eg

2 .

Drop impact ( impregnation pressure)

주입

[ e
~~
"
N Dp ~ prrser
는
자
r

eg 3 .

Submerged surface ( under water )

↓
Jo oghrer
n
로op -

ghrer > become wenzel

stater

chemical 씨 hefrogeneous surface

- Q IX
,
.
randfi
↓ 수 "1
CX

.
:
fa areafraction

.
*

original surface
. . .
o. .

areo area
fz. coated surface
dE =f , (dsc -Dsv ,d 사Fr(DsuDwlzdxt
rcosoo ) -

dE ocin
=

equil : brium state )

Coso+= ficos θ tf cos ⑨ =)

*
2

coating 을 조절가능통해
θ

Contact line pinning at corners

possible rangeㅇQe 8
of angles d:o
I ㅡ
"
σ
ranye 존재 a finite range of contact anyles can arise at cornert
ㅡ. N "
n

사
11
atcorners De 1
, ⇒
AdVancing Contact line wil 1 be corners
I
" at
" De
" 1

A) 모두가는
ㄱ -
ilmoving
0

,
,

( roughmeslimpurifi . hysteresis 발생
는
)

/ I
P Oe 표면의
" 모세관
fcontact angle histeresis
.

ENPerimental observation
observe (. hysteresis )
angle
0

* is nof frue

무… 시스야비
.OA
… " "
For a
given solid , liquidi a static contact angle θs
"
has
,

possible range
ㅡ

"

남니다
a

pumping : on

Or < OsKOa
더 ( ) aduancing contact angle
he ㅍ static
angle
angleequilibrium
Stati receding
( )
서nerimentally observed
contalt angle static

* or ( oun
θ < e ( osFoe always )

* static contact
angle
measured for Static contact line ←7
dynamic contact angle
measuredfor moving
contact ine
* contact
angle hysteresis describes
Do =θa or -

"

Origin of hysteresis of contact angle

Impurities on d substrate Cause locadlPinning andresist the Contact line rotions

ffontate 융촌크희
~

LE
켓출표나와
매 "
o아
aly pinning

orough guidelinee
very dean Surface DO ~ 50

normal surface DO ~ 200 400

-

rough dirfy surfaie

,
DD 2500
.
menifestafions of Contact
dngle hysteresis
-
1:
quid column frapped n capi11 any Tube a θ z can be as large as advancing contact angle
Oa and θ Can be as small as receding
,
, contact angle θ r In.

general ,
θ 2 > Dl 9 so thereas

capillary
colunassociated
a nef alailabletorce
Weight to Suppont the af the Liqu : d

) withr

170
12

M 개품
.%
-
6030 6010 ) 00 째
R라 (

contact
~

ineforce
. -

gRH themaximum,
weight
weight that canbe supported
0
Cos - CosO = -

25
by contact ine force gRH = cosr - CosO
259 의

Rain drops Window glass

-

on

/ :I
.이 " a droplef can be adhesive on a Window glass against gravity
C1
. 3

FgNeR g , FcNR5 ( coso -

Cos θ . ) ,
Rmax 2 = .
⇒ Fg 스 FC

Rmax Z
tey - cosOr
: (
:
)]
.

- cosoa
r

the of force
magnitude the contactline due the angle hysteresis
.
on to coutact

fresk저항힘
dir

oeiauidr
→ 는 → rcosD -

fres fso = -

fsL

. fres f(cosD Cosoe )

~
… ) = -

등 강
.. s
.화

> rcose= 6
.- .
..