HS 09pre incidentPlanScenario5toxicwastewaterleakage

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Pre-incident Plan

应急预案
SCENARIO FIVE 预案5- TOXIC WASTE WATER LEAKAGE
AT GASIFIER (U-1700) 气化框架U-1700有毒废水泄漏

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YYCG MANAGEMENT SYSTEM

TABLE OF CONTENT
目录

SCENARIO FIVE 预案5- TOXIC WASTE WATER LEAKAGE AT GASIFIER (U-1700) 气化


框架U-1700有毒废水泄漏......................................................................................................................4
1 SCENARIO DESCRIPTION 情景描述.......................................................................................4
2 ASSESSMENT OF THE DETECTION TIME 探测时间评估..................................................4
3 DETERMINE THE FUEL SUPPLY REDUCTION MEASURES 确定工艺控制措施..........4
3.1 FROM THE CCR 中控室............................................................................................................4
3.2 FROM THE FIELD 现场..............................................................................................................5
4 IDENTIFY BEHAVIOUR OF RELEASED PRODUCT 泄漏物质的特性..............................5
5 IDENTIFY THE CONSEQUENCES OF LEAKAGE泄漏的后果............................................5
6 PRIORITISE THE PROTECTION MEASURES优先的措施..................................................5
7 QUANTIFY THE FIRE FIGHTING MEASURES消防设备的配备........................................6
8 ASSESSMENT OF THE SURFACE DRAINAGE CAPACITY地表排水容量的评估...........6
SHORT REFERENCE SHEET 1 OF 1................................................................................................7

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SCENARIO FIVE 预案5- TOXIC WASTE WATER LEAKAGE


AT GASIFIER (U-1700) 气化框架U-1700有毒废水泄漏

1 Scenario Description 情景描述


The Emergency is defined around U-1700
此应急预案的发生区域为U-1700
At 0 meter level of gasifier structure U1700, a mechanical seal of P1701A fails and cause
waste water leakage.
在0米层的U1700单元气化框架,P1701泵的机械密封失效导致废水泄漏。
The leaking liquid at this location with temperature 90℃ will release some dissolved toxic
gas ,for example HCN、H2S. Most toxic gas remained in waste water. Leakage toxic waste
water will enter into clean storm/rain water sewer which was connected with clean storm/rain
water sewer in Power Department of Baling Petrochemical Co. At last, leakage waste water
will be let down to Dongting Lake and cause water environment pollution.
在此处位置泄漏的液体温度为90℃,会释放出一部分溶解的剧毒气体如HCN、H2S。大部分剧
毒气体仍然溶解在废水中,泄漏的有毒废水进入工厂清洁下水管道。该清洁下水管道与巴陵石
化有限公司动力事业部清洁下水管道连通后,最后排放到洞庭湖,造成水体环境污染。

2 Assessment of the Detection Time 探测时间评估


In normal conditions this unit does not need manual operation and operator patrol will be
done for routine equipment rounds. Field detection may take 15-20 minutes before an
operator smell the odour. Local gas detector may detect in 5-10 minutes.
在通常情形下,这个单元不需要手动操作,操作工会进行日常的设备巡检。现场操作工察觉到
泄漏也许在泄漏后的15-20分钟。现场气体探测器的发现时间可能在5-10分钟。
There is little likelihood of detection from within the CCR
从CCR察觉泄漏的可能性很小。

3 Determine the process control Measures 确定工艺控制措


3.1 From the CCR 中控室

 When field confirms mechanic seal leakage in one of P1701A/B, panel operators in
CCR will shut down failure pump and cut in standby pump. If field confirms mechanic
seal leakage in both P1701A/B, panel operators should trip failure pump and stop
steam ejecting in C1701.

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 当现场确认P1701A/B中某一台出现机械密封泄漏,主控键盘操作员将故障泵停车,切
换到备用泵。如果P1701A/B都出现机械密封泄漏,主控键盘操作员将故障泵停
车,C1701停止加入蒸汽。
This will take more than 5 minutes.

