Sor The: TS Laws Tels Conservation a tne DrTaing by DQM n + Temphign tow {reins ativees® of Hert) AG = — sar tvap +E pldue oT ¢ FT sy 3 ab exbsolute Zero temp: the en hePy oh Yhe any Component wht be at bs mtn- Nevlare . fealty eff pride creas gow PS p atercce ton ° “T2p potential > UW, hy Gra Srp Reputavon. 7P ‘rears Lak C00 gpd uh , Pa Mer at ie Ca ‘i a HY dep s — SAL +Nap +S puidre Ba ow A ‘ewe Bor deed Cras 4 [Sothermat Concll Totat energy ve. E> y 6 ¥ Hembelte Pre energy Maxe anafleble wok A= UNG SI) Heet vecleved by the ays % Pore foree energy Cor) Max aveiPaie lest fud wm tmatpy CH) Cmax. work ) > A= UPN? woo done lay the AY for it existence. (A @URY) wee arin be esd 1 - Bison gurromate! Gab tanec Re” Bw F% ae fer > += $P o b= Fy Ge= HoT. © das)’ THER in caetch, fancitn, Max: aval) oka lable Omer 908k. via Boba wintans chenfTable ® Reversible proceas—> ew [Afae a2) [FST] % breversi ble Process > [ASzE} Con Qa ¥ Total vor” or Total molar Yelm \/ NE Sp vom = mL, Tet mas Motax Vor = NE av ye Ste. States State % tonic - benaves Ldeallg-—» <> P iv pot [# pat? spre f+ Brite f | duc te motecelae pater. = fe laced + + etter of Temp on Fugees ty & sete aroun Fi OT Rre aes é fo effeeh pos pager lke. 3 EE Ney ay apt ar we Cateatarfon rp fogeatty, (Resgesd ns 0) Compress fbittg frerer @damc y CL (TA Hy ty ha) = mele vol™ oh reat ges LP we & g fetare Mate * taea ni. Smeteret tamobece 8 | pol ily) =e ene oir dat = - star +Nap + = hidhi On: 7 = four is (Ba° TiPinegt a ay udtey ReeP qual Voir DS Mole VaiM of veAy tas | HSE Doha _ deat gus a”% fer sto state p?»0 wD Py ust e yp Lente Jon (F/p°) = (HH) TOs) RT + tnlSlp)- fie 7: ZP) repulsion . Tor pte Ges Zé! attsauten domi nates ae Feo Vancler waat og” gf state ~ ? (P+4. )lv-b= RT cee oo a) yea + coitena of Prase eqn” * JAH G)= 9] THE He bom Ed phases are Same Jos Chrne pot cto Sarme. ' Mf Poa mn, oe agit Panthas molar Properties = Moles preperiits C1) preps Pare Compone Ve pv Per Unt + vot mole > Hal melas prepertiza > measare the Cents bution ef that Compment dn pe totad moler Pmp ag tek olix. nti? anioterr PUPS ( pure Com ponent) dortes ayvts 4 & douge FZ, totat melay prp. Je in Feb ne |) ee ee eee ae es, Tr at Ideas ges Parkas | my, = rm ,: Tat PYP= Tore pap | parte _ | amt ie | oo nt) TP, myAy a melee pap atoty Bb uny oily: i Es Ga) ae Ne fe Col tutation of Pevrthos Prep ae Phy Fee Me Hye a) ee m+ (1-%)) Om | ox, BmPlarly- 11 7G din He Uluka c9y2d m= m—x,a0 nas On, en = mi seogpam Dy b Pagatg of Lequids 4 Lolfes > ee rane "| sey 9 Pye a fps Mr @VLE 1D ak Lew pr py lew boro eee # ie a ep Jevs p™ & pee a Qpowr'l\ da the vapour P ue ator ath o> Verpour ri