.
C8 H18( g) = +160 kJ mol

Q19 Among the following, the number of state

(A) −6.2 kJ functions
(B) −37.4 kJ are.................. Enthalpy, work, Internal energy,
(C) −35.5 kJ Entropy, heat, Free Energy.
(D) −20.0 kJ
Q20 The entropy change for a phase transformation
Q14 The difference between heats of reaction at is :
constant (A) ΔU

γ+dT
pressure and constant volume for the reaction :
(B) ΔT

2C6 H6 (ℓ) + 15O2( g) ⟶ 12CO2( g) at 23 C

∘ ΔH

(C) ΔH

T
+ 6H2 O(ℓ)
(D) ΔH +ΔG

in kJ is : T

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Q21 Calculate Δf H for ZnSO4 (s) from the constant pressure for the formation of 1 mole of
following data C6 H5 COOH(l) at 300 K , will be:
ZnS(s) → Zn(s) + S (rhombic) , ΔH1 (A) 24 × 10 cal
2

= 44 kcal/mol (B) −24 × 102 cal

2ZnS(s) + 3O2 ( g) → 2ZnO(s) + 2SO 2 ( g), (C) 18 × 102 cal
ΔH 2 = (D) −3 × 10−2 cal
−221.88 kcal/mol

2SO 2 ( g) + O2 ( g) → 2SO 3 ( g), ΔH3

Q26 Calculate the enthalpy of the following

= −46.88 kcal/mol
homogeneous gaseous reaction
CH3 COCH3 + 2O2 → CH3 COOH + CO2
ZnSO4 (s) → ZnO (s) + SO 3 (g), Δ H4
+ H2 O
= 55. 1 kcal / mol
from the following data.
(A) −233.48 kcal/mol
Bond energies
(B) −343.48 kcal/mol
(kJ/mol) : C − H = 414; C − C = 348 ;
(C) −434.84 kcal/mol
C = O = 580; C − O = 354; O = O = 610;
(D) −311.53 kcal/mol
O − H = 462;

Q22 Equilibrium Magnitude of resonance energies (kJ/mol) :

For the process H2 O(l) ⇌ H2 O(s)
COOH = 118; CO2 = 140 .
Select the correct option.
(A) −348 kJ
(A) ΔH = − ve, ΔS = + ve, ΔV = − ve,
(B) 168 kJ
ΔG = 0
(C) −168 kJ
(B) ΔH = − ve, ΔS = − ve, ΔV = + ve,
(D) −348 kJ
ΔG = 0

(C) ΔH = + ve, ΔS = + ve, ΔV = − ve, Q27 What is the change in internal energy when a
ΔG = 0 gas contracts from 377 mL to 177 mL under a
(D) ΔH = − ve, ΔS = − ve, ΔV = − ve, constant pressure of 1520 torr , while at the
ΔG = 0 same time being cooled by removing 124 J

heat?
Q23 Consider the ΔG
∘
and ΔH
∘
(kJ/mol) for the
f f
(A) 40.52 J
following oxides. Which oxide can be most
(B) −83.48 J
easily decomposed to form the metal and
(C) −248 J
oxygen gas?
(D) None of these
(A) ZnO (ΔG∘ = −318.4, ΔH
∘
= −348.3)

(B) Cu2 O (ΔG∘ = −146.0, ΔH

∘
= −168.8) Q28 For the auto-ionization of water at
+ −
(C) HgO(ΔG∘ = −58.5, ΔH
∘
= −90.8)
∘
25 C, H2 O(l) ⇌ H (aq) + OH (aq)

(D) PbO(ΔG∘ = −187.9, ΔH

∘
= −217.3) equilibrium constant is 10
−14
. What is ΔG
∘
for
the process?
Q24 Consider a reversible isentropic expansion of 1
(A) ≃ 8 × 10
4
J
mole of an ideal monoatomic gas from 27 ∘
C to
(B) ≃ 3.5 × 10
4
J
∘
927 C . If the initial pressure of gas was 1 bar,
(C) ≃ 10
4
J
then the final pressure of gas becomes
(D) None of these
(A) 4 bar (B) 8 bar
(C) 32 bar (D) 0.25 bar Q29 Sublimation energy of Ca is 121 kJ/mol .
Dissociation energy of Cl2 is 242.8 kJ/mol, the
Q25 The difference between heat of reaction at
total ionization energy of Ca(g) → Ca
2+
(g) is
constant volume and heat of reaction at