 此过程将用时大于5分钟。

3.2 From the Field 现场

迅速撤离泄漏污染区人员至上风处,起动气防报警。立即设置隔离150m,严格限制其他人员进
入危险区。
作好防护准备后(基本劳动保护及全面式防毒面具、防化服、防化手套。)进入工作现场,对P-
1701A/B进行倒泵处理(从P-1701A倒至P-1701B运行)。
Immediately evacuate site personnel from area polluted by H2S leakage to upwind location
and activate gas alarm. As the leaking gas contains H2S、NH3、CO2、HCN a barricade of 150
m in radius shall be established at once. Non authorized entry into hazardous area will be
permitted.
Field operators fully protected with basic PPE and full face masks, chemical protection
coveralls and gloves go to site to switch P-1701A to P-1701B.

4 Identify Behaviour of Released Product 泄漏物质的特性


The toxic gas will release in the form of a toxic cloud which may or may not ignite.
有毒气体将以毒气烟云的形式扩散并存在被点燃的风险。。
Some parts of the cloud will tend to be heavier than air, with the noxious components tending
to descend down wards as they cool.
部分烟云比空气重,其中的有害成分会随温度的降低而向下方向扩散
Leakage toxic waste water will flow over the ground to the nearest drainage points and enter
into clean storm/rain water sewer.
泄漏有毒废水将沿地面流动进入最近的雨水井,并进入清洁下水管道。

5 Identify the consequences of waste water leakage泄漏的


后果
The toxic gas leakage will cause personnel poisoning. Leakage toxic waste water will flow
into clean storm/rain water sewer and cause water environment pollution.泄漏出来的有毒气
体会导致人员中毒。同时泄漏液体将进入清洁下水管道,引起水体环境污染。

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6 Prioritise the Fire protection measures优先的消防措施


FIT member with wearing breathing equipment connect HP fire water hydrant to fire hose
and approach behind a water curtain to ensure quick dispersal of the gas.
将消防水带与高压消防栓连接,第一干预小组成员穿戴空气呼吸器在水幕后确保气体的及时稀
释。
Inform Baling Petrochemical Co and Baling Branch to start up Pre-incident Plan respectively,
ready to block up toxic waste water, evacuate personnel and avoid poisoning.
通知巴陵石化有限公司和巴陵分公司分别启动各自的应急预案,准备封堵有毒废水,疏散人
员,防止中毒。

7 Medical emergency response measures 医疗应急措施

可能出现的医疗紧急状况为,现场人员窒息、中毒、烫伤等人身伤害。启动现场急救预案
现场的公司急救员必须在人员受伤后4分钟之内对受伤人员进行急救,如在中毒状况下将人员
安全移至空气新鲜处,保持呼吸道通畅。呼吸心跳停止时,立即进行人工呼吸和胸外心脏按压
术。
如果发生人员伤害,应立即拨打岳阳市第一人民医院的急救电话(8080120),并启动“绿色
通道”。
Possible medical emergency is staff asphyxiation, toxic and burn.Site first aid pre –incident
plan should be activated.
Site first aiders have to attend the injured within 4 minutes. In case of poison move the
injured to fresh air and keep breathing pass free. . If breathing and heart beat stop,
immediately provide manual breathing and press the heart from outside the chest.
In case of injuries immediately call 8080120-Yueyang No.1 Hospital and activate the “Green
Channel”.

8 Environmental emergency response measures 环境应急

措施

构筑围堰用吸收棉围堵。
Build a dam with cotton to absorb leakage.

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Short Reference Sheet 1 of 1简要说明1


Key information about the emergency response plan 应急预案关键信息
1 对象 P1701, mechanical seal failsP1701机械
Scenario 密封失效。
2 路线/位置 Route/Location See Sheet 2见表二
3 需要最少人员 3人在地面
Min. personnel required 3 at ground
4 消防水供应和可利用设备 2” hose (local box or CCR)二英寸的水
Fire fighting water supply and 带(在现场消防箱或主控获取)
equipment available spray nozzle (CCR)(喷枪主控获取)
5 留白备用 Blank box
6 现场物质 危险种类 Preferred Second Remark
Substance Risk Type extinguisher extinguisher
HCN、H2S 有毒 Water
易燃 水
Toxic
Flammabl
e
7 细节 Details  Dilute leakage toxic water
 稀释有毒废水

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