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Arjuna JEE AIR (2024)

PERIODIC TABLE ASSIGNMENT - 01

1. If A, B and C are the three element of Dobereiner’s 7. Which of the following atomic numbers represent s,
Triad and atomic mass of A and B are 7 and 15 p and d-block respectively.
respectively then the atomic mass of C is (1) 10, 41, 23 (2) 20, 82, 46
(1) 1 (2) 11 (3) 4, 44, 19 (4) 32, 55, 16
(3) 23 (4) 25
8. The “atomic volume” of an element is defined as
2. According to the Lother Meyer’s curve which of the (1) the volume occupied by an atom
following statement is incorrect. (2) the volume occupied by one gram of an atom
(1) The element having similar properties will (3) the volume occupied by the one gram-atom of an
occupy the same position in the curve. element
(2) Alkaline earth metals are at the peaks of the (4) none of these
curve.
(3) Halogens are at ascending part of the curve. 9. Find the odd element from the given electronic
(4) The atomic volume of the elements in a period configuration.
initially decreases and then increases. (1) 1s2 2s2 2p6 3s1 (2) 1s2 2s1
(3) 1s2 2s2 2p6 3s2 3p1 (4) 1s2 2s2 2p6 3s2 3p6 4s1
3. For which set of elements “diagonal relationship” is
not existing. 10. The total number of element present in 4th period in
(1) B, Si (2) Li, Mg the long form of periodic table.
(3) B, Mg (4) Be, Al (1) 18 (2) 2
(3) 8 (4) 32
4. Which of the following element is not a ‘p’ block
element. 11. An element having electronic configuration of [Ar]
(1) Bi (2) Ga 3d3 4s2 belongs to
(3) Sn (4) Cd (1) s-block (2) p-block
(3) d-block (4) f-block
5. Which of following is not correctly matched
(1) d-block element : electronic configuration is ns0-2 12. Which of the following element is/are of d-block
(n–1) d1-10. element (for which the atomic numbers are given).
(2) p-block element : electronic configuration is ns1– (1) 19 (2) 81
2
np1–6 (3) 46 (4) 58
(3) s-block element : electronic configuration is ns1–2
(4) Ce : f-block’s first member. 13. The elements in which 5f-orbitals are progressively
filled are called as
6. Which is not transition element. (1) Lanthanides (2) Actinides
(1) Cu (3) Transition elements (4) None of these
(2) Ac
(3) Zn 14. Which of the following is ‘d’ block element.
(4) Pd (1) Bi (2) Sn
(3) Nb (4) In
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15. The elements P, Q and R are one of the Dobereiner’s 21. If x, y and z are the three elements of Dobereiner’s
triad of elements in the increasing order of their triad and the atomic masses of x and z are 7 and 23
atomic masses. If the atomic masses of P, Q and R are respectively, the atomic mass of y is
x, y and z respectively, then (1) 15 (2) 11
(1) x = 2y + z (2) z = x + y (3) 12 (4) 24
(3) z = 2 x – y (4) x + y + z = 3y
22. In the general electronic configuration (n–2)f1–14(n–1)
16. Which of the following statement is incorrect for d0-1ns2, if value of n = 7 the configuration will be :
Lother Mayer’s curve? (1) Lanthanides (2) Actinides
(1) Atomic volumes of elements were taken on y- (3) Transition elements (4) None
axis and atomic masses of elements on x-axis.
(2) All the peaks were occupied by alkali metals. 23. Find the species not having same number of d-
(3) Halogens were present on the descending curve. electron in last possible filled d-subshell as in Zn.
(4) Alkaline earth metals were present on the (1) Ga (2) Pd
descending curve. (3) Cd (4) Pt

