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SAFETY DATA SHEET

Spot Lifter (439)

SECTION 1: IDENTIFICATION OF THE SUBSTANCE/PREPARATION


AND THE COMPANY/UNDERTAKING

Product Name: Spot Lifter (833)

Manufacturer: Sprayway, Inc.


1005 Westgate Drive
Addison, IL 60101
United States of America

Information Phone Number: 630-628-3000


Emergency Phone Number: 1-866-836-8855 Outside US: 952-852-4646
SDS Date of Preparation: 05/31/05
Product Use: Spray cleaner for consumer and professional use

SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name CAS# / EINECS# % EU Classification (67/548/EEC)


Pentane 109-66-0 / 203-692-4 30-50 F+, Xn, N R12, R51/53, R65,
R66, R67
Cyclohexane 110-82-7 / 203-806-2 30-50 F, Xn, N R11, R38, R50/53, R65,
R67
Methylal 109-87-5 / 203-714-2 5-10 F, R11
Amorphous Silica 112926-00-8 / 231-545-4 1-5 Not Applicable
112945-52-5 / 231-545-4
Propane 74-98-6 / 200-827-9 30-50 F+ R12
See Section 16 for further information on EU Classification.

SECTION 3: HAZARDS IDENTIFICATION

Off-white aerosol spray with a solvent odor.

EMERGENCY OVERVIEW: Flammable aerosol. Contents under Pressure. Heated can may rupture. May cause eye and skin
irritation. Repeated skin exposure may cause dryness or cracking. Inhalation may cause irritation, headache, dizziness and
drowsiness. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

EU Preparation Classification (1999/45/EC): Extremely Flammable (F+) Irritant (Xi), Dangerous for the Environment (N)
R12, R38, R51/53, R66, R67

SECTION 4: FIRST AID MEASURES

Eye: Rinse thoroughly with water for at least 15 minutes, holding the eye lids open to be sure the material is washed out. Get
immediate medical attention.

Skin: Remove contaminated clothing. Wash exposed area with soap and water. Get medical attention if irritation or symptoms
of exposure develop. Launder clothing before re-use.

Inhalation: Remove victim to fresh air. Give artificial respiration if needed. If breathing is difficult, oxygen should be
administered by qualified personnel. Get immediate medical attention.

Ingestion: Ingestion is an unlikely route of exposure for aerosol products. If ingestion occurs rinse mouth with a small amount of
water. Immediately call local poison control center or go to an emergency department. Aspiration hazard – DO NOT Induce
Vomiting. Never give anything by mouth to an unconscious or drowsy person.

SECTION 5: FIRE-FIGHTING MEASURES

Extinguishing Media: Use foam, carbon dioxide or dry chemical.

Special Fire Fighting Procedures: Wear approved, positive pressure, self-contained breathing apparatus and full protective
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SAFETY DATA SHEET
Spot Lifter (439)
clothing. Cool fire exposed containers with water. Protect against bursting cans.

Unusual Fire Hazards: Contents under pressure. Keep away from heat and open flames. Container may rupture or explode in the
heat of a fire. Prolonged exposure to temperatures above 48.9ºC may cause cans to burst.

Hazardous Decomposition Products: Carbon dioxide, carbon monoxide, hydrocarbons.

SECTION 6: ACCIDENTAL RELEASE MEASURES

Spill: Wear appropriate personal protective equipment. Eliminate all sources of ignition. Ventilate area. Collect material into a
suitable container for disposal. Report spills and releases as required to appropriate authorities.

SECTION 7: HANDLING AND STORAGE

Handling: Avoid contact with eyes and skin. Avoid breathing vapors and mists. Use only with adequate ventilation. Wash
exposed skin thoroughly with soap and water after use. Keep away from heat sources. Contents under pressure. Do not puncture
or incinerate container.

Please read and follow the directions on the product label; they are your best guide to using this product in the most effective
way, and give the necessary safety precautions to protect your health.

