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J. Applied Membrane Science & Technology, Vol. 28, No.

1, April 2024, 1–13


© Universiti Teknologi Malaysia

Photocatalytic Membranes for Organic Pollutants Removal from


Water and Wastewater: A Review
K. I. Ikraria,b, W. N. W. Salleha,b*, H. Hasbullah a,b, K. Nakagawac, T. Yoshiokac,
H. Matsuyamac
a
Advanced Membrane Technology Research Centre (AMTEC), Universiti Teknologi
Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia
b
Faculty of Chemical and Energy Engineering, Universiti Teknologi Malaysia, 81310
UTM Johor Bahru, Johor, Malaysia
c
Graduate School of Science, Technology and Innovation, Research Center for
Membrane and Film Technology, Kobe University, Nada, Kobe 657-8501, Japan

Submitted: 8/10/2023. Revised edition: 14/11/2023. Accepted: 29/11/2023. Available online: 28/3/2024

ABSTRACT

The insufficient removal of organic pollutants obstacles the reclamation of wastewater and
threatens water security. Photocatalytic membrane, a hybrid water treatment method by
integrating photocatalysis with membrane filtration, has drawn considerable attention in the
removal of organic pollutants from various sources of wastewater such as textile industries,
palm oil mill effluent, sewage, and industrial wastewater. This review consolidates the recent
advances in the application of photocatalytic membranes for the removal of organic pollutants
from contaminated water. Various types of polymer-based photocatalytic membranes and TiO2-
based photocatalytic membranes have been reviewed. Strategies to enhance the photocatalytic
activity by implementation of different immobilization methods for fabricating photocatalytic
membranes are also addressed. Furthermore, the applications of typical TiO2-based
photocatalytic membranes and key factors affecting organic pollutants removal are discussed
based on the literature database. Overall, utilization of the photocatalytic membrane presents a
promising approach towards the development of an effective photocatalyst and membrane
performance in simultaneous process.

Keywords: Photocatalyst, photocatalytic membrane, photodegradation, wastewater treatment

1.0 INTRODUCTION supporting substrate for the


photocatalyst particles [2]. Pollutants
Membrane process is a selective barrier feed water passes through the
which can achieve separation of solid membrane in filtration process. The
particles from liquid effectively. pollutant adhered on the membrane
Application of coupled membrane surface which may led to reduce the
process with photocatalytic process has membrane permeability or membrane
reported improvement the reusability of fouling [3]. The presence of the
the photocatalyst in the photocatalytic photocatalyst in the photocatalytic
systems. This process employed membrane system may perform
separation of photocatalyst and treated photocatalytic degradation reaction of
water and keeping the photocatalytic the pollutant which separated by the
activity simultaneously [1]. The membrane, thus reduce the membrane
membrane provides a selective barrier fouling in the membrane surface [2-3].
to separate the pollutant, as well as the There are two primary configurations

* Corresponding to: W. N. W. Salleh (email: hayati@petroleum.utm.my)


DOI: https://doi.org/10.11113/amst.v28n1.280
2 K. I. Ikrari et al.