17. Which one of the following statements is not correct? 24. According to modern periodic law, properties of the
(1) Li shows similarity in properties with Mg elements are the periodic functions of their
(2) Li, Na and K forms Doberenier’s Triads. (1) Atomic weight (2) Surface area
(3) In the Lother Meyer’s curve alkaline earth metals (3) Atomic number (4) Density
occupy the ascending positions of the curve
(4) IUPAC name of the element having atomic 25. The element having the lowest atomic number and a
number 112 is Uub. ground state electronic configuration of (n–1) d6 ns2
is placed in
18. The period number, group number, and block of the (1) Fifth period (2) Fourth period
element having atomic number 39 will be : (3) Sixth period (4) Third period
(1) 5, 5, d (2) 5, 4, d
(3) 5, 3, d (4) 5, 15, p 26. Select the configuration of neutral atom(s), which
belongs to s-block?
19. In the Modern long form of periodic table, 4th period (1) [Xe] 4f14 5d10 6s2 (2) [Xe] 5d1 6s2
contains only 18 elements. It is due to filling of (3) [Xe] 4f7 3d0 6s2 (4) [Xe] 6s2
electrons in the :
(1) 4s, 4p and 4d sub-shells 27. Select the pair of elements which are present in same
(2) 4s, 3d and 4p sub-shells group but in different sub group in Mendeleev’s
(3) 4s, 4p, 4d and 4f sub-shells periodic table.
(4) 3s, 3p and 3d sub-shells (1) F, Ar
(2) Cl, B
20. Which of the following element does not belongs to (3) K, Cu
p-block? (4) Be, Mg
(1) Cl
(2) S 28. Select the pair of elements which are present in same
(3) H period in long form of periodic table.
(4) Ne (1) C, Ar
(2) Sc, Y
(3) Na, La
(4) P, S
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29. If an orbital can have maximum 4 electrons then, how 35. In which group of periodic table, the elements of 4th,
may elements can be present in 8th period? 5th and 6th period have different ground state
(1) 100 (2) 75 electronic configuration for last two shells, from each
(3) 128 (4) 64 other?
(1) 8 (2) 9
30. Principle of modern periodic table is given by: (3) 10 (4) 18
(1) Mosley (2) Mendeleef
(3) Doberinier (4) Newland 36. Identify the atom which has ground state
configuration [Ar] 3d104s2 4p1
31. In the Lother - Mayer graph, A, B, C, D & E element (1) Al (2) Ga
are (3) In (4) Tl

37. Name of element with atomic number (z)=110.

(1) Unnilbium (2) Ununnillium
(3) Unnilunium (4) Ununtrium

38. Which of the following statement is correct for an

element having atomic number (z) = 98?
(1) Halogens (2) Alkaline earth metals (1) It is s-block element.
(3) Alkali metals (4) Transition metals (2) It is p-block element.
(3) It is transition element.
32. Most of the ‘d’ block elements are known as : (4) It is inner transition element.
(1) Alkali metals
(2) Alkaline earth metals 39. Which of the following is not a bridge element of in
(3) Innertransition element Mendeleev’s table?
(4) Transition element (1) Mg (2) Al
(3) Si (4) Ar
33. If the atomic number of an element is 33, it will be
placed in the periodic table in the ________. 40. What will be the atomic number of yet undiscovered
(1) first group (2) third group element directly below Fr in periodic table?
(3) fifth group (4) seventh group (1) 117 (2) 118
(3) 119 (4) 120
34. Match column I (atomic number) with column II
(position in the Periodic Table) and select the correct 41. Which of the following is p-block element.
answer using the codes given below: (1) Zn (2) Rb
Column I Column II (3) Pb (4) Nb
I. 52 P. s-block
II. 56 Q. p-block 42. The outer electronic configuration of an element in
III. 57 R. d-block ground state is 5s2 4d105p3. The properties of element
is likely to be similar to that of
IV. 60 S. f-block
(1) Chlorine (2) Sulphur
(1) I-P, II-Q, III-S, IV-R
(3) Phosphorus (4) Aluminium
(2) I-Q, II-P, III-S, IV-R
(3) I-P, II-Q, III-R, IV-S
43. In the sixth period, the orbitals are filled as-
(4) I-Q, II-P, III-R, IV-S
(1) 6s 5f 6d 6p (2) 6s 4f 5d 6p
(3) 5s 5p 5d 6p (4) 6s 6p 6d 6f
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44. 52. In the modern periodic table the maximum number of