aatunatton, ph ave = Antes, > perefat molar vorrlis) ap Ajon ph > sto h heyuid A at é}o- cata a Some mp. Netatton + Tetot molar prvp: gm Tele, preps ock, Mix ae 1 Gy Se the P pentres moles prop. of | mix = m1, P2 at High pr PO ep) piviauny ey Ain of ymca sur (Pear )* gout a tes det Spd eu A fagochrg of soutt > JF FT] ah re $ > tegatny O =F pro Activity > a= FT i - cate Pater [EZ PRE Rayo efferefve loner coe @ iw tare fod? & asi) * crt 2 (Gy Melee Pteap- oa cae yt crc = RT In(41¢0) wom a 4 (r-G? = RTIna. Mo mM-% er ° effet porary Mea = = % 2 = Vopape PP) ee Rr ae be Ge Gx) 2 ps Vey effet of Temp- # effect st Temps p-conat o ° aa 9 nas HH pre oa aH ana ears: i hr Pend T ieee ae RT Ph, | pe efter Peat he: * Cotewtatton of ach hog a > pie Wy . : de, 24M OR RD 7? wy Notation. + ChenP cat potenrtias 3() + feqety oe + partial derivative of sofat = Fugal of 0 om the sof? ff molar prepa fe act ET ro: gene og rari ff oh motel Bred “ts tre partios Molar property © ” vow SAD? State fF i. aD rae eG Thee fs we tom Lbke paretlas fe = Ste pee ' OL tatol pteop tn fugadtry.. G> partias devivatiue of TD de fagetty pt t tie 40109 pene a ee ee | asset eG, de glee % | kK olG, = RT ALF %| eo egatit bf eC bn wet fore iy wh _h Ren by woul bows 5 fe = phy AY NLE the fugaitty of Pin the ees €0l PS eal ty He © Par Hat Proof & , Te Fagaliy of pure fo equas to vapour pr @ Loio wep. pr . 1 Ee Lv = er a stor Tatecs Saunas E es ol Bre ore BP = xt Pata gor leat £01 @viE A Conte goi, “ge Hops Lane Henseg tome fon tae ge he estat, Franek 4, = Bos otvie = BF Si oxen] ene vail foe dP lubect fetear 15° £01 H fugadiry of C to (deaf fol ¥ ahiy otic tne pone ews Randell Rute, > ope 2 Fagauty pine G fo le? Fug of 8 tm toleat dol? «Cie Bod mate Priston 4 C &, Gps “Ost ani: Fi ctep a] Fi = Fi , faa Rofo on > te pal) Gy Fe Coble 5 = tf ee er be( $2) A if 4019 4 A £ wee ae je -Ms RT a?8) Selection of stp: state. fen crasee + —Te pure component of gat fa LAF Leleat Atctr at bot: ¢cnemleat equlltis! ft tr ae “Me pure Component gas at 2yx pr a ae = #- 2 ft Tapoxe ; For i dest sof. aly for Nene deat gay? atiivlty coneff. 3 nnen fot zee, fe -Yerar d L NaaPeecte “dearer for eg" Peas alee etenitty. Yih a, © efece ch temp 4 pr on aunty ey. crop: A pi acini (Dp. © 3 dn (trnt) = fact, Pe Coner Hy- Hr — for pe &- Lubgion O47” bY = @EmeeLS ) . @ [at 2[6 8-072] Inj = Zh Let a[m B-e]e,) 2 Vrew Rr al x44 (¥) X 2L% eerie ) 264, re et. molar YoI™ J Onp- ALS usonlU Com Ant, = [A+2(8-) 2] In, = @[ B+a(n-a)ay] | * Maryulels 6 > [h=%, 244s \ | ey eee ieee | 24. Sy | Phebe =a, | Azo | Ant = Ba AnYy, = Ze “OZ cujpin en used DD *epretont tm NILE elota of Kys, 1Plee Lutons L