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ARJUNA NEET (2024)

State of Matter Gases and Liquids DPP-07

1. When is deviation more in the behaviour of a gas 7. The compressibility factor for a real gas at high
from the ideal gas equation PV = nRT? pressure is
(1) At high temperature and low pressure RT
(2) At low temperature and high pressure (1) 1 + (2) 1
pb
(3) At high temperature and high pressure
(4) At low temperature and low pressure pb pb
(3) 1+ (4) 1−
RT RT
2. In van der Waal's equation of state of the gas law,
the constant 'b' is a measure of 8. The compressibility of a gas is greater than unity at
(1) volume occupied by the molecules
1 atm and 273 K. Therefore
(2) intermolecular attraction
(3) intermolecular repulsions (1) Vm > 22.4 L (2) Vm < 22.4 L
(4) intermolecular collisions per unit volume (3) Vm = 22.4 L (4) Vm = 44.8 L

3. In van der Waal's equation of state for a non-ideal 9. For which of the following gases should the
gas, the term that accounts for intermolecular correction for the molecular volume be largest:
forces is
CO, CO2, NH3 or SF6?
(1) (V – b) (2) RT
(1) CO (2) CO2
 a 
(3) P + 2  (4) (RT)–1 (3) NH3 (4) SF6
 V 

4. The values of Vander Waal’s constant ‘a’ for the 10. Maximum deviation from ideal gas is expected
gases O2, N2, NH3 and CH4 are 1.360, 1.390, 4.170 from
and 2.253 L2 atm mol–2 respectively. The gas (1) NH3(g) (2) H2(g)
which can most easily be liquefied is (3) N2(g) (4) CH4(g)
(1) O2 (2) N2
(3) NH3 (4) CH4 11. The units of van der Waals’ constants a, b
respectively, are:
5. The units of constant a in Van der Waal’s equation
is (1) Latm2 mol−1and mol
(1) dm6 atm mol–2 (2) dm3 atm mol–1 (2) Latm2 mol2 and mol L
(3) dm atm mol–1 (4) atm mol–1
(3) L2 atm mol−2 and mol –1L

6. At low pressure the Van der Waal’s equation is (4) L−2 atm−1 mol−1and mol L
reduced to
pVm a
(1) Z= =1− 12. Which of the given sets of temperature and
RT Vm RT pressure will cause a gas to exhibit the greatest
pVm b deviation from ideal gas behavior?
(2) Z= =1+ p
RT RT (1) 100℃ and 4 atm
(3) pVm = RT (2) 100℃ and 2 atm
pV a (3) −100℃ and 4 atm
(4) Z = m =1−
RT RT (4) 0℃ and 2 atm
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13. At low pressure, van der Waals’ equation is 16. The compressibility factor of an ideal gas
 a  (1) 0
reduced to  p + 2  V = RT . The compressibility
 V  (2) 
factor can be given as (3) 1
a (4) –1
(1) 1+
RTV
RTV 17. 1 mol CO2 occupies 0.4 lit at 27°C and 40 atm
(2) 1− calculate the compressibility factor
a
(1) 0.65
RTV
(3) 1+ (2) 0.85
a
(3) 0.15
a
(4) 1− (4) 1.65
RTV
18. Vanderwaal equation for 0.2 mol of a gas is:
14. Mark out the wrong expression
 a 
b (1)  P + 2  + ( V − 0.2b ) = 0.2RT
(1) Boyle’s temperature TB =  V 
aR
 a 
Critical pressure pc =
a (2) P +  ( V − b ) = 0.02RT
(2)  0.04V 2 
27b2
 0.2a 
(3) Critical temperature, Tc =
8a (3)  P + 2  ( V − 0.2b ) = 0.2RT
27 Rb  V 
Critical volume Vc = 3b  0.04a 
 ( V − 0.2b ) = 0.2RT
(4) (4) P +
 V2 
15. Given van der Waals constant ‘a’ for NH3, H2, O2
and CO2 are respectively 4.17, 0.244, 1.36 and 19. The pressure of real gases is less than that of ideal
3.59, which one of the following gases is most gas because of
easily liquified? (1) increase in the number of collisions
(2) finite size of particles
(1) NH3 (2) H2
(3) intermolecular attraction
(3) O2 (4) CO2
(4) increase in kinetic energy of the molecules
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Note: Kindly find the Video Solution of DPPs Questions in the DPPs Section.
Answer Key
1. (2) 11. (3)
2. (1) 12. (3)
3. (3) 13. (4)
4. (3) 14. (1)
5. (1) 15. (1)
6. (1) 16. (3)
7. (3) 17. (1)
8. (1) 18. (4)
9. (4) 19. (3)
10. (1)

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