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wOHhk fmdÿ iy;sl m;% ^Wiia fm<& úNd.h" 2023 ^2024 ckjdß&
General Certificate of Education (Adv. Level) Examination, 2023 (2024 January)

ridhk úoHdj I meh 2

Chemistry I 2 Hours

ie,lsh hq;=hs
} fuu m% Yak m;%h msgq 10 lska hqla; fõ. (wdj¾;s;d j.=j la imhd we;.)
} ish¨ u m%Yak j,g W;a;r imhkak.
} .Kl hka;% Ndú;hg bv fokq fkd,efí'
} W;a;r m;%fha kshñ; ia:dkfha Tfí úNd. wxlh ,shkak'
} W;a;r m;%fha msgqmi § we;s wfkla Wmfoia o ie,ls,u s ;a j lshjkak'
} 1 isg 50 f;la jQ tla tla m%Yakh ioyd (1), (2), (3), (4), (5) hk ms<s;=rej,ska ksjerÈ fyda b;du;a .e<fmk ms<;
s =r
f;dardf.k" th W;a;r m;%fha msgqmi ±lafjk Wmfoia mßÈ l;srhla (×) fhdod olajkak'

id¾j;% jdhq ksh;h" R = 8.314 J K-1 mol-1

wej.dâfrda ksh;h" NA = 6.022 × 1023 mol-1
ma,dkalf
a .a ksh;h" h = 6.626 × 10-34 J s

01. my; ±lafjk mÍCIK $ fidhd.ekSï yd iïnkaO úoHd{hka ms<sfj<ska we;=<;a jrKh f;darkak'
(A) mrudKqljdoh bÈßm;a lsÍ u' (C) bf,lafg%dakfha wdfrdamKh .Kkh lsÍu'
(B) Ok lsrK fidhd .ekSu (D) bf,lafg%dakfha e/m wkqmd;h .Kkh lsÍu'
(1) fcdaka fvda,agka" ú,shï lDDlaia" ñ,slka" ro¾*â
(2) fcdaka fvda,agka" ú,shï lDDlaia" uhsl,a *erfâ" f;dïika
(3) fcdaka fvda,agka" f.da,aâiaghska" ñ,slka" ro¾*â
(4) fcdaka fvda,agka" ú,shï lDDlaia" ñ,slka" ro¾*â
(5) fcdaka fvda,agka" f.da,aâiaghska" ñ,slka" f;dïika

02. my; ±la fjk m%ldY w;ßka l=ula wi;H fõo@

(1) N3- wekdhkfha wrh O2- wekdhkfha wrhg jvd úYd, fõ'
(2) iEu uQ,øjH wekdhkhlgu ns2 np6 WÉp jdhq úkHdih mj;S'
(3) we;eï uQ,øjH legdhk j,g WÉp jdhq úkHdih fkdmj;S'
(4) wdj¾;s;d j.=fõ ;=kajk wdj¾;h Tiafia ol=Kg hdfï§ uQ ,øjHj, Wmßu TlaislrK wxlh l%ufhka jeäfõ'
(5) 16 ldKavfha my<g +4 TlaislrK wjia:dj jvd ia:dhS fõ'

03. fuys oelafjk khs gu

% hs â wKqj ms<sn|j § we;s m%ldY i,lkak' fuys iels,a, my; wdldr fõ'

(A) N1 yd N2 hk khsg%c ka mrudKq ms< sfj,ska sp2 iy sp2 uqyqïlrKhg Ndckh ù we;'
(B) N2 hk khsg%cka mrudKqj u; odhl iy iyixhqc hk nkaOk foj¾.hu we;'
(C) ¨úia jHqyfha ish¨u mrudKq u; we;s uq¿ tlir hq .,a ixLHdj 6 ls'
(D) wKqfõ yevh N1 mrudKqj jgd p;=ia;,Sh jk w;r N2 mrudKqj jgd ;s%fldaKdldr msr ñãh fõ' by;
tajdhska l=uk m%ldYh $ m%ldY i;H fõo@
(1) A muKs' (2) A, B yd D muKs' (3) B yd C muKs'
(4) B, C yd D muKs' (5) D muKs'

