JEE (Main + Advanced) 2024

NURTURE COURSE

INORGANIC CHEMISTRY QUIZ # 24 TIME : 30 Min.

SECTION–I (i) (Maximum Marks - 30)
This section contains 10 questions.
Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four option(s) is correct.
For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS
Marking scheme :
+3 If only the bubble(s) corresponding to all the correct option(s) is (are) darkened
0 If none of the bubbles is darkened
–1 In all other cases
1. Which will have the maximum value of electron affinities.
OX , OY , OZ (where X, Y, Z are respectively 0, –1, –2)
(A) OX (B) OY (C) OZ (D) All of these
2. Which of the following element having atomic number(s) given below, has highest ionisation energy
(A) 12 (B) 13 (C) 15 (D) 33
3. In which of the following case the FBrF angle is less than 90°
–
(A) BrF3 (B) BrF4 (C) BrF5 (D) (A) and (C) both
4. 3
Find the maximum number of same atoms which have sp hybridisation in ethylene diaminetetraacetic
acid
HOOC–CH2 CH2COOH
NCH2CH2N
HOOC–H2C CH2COOH
(A) 4 (B) 6 (C) 8 (D) 2
5. Which formula of electronegativity provide a recipe for calculating only differences in electronegativity
of two atom :
IE EA
(A) 0.102 EA B EA A EB B (B)
2
0.359Z eff .
(C) + 0.744 (D) All of the above
r2
6. Which of the following specie does not contain any ring
6–
(A) [B2O4(OH)4]2– (B) B3O63– (C) P4O13 (D) g-SO3
7. 3pp – 3pp is shown by
(A) P4 (black) (B) SiO2 (C) S8 (rhombic) (D) None of these
8. Statement-1 : O ¾® O2– is associated with energy absorbed but yet several oxides are stable enough.
Statement-2 : The lattice energy involved to form its oxides overcomes the other energy absorbed.
(A) Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.
(B) Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1.
(C) Statement-1 is true, statement-2 is false.
(D) Statement-1 is false, statement-2 is true.

1/1 INORGANIC CHEM. / QUIZ # 24

 JEE (Main + Advanced) 2024
NURTURE COURSE

9. Total number of molecules which have cation-anion pair out of I2(s), I2Cl6(s), PCl5(s), N2O5(s), PBr5(g)
is :
(A) 3 (B) 2 (C) 1 (D) 0
10. If elements were discovered in furture in which the electrons would be present in g subshell. Then these
g-orbitals starts and ends up with atomic number
(A) 121, 139 (B) 121, 138 (C) 122, 140 (D) 122, 139

SECTION–I (ii) : (Maximum Marks : 24)

This section contains 6 questions.
Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these
four option(s) is correct.
For each question, darken the bubble(s) corresponding to all the correct option(s) in the ORS
Marking scheme :
+4 If only the bubble(s) corresponding to all the correct option(s) is (are) darkened
0 If none of the bubbles is darkened
–1 In all other cases
11. Which of the following order(s) is / are CORRECT :
(A) Li < Be < B < C (IE1)
(B) HF < HCl < HBr < HI (Bond length)
(C) Na2O < MgO < Al2O3 < SiO2 < P2O5 (Acidic)
(D) Li+(g) < Na+(g) < K+(g) < Cs+(g) (Ionic radius)
12. Which of the following property is/are associated with hydrogen bonding
(A) Slippery nature of graphite (B) Dimerization of CH3COOH in vapour phase.
(C) Viscous nature of glycerol (D) Cage like structure of ice
13. Select CORRECT statement :-
(A) 2nd period element can't form more than four covalent bonds
(B) All oxyacids of 's' has basicity two generally
(C) Hybrid orbital of diamond have more s-character than the hybrid orbitals of graphite
(D) Number of covalent bonds formed by a single phosphorus is more in black phosphorus
than the white phosphorus
14. Which of the following is CORRECT for SOF2 and SO2F2 :

(A) F S F bond angle ; SOF2 < SO2F2

(B) SOF2 is sp2 hybridised
(C) SO2F2 is sp3 hybridised
(D) Number of hybrid orbitals of sulphur ; SOF2 < SO2F2
15. Select correct order of size :
(A) Ti2+ < Ti < Zr (B) Ti2+ < Ti < Hf (C) Zr2+ < Zr » Hf (D) Hf2+ < Hf » Zr

2/2 INORGANIC CHEM. / QUIZ # 24

 JEE (Main + Advanced) 2024
NURTURE COURSE
16. Identify the incorrect order(s)-
(A) ns < np < nd < nf : (penetration power order)
(B) Li < Na < K < Cs : (zeff order)
(C) Sc < Y < La : Atomic radius order
(D) Sc > Y > La : Ist ionisation energy order

SECTION-IV : (Integer Value Correct Type)

This section contains 4 questions. The answer to each question is a single digit Integer, ranging from
0 to 9 (both inclusive) 4(–1)

1. Find number of exchanges possible in 4f7 subshell.

Fill your answer as sum of digits till you get the single digit answer.
2. Find total number of cations for which I.P. of cation is lower than corresponding atom.
K+, O+, Ne+, P+, Be+, Na2+, Fe+, Sn2+
3. Write the number of pairs in which size of first element or ion is higher as compare to IInd out of fol-
lowing nine pairs.
+2 +2 +3 +2 +
(Ba aq ) (Beaq ), (Al aq) (Beaq), (Kr, Ne), (Na, Na+), (Cl, Cl–), (I– , Cl–), (LiAq. +
, NaAq.), (Li, Na), (Li+ , Na+)
4. Which of the following molecules having lone pair less than or equal to ten.
SOF4 , NH3 , COCl2

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