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2422 kJ/mol and electron affinity of Cl is (B) 595.14 J/mol

−355 kJ / mol . Lattice energy of CaCl2 is (C) −5951.4 J/mol
−2430.8 kJ/mol . What is ΔH for the process (D) None of these
Ca(s) + Cl 2 (g) → CaCl2 (s)?
Q34 Out of internal energy (I), boiling point (II), pH (III)
(A) −355 kJ mol −1
and E.M.F. of the cell (IV) intensive properties are
(B) +3550 kJ mol −1
:
(C) −35.5 kJ mol −1
(A) I, II (B) II, III, IV
(D) −1720 kJ mol −1
(C) I, III, IV (D) All of these
Q30 One mole of an ideal gas at ∘
25 C expands in
Q35 The heat capacity of bomb calorimeter is
volume from 1.0 L to 4.0 L at constant
500 J/ C
∘
.A ∘
2 C rise in temperature has been
temperature. What work (in J ) is done if the
observed on the combustion of 0.1 g of
gas expands against vacuum (Pexternal = 0) ?
methane. What is the value of ΔE per mole of
(A) −4.0 × 102
methane?
(B) −3.0 × 102
(A) 1 kJ
(C) −1.0 × 102
(B) 160 kJ
(D) Zero
(C) −160 kJ
Q31 A 0.05 L sample of 0.2M aqueous hydrochloric (D) −1 kJ
acid is added to 0.05 L of 0.2M aqueous
Q36 If three moles of an ideal gas at 300 K expand
ammonia in a calorimeter. Heat capacity of
isothermally from 30 dm3 to 45 dm3 against a
entire calorimeter system is 480 J/K . The
constant opposing pressure of 80 kPa, then the
temperature increase is 1.09 K . Calculate
amount of heat transferred is _________J.
Δr H
∘
in kJ/mol for the following reaction :
HCl( aq. )+NH3 (aq.) ⟶ NH4 Cl( aq. ) Q37 Which of the following is not correct?
(A) -52.32 (B) -61.1 (A) ΔG is positive for a non-spontaneous
(C) -55.8 (D) -58.2 reaction
(B) ΔG is positive for a spontaneous reaction
Q32 An ideal gas undergoes isothermal compression
(C) ΔG is negative for a spontaneous reaction
from 5 m
3
to 1 m
3
against a constant external
(D) ΔG is zero for a reversible reaction
pressure of 4 Nm
−2
. Heat released in this
process is used to increase the temperature of 1 Q38 Standard enthalpy of vapourisation for CCl4 is
mole of Al . If molar heat capacity of Al is 30.5 kJ mol–1. Heat required for vapourisation of
, the temperature of
−1 −1
24 J mol K Al
284 g of CCl4 at constant temperature is
increases by ______ kJ. (Given molar mass in g mol–1; C = 12,
(A) 3

2
K
Cl = 35.5)
(B) 1 K

(C) 2 K
Q39 An ideal gas undergoes a cyclic transformation
(D) 2
K
starting from the point A and coming back to
3
the same point by tracing the path
Q33 18gm of ice is converted into water at 0∘ C and A → B → C → A as shown in the diagram
1 atm . The entropies of H2 O(s) and H2 O(l) below. The total work done in the process is
are 38.2 and 60 J/molK respectively. The ________J.
enthalpy change for this conversion is :
(A) 5951.4 J/mol

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Choose the most appropriate answer from the

options given below:
(A) (C) and (D) only
(B) (B) and (C) only
(C) (A) and (B) only
(D) (B) and (D) only

Q44 The true statement amongst the following is:

