Ww 12 1.3, 14 45 1.6 17 18 19 110 4 42 SECTION : STRAIGHT OBJECTIVE TYPE A partially dried clay mineral contains 8% water . The original 63m ‘The % of silica in the partially dried sample is nearly. (4)47% (1) 50% (2)49% (3)55%, ple contains 12% water ‘and 45% silica, ‘4 Ifthe mole fraction ofa soluteis changed fm + to ; byadding some solute in he 800 g of H,0 solvent, then the ratio of molality of two solutions willbe: (11:3 (2)4:4 (3)2:3 Inthe balanced equation : ‘ ; a 2. Fes +Mno- HY, Fe + S02 + Mn tie stoichiometric coefficients of FeS and MnO,” are in the ratio: — (1)8:5 (2)5:8 #(3)9:5 (4)5: K,Cr,0, +074 H,80,—+K,SO, +€0, + Cr{(S0,),* H.0 eee In above reaction, identify the elements which do not undergo change in their oxidation state: aye (2)S&Cr (3)K,0,S&H (4)C&O a From the mixture of 4 moles Ca,(PO,), and § moles of P,O,, and 6 moles of H,PO, all the phosphorus atoms are removed then moles of P, molecule formed from all these atoms is (185 @17 (3)34 (4)10 The density of a liquid is 1.2 g/mL. There are 35 drops in 2mL. The number of molecules in one drop (mo mass of liquid = 70 g/mol) is : (41:2 a) (Zs. @ é (gy Ny (3) we (4)1.2N, ' 1: ‘Sulphur existin different allotropic forms ike S,, S,and S, etc. If equal moles of these three forms are taken in separate containers, then the ratio of number of atoms present in them respectively is : ibe (1) 4:324 tetas (3)12:4:3 (4)4:3:1 i There are two sample of HC! having molarity 1M and 0.25 M. Find volume of these sample taken in order| prepare 0.75 M HCI solution. (Assume no water is used) (1) 20 ml, 10 ml (2) 100 mi, 60 mi (3) 50 ml,20ml ~ (4) 50 ml, 35 ml Equivalent weight of KHC,O,.3NaHC, reaction with acidic KMnO, is (M = Molar mass) M i M OF Az ; @M ws The vapour density of a mixture containing equal number of moles of methane and ethane at STP is. (1911.5, = one (2) 11.0 (3)23 (4)12.0 The temperature at which molarity of pure water is equal to its molality i (1)273K (2) 298K (3)277K (4)None 4 ‘Acompound has the molecular formula X,0,-If 10 g of X,O,has 5.729 of X. th i (1)32. amu (2)37 amu (3)42.amu . then atomicmass of Xis (4)98 amu4.13 414, 145 1.16 117 1.18 419 1.20 4.24 1.22 1.23 1.24 1.25 1.26 4.27 1.28 Equal masses of oxygen, hydrogen and methane are taken in a container in identical conditions. Find the ratio of their moles. (1)1:16:2 (2) 4:16:41 (3) 16:14:41 (4) 162221 Number of electrons in 1.8 mL of H,0(¢) (1) 6.02 t¢=—— (2)3.011* 10 (3)0.6022 «10 (4) 60.22 x 102 What is the molarity of H,SO, solution that has'a density 1.84 g/cc at 35°C and contains 98% by weight- (1)4.18M (2)8.14M. (3) 18.4M (4)18M How many grat 1S of SO, "are present in 1 gram molecule of K,SO,.Al,(SO,),. 24H,0 : (2 3 @)1 a ae Which of the following contains the same number of molecules ? (1) 1g 0f 0,, 2g of SO, (2) 1g of CO,, 1g of NO. (3) 112 m1 of O, at STP, 224 mlof He at 0.5 atm and 273 K (4) All of these The density of water at 4*Cis 1 * 10° kg m~. The volume occupied by one molecule of water is approximately: (1)9% 10 mL (2)6* 102 mt. (3)3* 10 mL (4)9 «102 mL. How many moles of KMnO, are needed to oxidise a mixture ‘of 1 mole of each FeSO, & FeC,O, in acidic medium : an me @s @3 @e In the reaction : Na,S,O, + 4C}, +5H,0 ——> Na,SO, + H,SO, + BHCI, the equivalent weight of Na,S, 0; will be : (M = molecular weight of Na,S,0,) (M4 (2) Me (a) MA (a2 Chlorophyll, the green colouring matter of plants responsible for photosynthesis, contains 2.68% of magnesium by mass. Calculate