Storage Store in a cool, well ventilated area at temperatures below 48.9ºC. Do not store in direct sunlight. Store as a flammable
aerosol.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

Chemical Name Exposure Limits


Pentane 600 ppm ACGIH TLV TWA
1000 ppm TWA DFG MAK
Cyclohexane 100 ppm ACGIH TLV TWA
200 ppm TWA DFG MAK
100 ppm UK EH40-OES, 300 ppm Short-term Limit
Methylal 1000 ppm ACGIH TLV-TWA
1000 ppm TWA DFG MAK
1000 ppm UK EH40-OES, 1250 ppm Short-term Limit
Amorphous Silica 10 mg/m3 ACGIH TLV TWA
4 mg/m3 TWA DFG-MAK
6 mg/m3 UK EH40-OES (inhalable)
Propane 1000 ppm ACGIH TLV-TWA (as aliphatic hydrocarbon gas)
1000 ppm TWA DFG MAK
Asphyxiant UK EH40-OES

Ventilation: General ventilation should be adequate for normal use. For operations where the occupational exposure limit may
be exceeded, mechanical ventilation such as local exhaust may be needed to maintain exposure levels below applicable limits.

Respiratory Protection: None needed under normal use conditions. For operations where the occupational exposure limit may be
exceeded, a local authority approved organic vapor respirator or supplied air respirator is recommended. Equipment selection
depends on contaminant type and concentration, select in accordance with good industrial hygiene practice. For firefighting, use
self-contained breathing apparatus.

Skin Protection: Impervious gloves are recommended for operations which may result in prolonged / repeated skin contact.

Eye Protection: Wear chemical safety glasses or goggles to prevent eye contact.

Other Protective Equipment: Protective clothing if needed to avoid prolonged / repeated skin contact. Suitable washing and
eye flushing facilities should be available in the work area. Contaminated clothing should be removed and laundered before re-
use.

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SAFETY DATA SHEET
Spot Lifter (439)

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

Appearance and Odor: Off-white aerosol spray with a solvent odor.

pH: Not applicable Specific Gravity: 0.6309


Boiling Point: 37°C (pentane) Melting Point: Not applicable
Vapor Pressure: 62 psig @ 21°C, 123 psig @54°C Water Solubility: Insoluble
Vapor Density: >2 Evaporation Rate: Not available
Flash Point: <-18°C (<0°F) (total) Flammable Limits:
->-40°C (-40°F) (concentrate) LEL: 1.0% (methylal)
UEL: 18% (propellant)
Aerosol Flame Extension: Greater than 18 inches Flashback: No
Aerosol Fire Protection Level: Level 3 Aerosol (NFPA 30B)

SECTION 10: STABILITY AND REACTIVITY

Stability: Stable: X Unstable:

Incompatibility/Conditions to Avoid: Avoid strong oxidizing agents, amines, halocarbons, bases and acids. Keep away from
heat, sparks, flames and other sources of ignition. Dropping containers may cause bursting.

Hazardous Decomposition Products: Combustion will produce carbon dioxide, carbon monoxide, various hydrocarbons.

Hazardous Polymerization: May Occur: Will not occur: X

SECTION 11: TOXICOLOGICAL INFORMATION

Potential Health Effects:

Eye: May cause irritation with redness, swelling and tearing.

Skin: May cause irritation. Prolonged or repeated contact may cause defatting of the skin with dryness and cracking.

Inhalation: Breathing vapors or mists may cause irritation of the mucous membranes and upper respiratory tract. Excessive
overexposure may cause headache, dizziness, drowsiness, depressed respiration and heart rate, heart rhythm irregularities,
shortness of breath, unconsciousness or death.

Ingestion: Ingestion is an unlikely route of exposure for aerosol products. May cause gastrointestinal irritation with nausea and
vomiting and nervous system effects similar to inhalation. Aspiration into the lungs during swallowing or vomiting may cause
serious lung damage.

