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Chemistry Question 12th 2024
Chemistry Question 12th 2024
Minerals Ores
Naturally occuring substances obtained by mining which Minerals that contain high percentage of metal
contain the metals in free state or in the form of from which it can be extracted conveniently
compounds like oxides, sulphides etc. are called minerals. and economically are called ores.
All the minerals are not ores All the ores are minerals
Mineral of Al is Bauxite and Clay Ore of Al is Bauxite
2. Differentiate Roasting and Calcination?
Roasting Calcination
The Ore is oxidised by heated in the presence of The ore is heated in the absence of oxygen in a
Oxygen in a furnace below the melting point of the furnace. The water molecules are removed as
metal. moisture
2 ZnS + 3 O2 → 2 ZnO + 2 SO2 CaCO3 → CaO + CO2
3. Differentiate Diamond and Graphite
GRAPHITE DIAMOND
1, Soft 1, Very hard
2, Sp2 hybridised carbon atoms 2, Sp3 hybridised carbon atom
0
3, C-C bond length is 1.41A 3, C-C bond length is 1.54A0
4, -electrons are delocalized over the entire 4, There is no free electrons for conductivity
sheet and responsible for electrical conductivity
5, Used as a lubricant either on its own or as a 5, Used for sharpening hard tools, cutting
graphite oil glasses,making bores and rock drilling
4. Give the difference between White Phosphorous and Red Phosphorus
White Phosphorous Red Phosphorus
It is poisonous in nature It is not poisonous
It glows in the dark It does not glow in the dark
Garlic smell Odorless
It undergoes spontaneous combustion in air at room It also does not ignite at low temperatures
temperature
5. Compare Lanthanoids and Actinoids
Sl.No Lanthanoids Actinoids
1. Differentiating electrons enters in 4f Differentiating electrons enters in 5f orbital.
orbital.
2. Binding energy of 4f orbitals are higher. Binding energy of 5f orbitals are lower
3. They show less tendency to form They show greater tendency to form
Complexes. complexes.
4. Most of the lanthanoids are colourless Most of the actinoids are coloured. For Eg.
U3+ (Red), U4+(Green),UO22+ (Yellow)
5. They do not form oxocations They do not form oxocations such
U022+,NpO22+
6. Oxidation states +2 ,+3 & +4 Oxidation states +3, +4, +5, +6 & +7
6. Give the difference between double salts and coordination compounds.
Sl.No Double salt Co-ordination compound
1, dissociating into ions their constituent Never dissociates to give simple ions in
simple ions in solutions. Solutions.
2, Loose their identity Does not loose its identity
3, Positive and negative ions are present Simple and complex ions are present
4, Example: Potash alum Example: K4[Fe(CN)6]
K2SO4.Al2(SO4)3.24H2O
7. What are difference between crystalline and amorphous solids
Crystalline Solid Amorphous Solid
Long range orderly arrangement Short range (or) random arrangement of
of constituents. Constituents.
Definite Shape. Irregular Shape.
Anisotropic Nature. Isotropic Nature.
True Solids. Pseudo Solids (or) Super cooled liquids.
Definite Heat of fusion. Heat of fusion not definite.
Have Sharp Melting Point. No Sharp Melting Point.
Ex.NaCl, Diamond. Ex. Rubber, Plastic.
8. Distinguish between Hexagonal close packing and cubic packing
Sl.No Hexagonal close packing Cubic close packing
1. The spheres can be arranged so as to fit In cubic close packing (ccp), the spheres of
into the depression in such a way that the the fourth layer are present above the
thirdlayer is directly over a first layer spheres of the first layer(ABC arrangement)
(ABA arrangement)
2. This type is found in metals like Mg,Zn, This type is found in metals like Cu, Ag,
etc. etc.
3. The unit cell of hexagonal close packing The unit cell of cubic close packing has 4
has 6 spheres. spheres.
4. The repeating unit of hexagonal close The repeating unit of hexagonal close
packing has two layers of spheres. packing has Threelayers of spheres.