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04. tlu f,dayfhka iEÿk f,day Tlaihs v foll Tlaiscka ialkaO m%;sY; ms<sfj,ska 27.6% yd 30.0% fõ' m<uq
Tlaihsvfha iQ;%h M3O4 kï wfkla Tlaihsvfha iQ;%h jkafka" (O = 16)
(1) MO (2) M2O3 (3) MO2 (4) M2O (5) M3O2

05. hk ixfhda.fha IUPAC kduh ñka l=ula o@

(1) 2-bromo-3-formylhex-5-eneamide (2) 1-bromo-2-formylpent-4-enamide

(3) 2-bromo-3-formylhex-5-enamide (4) 2-bromo-3-formylhexene-5-amide
(5) 5-bromo-4-formylhex-1-enamide

06. NaOH yd Mg(OH)2 ñY%Khlska 2g la f.k 100cm3 l ødjKhla ms<sfh< lrk ,§' Mg(OH)2 j,ska fldgila muKla
Èh jQ w;r Wvq .sh ødjKfha Mg2+ idkaøKh 5×10-3 moldm-3 úh' Mg(OH)2 ys Ksp=1.8×10-5 mol3dm-9 kï
ñY%Kfha NaOH ys ialkaO m%;sY;h fldmuK o@ (H=1 , O=16 , Na=23 , Mg=24)
(1) 12% (2) 10% (3) 11% (4) 1% (5) 2%

07. my; m%;sl%shd wkql%uh i,lkak'

A, B yd C ksjerÈj ms<sfj,ska ±lafjk ms<s;=r l=u lao@

(1) (2)

(3) (4)

(5)

08. NaOH idkaøKh 40 ppm jQ ødjKhl 40 cm3 la yd KOH ys idkaøKh 56 ppm jQ ødjKhl 60 cm3 la ñY%lr
,efnk ødjKfha 20cm3 la iu. m%;sls%hd ùug H2SO4 ødjKhlska 50 cm3 la jeh úh' H2SO4 ødjKfha idkaøKh
jkafka" (Na=23 , K=39 , H=1 , O=16 , S=32)
(1) 392 ppm (2) 0.01 moldm-3 (3) 0.4 moldm-3 (4) 196 ppm (5) 19.6 ppm

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09. A2B jdhq ialkaOhla oDV n`ÿkla ;=< ;nd ksh; WIaK;ajhla hgf;a my; mßÈ .;sl iu;=,s;;djhg t<öug bv
yßk ,§'
A2B(g) 2A(g) + B(g) .;sl iu;=,s; úg A ys mßud m%;sY;h 20% la jk w;r moaO;sfha uq¿ mSvkh 1 ´ 105Pa fõ'
A2B(g) ys iu;=,s; wdxYsl mSvkh jkafka" (Pa)
(1) 2 ´ 102 (2) 5 ´ 10 4 (3) 6 ´ 102 (4) 7 ´ 104 (5) 8 ´ 104

10. l=re÷ fld<j, wvx.= cinnamaldehyde ys jHqyh my; ±lafõ'

fuu wKqj iïnkaOj wi;H m%ldYh jkqfha ñka l=ulao@

(1) f*a,sx ødjKh iu. r;a l< úg r;= ÿUqre meye wjlafIamhla ,efí'
(2) NaBH4 iy fu;fkda,a iu. m%;sls%hd lrjQ úg ,efnk M,h m%ldY iudjhúl;dj olajhs'
(3) fgd,kaia m%;sldrlh iu. r;a l< úg ߧ levm;la ,efí'
(4) Zn/Hg idkaø HCl iu. m%;l s s%hd lrjQ úg ,efnk M,h cHdñ;sl iudjhúl;dj olajhs'
(5) fn%daóka Èhrh új¾K lrhs'