Chronic Hazards: None currently known.

Carcinogen Status: None of the components of this product are listed as carcinogens by IARC or the EU Directive.

Medical Conditions Aggravated by Exposure: Persons with pre-existing skin, respiratory and cardiovascular disorders.

Acute Toxicity Values:

Pentane: Oral Rat LD50 >2,000 mg/kg, Inhalation Rat LC50 364 gm/m3/4H
Cyclohexane: Oral Rat LD50 >5,000 mg/kg, Dermal rabbit LD50 >2000 mg/kg, Inhalation Rat LC50 >4,000 ppm/4H
Methylal: Oral Rat LD50 >7,950 mg/kg, Inhalation Rat LC50 15,000 ppm/4H
Amorphous Silica: No toxicity data available

SECTION 12: ECOLOGICAL INFORMATION

Pentane: The LC50/96-hour values for fish are over 1-10 mg/l..
Cyclohexane: The LC50/96-hour value for fathead minnow is 93 mg/l..
Methylal: The LC50/96-hour value for minnow is 5000 mg/l..

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SAFETY DATA SHEET
Spot Lifter (439)
This product is classified as toxic to aquatic organisms with possible long-term effects.

SECTION 13: DISPOSAL CONSIDERATIONS

Dispose in accordance with all local, regional and national regulations. Do not puncture or incinerate containers. When contents
are depleted, continue to depress button until all gas is expelled.

SECTION 14: TRANSPORT INFORMATION

DOT Proper Shipping Name: Consumer Commodity


DOT Technical Name: None
DOT Hazard Class: ORM-D
UN Number: None
DOT Labels Required (49CFR172.101): None
Hazardous Substance (49CFR172.101): None
Reportable Quantity: N/A

IMDG Shipping Description: Aerosols, 2, UN1950, FP -18 C, Limited Quantity


ID Number: UN1950
Hazard Class: 2
Packing Group: None
Labels Required: None
Marking Required: Aerosol Marking On Carton
Placards Required: Limited Quantities On Transport Containers

ADR Shipping Description: UN1950, Aerosols, 2.1


ID Number: UN1950
Class: 2
Classification Code: 5F
Packing Group: None
Labels Required: 2.1
Marking Required: UN1950

SECTION 15: REGULATORY INFORMATION

INTERNATIONAL REGULATIONS:

European Community Labeling:


R38 Irritating to skin.
R51/53 Toxic to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.
R66 Repeated exposure may cause skin dryness or cracking.
R67 Vapours may cause drowsiness and dizziness.
S2 Keep out of reach of children.
S16 Keep away from sources of ignition - No Smoking!
S23 Do not breathe spray.
S29/56 Do not empty into drains, dispose of this material and
Extremely Irritant Dangerous for its container to hazardous or special waste collection point.
Flammable the Environment S51 Use only in well ventilated areas.
Do not spray on naked flame or any incandescent material.
Pressurized container. Protect from sunlight and do not expose
to temperatures exceeding 50°C. Do not pierce or burn, even
after use.

European Inventory of Commercial Chemical Substances: All of the components of this product are listed on the EINECS
inventory.

SECTION 16: OTHER INFORMATION

Revision Summary: New Product

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SAFETY DATA SHEET
Spot Lifter (439)
EU Classes and Risk Phrases for Reference (See Sections 2 and 3):
Xi Irritant
Xn Harmful
F+ Extremely Flammable
F Highly Flammable
N Dangerous for the Environment
R11 Highly Flammable
R12 Extremely flammable
R38 Irritating to skin.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R65 Harmful: if swallowed may cause lung damage
R66 Repeated exposure may cause skin dryness or cracking.
R67 Vapours may cause drowsiness and dizziness.

While the information set forth herein is believed to be accurate as of the date hereof, the Company makes no warranty or
guarantee, express or implied, and disclaims all liability arising out of the use of this information.

As of: August 9, 2006

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