Test ID : 521

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.WEEKEND TEST - 1.
Std : Long Term (Batch – A) Max. Marks: 180
Test Date : 11.02.2021 CHEMISTRY Time : 1 Hr.
Note :
For every correct answer four marks will be awarded. For every wrong answer one mark
will be reduced. For unanswered questions zero mark.
Choose the correct answer : 45 x 4 = 180
1. Which of the following group 15 element(s) 6. Which gas is evolved when urea is treated
is/are non-metal(s) in elemental state? with water?
1) As only 2) P only 1) Nitrogen 2) Ammonia
3) Sb only 4) Both P and As 3) Nitric oxide 4) Laughing gas
2. Moscovium is a synthetic radioactive element,
7. Which of the following is/are neutral oxides?
which of the following is correct electronic
1) N2O 2) NO2
configuration of Moscovium
1) [Xe] 4f145d106s26p3 3) Both (1) and (3) 4) N2O5
14 10 2 2
2) [Xe] 4f 5d 6s 6p 8. Which gas is evolved when ammonium

3) [Rn] 5f146d107s27p3 chloride treated with calcium hydroxide?

4) [Rn] 5f146d107s27p2 1) Nitrogen 2) Ammonia
3. Maximum covalency of Nitrogen is 3) Nitrous oxide 4) Nitric oxide
1) 3 2) 4 9. Which of the following has the highest pπ-pπ
3) 2 4) 1 bonding tendency with itself?
4. Which of the following statement is not 1) N 2) P
correct for Nitrogen in 15th group?
3) As 4) Sb
1) Its electronegativity is very high
10. Which of the following has the lowest boiling
2) d-orbitals are available for bonding
point?
3) It’s a typical non-metal
4) Its size is small 1) NH3 2) PH3
5. Which of the following statement(s) is/are 3) AsH3 4) SbH3
correct? 11. The correct order of basic strength is
1) N-N bond is weaker than P-P bond 1) AsH3 > SbH3 > PH3 > NH3
2) Interelectronic repulsions between non- 2) SbH3 > AsH3 > PH3 > NH3
bonding electrons are higher in N-N than
3) NH3 > PH3 > AsH3 > SbH3
P-P only
4) PH3 > AsH3 > SbH3 > NH3
3) Both (1) and (2) are correct
4) N≡N bond is weaker than P-P bond
 2 Test ID : 521
12. Which of the following gas is evolved on 20. Copper on reaction with dilute HNO3 gives X
thermal decomposition of ammonium and Zn on reaction with concentrated HNO3
dichromate? gives Y
1) NH3 2) N2 1) X = NO2, Y = NO 2) X = N2O, Y = NO
3) N2O 4) NO2 3) X = NO, Y = NO2 4) X = N2O, Y= NO2
13. The shape of ammonia molecule is 21. Which of the following is the correct order of
1) Tetrahedral reactivity of allotropes of phosphorus?
2) Pyramidal 1) white > red > black
3) Planar triangle 2) red > white > black
4) Trigonal bipyramidal 3) black > red > white
14. Of the following hydrides which is the 4) red > black > white
strongest reducing agent?
22. Pure phosphine is not combustible while
1) PH3 2) AsH3
impure phosphine is combustible, this
3) BiH3 4) NH3 combustibility is due to the presence of
15. The brown ring test for nitrate ion is due to the 1) P2H4 2) N2
formation of complex ion with the formula is
3) PH5 4) P2O5
1) [Fe(H2O)6]+2 2) [Fe(NO)(CN)5]+2
23. PCl3 reacts with water to form
3) [Fe(H2O)5NO]+2 4) [Fe(H2O)5NO]+3
1) PH3 2) H3PO4
16. Ammonium nitrate on thermal decomposition
3) POCl3 4) H3PO3
produces
1) N2O 2) NO 24. The number of hydrogen atom(s) attached to
phosphorus atom in hypophosphorus acid is
3) NO2 4) NH3
1) three 2) one
17. The catalyst used in the manufacture of HNO3
by Ostwald’s process is 3) two 4) zero
1) Platinum gauze 25. Ortho phosphorus acid on heating produces
2) V2O5 1) H3PO4 and PH3 2) H3PO2, PH3