methoul , ete Qtupmr wepresen's Aufigenty + Aecxokely the aehelry Coetl. Oh dupe Ayust Me. wohae oe Ader fH aPee, Veun= aur. ea cas 4B Inj, = Ze pany, = The Ze KR % ( I $25: i oe Fp: t rule) agra) Az Soy fig Dy Dn! WO Stes, be Deth [ir Cebus V2 ¥ as i reel ay) eh cf a effectPee of? Peescsttiog ; (om penn tn Ath :Tibbs DunemM Ee rs USeel to Zs Wyo ny Culentectt act Ponal molar Paste yf Of eet Aol. bho yer isay ee v, ; Pe | ig d,0, 0 fe ntiet RE SAE | lettin, jee ue ee | ” yer FF 4) QA+b®— co+ap abe? - 0,0 io 02 B+ ChB ALO CAAD =o i a “ites + oh Abuse, etme ber Coty 4f yeutony e et, b Eve ; ome tap Oey Anp = Vy i Extent of Feit te eet : AKL, oR 1” me § eos Mae =p Sang Conte terra merase eh WP = Nin + WS, lot ° a ‘Ant Het mel ae re pes mobs 5 At axeotrt® oe aoe we de yn = Mot VT, si 4 coey eyed : Lois The Apeia() mole eh ne 4 Jotet moles Sh mix a ole ane = ig ne Mie + YY - ; f ; dy” ape aut vy eke fein weg ptnn ot. : i (> ; Copmtes-199 @) : oy oh (%) ( Pear) ao LWitfap te — ffnod mols ‘ afmeley i ae gy P THEA te 4 "tee (Fat) MetExcess properry @® ME= actual prep Step d. Ideal wh 40h e gtm — ee ust temp AP 4 ap ra Basically urd to Coteutate | achat pep qd Sef = Sr ce 2 Sey} 3 RT ra s RAS tee ve 8 Pibeny = —naeati iS . , , I=. © A Chany = WRT SO dno} ae | AGmig = AB ig +RT E xy bot 2 | Atti, = 2 NeNeiv = 9 on. Festi »AGro, Kt, ott © a eoo a a T opt effets Pe-ve PA, dager | Gwen TT Woe, Bete ce Residual prep: > Me Me md Gf. Galt Na v- vig wide v= =RT/p ee vf = reg} Me Dy ple HR = TRS), Jae terler) f[t- eft Ateule He Equation Ndi 24" for seal gos = [P&)o-w= ar te 4, Corvenia 4 KY ——— A pe fr - a a= SHEE ye RT 64 Pe 8 ho ke Tx Net glen rere DXophes mir Hm? Gey om jr k to Wolepenoturt om PTHK, P- kK Key Terms Be Tite sfermty) , Boglels hans + aoe | mela vel | aT fe Te ; nity | P # oP A asked (activity Castles no @ Pp Aateine ae Inpete A- Ce-€tt) Thin by modified Roultls 2. Chacebsls (ae ae eviticat point = thgher t Tlenp an above A preys: above whith oa Liq: cle Comlt exiat. Fe Compremor woostk done > e Latent hear of fusion > Stagle Stage pyM=C “km of Rent absnrbed dairy 2, (Ps meLti pore Lexs. ae nfo [Ge 14] | Hear of Vapeuridattn Amt: ¢ test absorred duh A= foe Compress ion natiO veg eee Fi [ee j= 81 | | : ae oo A MLA Ege co + Saturated Liq + Liquid ushich b Syne TAR | 2qm wate Gn mom Nmprur & cea (+ 7) Apshd TAP [Aame ov L Put Im above 29% [+f Saturated Napeur J, thse TAP Cprd sak Teng po Comat Temp 2 pt A Bat ples. og uy es Ey, Atak. + Super heated vapour %y vepous ex ating at +temp- above are paid?” Tour QP a Thee temp diveharg, Teiple point > AU tnece phous of Atmpe are conesier fa qh Y Tee Jamiahie Arpurd