SCH4U Final Exam 2024 /50

Multiple Choice [15 Marks]

Identify the choice that best completes the statement or answers the question.

____ 1.

The correct name for the compound given above is which of the following?
a. 2-methyl-1-butene d. 3-methyl-2-butene
b. pentene e. 2-ethyl-1-pentene
c. 2-ethyl-1-propene

____2. What results when a secondary alcohol is oxidized?

a. a ketone d. an acid
b. an amine e. no reaction
c. an aldehyde

____ 3. 2-methyl-4-ethyl-3,3-dicyclopropyl-1-hexene is the correct name for which of the following?

a. c.

b. d.

____ 4. Esters are

a. found in some medicines d. found in some types of flavorings
b. often fragrant e. all of the above
c. essential oils in fruits and flower

____ 5. Which of the following compounds is a secondary alcohol?

a. 1-pentanol c. 2-pentanone
b. 2-pentanol d. 2-methyl-2-butanol

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 ____ 6. Which of the following bonds is likely to exhibit the greatest ionic character?
a. H-F d. Cl-Cl
b. F-F e. Cl-F
c. H-Cl

____ 7. Which forces exist between methane, CH4 particles?

I. Van der Waals
II. metallic bonding
III. hydrogen bonding
IV. dipole
a. I only d. I, III and IV only
b. I and IV only e. I, II and III only
c. I and II only

____ 8. When solid NaOH is dissolved in water the temperature of the water rises. This system has which of the
following?
a. increased entropy and decreased enthalpy
b. decreased entropy and increased enthalpy
c. increased both entropy and enthalpy
d. decreased both entropy and enthalpy
e. none of the above are true

____ 9. What type of substance is graphite?

a. ionic d. metallic
b. molecular e. none of the above
c. covalent network

____10. Which of the following reactions is exothermic?

a. H2(g) + 1/2 O2(g) → H2O(g) ςH = –243 kJ/mol
b. 1/2 N2(g) + 1/2 O2(g) + 90.7 kJ → NO(g)
c. CO(g) + 111 kJ→ C(s) + 1/2 O2(g)
d. 1/2 H2(g) + 1/2 I2(g) → HI(g) ςH = +26 kJ/mol
e. H2O(g) →H2(g) + 1/2 O2(g) – ςH = –243 kJ/mol

____ 11. For which one of the following substances is the standard enthalpy of formation, ΔHf, equal to zero?
a. water [H2O(l)] d. carbon dioxide [CO2(g)]
b. lead [Pb(s)] e. tin [Sn(g)]
c. carbon dioxide [CO2(s)]

____12. If for the reaction , the rate law is determined to be , then

a. doubling the concentration of Y will double the rate of the reaction
b. halving the concentration of Y will double the rate of the reaction
c. doubling the concentration of X will double the rate of the reaction

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 d. halving the concentration of X will double the rate of the reaction
e. only changes to the concentration of Y will affect the rate of the reaction

____ 13. The theoretical effect of a catalyst can be explained in terms of collision theory because it affects
I. the collision geometry involved in the reaction
II. the total number of collisions that occur
III. the fraction of collisions that are effective
IV. the required activation energy for a reaction
a. both I and IV d. both III and IV
b. I, II and III are true e. II only
c. both II and III

____14. Based on the heat of formation of MgO, how much energy is required to decompose 48.6 g of MgO?
a. 603 kJ d. 60.3 kJ
b. 725 kJ e. 1504 kJ
c. 301 kJ

____ 15. The oxidation number of in is

a. +1 d. +4
b. +2 e. 0
c. +3

Short Answer [35 Marks]

1. Write the reaction showing how the ester. [3]

,
can be prepared from carboxylic acid and alcohol. Provide the names of all reactants below your equation.

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 2. Write the electron configuration for Scandium, Sc. [2]

3. Draw Lewis (electron-dot) diagrams for each of the following molecules and predict:
(i) the molecular & geometric shape of each molecule by drawing VSEPR structures. [6]
(ii) whether the molecule is polar or no polar.
a) SF2

b) PF3

4. What is the oxidation number of Cl in ? [2]

5. Iron(III) oxide reacts with carbon monoxide to produce elemental iron and carbon dioxide. [5 Marks]

Fe2O3(s) + 3CO(g) → 3CO2 (g) + 2Fe(s)

a) Determine the enthalpy change of this reaction, using known enthalpies of formation. [3]

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 b) State whether this reaction is endothermic or exothermic and draw and label an enthalpy diagram.[2]

6. The initial rate of the reaction: 2I-(aq) + S2O82-(aq) 🡪 I2 (aq) + 2SO42-(aq)

has been measured at the reactant concentrations shown (in mol/L) [7 Maks]

Experiment [I-] [S2O82-] Initial rate (mol/(L·s))

1 0.04 0.04 6.25 x 10-6
2 0.08 0.04 1.25 x 10-5
3 0.04 0.08 1.25 x 10-5

(a) Calculate order of this reaction w.r.t. both reactants and the overall order of reaction.[3]

(b) According to these results, what is the rate law for this reaction? [2]

(c) What is the value of the rate constant? [2]

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 7. Consider the following organic molecules: [8 Marks]

A) Butanone B) 3-methyl-3-pentanol C) 1,3-diethyl 1-pentene

i. Draw all three organic molecules. [3]

ii. Which molecule would you expect to have the highest boiling point? [2]
iii. Which molecule would undergo an addition reaction with H2O? Draw the product that is formed and
state its IUPAC name. [3]

8. The element iodine exists as solid crystals composed of I2 molecules. A chemist wishing to dissolve
iodine has a choice of two solvents; water and tetrachloromethane. Which of these two solvents would be the
best choice? Explain your answer. [2]

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