CHEMISTRY

SOLUTION

SYMBOL OF EXCELLENCE

CLASS XII MARKS : 40 DATE: TIME: STP-1

1. The effect of increase in the temperature of an aqueous (d) 1.5 M

solution of a substance is 7. Mole fraction of C3 H5  OH 3 in a solution of 36 g of
(a) Decrease in its molality
water and 46 g of glycerine is:
(b) Increase in its molality
(a) 0.46 (b) 0.36
(c) Increase in its mole fraction
(d) Decrease in its molarity (c) 0.20 (d) 0.40
2. Molar concentration of a solution in water is:
8. 25 mL of 3 MHCl were added to 75mL of 0.05 M HCl.
(a) Always equal to normality
The molarity of HCl in the resulting solution is
(b) More than molality of the solution
approximately-
(c) Equal to molality of the solution
(a) 0.055 M (b) 0.35 M
(d) Less than the molality of the solution

3. 171 g of cane sugar C12 H22O11  is dissolved in 1 litre

(c) 0.787 M (d) 3.05 M

of water. The molarity of the solution is 9. Which of the following gas will have most solubility in
(a) 2.0 M (b) 1.0 M water?
(a) NH3 (b) H2
(c) 0.5 M (d) 0.25 M
(c) O2 (d) He
N
4. With 63 gm of oxalic acid how many litres of 10. The order of KH values of A, B and C gases is
10
solution can be prepared K H A  K HC  K H B . Then, the correct order of their
(a) 100 litre (b) 10 litre solubility in liquid at given temperature is

(c) 1 litre (d) 1000 litre (a) A > C > B (b) B > A > C

(c) B > C > A (d) A > B > C

5. 200 ml of a solution contains 5.85 g dissolved sodium
chlorid. The concentration of NaCl in the solution will
be (Na = 23; Cl = 35.5 ) Answers
1-d 2-d 3-c 4-b 5-c 6-c 7-c 8-c 9-a 10-c
(a) 1 molar (b) 2 molar

(c) 0.5 molar (d) 0.25 molar

6. 4.0 gm of NaOH are contained in one decilitre of

solution. its molarity would be
(a) 4 M
(b) 2 M
(c) 1 M
 CHEMISTRY
SOLUTION

SYMBOL OF EXCELLENCE

CLASS XII MARKS : 40 DATE: TIME: STP-2

1. Among the following that forms an ideal solution: (a) Shows a (+ve) deviation from Raoult’s law
(a) Water and methanol (b) Shows no deviation from Raoult’s law
(b) Acetone and ethanol (c) Shows (+ve) deviation from Henry’s law
(c) Benzene and toluene (d) Shows (-ve) deviation from Henry’s law
(d) Water and HCl 8. The vapour pressure of a solution having solid as
2. Among the following, that does not form an ideal solute and liquid as solvent is:
solution is:
(a) Directly proportional to mole fraction of
(a) C6 H 6 and C6 H 5CH 3 the solvent
(b) C2 H 5 Cland C6 H 5OH (b) Inversely proportional to mole fraction of
the solvent
(c) C6 H 5 Cland C6 H 5 Br
(c) Directly proportional to mole fraction of
(d) C2 H 5 Br and C2 H 5 I the solute
3. Which condition is not satisfied by an ideal solution? (d) Inversely proportional to mole fraction of
(a) H mixing 0 the solute
9. The relative lowering of the vapour pressure is
(b) V mixing 0 equal to the ratio between the number of
(a) Solute molecules and solvent molecules
(c) S mixing 0 (b) Solute molecules and the total molecules in
the solution
(d) Obeyance of Raoult’s law
(c) Solvent molecules and the total molecules
4. A mixture of liquid showing positive deviation in in the solution
Raoult’s law is (d) Solvent molecules and the total number of
(a) CH3 2 CO  C2 H5OH ions of the solute
10. The vapour pressure lowering caused by the
(b) CH3 2 CO  CHCl3 addition of 100 g of sucrose ( molecular mass = 342
(c) C2 H5 2 O  CHCl3 ) to 1000 g of water if the vapour pressure of pure
water at 25oC is 23.8 mm Hg
(d)
CH3 2 CO  C6 H5 NH2 (a) 1.25 mm Hg
5. Which of the following plots does not represent the (b) 0.125 mm Hg
behavior of an ideal binary liquid solution: (c) 1.15 mm Hg
(a) Plot of PA Versus XA ( mole fraction of A in (d) 00.12 mm Hg
liquid phase) is linear
(b) Plot of PB versus XB is linear
(c) Plot of ptotal versus XA (or XB) is linear Answers
(d) Plot of ptotal versus XA is non linear
1-c 2-b 3-c 4-a 5-d 6-d 7-a 8-a 9-b 10-
6. Azeotropic mixture are: b
(a) Mixture of two solids
(b) Those which boil at different temperatures
(c) Those which can be fractionally distilled
(d) Constant boiling mixtures
7. An azeotropic mixture of two liquids has b.p. lower than
either of them when it:
 CHEMISTRY
SOLUTION