for photocatalytic membrane reactors: increases its photoactive performance


suspended photocatalyst and [8]. In addition, it is important to
immobilised photocatalyst. Due to the prevent the supporting membrane
large total surface area photocatalyst material damaged from self-oxidizing
per unit volume, the suspended in the photocatalytic reaction.
photocatalyst or slurry reactor Polymeric membranes offer
configuration was favoured [4]. The inexpensive materials, also can be
major parameter was the amount of modified to enhance the stability and
photocatalysts supplied to the reactor, efficiency under light irradiation or
and nanoparticle TiO2 has been oxidizer agents. It is better option for
frequently employed and found to have industrialization than the high-cost
a better photocatalytic efficiency. ceramic membranes [7]. Comparison of
Nevertheless, it is challenging to application of polymer-based
separate from treated water, and the photocatalytic membrane shown in
opacity of the overconcentrated slurry Table 1.
suspension may reduce light irradiance Bhattacharyya et al., (2023) [9]
[5]. Consequently, immobilised reported the use of TiO2 deposited on
photocatalyst enables both physical the commercial Polyethersulfone (PES)
separation via membrane filtering and for methyl orange (MO) removal.
photocatalytic decomposition of Modification of membrane surface with
contaminants in a single unit [6]. 0.25% resulted in high
photodegradation of MO 82.3% under
UV light for four hours. They also
2.0 POLYMER-BASED reported reusability of the
PHOTOCATALYTIC photocatalytic membrane with 79%
MEMBRANE MO removal after 3 cycles.
Another research on modification of
It is feasible to create immobilized polymeric membrane was reported by
photocatalytic membranes by Feng et al., (2023) [10]. They mixed
depositing photocatalyst on the porous nano photocatalyst NH2-MIL-
membrane surface or including it into 88B(Fe) with polyaryl ether nitrile
membrane casting solutions. (PEN) then grown Ag2S on the surface
Nevertheless, the fabrication of of the composite membrane. The
immobilized photocatalytic membranes composite photocatalytic membrane
presents several obstacles, including reported 99.97% removal of an
limited photocatalytic activity in the antibiotic Sulfadiazine (SDZ). It also
visible light area and the possibility of has high removal of SDZ as 91.76%
membrane structural breakdown [7]. after 8 cycles. Moreover, it also has
The method in which photocatalyst is good strength, toughness, and high
placed on the membrane is one of the temperature resistance. In another
variables that contribute to the high research of composite polymeric
effectiveness of photocatalytic membrane, Wu et al., (2023) [11]
membranes. Entrapped photocatalyst studied MIL-53(Fe)/PVDF mixed
inside membranes reduces light matrix membrane. The composite
irradiance and, thus, photocatalytic membrane also showed high
efficacy. In contrast, the well-dispersed photodegradation of tetracycline, an
photocatalyst on the surface of the antibiotic compound, until 93% under
coated photocatalytic membrane UV light irradiation.
Photocatalytic Membranes for Organic Pollutants Removal 3

Table 1 Comparison polymeric membrane materials

Polymer Remarks Ref.


Commercial • 0.25 wt.% TiO2 layer on the surface [9]
membrane • 82.3% degradation of Methyl Orange in four hours under
PES UV lamp
(NF) • 79% MO degradation after 3 cycles

PEN • Double heterojunction photocatalyst Ag2S/NH2-MIL- [10]


88B(Fe)
• Degradation of SDZ 99.97%, mineralization rate 85.41%
• 91.76% removal rate of SDZ after 8 cycles

PVDF • Immobilization of MIL-53(Fe) 1-5 wt.% [11]


• High rejection of 87% TC
• 93% photodegradation of TC under UV light

PS, PTFE, • Direct hydrolysis of TiO2 on the membranes surface [8]


PVDF • Amount TiO2: TiO2/PS 11.0 wt%, TiO2/PTFE 2.7 wt%,
(MF) and TiO2/PVDF 3.3 wt%.
• Degradation DCF: TiO2/PS 93%; TiO2/PVDF 92%;
TiO2/PTFE 89%
• Degradation EE2: TiO2/PS 96%; TiO2/PVDF 94%;
TiO2/PTFE 92%
• TiO2/PS highest photocatalytic activity, damaged after
first photocatalysis cycle
• TiO2/PTFE significant increased permeate flux after first
photocatalysis cycle
• TiO2/PVDF high photocatalytic activity, stable permeate
flux

PES • Incorporation metal-nonmetal doped (K-B-N-TiO2) 0.5% [13]


(NF) • High permeation 27 kg/m2, dye removal 98%, and COD
removal 90%

PP, PS, PES • Decreased membranes resistance within UV exposure for


(MF) 24 h: PP 20%; PS 26%; PES 30% (all membranes
breakdown within 3 days of UV exposure)

PAN • Structure stability within 30 days of UV exposure


PTFE • TOC released after 30 days of UV exposure: PTFE 13.0; [12]
PVDF- PVDF-hydrophilic 3.6 ppm; PVDF-hydrophobic 109.0
hydrophobic ppm; PAN 29.0 ppm
PVDF- • Breakdown within 10 days H2O2/UV exposure: PAN
hydrophilic
(MF)

PS • N,Pd co-doped TiO2 in PS membrane [14]


(UF) • 87-97% pollutant removal (dye) within 4 h under visible
light
• Slower initial rate of photoreaction in the first hour
• No flux data
4 K. I. Ikrari et al.