elements are present in :
(1) Group I and period number 5
(2) Group III and period number 6
(3) Group V and period number 7
In above figure if ‘Z’ is the atomic number then (4) Same for all
identify the period number of element ‘X’ in periodic
table- Effective Nuclear Charge:
(1) 5th (2) 4th 53. Choose the correct statement from the following:
(3) 6th (4) 7th (1) Zeff on ‘d’ electron of Sc2+ is 18
(2) Zeff values on an electron present in 4s and 4p
45. Identify the group number of Tl element in periodic orbital of an atom are identical.
table. (3) Zeff values on an electron present in 3s and 4s
(1) Group number = 13 orbital of an atom are identical.
(2) Group number = 4 (4) the screening constant value on one electron in
(3) Group number = 16 H–ion is 0.35.
(4) Group number = 7
54. According to Slater rule, which set of elements show
incorrect order of zeff.
46. Mendleeve left the space for elements in periodic
(1) Al>Mg (2) Na>Li
table, the element is not
(3) K>Na (4) None of these
(1) Ga (2) Sc
(3) Ge (4) Te 55. The value of screening constant (σ) for N-atom is 3.10
and that for O-atom is
47. The number of elements in 6th period of the modern (1) 3.10 (2) 2.75
periodic table are : (3) 3.45 (4) 3.80
(1) 8 (2) 18
(3) 32 (4) None of these 56. In a given shell the order of screening effect is
(1) s>p>f>d (2) s>d>p>f
48. The number of groups in modern periodic table that (3) s>p>d>f (4) s<p<d<f
belong to d-block are :
(1) 18 (2) 10 57. Calculate the effective nuclear charge for the outer
(3) 6 (4) 2 most electron of oxygen atom.
(1) 3.45 (2) 4.55
49. Which of the following is a transition element? (3) 0.85 (4) 6.4
(1) Zn (2) Cd
58. What will be the difference of Zeff in N and O for last
(3) Hg (4) Cu
electron.
(1) 0.35 (2) 0.65
50. The number of elements present in the group 3 of the
(3) 2.1 (4) 0.85
modern periodic table is:
(1) 4 (2) 8 59. The outermost and penultimate shell of an element
(3) 18 (4) 32 contains 2 and 8 electrons, respectively. The effective
nuclear charge for the valence electron of this
51. The elements with given atomic numbers that belong to element, according to Slater’s Rule, should be :
the group number 16 of the modern periodic table is: (1) 2.20 unit (2) 2.50 unit
(1) 34, 52 (2) 15,33 (3) 2.85 unit (4) 7.15 unit
(3) 38,56 (4) None of these
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60. Which of the following pair of elements have the Size:

same value of shielding constant (σ) for 3s-electron. 69. In Which of the following case the size ratio is
(1) Mn & Zn (2) Fe & Na maximum:
(3) Ar & Cl (4) All of these (1) Cl–/ Cl (2) I–/ I
(3) H-/ H (4) F–/ F
61. Which of the following pair has the same value of
screening constant for ‘3s’ electron? 70. Among the following species the highest radius is of
(1) Cl & Mg (2) Mg & Ca (1) Al3+ (2) F–
(3) N & Na (4) K & Ca (3) Na (4) N3–

62. The value of σ for the 4s and 5s electron of Rb is 71. Select the correct sequence of increasing radius (left
respectively? to right)
(1) 27.75 and 34.80 (2) 28.95 and 34.80 (1) Se2–, O2–, F–
(3) 27.75 and 28.10 (4) 28.10 and 28.95 (2) Ca2+, Ar, K+
(3) Se, As, Ge
63. Effective nuclear charge on last electron of Fe2+ (4) Fe, Fe2+, Fe3+
(Using Slater’s Rule)
(1) 7.5 (2) 7.45 72. Atomic radii of fluorine and neon in Angstrom units
(3) 6.25 (4) 19.75 are respectively given by
(1) 0.72,1.60
64. Zeff for the valence electron of Al(Z = 13) is : (2) 1.60,1.60
(1) 9.50 unit (2) 3.50 unit (3) 0.72,0.72
(3) 3.85 unit (4) 3.15 unit (4) 1.60,0.72

