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Photocatalytic Membranes For Organic Pollutants Removal From Water and Wastewater: A Review
Photocatalytic Membranes For Organic Pollutants Removal From Water and Wastewater: A Review
Submitted: 8/10/2023. Revised edition: 14/11/2023. Accepted: 29/11/2023. Available online: 28/3/2024
ABSTRACT
The insufficient removal of organic pollutants obstacles the reclamation of wastewater and
threatens water security. Photocatalytic membrane, a hybrid water treatment method by
integrating photocatalysis with membrane filtration, has drawn considerable attention in the
removal of organic pollutants from various sources of wastewater such as textile industries,
palm oil mill effluent, sewage, and industrial wastewater. This review consolidates the recent
advances in the application of photocatalytic membranes for the removal of organic pollutants
from contaminated water. Various types of polymer-based photocatalytic membranes and TiO2-
based photocatalytic membranes have been reviewed. Strategies to enhance the photocatalytic
activity by implementation of different immobilization methods for fabricating photocatalytic
membranes are also addressed. Furthermore, the applications of typical TiO2-based
photocatalytic membranes and key factors affecting organic pollutants removal are discussed
based on the literature database. Overall, utilization of the photocatalytic membrane presents a
promising approach towards the development of an effective photocatalyst and membrane
performance in simultaneous process.
(PAA) grafted on the PES membrane removal after 3 hours under UV light
then coated by TiO2 nanoparticles for irradiation. The membrane also
phenol removal. The photocatalytic indicated minimal leaching after 72
membrane showed 62% phenol hours of cross-flow filtration test.
Méricq et al., (2015) [21] reported separation using DMAc solvent and
fabrication of PVDF/TiO2 membranes PEG additive. Increasing TiO2 content
by non-solvent induced phase led to enhancement the membrane
8 K. I. Ikrari et al.
permeability and flux performance. The permeability. The flow of pure water
presence of the photocatalyst also through the coated membrane was 65-
enhanced the photocatalytic 80% lower than that of the untreated
performance by preventing pure water membrane. In addition, the
flux decline under UV irradiation. photodegradation experiment resulted
Deposition of the photocatalyst on the in greater than 30 and 40 percent
membrane surface also influenced the degradation of MB and CHD,
photocatalytic performance. respectively.
Rahimpour et al., (2008) [23] compared Sputtering photocatalyst onto
the membranes performance and membrane surface is another method
antifouling properties of TiO2- for immobilizing on the membrane
entrapped and TiO2-coated in the PES surface. Fischer, Gläser and Schulze,
membranes. They reported that the (2014) [26] synthesized a TiO2/PES
coated TiO2 membrane has better membrane by magnetron-sputtering a
performance than the entrapped TiO2 titanium film onto a PES membrane,
inside membrane matrix which proven followed by anodization and
by higher flux recovery. It was shown crystallization of the membrane using
99% of protein rejection from milk two distinct processes (vapor-thermal
water permeation and the flux and hydrothermal). Photocatalytic
membrane was 63% after 4 h milk testing with methylene blue resulted in
ultrafiltration, which higher than flux of 50% and 40% degradation after 120
the neat membrane (42%). This result minutes for vapor-crystallized and
proved that the presence of TiO2 hydrothermally crystallized TiO2
nanoparticles and UV irradiation nanotubes, respectively. The improved
enhanced the antifouling properties of surface area and light-harvesting
the membrane. Chakraborty et al., capabilities of the anatase nanotubes
(2017) [24] examined three structures had an influence on the
immobilization techniques for membrane.
depositing TiO2 nanoparticles on The immobilizing of photocatalyst
polymeric hollow fibre membranes by electrospinning has been explored.