Research reported by Chin, Chiang and different photocatalytic membranes


Anthony, (2006) [12] made a employing direct hydrolysis of TiO2 on
comparison of ten different types of hydrophilic PTFE, PVDF, and PS
polymeric membranes for membranes. The polymeric membranes
photocatalytic use. They observed the were first activated in alcoholic
oxidative effects of photocatalysis and solutions and then immersed in
UV exposure effects on the membranes ethanolic solutions containing titanium
structure. UV-screening test by 24 h of (IV) isopropoxide (TTIP) as titania
UV exposure on membranes made a precursors for in-situ hydrolysis
change in resistance membranes directly on the membrane surface. TGA
indicated membranes damaged. was used to determine the quantity of
Polypropylene (PP) which consist only TiO2 on the polymeric membranes,
methyl groups (-CH-) had 20% yielding TiO2/PS 11.0 wt%, TiO2/PTFE
resistance change associated with the 2.7 wt%, and TiO2/PVDF 3.3 wt%.
breaking of the chemical bonds of the Under UV irradiation, diclofenac
methyl group by UV energy. This also (DCF) and 17- ethinylstraddiol (EE2)
happened to the membranes which degradation was used to assess the
contain sulphur like polyethersulfone photocatalytic activity of membranes.
(PES) and polysulfone (PSf) with 26 TiO2/PS membranes were the most
and 30% decreased membranes photoactive in removing model
resistance, respectively. The other pollutants (93% and 96% for DCF and
parameter which used for indicating EE2, respectively), followed by
membrane breakdowns was releasing TiO2/PVDF membranes (92% and 94%
total organic carbon (TOC). The for DCF and EE2, respectively) and
released TOC amount from PS and PES TiO2/PTFE membranes (89% and 92%
was higher than other membranes. for DCF and EE2, respectively). The
Furthermore, they set up longer UV results demonstrated that the
exposure for the screening test. membrane's TiO2 content affected the
Polytetrafluoroethylene (PTFE), photocatalytic activity. Nevertheless,
PVDF-Pall (hydrophilic), PVDF photocatalytic performance of TiO2/PS
(hydrophobic), and polyacrylonitrile was comparable to that of TiO2/PVDF
(PAN) membranes were shown its despite substantial changes in TiO2
structure stability in 30 days of UV test concentration. This indicated that the
and the amount TOC released were way in which photocatalyst deposited
13.0; 109.0; 3.6; 29.0 ppm, on membranes also influenced
respectively. Oxidation test was photoactivity. In situ growth of TiO2
conducted using H2O2 as powerful clusters on the surface of a PS
oxidizer and UV exposure for analysing membrane reduces UV-led irradiation
effects of the oxidizer on the membrane of TiO2 particles. By estimating the
surface. PAN membranes broke down permeate flow, membrane stability was
after 10 days of H2O2/UV exposure. investigated. Although TiO2/PS had the
This indicated that weaker polymer highest photocatalytic activity, it was
chemical bonds tended to break down damaged after the first photocatalysis
under UV exposure and presence of cycle. TiO2/PTFE exhibited a
powerful oxidizer. PAN membrane significant decrease in membrane
contain the larger number of -CH- performance due to an increase in
bonds which weaker than PTFE (- permeate flux after the first cycle of
CF2CF2-)n and PVDF (-CH2CF2-)n photocatalysis, whereas TiO2/PVDF
[12]. Dekkouche et al., (2021) [8] exhibited not only high photocatalytic
published an investigation comparing activity but also excellent membrane
Photocatalytic Membranes for Organic Pollutants Removal 5

