JEE

Prayas JEE 2.0 2025

Chemistry
DPP: 6
Atomic Structure

Q1 Bohr's model may be applied to Q7 According to Bohr's theory. the

10+ th
(A) Na ion angular momentum for an electron in 5 orbit
(B) He atom is
2+
(C) Be ion (A) 2.5 h/π
6+
(D) C ion (B) 5 h/π
(C) 25 h/π
Q2 If the radius of first orbit of H -atom is x Å,
(D) 5π/2π
then the radius of the second orbit of Li2+ ion
will be Q8 The radius of first Bohr's orbit for hydrogen is
o
(A) x Å 0. 53 A . The radius of third Bohr's orbit would
(B) 4x Å
3 be
(C) 9x Å (A) 0. 79 o (B) 1. 59 o
2
A A
(D) 4x Å o o
(C) (D)
3. 18 A 4. 77 A
Q3 The ratio of circumference of third and second
orbits of He+ ion is Q9 If velocity of an electron in Ist orbit of H atom is
(A) 3 : 2 (B) 2 : 3 V , what will be the velocity of electron in 3rd
(C) 9 : 4 (D) 4 : 9 orbit of Li+2
(A) V (B) V/3
Q4 An electron revolves round Li2+ nucleus at a (C) 3V (D) 9V
distance of 1.587Ao . The speed of electron
should be Q10 The energy of an excited H-atom is −1.51eV.
(A) 2.188 × 10 m/s 6 Angular momentum of e− in the given orbit will
(B) 6.564 × 106 m/s be
(C) 7.293 × 105 m/s (A) 3 h/π
(D) 7.293 × 10 m/s 6 (B) 3 h/2π
(C) 2 h/π
Q5 Which of the following is not a permissible value (D) h/π
of angular momentum of electron in H -atom?
(A) 1.5 hπ Q11 The radius of an orbit of Be+3 ion is 0.529Ao .
(B) 0.5 hπ The velocity of electron in this orbit will be
(C) 1.25 hπ (A) 0.545 × 106 m/s
(D) All of these (B) 2.18 × 106 m/s
(C) 4.36 × 106 m/s
Q6 The ratio of energies of first excited state of (D) 1.09 × 106 m/s
+
He ion and ground state of H -atom is
(A) 1:1 (B) 4:1 Q12 For which species, Bohr's theory does not apply
(C) 1:4 (D) 16:1 (A) H
(B) Be

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+
(C) He
2+
(D) Li

Q13 The frequency of radiation emitted when the

electron falls from n = 4 to n = 1 in a hydrogen
atom will be (Given, ionization energy of H =2.18
x 1
−18 −1 −34
0 J atom and h = 6. 625 X 10 Js)
(A) 1.54 × 1015 s−1
(B) 1.03 × 1015 s−1
(C) 3.08 × 1015 s−1
(D) 2.00 × 1015 s−1

Q14 As the orbit number increases, the K.E. and P.E.

for an electron:
(A) both increases
(B) both decreases
(C) K.E. increases but P.E. decreases
(D) P.E. increases but K.E. decreases

Q15 What is the frequency of the second line of the

Paschen series in the spectrum of He+ ion?
(A) 64 R.C
225
(B) 64R
225
225
(C) 64R
(D) 225C
64R

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Answer Key
Q1 (A) Q9 (A)

Q2 (B) Q10 (B)

Q3 (C) Q11 (C)

Q4 (A) Q12 (B)

Q5 (C) Q13 (C)

Q6 (A) Q14 (D)

Q7 (A) Q15 (A)

Q8 (D)

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