65. Find Zeff (using Slater’s Rule) on 3d electron of 73. Choose the correct ionic radius order:
Cu(29) (1) N3– < N2–
(1) 8.3 (2) 6.85 (2) N3– < P3–
(3) 7.85 (4) None of these (3) K+ < Ca2+
(4) O2– < Mg2+
66. Choose the following atom which has maximum
value of Zeff ? 74. In which of the following compound size of cation to
(1) Na (2) Li anion ratio is minimum :
(3) S (4) O (1) CsF (2) LiI
(3) LiF (4) CsI
67. Calculate the value of Zeff for 3d electron of 21Sc.
(1) 18.69 75. The Lanthanide contraction is caused by
(2) 21.69 (1) sudden increase of number of proton inside the
(3) 3.69 nucleus of an atom.
(4) 3.00 (2) sudden decrease of number of valence shell
electrons.
68. Which of the following transition element has (3) presence of large number of d and f-electrons
minimum value of effective nuclear charge having poor shielding effect.
(according to Slater’a rule). (4) the repulsion of inner shell electrons.
(1) Zn (2) Cu
(3) Ni (4) Mg
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76. Atomic radius variation of an unknown group in the 83. For an element, the covalent radius is xÅ, metallic
periodic table is as below radius is yÅ and the Vanderwaal’s radius is zÅ.
Which of the following order is correct?
(1) x < y < z (2) y < x < z
(3) z < y < x (4) x< z < y

84. Which of the following is incorrect order of ionic

radii?
The element B & C respectively are : (1) N– < N2– < C4–
(1) Cl & Br (2) Be & Mg (2) O– < N3–
(3) Si & Ge (4) Al & Ga (3) Mg+ < Al3+
(4) Si4+ < Al2+ < Al+
77. Choose the incorrect ionic radius order.
(1) Al3+ < Li+ (2) O2– > C4– 85. Choose the correct order of size.
(3) Cl– < S2– (4) Na+ > Li+ > H+ (I) Fe2+ > Fe3+ (II) Cu < Zn
2+ +
(III) Cu > Cu (IV) Hg22+ > Hg2+
78. The smallest size cation and anion available are (1) I, II & IV (2) I, II & III
respectively. (3) I, III & IV (4) II & IV
(1) H+ and H– (2) H+ and F–
–
+
(3) Li and F (4) Li+ and H– 86. Among the following species the highest radius is of
(1) Na+ (2) Mg2+
79. Select the correct order of ionic radii. (3) Al 3+
(4) Si4+
(1) O2–>S2–>Se2–>Te2–
(2) S2–>O2–>Se2–>Te2– 87. The correct order of atomic radii is
(3) Te2–>Se2–>S2–>O2– (1) K+<Ca2+<Cl–<S2– (2) Cl–<K+<Ca2+<S2–
(4) Se2–>Te2–>O2–>S2– (3) Cl–<S2–<K+<Ca2+ (4) Ca2+<K+<Cl–<S2–