3) Finely divided Nickel 3) H3PO2 and H3PO4 4) H4P2O7
4) Finely divided Iron 26. Electron affinity of sulphur is
18. Which of the following are acidic oxides? 1) more than O and Se
1) N2O3 2) P2O3 2) more than O but less than Se
3) Both (1) and (2) 4) As2O3 3) less than O but more than Se
19. Nitrogen oxide(s) that contains N-N bond(s) 4) equal to O and Se
is/are 27. Which of the following hydride is most
a) N2O b) N2O3 acidic?
c) N2O4 d) N2O5 1) H2O 2) H2S
1) a, c, d 2) c, d 3) H2Se 4) H2Te
3) a, b, c 4) all
 3 Test ID : 521
28. Oxygen molecule is 36. Which of the following product is formed by
1) diamagnetic with odd no. of electron(s) the reaction of sulphur dioxide with chlorine
2) diamagnetic with even no. of electron(s) in presence of charcoal?
3) paramagnetic with odd no. of electron(s) 1) SO2Cl 2) SO2Cl2
4) paramagnetic with even no. of electron(s) 3) SOCl2 4) SO3Cl
29. Which of the following is an acidic oxide? 37. Which of the following has the largest bond
1) Mn2O7 2) Na2O angle?
3) N2O 4) BaO 1) H2O 2) H2S
30. What is X in the following reaction? 3) H2Se 4) H2Te
X
2SO2(g) + O2(g)  → 2SO3(g) 38. Assertion : Sulphur exhibits paramagnetic
1) V2O5 2) CuO behaviour in vapour state.
3) CuCl2 4) MnO2 Reason : In vapour state sulphur partly exist
31. Which of the following oxoacid of sulphur has as S2 molecule which has two unpaired
O-O bond? electrons in antibonding π* orbitals.
1) H2S2O7 2) H2S2O5 1) Both Assertion and Reason are true and
3) H2S2O6 4) H2S2O8 Reason is the correct explanation of
32. Sucrose on reaction with concentrated H2SO4 Assertion
produces 2) Both Assertion and Reason are true but
1) carbon and water Reason is not correct explanation of
2) CO2 and water Assertion
3) glucose and water 3) Assertion is true, Reason is false
4) glucose and fructose 4) Assertion is false, Reason is true
33. In Lewis structure of SO2, number of bonds 39. S-S bond is not present in which of the
are following structures?
1) two σ and two π 2) two σ and one π 1) H2S2O4 2) H2S2O5
3) two σ and three π 4) two σ 3) H2S2O3 4) H2S2O7
34. In the reaction 40. Which of the following is/are correct
O3 + 2I− + H2O → 2OH− + X + O2 statement(s)?
The compound (X) is a) Conversion of O2 to O3 is exothermic
1) I2 2) IO3− b) Se2Cl2 can undergo disproportionation
3) IO4− 4) I2O5 c) O-O bonds in ozone are identical
35. Sulphur on oxidation with hot sulphuric acid 1) only a
gives 2) only a and b
1) SO3 2) SO2 3) only b and c
3) H2SO3 4) H2S2O3 4) all
 4 Test ID : 521
41. The oxidation states of sulphur in anions 44. On reaction of moist SO2 with potassium
SO3−2, S2O4−2 and S2O6−2 follows the permanganate in acidic medium, which is
1) S2O6−2 < S2O4−2 < SO3−2 correctly observed?
2) S2O4−2 < SO3−2 < S2O6−2 1) colour of KMnO4 is decolourised
2) SO2 is oxidized to SO3
3) SO3−2 < S2O4−2 < S2O6−2
3) MnO4− is reduced to MnO2
4) S2O4−2 < S2O6−2 < SO3−2
4) All of these
42. Formic acid on reaction with con. H2SO4 at
high temperature to give 45. Which of the following conditions are needed
in the manufacture of H2SO4 by contact’s
1) CO 2) C
process?
3) CO and CO2 4) C2H4O4
1) High temperature, High pressure
43. When Cu is reacted with hot concentrated
2) High temperature, Low pressure
solution of H2SO4 then the gas obtained is
3) Low temperature, Low pressure
1) O2 2) H2
4) Low temperature, High pressure
3) SO2 4) SO3

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