stability under UV exposure, as Composite membrane reactor can be


evidenced by the stable permeate flux. made from several materials such as
Other study by Kuvarega et al., (2018) ceramic, inorganic/organic material,
[14] reported N,Pd co-doped TiO2 in and polymer [1]. TiO2 polymer
PSf membrane for degradation of eosin composite membranes mostly were
yellow as model pollutant by phase applied for the treatment of wastewater
inversion method under visible light and purification of water which
irradiation. Their objectives were polymer as support material. TiO2
fabricating efficient, low cost, and low particle can be dispersed in the polymer
energy consumption membrane for matrix or coated on the polymer
wastewater treatment. The fabricated surface. Most studies of TiO2-based
membrane performed good composite membrane were employed
photocatalytic activity by 87-97% support materials of polyvinylidene
pollutant removal (eosin yellow) within fluoride (PVDF), polysulfone (PSf),
4 h. The result can be achieved due to polyamine (PA), polyaniline (PANI).
increasing porosity of the nanoparticles Fabrication of these composite
embedded membrane which led faster membranes often used phase inversion
permeation of the aqueous solution into method and phase separation method
membrane. However, it shown a slower using pore-forming additive like
initial rate of photoreaction in the first polyethylene glycol (PEG), in which
hour of visible light irradiation and employed N-methyl-2-pyrrolidinone
increased thereafter. (NMP) or N,N-dimethylacetamide
Overall, PVDF was promising (DMAc) as solvent [1], [7]. Several
material as a support membrane for fabrications of TiO2-based polymer
photocatalytic membrane. It shown composite membranes were
better stability performance under UV summarized in Table 2.
irradiation, resistance from oxidizing Kumaravel et al., (2023) [18] studied
agents, and doped TiO2 photocatalyst photocatalytic composite membrane
also provided high photocatalytic from PVDF and Ru-TiO2 photocatalyst.
activity and stable permeate flux [6–8]. The photocatalytic membrane was
tested for decolorization of methylene
blue (MB) and crystal violet (CV).
3.0 TiO2-BASED Immobilization of 1% Ru-TiO2 showed
PHOTOCATALYTIC significant photocatalytic degradation
MEMBRANE of the dyes with 84% and 83% for MB
and CV, respectively. The
TiO2 is one of useful semiconductor mineralization of the dyes was 64% and
materials for photocatalysis. It is 61% of MB and CV, respectively. The
inexpensive compared to other membrane also exhibited high stability
materials used for water treatment, less in recyclability test. Another
toxicity, and high chemical stability [1], approached of PVDF-TiO2 membrane
[4], [15]. In comparison, ZnO is prone was reported by Liu et al., (2023) [19].
to photo-corrosion by UV light [7], They evaluated the photocatalytic
SnO2 and CdS may produce toxic membrane for degradation of a steroid
product during photocatalysis [16-17]. hormone E2 under UV exposure.
TiO2-based photocatalytic membrane Loading 6.5% of Ti showed highest E2
can be fabricated as composite TiO2 (100 ng/L) removal up to 96% and flux
photocatalytic membrane reactor or of 60 L/m2h.
pure TiO2 as freestanding Research by Damavandi et al.,
photocatalytic membrane reactor. (2023) [20] utilized polyacrylic acid
6 K. I. Ikrari et al.

(PAA) grafted on the PES membrane removal after 3 hours under UV light
then coated by TiO2 nanoparticles for irradiation. The membrane also
phenol removal. The photocatalytic indicated minimal leaching after 72
membrane showed 62% phenol hours of cross-flow filtration test.

Table 2 Fabrication of TiO2-based polymer composite membranes

Configuration TiO2 Fabrication Remarks Ref.


& Membrane precursor method
type (loading)
• PVDF TTIP Phase • Ru-TiO2/PVDF 1%/12%, [18]
Ru-TiO2 inversion casted on the glass plate
(1%) • Decolorization of MB 84%,
CV 83% under visible light
irradiation
• PVDF TTIP • TiO2 6.5%, E2 feed 100 ng/L [19]
• Removal 96% of E2, flux 60
L/m2h, 25 mW/cm2
• PES TiO2 P25 Phase • PES membrane: [20]
inversion PES/TEG/DMF 15/20/65
wt.%, grafted PAA
• Dip coating TiO2 0.1%
• Removal 62% of phenol after
3 h, under UV light
irradiation
• PVDF TiO2 NPs Phase • Casting solutions: 25 wt% of [21]
(25 wt.%) separation TiO2/PVDF, PEG200,
DMAc solvent
• Casting media: Teflon sheet
covering a glass plate
• Immersion: tap water
coagulation bath, washed DI
water
• Max permeates flux 150
L/h/m2
• Flux recovery ratio under
UV: 77-112%
• No data % degradation of
pollutant

• PVDF/ TiO2 NPs Phase • Polyethersulfone sulfonation [22]


SPES (4 wt.%) inversion treatment (SPES)
• Casting solutions: PVDF,
SPES, 4%/76% TiO2/DMAc
solvent, polyvinyl
pyrrolidone (PVP) additive
• Casting media: polyester
non-woven fabric
• Immersion: Water
• Photo-bactericidal properties
• No data % degradation of
pollutant
Photocatalytic Membranes for Organic Pollutants Removal 7

Configuration TiO2 Fabrication Remarks Ref.