80. Which of the following is smallest anion. 88. The correct order of ionic radii is
(1) F⊖ (2) H⊖ (1) N3– > Na+ > O2– > F–
(3) Cl⊖ (4) O2– (2) Na+ > O2– > N3– > F–
(3) O2–> F– > Na+ > N3–
81. Which of the following is the correct increasing size? (4) N3– > O2– > F– > Na
(1) Cl– < Ca2+ < S2– < Al3+
(2) Mg2+ < K+ < Li+ < Al3+ 89. The correct order of ionic radii is:
(3) Mg2+ < Na+ < F– < O– < N3– (1) Te2– > I– > Cl– > Ar+
(4) F– < Na+ < Mg2+ < O2– (2) I– > Te2– > Cl– > Ar+
(3) I– > Te2– > Ar+ > Cl-
82. Which of the following elements have smaller size (4) I– > Cl– >Te2– > Ar+
than carbon?
(1) Lithium 90. The Lanthanide contraction is responsible for the fact
(2) Nitrogen that:
(3) Neon (1) Zr and Y have almost the same radius.
(4) Sodium (2) Zr and Nb have similar oxidation state.
(3) Zr and Hf have almost the same radius.
(4) Zr and Zn have the same oxidation state.
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91. Select the correct order of ionic radii : 99. Select the pair of almost same size.
(1) Te2–>Se2–>S2–>O2– (1) Al, Ga (2) Zr, Hf
(2) Te2–<Se2–<S2–<O2– (3) Fe, Co (4) All of these
(3) Te2–=Se2–>S2–=O2–
(4) None 100. Choose the correct order of atomic / ionic radii.
(1) Sc < Y < La (2) Fe < Co < Ni
92. Which one is correct order of the size of the Nitrogen (3) Be2+ < Mg2+ < Al3+ (4) Tl+ < Pb2+ < Bi3+
species?
(1) N+ < N < N– 101. Arrange in the increasing order of atomic radii of the
(2) N > N– > N+ following elements O, C, F, Cl, Br
(3) N+ > N– > N (1) F<O<C<Cl<Br (2) F<C<O<Cl<Br
(4) N > N+ > N– (3) F<Cl<Br<O<C (4) C<O<F<Cl<Br
102. The ionic radius of Na , Mg2+ and Al3+ ions are in
+