11. § we;s WIa K;ajhl§ 2A(g)+3B(g) ® 2C(g)+D(g) hk m%;sls%hdfõ B ys idkaøKh ksh;j ;nd A ys idka øKh fo.=K
l<úg iS>%;djh fo.=Khlska jeäfõ' A yd B hk foflysu idkaøK y;r .=Khlska jeä l<úg iS>%;dj y;r
.=Khlska jeäfõ' by; m%;sls%hdfõ iS>%;d iólrKh úh yelafla"
(1) R=k[A][B] (2) R=k[A][B]0 (3) R=k[A]2[B]3 (4) R=k[A][B]2 (5) R=k[A]2[B]

12. 2Au(s)+2HNO3(aq)+8HCl(aq)®2HAuCl4(s)+2NO(g)+4H2O(l)
HAuCl4 , NO , H2O , HCl , HNO3 , Au(s) hk m%fNaoj, iïu; tkafg%dmSka ms<sfj,ska 117 Jmol-1K-1 , 521Jmol-1K-1,
305.38 Jmol-1K-1 , 372.51 Jmol-1K-1 , 399.58 Jmol-1K-1 yd 98.88 Jmol-1K-1 fõ'
by; m%;sls%hdjg wkqr Em tkafg%dms fjki jkafka"
(1) 1479.48 Jmol-1K-1 (2) -1479.48 Jmol-1K-1 (3) -147.948 Jmol-1K-1
(4) -739.74 Jmol-1K-1 (5) 147.948 Jmol-1K-1

13. my; m%ldY w;ßka wi;H jkafka"

(1) uex.kSia úoHq;a Ok uQ,øjHla f,i ie,lsh yels w;r ;kql wï, ;=< Èh fõ'
(2) wdï,sl udOHfha§ MnO4- jeämqr Tlaisydrl iu`. m%;sl%shdfjka Mn2+ ,efí'
(3) MnO2 WNh.=KS jk w;r MnO NdIañl fõ'
(4) uo jYfhka wdï,sl Mn2+ ødjKhla ;=,ska H2S nqnq,kh l< úg MnS frda i meye wjlafIamh ,efí'
(5) MnO2-4 " wdï,sl l< úg MnO2 yd MnO4- iEfoa'

14. my; ±la fjk m%;sls%hdj i,lkak'

H2(g) + I2(g) º 2HI (g)
; DHq = +26 kJmol-1
DSq = +20 JK-1mol-1
fï m%ldYkj,ska i;H jkafka'
(a) fuh frfvdlaia m%;sls%hdjls'
(b) 298K ka my< WIaK;ajj, § fï m%;sl%shdj isÿúh yels h'
(c) mßudj ixfldapkh l< úg mSvkh jeäj;au iu;=,s; HI(g) idkaøKh fjkia fõ'
(d) WIaK;ajh jeäj;au iu;=,s; HI(g) idkaøKh jeä fõ'
(e) WIaK;ajh jeäl<úg miq m%;sls%hdfõ iS>%;djh wvq fõ'
(1) (a) iy (b) muKs' (2) (a) iy (d) muKs' (3) (a) , (c) iy (d) muKs'
(4) (d) iy (e) muKs' (5) (b) , (d) iy (e) muKs'

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15. wdj¾;s;d j.=fõ d-f.dkqjg wh;a X kï uQ,øjHhla my; .=K olajhs'
ò th ;kql HCl iuÕ m%;l s s%hd ù H2 uqod yÍ'
ò th XSO4.7H2O wdldr ic, i,af*aghla idohs'
ò th X(OH)2 wdldr fld< mdg yhsfv% dlaihsvhla idok w;r th jeämqr c,Sh NH3 ;=< Èh ù ;o ks,amdg
ødjKhla idohs'
ò th [XCl4]2- wdldr laf,drhsfvd ixlS¾Khla idohs'
X úh yelafla"
(1) Fe (2) Co (3) Ni (4) Cu (5) Zn