& Membrane precursor method
type (loading)

• TiO2 TiO2 NPs Phase • Dip coating: 0.03 wt% of [23]


coated (0.03 wt.%) inversion-dip TiO2, 15 min immersion, 15
membrane coating min UV irradiation
• PES • Casting solutions: PES, TiO2,
additive PVP, DMAc solvent
• Casting media: no data
• Immersion: Water/isopropyl
alcohol
• Flux 63% after 4 h
• Rejection: 99% protein

• PES TiO2 NPs TiO2 • Spray & vacuum coating: [24]


• PVC-PAN TiO2 Sol spraying, 0.1% w/v TiO2/DI water
(0.1 wt.%) vacuum • Spraying and vacuum
coating, sol- coating: negligible
gel coating permeability
• Sol-gel coating: 65-80% pure
water permeability; more
than 30 and 40% degradation
of MB and CHD,
respectively

• PAN Titanium Electrospinni • In situ polymerization of [25]


butoxide ng aniline
(2 wt.%) • 16.6 mg/g adsorption of
congo red
• 91% regeneration capacity
• PES Titanium Magnetron • Degradation of MB after 120 [26]
foil sputtering min under visible light:
(0.1 g) vapor-crystallized TiO2
nanotubes 50%;
hydrothermal crystallized
40%
• PVDF TTIP:PVP Electrospinni • photodegradation of BPA [27]
2:3 ng-hot press under visible light: 84.53%,
77,61%, and 62.54% for
PVDF/TiO2-100°C,
PVDF/TiO2-160°C,
PVDF/TiO2-180°C
• Higher hot-press temp, lower
water flux
• Hot-pressed temp 60°C the
membrane not adhered
completely

Méricq et al., (2015) [21] reported separation using DMAc solvent and
fabrication of PVDF/TiO2 membranes PEG additive. Increasing TiO2 content
by non-solvent induced phase led to enhancement the membrane
8 K. I. Ikrari et al.

permeability and flux performance. The permeability. The flow of pure water
presence of the photocatalyst also through the coated membrane was 65-
enhanced the photocatalytic 80% lower than that of the untreated
performance by preventing pure water membrane. In addition, the
flux decline under UV irradiation. photodegradation experiment resulted
Deposition of the photocatalyst on the in greater than 30 and 40 percent
membrane surface also influenced the degradation of MB and CHD,
photocatalytic performance. respectively.
Rahimpour et al., (2008) [23] compared Sputtering photocatalyst onto
the membranes performance and membrane surface is another method
antifouling properties of TiO2- for immobilizing on the membrane
entrapped and TiO2-coated in the PES surface. Fischer, Gläser and Schulze,
membranes. They reported that the (2014) [26] synthesized a TiO2/PES
coated TiO2 membrane has better membrane by magnetron-sputtering a
performance than the entrapped TiO2 titanium film onto a PES membrane,
inside membrane matrix which proven followed by anodization and
by higher flux recovery. It was shown crystallization of the membrane using
99% of protein rejection from milk two distinct processes (vapor-thermal
water permeation and the flux and hydrothermal). Photocatalytic
membrane was 63% after 4 h milk testing with methylene blue resulted in
ultrafiltration, which higher than flux of 50% and 40% degradation after 120
the neat membrane (42%). This result minutes for vapor-crystallized and
proved that the presence of TiO2 hydrothermally crystallized TiO2
nanoparticles and UV irradiation nanotubes, respectively. The improved
enhanced the antifouling properties of surface area and light-harvesting
the membrane. Chakraborty et al., capabilities of the anatase nanotubes
(2017) [24] examined three structures had an influence on the
immobilization techniques for membrane.
depositing TiO2 nanoparticles on The immobilizing of photocatalyst
polymeric hollow fibre membranes by electrospinning has been explored.
utilizing PES and PVC-PAN as Nor et al., (2016) [27] prepared
catalytic supports. They evaluated the electrospun PVDF/TiO2 nanofibers by
modified membrane for degradation of hot pressing nanofibers photocatalyst
MB and chlorhexidine digluconate on the surface of PVDF flat sheet
(CHD) under simulated solar radiation membrane. The PVDF membrane was
by spraying, vacuum coating, and sol- fabricated by phase inversion method
gel coating. Spray and vacuum and TiO2 nanofiber was synthesized
procedures result in an additional layer using electrospinning technique. Then,
on the membrane's surface, reducing its the elctrospun TiO2 nanofibers were
permeability. The pore-blocking placed and hot pressed on the surface of
deposition of TiO2 shown by SEM PVDF membrane within constant
examination to have low membrane pressure 80 bars and varied temperature
permeability. The sol-gel technique was (60°C, 100°C, 160°C and 180°C) for 30
utilized using diluted sol as the coating min. photodegradation of BPA under
solution, and the membrane was then visible light shown 84.53%, 77,61%,
dipped into the solution to deposit TiO2 and 62.54% for PVDF/TiO2-100°C,
onto the membrane surface. Controlling PVDF/TiO2-160°C, PVDF/TiO2-
the concentration of TiO2 solution was 180°C, respectively. By using similar
used to determine the optimal coating method, Xu et al., (2020) [25]
procedure for maintaining membrane developed a PAN/TiO2/PANI for
Photocatalytic Membranes for Organic Pollutants Removal 9