93. Which one is correct order of the size of the iodine order.
species? (1) Na+ < Mg2+ < Al3+
(1) I– > I > I+ (2) I > I– > I+ (2) Na+ > Mg2+ > Al3+
(3) I+ > I– > I (4) I > I+ > I– (3) Na+ = Mg2+ = Al3+
(4) Na+ < Al3+ < Mg2+
94. Correct order of radius among the following
F–, Al3+, Na+ are 103. In following compound which has minimum ionic
(1) Al3+ = Na+ = F– (2) Al3+ > Na+ > F– radius of maganese is:
–
3+
(3) Al = Na > F+
(4) Al3+ = Na+ < F– (1) Mn2(SO4)3 (2) MnO
(3) KMnO4 (4) MnO2
95. The ionic radii of Fe2+ and Fe3+ are x and y
respectively the correct relationship between x and y 104. Choose the compound in which ‘Cr’ atom has
is : minimum atomic radii:
(1) x > y (2) x < y (1) Cr2O3
(3) x = y (4) can’t be predicted (2) CrO
(3) K2Cr2O7
96. The ions O2–, F–, Na, Mg2+ and Al3+ are isoelectronic. (4) All molecule has same atomic radii of Cr
Their ionic radii show:
(1) an increase from O2– to F-and then decrease from 105. Which of the following pair of element has incorrect
Na+ to Al3+ order of atomic radii?
(2) a decrease from O2– to F-and then increase from (1) Fe ≃ Co (2) La ≃ Y
Na+ to Al3+ (3) Pt ≃ Pd (4) Zr ≃ Hf
(3) a significant increase from O2– to Al3+
(4) a significant decrease from O2– to Al3+ 106. Atom which has largest atomic radii in following -
(1) Se (2) Br
97. The correct order of ionic radii is : (3) Te (4) I
(1) O->F->Li+>B3+ (2) F->O->Li+>B3+
3+
(3) F->B >O->Li+ (4) O->F->B3+>Li+ 107. Which options are correct for atomic radii?
(1) Ne>F
98. Which of the following pair of species having nearly (2) F>Cl
same atomic size (3) F>Ne
(1) Zr & Hf (2) Pd & Pt (4) Cl>Ar
(3) Fe & Co (4) All of these
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108. Which of the following has the largest size? 117. Ionisation energies of element X are given below (in
(1) K+ (2) Ca+2 kJ/mol)
(3) Ar (4) S2– IE1 IE2 IE3
520 7,340 11,000
109. Among the following species the highest radius is of If ‘X’ reacts with different elements which
(1) Al3+ (2) Mg2+ compounds are possible
+
(3) Li (4) Na+ (1) XF (2) X2 O
(3) X3N (4) All of above
Ionisation Energy:
110. Find the highest ratio of IP values of given pair of 118. The correct order of ionisation energy of Al, K, Fe,
elements: Mg is
(1) He : Ne (2) Ne : Ar (1) K<Al<Mg<Fe (2) K <Mg<Al<Fe
(3) He : Xe (4) Kr : Xe (3) Mg<K<Al<Fe (4) Mg<Fe<Al<K
111. Which one of the following electronic configuration
of an atom has the lowest ionisation energy 119. One element (A) is having four valence shell electron
(1) 1s2 2s2 2p3 (2) 1s2 2s2 2p6 3s1 and which of following values will be maximum.
(3) 1s2 2s2 2p6 (4) 1s2 2s2 2p5 (1) EA of ‘A’ (2) IE4 – IE3
(3) IE5 – IE3 (4) IE2 – IE1
112. The first five ionization energies of an element are
9.1, 16.2, 24.5, 35 and 205.7 eV respectively. Then 120. The 2nd ionisation potential of Mg is less than that of
number of valence electron in the atom is Na because
(1) 2 (2) 3 (1) Atomic size of Mg is less than that of Na.
(3) 4 (4) 5 (2) Atomic size of Mg is greater than that of Na.
(3) 2nd electron removal from Na occur from inert
113. Which one of the following electronic configuration gas configuration, while the same for Mg results
of an atom has the highest ionisation energy inert gas configuration.
(1) 1s2 2s2 2p3 (2) 1s2 2s2 2p6 3s1 (4) Both are having same Zeff value for 3s electron.
(3) 1s2 2s2 2p6 (4) 1s2 2s2 2p5
121. Which of the following set of elements are having
114. Which of the following magnetic moment values will strongest tendency to form cation?
correspond to highest ionisation energy for cobalt (1) I, Cl, Br (2) C, Sn, Se
specie. (3) Na, K, Sr (4) Mn, Ti, Fe
(1) 2 2 (2) 15
122. The ionisation potential values 54.40 eV & 39.30 eV
(3) 35 (4) 24
correspond to
(1) H+& H (2) Li & Li+
115. Which of the following has 2nd I.P. < 1st I.P. +
(3) He & He (4) He+ & He
(1) Mg (2) Ne
(3) C (4) None of these
123. The ionisation energy for ‘Sc’, ‘Y’ and ‘La’ are x, y
and z kcal/mol respectively. Choose the correct
116. Highest difference between Ist & IInd ionisation
relationship between them.
energies will be observed in:
(1) z > x ≈ y
(1) Li (2) B
(2) x > y > z
(3) O (4) F
(3) x > z ≈ y
(4) x < y > z
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124. For an element ‘A’.

130.
A ⎯⎯
IE1
→ A+ ⎯⎯→
IE 2
A2+ ⎯⎯
IE3
→ A3+ ⎯⎯
→
……….
The IE1 and IE3 values are 27kJ / mole and 51kJ /
mole respectively. Then the value of IE2 is kJ/mole.
(1) 21 (2) 33
(3) 59 (4) 63

Above graphs represent successive ionisation

125. Which of the following atom has highest ionisation
energies of an element.
energy.
Given : x < y < 11 eV and z > 16 eV ; a < 11eV and
(1) N
b > 16eV
(2) O
Which of the following is incorrect according to
(3) P
above two graphs?
(4) S
(1) Graph I may belong to the elements of 13th group.
(2) Graph II may belong to the elements of 2nd group.
126. Rb forms Rb+ ion but it does not form Rb2+ because
(3) Stable oxidation state of metal ion according to
(1) Very low value of (I.E.)1 and (I.E.)2
Graph-II would be +2.
(2) Very high value of (I.E.)1 and (I.E.)2
(4) ns2 np1 may be the general electronic
(3) low value of (I.E.)1 and low value of (I.E.)2
configuration of element according to Graph-II.
(4) low value of (I.E.)1 and high value of (I.E.)2