SYMBOL OF EXCELLENCE

CLASS XII MARKS : 40 DATE: TIME: 10 MINS DPP-3

1
1. Which inorganic precipitate acts as semipermeable (c)  0.08205  273
membrane? 0.1
(a) Calcium sulphate 0.1 273
(b) Barium oxalate
(d) 
1 0.08205
(c) Nickel phosphate
8. The molal elevation constant for water is 0.56o K kg
(d) Copper ferrocyanide
mol-1. Calculate the boiling of the solution made by
2. In case of osmosis, solvent molecules move from dissolving 6.0 gm of urea in 200 gm of water
(a) Higher vapour pressure to lower vapour pressure
(b) Higher concentration to lower concentration (a) 100.28 C (b) 100 C
(c) Lower vapour pressure to higher vapour pressure (c) 0.28 C (d) 200.28 C
(d) Higher osmotic pressure to lower osmotic pressure 9. Osmotic pressure of 30 % solution of glucose is 1.20
3. An aqueous solution freezes at- atm and that of 3.42 % solution of cane sugar is 2.5 atm.
0.186 C  K f  1.86 ; Kb  0.512  . What is the The osmotic pressure of the mixture containing equal
volumes of the two solutions will be
elevation in boiling point? (a) 2.5 atm (b) 3.7 atm
(a) 0.186 (b) 0.512 (c) 1.85 atm (d) 1.3 atm.
10. Equal volume of 0.1 M urea and 0.1 M glucose are
0.512 mixed. The mixture will have:-
(c) (d) 0.0512
1.86 (a) Lower osmotic pressure
(b) Same osmotic pressure
4. A solution containing 500 g of a protein per litre is (c) Higher osmotic pressure
isotonic with a solution containing 3.42 g of sucrose per (d) None of these
litre. The molecular mass of protein is:
(a) 5 (b) 146 Answers
(c) 34200 (d) 50000
5. If the elevation in boiling point of a solution of 10 g of 1-d 2-a 3-d 4-d 5-b 6-b 7-a 8-a 9-c 10-
solute ( mol wt. = 100 ) in 100 g of water is  Tb , then b
the ebullioscopic constant of water is
(a) 100Tb (b) Tb
Tb
(c) (d) 10Tb
10
6. The temperature, at which the vapour pressure of a
liquid becomes equal to the atmospheric pressure is
known as
(a) Freezing point
(b) Boiling point
(c) Absolute temperature
(d) None of these
7. Osmotic pressure of a solution containing 0.1 mole of
solute per litre at 273 K is inatm
0.1
(a)  0.08205  273
1
(b) 0.1 1 8.314  273
 CHEMISTRY
SOLUTION

SYMBOL OF EXCELLENCE

CLASS XII MARKS : 40 DATE: TIME: 10 MINS DPP-4

1. Van’t Hoff factor is

6. The substance when dissolved in water would
(a) Less than one in case of dissociation
decrease the vapour pressure of water to the
(b) More than one in case of association
greatest extent is:
(c) Always less than one
(a) 0.1 MKCl (b) 0.1 M urea
(d) Less than one in case of association
(c) 0.1 M Ba Cl2 (d) 0.1 M NaCl
2. The experimental molecular weight of an
7. In which case van’t Hoff factor is maximum
electrolyte will always be less than its
(a) KCl, 50 % ionized
calculated value because the value of vant Hoff
(b) K2 SO4 40 % ionized
factor, ‘i' is:
(c) FeCl3, 30 % ionized
(a) Less than 1
(d) SnCl4, 20 % ionized
(b) Greater than 1
8. Which has the equal boiling point?
(c) One
i. 0.1 M Na2SO4
(d) Zero
ii. 0.1 M C6H12O6 (glucose)
3. The value of observed and calculated
iii. 0.1 M MgCl2
molecular weight of silver nitrate are 92.64 and
iv. 0.1 M Al(NO3)3
170 respectively. The degree of dissociation of
(a) i and ii
silver nitrate is:
(b) ii and iii
(a) 60 % (b) 83.5 %
(c) iii and iv
(c) 46.7 % (d) 60.23 % (d) none of these
9. Assuming each salt to be 90 % dissociated,
4. The freezing point of equimolal aqueous
which of the following will have highest
solution will be highest for:
boiling point?
(a) C6 H 5 NH 3Cl (b) Ca  NO3 2 (a) Decimolar Al2(SO4)3
(c) La  NO3  3 (d) C6 H12O6  Glu cos e  (b) Decimolar BaCl2
(c) Decimolar Na2SO4
5. Among 0.1 M solutions of urea, Na3PO4 and
(d) A solution obtained by mixing equal
Al2(SO4)3:
volumes of (b) and (c)
i. The vapour pressure and freezing point
10. The ratio of the value of any colligative
are the lowest for urea
property for KCl solution to that for sugar
ii. The vapour pressure and freezing point
solution is nearly……………….
are the highest for urea
(a) 1 (b) 0.5 (c) 2 (d) 2.5
iii. The elevation in boiling point is the
highest for Al2(SO4)3
iv. The depression in freezing point is the
Answers
highest for Al2(SO4)3
1-d 2-b 3-b 4-d 5-c 6-c 7-c 8-a 9-a 10-
(a) only i (b) ii and iii both c

(c) ii, iii and iv (d) i, ii ,iii and iv