utilizing PES and PVC-PAN as Nor et al., (2016) [27] prepared
catalytic supports. They evaluated the electrospun PVDF/TiO2 nanofibers by
modified membrane for degradation of hot pressing nanofibers photocatalyst
MB and chlorhexidine digluconate on the surface of PVDF flat sheet
(CHD) under simulated solar radiation membrane. The PVDF membrane was
by spraying, vacuum coating, and sol- fabricated by phase inversion method
gel coating. Spray and vacuum and TiO2 nanofiber was synthesized
procedures result in an additional layer using electrospinning technique. Then,
on the membrane's surface, reducing its the elctrospun TiO2 nanofibers were
permeability. The pore-blocking placed and hot pressed on the surface of
deposition of TiO2 shown by SEM PVDF membrane within constant
examination to have low membrane pressure 80 bars and varied temperature
permeability. The sol-gel technique was (60°C, 100°C, 160°C and 180°C) for 30
utilized using diluted sol as the coating min. photodegradation of BPA under
solution, and the membrane was then visible light shown 84.53%, 77,61%,
dipped into the solution to deposit TiO2 and 62.54% for PVDF/TiO2-100°C,
onto the membrane surface. Controlling PVDF/TiO2-160°C, PVDF/TiO2-
the concentration of TiO2 solution was 180°C, respectively. By using similar
used to determine the optimal coating method, Xu et al., (2020) [25]
procedure for maintaining membrane developed a PAN/TiO2/PANI for
Photocatalytic Membranes for Organic Pollutants Removal 9
removal of congo red as target pollutant one factor that affect the
and recovered the photocatalytic photodegradation process [33–35]. This
membrane employed visible light is connected to the charge repulsion
irradiation. the membrane was prepared between the pollutant and photocatalyst
by electrospun PAN/TiO2 membrane nanoparticles because the capacity of a
then added aniline directly on the pollutant to adsorb can be critical for a
PAN/TiO2 membrane for in situ catalyst's high catalytic activity, as it
polymerization. The membrane tested can improve electron/hole transfer
of the adsorption towards congo red efficiency and interaction with
shown 16.6 mg/g adsorption capacity photogenerated active species [36]. The
which higher than PVA/PAA/GO- photocatalyst loading in the membrane
COOH fiber membrane (8.88 mg/g). system give significant impact in the
Regeneration of the membrane membrane properties. It may act as a
evaluated using visible light irradiation. pore forming agent in the fabrication
Overall, the regeneration capacity of the process of symmetric membrane until
prepared membrane was 91%, three the optimum composition achieved. At
times higher than water-wash the higher amount of photocatalyst
regeneration (31%). loading, it may agglomerate in the
membrane pores which results defect
membrane pore structure and decrease
4.0 CONCLUSION AND FUTURE the permeability [37-38].
DIRECTIONS Utilization of the photocatalytic
membrane has become an advanced
Despite the selection of photocatalyst option for wastewater treatment.
and polymeric membrane, the selection Development toward solar-driven
of methods used also needs to be photocatalytic membrane as the greener
consider enhancing the photocatalytic energy has emerged recently. Also,
activity of the photocatalytic optimization of photocatalytic
membrane. Compared to the suspended membrane configuration may be
photocatalytic membrane system, the explored like different photocatalytic
embedded photocatalyst in the membrane system designs and
membrane system will reduce the configurations to enhance the
membrane fouling significantly that photodegradation efficiency. This could
may improve the water permeability. include exploring variations in the
TiO2 photocatalyst nanoparticles immobilization technique, catalyst
entrapped in the membrane system will loading, membrane properties, and light
not be released to the liquid pollutant distribution to improve the contact
stream during filtration process and will between the immobilized photocatalyst
give higher pollutant removal and the target pollutant.
efficiency because of the photocatalytic
reaction that occurs on the membrane
surface also in the membrane pores CONFLICTS OF INTEREST
during filtration process when the
pollutant is permeated through the The authors declare that there is no
membrane [28–32]. conflict of interest regarding the
Moreover, there are several factors publication of this paper.
that reported affect the embedded
photocatalytic membrane
performances. In the photodegradation
system, pH of the pollutant feed may be
10 K. I. Ikrari et al.