- 3-
16. 0.10mol Cl (aq) yd 0.01mol PO4(aq) iys; 500cm3 ødjKhlg (tys mßud fjkia fkdjk mßÈ) Ag+(aq) whk tl;=
lrk ,§' wjlafIamhla isÿùug wjYH wdrïNl Ag+(aq) whk idkaøKh yd isÿjk uq,au wjlafIamh ms<sfj,ska"
(Ksp AgCl(s)=1.6×10-6 = Ksp Ag3PO4 = 1.8×10-10)
(1) 8×10-6 iy AgCl(s) (2) 3×10-3 iy Ag3PO4(s) (3) 32×10-2 iy Ag3PO4(s)
(4) 38×10-10 iy AgCl(s) (5) 32×10-8 iy AgCl(s)

17. fndfydauhla me<Eáj, iy t<j¿j, Tlaie,sla wï,h (H2C2O4) wka;¾.; fõ' Tlaie,sla wï, ødjKhlska
25.0cm3 la iuÕ iïmQ¾Kfhka m%;l
s s%hd lsÍu i|yd 0.1moldm-3 KOH ødjKhlska 24cm3 la jehúh' Wla; Tlaie,sla
wï, ødjKfha 20.0cm3 la f.k wdï,sl lrk ,§' fuf,i ,efnk ødjKh iuÕ m%;sls%hd lsÍu i|yd idkaøKh
0.025moldm-3 jk KMnO4 ødjKhlska fldmuK mßudjla jeh fõ o@
(1) 19.2cm3 (2) 4 cm3 (3) 15.36cm3 (4) 7.68cm3 (5) 30.72cm3

18. my; i|yka ixfhda. wdï,sl;djh jeäjk ms<sfj<g ilikak'

OH

CH CH
P Q R S
(1) S<Q<R<P (2) S<R<Q<P (3) R<Q<P<S (4) R<P<Q<S (5) R<S<Q<P

19. mßudj 500.0cm3 jk oDV Ndckhl i,a*¾" S(s) 0.032g iuÕ jeämqr maÆfjdÍka" F2(g) jdhq j we;' fïjd tlsfkl
m%;sls%hd ùug m%:u moaO;sfha mSvkh 2.5 x 104Pa iy WIaK;ajh 270C fõ' S(s) ish,a, m%;sls%hd lrñka SF6 jdhq uh
M,h ,ndfok f,i m%;sls%hdj isÿl< miq 27 0C § moaO;sfha wjidk mSvkh jkafka" S ys mßudj fkd.sKsh yels nj
i,lka k' (S = 32.0, F = 19.0)
(1) 0.5 x 104Pa (2) 1.0 x 104Pa (3) 1.5 x 104Pa (4) 2.0 x 104Pa (5) 2.5 x 104Pa

20. A kï ldnksl ixfhda.hla HNO2 iu. m%;slh

%s d lr N2 jdhqj msglr m%ldY iudjhúl;djh fkdfmkajk B kï ixfhda.h
njg m;ajk w;r B , Br2 Èhr új¾K fkdlrhs' B idkaø H2SO4 iu. ;dmlsÍfuka C kï cHdñ;sl iudjhúl;djh
fmkajk ixfhda.h idok w;r C , Br2 Èhr új¾K lr m%ldY iudjhúl;djh fmkajk D idohs' fï wkqj A úh yelafla"

(1) (2)

(3) (4)

(5)

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21. ldnksl ridhkfha ksjerÈ m%;sls%hd hdka;%K mshjrla jkafka"

(1)

(2)

(3)

(4)

(5)

22. 25 0C § idkaøKh C0 moldm-3 jk CH3COOH 25.00cm3 la NaOH uÕska wkqudmkfha § iul;d ,CIHfha pH w.h
i|yd my; tajdhska ksjerÈ m%ldYkh l=ula o@ fuys S hkq iEfok ,jKfha idkaøKh jk w;r Ka hkq CH 3COOH
yS ú>gk ksh;h jk w;r KW hkq 250C § c,fha ú>gk ksh ;h fõ'
(1) pH = ½pKa + ½pKw + ½log S (2) pH = pKw + log S
(3) pH = pKa (4) pH = ½pKa - ½ log C0
(5) pH = - ½pKa + ½pKw + log S