the number of magnesium atoms in 2.00g of chlorophyll. (1) 1.345 «10 (2)1.345 « 10” (3) 13.45 « 10" (4) 1.345 x 108 In the reaction 2NH,' + 6NO, (aq) + 4H'(aq) —> 6NO,(g) + N,(g) + 6H,0 the reducing agent is, (1) NH." (2)No, (3) H"(aq) (4)NO, * 6 litre of mixture of methane and propane on complete combustion gives 7 litre of CO,, Find out the composition of the mixture? (1) 5:5 fit, 0.5 fit, (2) 45 lit, 1.5 lit. (3) 3.5 lit, 2.541 (4)None of these Carbon occur in nature as a mixture of C-12 and C-13. Average atomic mass of carbonis 12.011 whatis the % abundance of C-12 in nature ? (1) 98.9% (2)60.9% (332.9% (4)1.4% Ina compound Carbon = 52.2%, Hydrogen = 13%, Oxygen = 34.8% are present and vapour density of the ‘compound is 46. Calculate molecular formula ‘of the compound ? CHO, QCHO, B)CH,,0 CHO, to neutralize 5g caustic soda. (1) 19.19 * (2)6.81 (344.44 (4) None of these 6g of ahydrocarbon on: ‘combustion in excess of oxygen produces 17.6 g of CO, and 10.8 g of H,O. The data illustrates the law of : e . (1Y conservation of mass (2) multiple proportions (3) constant proportions (4) reciprocal proportions, ‘ag KHC;O, are required to reduce 100 mL of 0.02 MKMnO, in acid medium and'b’ g KHC,O, neutralises 100 mL of 0.05 M Ca(OH),.then : ()a=b (3)a=2b (4)None of these* 4.29 1.30 1.31 1.32 1.33 1.34 1.35 1.36 1.37 1.38 1.39 1.40 4.41 1.42 1.43 1.44 Which of the following reactions represents disproportionation ? (1)CrO, — Cr** + 0, QO, +r +H'— I, (8) Cr0,C1, + NaOH —>Na,CrO,+NaCI+H,O (4) Na,S,0, + H,SO, —>,Na,S0, +SO, +, +H,0 A\resh H,0, solution is labelled 11.2 V. This solution has the same concentration as a solution which is. 7 (1) 3.4% (wttwt) (2)3.4% (volvo!) (3)3.4% (wtlvol) (4)None of these {n which of the following compound, oxidation state of 'S"is other than the +6. (1)peroxomonosulphuricacid (Caro's acid) (2) peroxodisulphuric acid (Marshall's acid) (3) pyrosulphuric acid (oleum) (4) sodium thiosulphate (hypo) Valency factor of the following compounds will be samen neutralisation - (1)S0, + H,S0, (2)NH,+ Ht > NH," d (3) N,O, -» 2HNO,, (4)Aand C have same valency factor White phosphorus reacts with caustic soda, the products are PH, and Nal,PO,. This reaction is an example of: : j (1) Oxidation (2)Reduction (8)Disproportionation _(4)Neutralisation How many mililitres of 2 9NH,SO, solution will bé required to neutralize completely 20 mL of a3.6N' solution? . = (1) 18.0 mt (2)8.0 mL (316.0mL = *—*—(4)80.0mL One ator’ of an element x weigh 6.643 « 10g, Number of moles of atom in 20 kgis : (14 (240 (3) 100 (4)500 a Rearrange the following (Ito IV)in the order-of increasing masses : © " e (1)0.5mole of 0, (0.5 gm atom of oxygen {il) 3.011 « 10° molecules of O, (W)56llitre of CO, at STP ()yiicivX +2¥ is made to take place. Assume the reaction to go to completion. Match the number of moles listed ‘in colurnn Iwith various species listed in Column |. List Listal (aA (P) 1/3 eB “ (a)218 (ox (R)00 @yY és (8) 4/3 (y16 fa) (b)(e) (A) (a) (b) 9) (Wis8 Rl Pane QiocP Geng s aye” SUMED STAT fay ra 4 eRe ST: Match List | with Listil and select the correct answer usiig the code given below the lists: List () List (tt) (2) §0 mL of 3M HC! solution + 150 mL of 1M FeCl, solution ()4.47m ~ (b) An aqueous solution of NaCl with male fraction of NaCl as 0.1 (@)(CH=3M (c)20% (wiw) propanol(C,H,0H) solution (H)=2.75M (¢) 10.95% (w/v) HG! solution 2 (s)6.1m ~ @ ®o © @ . @ © © -(@)- 6 s- Pp Died 2) 4 s t q- Qe 4 8 Pp q 4 4 t Pp s