removal of congo red as target pollutant one factor that affect the
and recovered the photocatalytic photodegradation process [33–35]. This
membrane employed visible light is connected to the charge repulsion
irradiation. the membrane was prepared between the pollutant and photocatalyst
by electrospun PAN/TiO2 membrane nanoparticles because the capacity of a
then added aniline directly on the pollutant to adsorb can be critical for a
PAN/TiO2 membrane for in situ catalyst's high catalytic activity, as it
polymerization. The membrane tested can improve electron/hole transfer
of the adsorption towards congo red efficiency and interaction with
shown 16.6 mg/g adsorption capacity photogenerated active species [36]. The
which higher than PVA/PAA/GO- photocatalyst loading in the membrane
COOH fiber membrane (8.88 mg/g). system give significant impact in the
Regeneration of the membrane membrane properties. It may act as a
evaluated using visible light irradiation. pore forming agent in the fabrication
Overall, the regeneration capacity of the process of symmetric membrane until
prepared membrane was 91%, three the optimum composition achieved. At
times higher than water-wash the higher amount of photocatalyst
regeneration (31%). loading, it may agglomerate in the
membrane pores which results defect
membrane pore structure and decrease
4.0 CONCLUSION AND FUTURE the permeability [37-38].
DIRECTIONS Utilization of the photocatalytic
membrane has become an advanced
Despite the selection of photocatalyst option for wastewater treatment.
and polymeric membrane, the selection Development toward solar-driven
of methods used also needs to be photocatalytic membrane as the greener
consider enhancing the photocatalytic energy has emerged recently. Also,
activity of the photocatalytic optimization of photocatalytic
membrane. Compared to the suspended membrane configuration may be
photocatalytic membrane system, the explored like different photocatalytic
embedded photocatalyst in the membrane system designs and
membrane system will reduce the configurations to enhance the
membrane fouling significantly that photodegradation efficiency. This could
may improve the water permeability. include exploring variations in the
TiO2 photocatalyst nanoparticles immobilization technique, catalyst
entrapped in the membrane system will loading, membrane properties, and light
not be released to the liquid pollutant distribution to improve the contact
stream during filtration process and will between the immobilized photocatalyst
give higher pollutant removal and the target pollutant.
efficiency because of the photocatalytic
reaction that occurs on the membrane
surface also in the membrane pores CONFLICTS OF INTEREST
during filtration process when the
pollutant is permeated through the The authors declare that there is no
membrane [28–32]. conflict of interest regarding the
Moreover, there are several factors publication of this paper.
that reported affect the embedded
photocatalytic membrane
performances. In the photodegradation
system, pH of the pollutant feed may be
10 K. I. Ikrari et al.

ACKNOWLEDGEMENT photocatalytic water treatment


technology : A review. Water
The authors gratefully acknowledge the Res., 44(10), 2997-3027. Doi:
financial support from JICA Technical 10.1016/j.watres.2010.02.039.
Cooperation Project for ASEAN [5] W. S. Koe, J. W. Lee, and W. C.
University Network/Southeast Asia Chong. (2019). An overview of
Engineering Education Development photocatalytic degradation:
Network (JICA Project for photocatalysts, mechanisms, and
AUN/SEED-Net) via the Collaborative development of photocatalytic
Education Program for Water and membrane. Colloid Interface Sci.
Wastewater Treatment Engineering J.
Research Consortium (Program [6] S. Leong, A. Razmjou, K. Wang,
Contract No: UTM CEP 2102 / Project K. Hapgood, X. Zhang, and H.
Number: R.J130000.7309.4B647). The Wang. (2014). TiO2 based
authors also would like to thank photocatalytic membranes : A
Universiti Teknologi Malaysia for the review. 472, 167-184. Doi:
Grants (Project number: 10.1016/j.memsci.2014.08.016.
Q.J130000.3009.03M15 and [7] Y. Shi, J. Huang, G. Zeng, W.
Q.J130000.2451.09G17). Cheng, and J. Hu. (2019).
Photocatalytic membrane in
water purification : Is it stepping
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