9. Distinguish between Tetrahedral and Octahedral voids
Sl.No Tetrahedral voids Octahedral voids
1, When the spheres of the second layer is When the spheres of the second layer partially
above the voids of the first layer is called covers the voids of the first layer is called as
as Tetrahedral voids Octahedral voids
2, The number of Tetrahedral voids is given The number of Octahedral voids is given by
by ‘2n’. where ‘n’ is the closed packed ‘n’. where ‘n’ is the closed packed spheres.
sphere.
3, There are 3 spheres in the lower layer and There are 3 lspheres in the power layer and 3
one in the upper layer. Total 4 spheres. in the upper layer. Total 6 spheres.
4, When the 4 spheres are joined the center When the 6 spheres are joined the center gives
gives a Tetrahedron. a Octahedron.
Same physical properties in all direction (refractive Different physical properties in different direction
index electrical conductance etc)
11. Differentiate rate and rate constant of a reaction.
Sl.No Rate of a reaction Rate constant of a reaction
1 It represents the speed in which thereactants are It is a proportional constant.
converted into products at any instant.
2 It is measured as decrease in the conc. of the It is equal to the rate of reaction, when the
reactants or increase in the concentration of concentration of each of the reactants in unity.
products.
3 It dependson the initial concentration of reactants. It does not depend on the initial concentration
of reactants.
12. Give the differences between order and molecularity of a reaction.
Sl.No Order of a reaction Molecularity of a reaction
1 It is the sum of the powers of It is the total number of reactant species that are
concentration terms involved in the involved in an elementary step.
experimentally determined rate law.
2 It can be zero (or) fractional (or)integer. It always a whole number, cannot be zero or
fractional.
3 It is assigned for an overall reaction. It is assigned for each elementary step of mechanism.
13. Give the difference between acids and bases.
Reagent Acids Bases
1, Taste Sour taste Bitter taste
2, With litmus paper It turns blue litmus paper Red. It turns red litmus paper blue.
3, With metal Liberates hydrogen gas No hydrogen gas is liberated
with zinc metal. with metals.
14. Distinguish between Lewis Acid and Lewis Base
Sl.No Lewis Acid Lewis Base
1. Electron Deficient. Ex. BF3 Electron Rich. Ex. NH3
2. All metal ions. Ex. Fe+2 All anions. Ex.OH¯
3. They contain Polar double bonds. Ex: CO 2 They contain carbon-carbon double Bond. Ex:
Ethylene.
4. They are CarboCation. They are Carbanion. Ex.CH3¯
5. They contain empty D-orbitals.And can All metal oxides. Ex.CaO
expand its octet. Ex:SF4.
15. Differentiate Chemisorption and Physisorption.
S.No` Chemical adsorption Physical adsorption
1. It is very slow. It occurs immediately.
It is very specific depends on nature of It is non-specific
2.
adsorbent and adsorbate.
Chemical adsorption is fast with Increase In Physical adsorption when pressure increases the
3.
pressure, it can not alter the amount. extent of adsorption increases.
When temperature is raised Chemisorption Physical adsorption decreases with increases in
4.
first increases and then decreases. temperature.
Heat of adsorption is high i.e., from Heat of adsorption is low in the order of
5.
40 - 400KJ / mole. 40kJ/mole.
Monolayer of the adsorbate is formed. Multilayer of the adsorbate is formed on the
6.
adsorbent.
16. Differentiate Homogeneous and Heterogeneous catalysis
Homogenous catalysis Heterogeneous catalysis
1, The reactants, products and catalyst are present 1,The reactants, products and catalyst are present
in the same phase. in the different phase.
NO(g) Pt(s)
2, Example : 2SO2(g) + O2(g)−−−−→ 2SO3(g) 2,Example : 2SO2(g) + O2(g)−−−→ 2SO3(g)
17. How will you differentiate primary, secondary and tertiary alcohols by Victor meyer’s
method ?
Primaryalcohol Secondaryalcohol Tertiaryalcohol
CH3 – CH2 – OH (CH3)2 CH – OH (CH3)3 C – OH
Ethyl alcohol Propan-2-ol 30-butyl alcohol
+ P / I2 + P / I2 + P / I2
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