(A) S is a function of temperature but ∆S is not a
function of temperature.
(B) Both ∆S and S are functions of temperature.
(C) S is not a function of temperature but ∆S is a
Q40 Two reactions are givenbelow: function of temperature.
2F e (s) +
3
O2(g) → F e 2 O3(s) , Δ H
o
=
(D) Both S and ∆S are not functions of
2
temperature
−822 kJ /mol
1 o
C(s) +
2
O2(g) → C O(g) , Δ H = −110 kJ
Q45 When 5 moles of He gas expand isothermally
/mol and reversibly at 300 K from 10 litre to 20 litre,
Then enthalpy change for following reaction the magnitude of the maximum work obtained
3C(s) + F e 2 O3(s) → 2F e (s) + 3C O(g) is is_______ J. (nearest integer) [Given: R= 8.3 JK–1
_______ kJ/mol. mol–1 and log2 = 0.3010]

Q41 Choose the correct option for free expansion of Q46 4.0 L of an ideal gas is allowed to expand
an ideal gas under adiabatic condition from isothermally into vacuum until the total volume
the following: is 20L. The amount of heat absorbed in this
(A) q ≠ 0, Δ T = 0, w = 0 expansion is________ L atm.
(B) q = 0, Δ T = 0, w = 0

(C) q = 0, Δ T < 0, w ≠ 0
Q47 Five moles of an ideal gas at 293 K is expanded

(D) q = 0, Δ T ≠ 0, w = 0
isothermally from an initial pressure of 2.1 MPa to
1.3 MPa against at constant external pressure
Q42 Given 4.3 MPa. The heat transferred in this process
(A) 2CO(g) + O2(g) → 2CO2(g) is_____kJ mol–1. (Rounded-off to the nearest
θ –1
ΔH
1
= −x kJ mol integer).
(B) C(graphite) + O2 (g) → C O2 (g) [Use R = 8.314 J mol–1 K–1]
θ –1
ΔH = −y kJ mol
2

The ΔH for the reaction

θ Q48 The magnitude of work done by a gas that

C(graphite) + 1
is undergoes a reversible expansion along the
O2 (g) → C O(g)
2
path ABC shown in the figure is __________J.
(A) x−2y
(B) x+2y

2 2

(C) 2x−y
(D) 2y – x
2

Q43 Which of the following relations are correct?

(A) ΔU = q + p Δ V

(B) ΔG = ΔH − T Δ S
qrew
(C) ΔS =
T

(D) ΔH = ΔU − ΔnRT

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Q49 For complete combustion of ethene.

C2H4(g) + 3O2(g) → 2CO2(g) + 2H2O(l) the
amount of heat produced as measured in
bomb calorimeter is 1406 kJ mol–1 at 300K. The
minimum value of TDS needed to reach
equilibrium is (–) _________ kJ.
Given : R = 8.3 JK–1 mol–1

Q50 For complete combustion of methanol

CH3OH(l) + O2(g) → CO2(g) + 2H2O(l)
3

The amount of heat produced as measured by

bomb calorimeter is 726 kJ mol–1 at 27°C.
The enthalpy of combustion for the reaction is –
x kJ mol–1, where x is_________. (Nearest
integer)
(Given : R = 8.3 J K–1 mol–1)

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Answer Key
Q1 (D) Q26 (D)

Q2 (C) Q27 (B)

Q3 (D) Q28 (A)

Q4 (A) Q29 (A)

Q5 (D) Q30 (D)

Q6 (C) Q31 (A)

Q7 (B) Q32 (D)

Q8 (D) Q33 (A)

Q9 (D) Q34 (B)

Q10 (A) Q35 (C)

Q11 (C) Q36 1200

Q12 (B) Q37 (B)

Q13 (B) Q38 56

Q14 (A) Q39 200

Q15 (B) Q40 492

Q16 (B) Q41 (B)

Q17 0 Q42 (A)

Q18 2 Q43 (B)

Q19 4 Q44 (B)

Q20 (C) Q45 8630

Q21 (A) Q46 0

Q22 (B) Q47 15

Q23 (C) Q48 48.00

Q24 (C) Q49 1411

Q25 (A) Q50 727

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