GREEN PARK COACHING CENTRE

LONG TERM - CHEMISTRY WORKSHEET – 14

8. Redox reactions
(Balancing of Redox Reactions, n-factors, Law of Chemical equivalence)
Choose the correct answer :
1. If equal volume of reactants are used, then 7. In the balancing of the reaction,
number of moles of KMnO4 (moles per litre)
used in acidic medium required to completely
the stoichiometric coefficients of Cr2O7- , NO2-
oxidize 0.5M FeSO3 is
and H+ respectively are
1) 0.3 2) 0.1
1) 1, 3, 8 2) 1, 4, 8
3) 0.2 4) 0.4 3) 1, 3, 12 4) 1, 5, 12
2. How many litres of Cl2 at STP will be 8. For the redox reaction,
liberated by oxidation of NaCl with 10g
KMnO4?
the correct coefficients of the reactants for the
1) 3.54 L 2) 7.08 L balanced reaction are respectively
3) 1.77 L 4) 0.88 L
3. The number of moles of KMnO4 that will be
1) 2, 5, 16 2) 16, 3, 12
required to react with two moles of ferrous
3) 15, 16, 12 4) 2, 16, 5
oxalate is (Acidic medium)
9. In the following reaction.
6 2
1) 2) Fe3O4 + MnO 4 −  → Fe2O3 + MnO2 + OH −
5 5
The number of moles of OH- liberated as per
4 the balanced equation in the basic medium is
3) 4) 1
5 1) 1 2) 2
4. a Cr(OH)3 + b IO3− → c I- + d CrO24 − balance 3) 3 4) 4
2-
the ionic equation in alkaline medium and find 10. MnO4 (1 mole) in neutral aqueous medium
a, b, c and d in the order disproportionate to
1) 1, 1, 1, 1 2) 2, 2, 2, 2 2 1
1) mol of MnO4- and mol MnO2
3) 2, 1, 1, 2 4) 1, 2, 2, 1 3 3
1 2
5. In the reaction x HI + y HNO3 → NO + I2 + 2) mol of MnO4- and mol MnO2
3 3
H2O, upon balancing with whole number
coefficients 1 1
3) mol of Mn2O7 and mol MnO2
3 3
1) x =3, y = 2 2) x = 2, y = 3
2 1
3) x = 6, y = 2 4) x = 6, y = 1 4) mol of Mn2O7 and mol MnO2
3 3
6. MnOΘ Θ Θ
4 + Br + H 2O → MnO 2 + BrO3 + OH
Θ
11.
+
HNO3 oxidises NH4 ions into nitrogen and
itself gets reduced to NO2. The moles of
balanced reaction the coefficients MnOΘ
4, HNO3 required by 1 mole of (NH4)2SO4 is
BrO3Θ and OH Θ are respectively:- 1) 4 2) 5
3) 6 4) 2
1) 1, 1, 2 2) 2, 1, 4
3) 2, 1, 2 4) 1, 2, 2
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12. 0.11 g of sample of As2O3 (molar mass = 198) 19. When BrO3- ion reacts with Br- in acidic
required 36.1 ml of KMnO4 solution for its medium, Br2 is liberated. The equivalent mass
titration. The molarity of KMnO4 solution is of Br2in this reaction is
(Acidic medium) 5M 5M
1) 2)
1) 0.02 2) 0.04 8 3
3) 0.0123 4) 0.3 3M 4M
3) 4)
13. In the disproportionation reaction 3HClO3 → 5 6
HClO4 + Cl2 + 2O2 + H2O, the equivalent 20. For the given reaction
mass of oxidizing agent is (molar mass of H2 + O2 → H2O
HClO3 is 84.5)
Eq. wt. of O2 and H2O can be correctly given by
1) 16.9 2) 32.2
M O2 M H 2 O M O2 M H 2 O
3) 84.5 4) 28.2 1) , 2) ,
2 2 4 4
14. How many moles of KMnO4 is required to
oxidise one mole of ferrous sulphate in acidic M O2 M H 2 O M O2 M H 2 O
3) , 4) ,
medium? 4 2 2 4
1) 2/5 2) 5/2 21. The equivalent mass of IO −4 when it is
3) 1/5 4) 5 converted into I2 in acid medium is
15. An ion is reduced to the element when it M M
absorbs 6 x 1020 electrons. The number of 1) 2)
6 7
equivalents of the ion is
M M
1) 0.1 2) 0.01 3) 4)
5 4
3) 0.001 4) 0.0001
22. 0.3g of an oxalate salt was dissolved in 100ml
16. Equivalent mass of H3PO2 when it N
disproportionate into PH3 and H3PO3 is solution. The solution required 90ml of
20
M KMnO4 solution for complete oxidation. The
1) M 2)
2 % of oxalate ion in salt is
M 3M 1) 33% 2) 66%
3) 4)
4 4 3) 70% 4) 40%
17. In the following reactions, 23. The weight of sodium bromate required to
+ - 3- 2-
As2S3 + H + NO3 → NO + H2O + AsO4 +SO4 prepare 55.5 ml of 0.672N solution for
The equivalent mass of As2S3 is related to its reaction
molecular mass by BrO3− +6H+ + 6e- → Br- + 3H2O is
M M 1) 1.56 g 2) 0.94 g
1) 2)
2 4 3) 1.23 g 4) 1.32 g
M M 24. 10ml of a solution containing Fe2+ and Fe3+
3) 4)
24 28 required 10ml of 0.1N KMnO4 for the end
-3
18. 6 x 10 mole K2Cr2O7 reacts completely with point during the titration acidic medium. The
9 x 10-3 mole Xn+ to give XO3- and Cr3+. The amount of Fe2+ in the solution is (At wt of Fe :
value of ‘n’ 56)
1) 1 2) 2 1) 0.056 g 2) 0.028 g
3) 3 4) None 3) 0.018 g 4) 0.28 g
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25. 10 ml of a Mohr’s salt solution required 10 ml 29. The number of moles of KMnO4 that will be
of a 0.1N K2Cr2O7 for complete oxidation. needed to react completely with one mole of
The amount of Mohr’s salt in 100 ml of the Fe2(C2O4)3 in acidic solution is
solution is 1) 5 2) 6
1) 39.2 g 2) 3.92 g 6 3
3) 4)
3) 5.16 g 4) 55.6 g 5 5
26. A solution containing 2.7 x 10-3 mol of A2+ M
ions required 1.6 x 10-3 mole of MnO4- for the 30. A solution of 10ml FeSO4 was titrated with
10
oxidation of A2+ to AO3- the medium used is KMnO4 solution in acidic medium. The
1) neutral 2) acidic amount of KMnO4 used will be
3) strong basic 4) none of these 1) 10ml of 0.02M 2) 10ml of 1.1M
27. A 3.4 g sample of H2O2 solution containing 3) 10ml of 0.5M 4) 5ml of 0.1M
x% H2O2 by mass requires x mL of a KMnO4
solution for complete oxidation under acidic
conditions. The molarity of KMnO4 solution is
1) 1 2) 0.5
3) 0.4 4) 0.2
28. Ratio of moles of Fe(II) oxidized by equal
volumes of equimolar KMnO4 and K2Cr2O7
solutions in acidic medium will be
1) 5 : 3 2) 1 : 1
3) 1 : 2 4) 5 : 6