131. Which of the following is the strongest reducing

127. Choose the correct Ionisation potential order :
agent in aqueous solution?
(1) O– > O (2) N– > N
– (1) 1s2 2s2 2p6 3s2 3p6 4s1
(3) H > H (4) None of these
(2) 1s2 2s1
(3) 1s2 2s2 2p6 3s1
128. An+(g) ⎯⎯
x
→ A(n+1)+ (g) + e⊖
(4) [Xe] 6s1
In above process ‘X’ is
(1) Electron gain enthalpy 132. For an element ‘A’ belonging to alkaline earth metal
(2) Electronegativity family.
(3) Ionisation energy A ⎯⎯ → A+ ⎯⎯→ A2+ ⎯⎯→ A3+ ⎯⎯→ A4+
IE1 IE2 IE3 IE4
(4) None of these
……… .. are defined. If IE3 and IE4 are respectively
129. HIE1 (First Ionisation Enthalpy) of Na, Mg and Si is 4.9 and 6.5 MJ / mol. What will be the values of IE1
and IE2 respectively.
496,737 and 786kJ mol–1, respectively. What will be (1) 1, 4 (2) 0.6, 1.1
the HIE1 value of Al? (3) 4, 4.5 (4) 1.5, 5.2
(1) 760 kJ mol-1 (2) 450 kJ mol-1
(3) 580 kJ mol-1 (4) 800 kJ mol-1 133. The ionisation enthalpy of sodium is 500kJ/mol at
TK. How many sodium atoms may be converted into
sodium ions (Na+) by the absorption of 200J heat at
TK ? (NA = 6 × 1023)
(1) 2.4 × 1023 (2) 2.4 × 1020
(3) 1.5 × 1021 (4) 1.5 × 1024
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134. The successive ionisation energies of an element (in 142. Which of the following elements has the lowest
eV / atom ) are : ionisation potential?
(I.E.)1 (I.E.)2 (I.E.)3 (I.E.)4 (I.E.)5 (1) Na (2) K
11.2 24.3 57.4 77.4 392.0 (3) Mg (4) Al
The outer electronic configuration of the element may
be : 143. Inert pair effect is prominent character of
(1) ns2 np0 (2) ns2 np3 (1) p-block element (2) d-block element
(3) ns2 np1 (4) ns2 np2 (3) s-block element (4) f-block element

135. Ionisation energies of Cl–, Cl and Cl+ are respectively 144. For element, A there is large energy difference
(in KJ/mol) between 5th and 6th ionisation energy. This element is
(1) 1251, 349, 2300 member of
(2) 2300, 349, 1251 (1) Pnictogen family (2) Chalcogen family
(3) 349, 1251, 2300 (3) Halogen family (4) Noble gases
(4) 349, 2300, 1251
145. Second ionization potential of Li, Be and B is in the
136. Which of the following isoelectronic species has the order
lowest ionisation energy? (1) Li>Be>B (2) Li>B>Be
(1) S2– (3) Li>Be<B (4) B>Be>Li
(2) K+
(3) Cl– 146. Consider following electronic configuration of atoms
(4) Ca2+ and select correct code in order of increasing
137. Which ionisation potential in the following equations ionization energy
involves the greatest amount of energy? [I] 1s2 2s2 2p6 3s2 [II] 1s2 2s2 2p6 3s1
(1) K+ → K2++ e– (2) Ca+ → Ca2+ + e– [III] 1s2 2s2 2p4 [IV] 1s2 2s2 2p5
(3) Fe → Fe+ + e– (4) Li+ → Li2+ + e– 2
[V] 1s 2s 2p2 6

(1) [ II ]<[ I ]<[ III ]<[ IV ]<[V]

138. Which of the following has the lowest second (2) [ II ]<[ III ]<[ IV] <[ I ]<[ V ]
ionisation energy? (3) [ II ]<[ IV ]<[ III ]<[ I ]<[ V]
(1) Sc (2) Ti (4) [ II ]<[ III ]<[ I ]<[ IV ]<[V]
(3) V (4) Ca
147. The incorrect statement among the following is :
139. Which of the following elements has the highest (1) The first ionisation energy of calcium is more
ionisation energy? than first ionisation energy of gallium
(1) [Ne] 3s2 3p1 (2) [Ne] 3s2 3p3 (2) The second ionisation energy of copper is greater
(3) [Ne] 3s2 3p2 (4) 3d10, 4s2 4p3 than that of potassium
(3) The third ionisation energy of Mg is greater than
140. The first ionisation potential (in eV) of N, O atoms the third ionisation energy of Al
are: (4) The IE1 of Mg+ is less than the IE1 of Na+
(1) 14.6,13.6 (2) 13.6,14.6
(3) 13.6,13.6 (4) 14.6,14.6 148. Choose the correct ionisation energy order.
(1) Li < B < Be < C < N < O < F
141. Ionisation potential of which element is highest? (2) Na < Mg < Al < Si < S < P < Cl
(1) H (2) Cl (3) K < Ga <Ca < Ge < As < Se < Br
(3) He (4) Fr (4) Rb < Sr < In < Sn < Sb < Te < I
 11

149. Select correct graph, which is plotted between 150. Which of the following has the highest second
Ionisation Energy of 2\text nd period elements and ionisation energy?
their atomic number. (1) Cr
(2) Mn
(1) (2) (3) Co
(4) Fe

(3) (4)

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 12

Answer Key
1. (3) 26. (4) 51. (1) 76. (4) 101. (1) 126. (4)
2. (2) 27. (3) 52. (2) 77. (2) 102. (2) 127. (4)
3. (3) 28. (4) 53. (2) 78. (2) 103. (3) 128. (3)
4. (4) 29. (1) 54. (3) 79. (3) 104. (3) 129. (3)
5. (2) 30. (1) 55. (3) 80. (1) 105. (2) 130. (4)
6. (3) 31. (3) 56. (3) 81. (3) 106. (3) 131. (2)
7. (2) 32. (4) 57. (2) 82. (2) 107. (1) 132. (2)
8. (3) 33. (3) 58. (2) 83. (1) 108. (3) 133. (2)
9. (3) 34. (4) 59. (3) 84. (3) 109. (4) 134. (4)
10. (1) 35. (3) 60. (1) 85. (1) 110. (3) 135. (3)
11. (3) 36. (2) 61. (4) 86. (1) 111. (2) 136. (1)
12. (3) 37. (2) 62. (1) 87. (4) 112. (3) 137. (4)
13. (2) 38. (4) 63. (3) 88. (4) 113. (3) 138. (4)
14. (3) 39. (4) 64. (2) 89. (1) 114. (1) 139. (2)
15. (4) 40. (3) 65. (3) 90. (3) 115. (4) 140. (1)
16. (3) 41. (3) 66. (3) 91. (1) 116. (1) 141. (3)
17. (3) 42. (3) 67. (4) 92. (1) 117. (4) 142. (2)
18. (3) 43. (2) 68. (2) 93. (1) 118. (1) 143. (1)
19. (2) 44. (3) 69. (3) 94. (4) 119. (3) 144. (1)
20. (3) 45. (1) 70. (4) 95. (1) 120. (3) 145. (2)
21. (1) 46. (4) 71. (3) 96. (4) 121. (3) 146. (1)
22. (2) 47. (3) 72. (1) 97. (1) 122. (4) 147. (2)
23. (4) 48. (2) 73. (2) 98. (4) 123. (2) 148. (4)
24. (3) 49. (4) 74. (2) 99. (4) 124. (2) 149. (1)
25. (2) 50. (4) 75. (3) 100. (1) 125. (1) 150. (1)

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