23. s-f.dkqfõ uQ,øjHj, ridhkh iïnkaOfhka i;H jkafka"

(1) s-f.dkqfõ uQ,øjH idok ish¨u ldnfkag yd nhsldnfkag c,fha Èhfõ'
(2) s-f.dkqfõ ish¨u uQ,øjH idok khsfÜ%g ;dm úfhdackfha § Tlaiscka uqodyÍ'
(3) fuu f.dkqfõ ish¨u uQ,øjH isis,a c,h iu. m%;sls%hdlr yhsv%cka uqodyß'
(4) tajd idok ish¿ yhsfv%dlaihs v m%N, NdIañ l .=K fmkajhs'
(5) s-f.dkqfõ uq,øjH idok ish¨u ixfhda. whksl fõ'

24. A2B(g) 1 mol la 300K § ixjD; n÷kla ;=< ;enQ úg .;sl iu;=,s;;djhg m;aúh' túg Ndckfha uq ¨ mSvkh
3×105 Pa úh' A2B(g) , X(g) yd Y(g) kï jdhq folla njg úfhdackh isÿjQ wdldrh my; m%ia;drfha ±lafõ'
úfhdackh iïnkaOj my; ±lafjk l=uk m%ldY i;H fõ o@

(1) X yd Y hk jdhq j, iQ;% A2(g) yd B(g) fõ'

(2) X(g) wdxYsl mSv kh 2×105 Pa fõ'
(3) Kp w.h 3.3×109 Pa2 fõ'
1
(4) Y(g) ujq, Nd.h fõ'
5
(5) DS w.h iDK w.hls'

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25. my; m%ldYj,ska i;H m%ldYh f;darkak'
(1) m<uq fm< m%;sl%shdjl w¾O Ôj ld,h m%;sl%shlfha wdrïNl idkaøKh u; r`od mj;S'
(2) Y+kH fm< m%;sl%shdjl§ fõ. ksh;fhys tall" m%;sl%shd iS>%;djfha tallj,g iudk fõ'
(3) m%;sl%shdjl fm< m%;sl%shl idkaøKh u; r`od mj;S'
(4) m%;sl%shdjl iS>%;d ksh;h fN!;sl idOl lsisjla u; r`od fkdmj;S'
(5) m%;sl%shdjlska ,efnk M, m%udKh il%shk Yla;sh u; r`od mj;S'

26. N2, H2 yd NH3 jdhq ms<sfj,ska 10mol, 30mol yd 20mol fhdod mßudj oDv n`ÿkla ;=, ;nd th T WIaK;ajhg
m;a lrk ,§' T WIaK;ajfha§ wdrïNl mSvkh P jQ w;r ál fõ,djl§ moaO;sfha mSvkh P/ olajd <`.d jq Ks'
ta wjia:dfõ§ n`ÿfka we;s N2 ujq, .Kk 5mol nj fidhd .kakd ,§' P/ ksh;j mj;S' P/ w.h weiq ßka"
(1) P/ = 2p (2) P/ = p (3) P/ = p (4) P/ = p (5) P/ = 1.5p

27. OQñld yd wï, jeis we;s ùug khsg%cka vfhdlaihsâ jdhqj fya;= fõ' NO2 iE§ug wod< m%;sls%hdjla fufia h'
O3(g) + NO(g) ºO 2(g)
+ NO2(g) ; Kc = 6×1034
tla;rd jd;h idïm,hla ;=< mj;sk O3(g) , NO(g) , NO2(g) iy O2(g) idkaøK ms< sfj<ska 1.0 × 10-6 moldm-3 ,
1×10-5 moldm-3 , 2.5×10-4 moldm-3 yd 8.2×10-3 moldm-3 fõ'
fï idïm,h iïnkaOfhka i;H jkafka"
(1) NO(g) iy O3(g) m%udK jeäùfï keUqre;djhla we;'
(2) NO2(g) iy O2(g) m%udK jeäùfï keUqre;djhla we;'
(3) NO2(g) iy O3(g) m%udK jeäùfï keUqre;djhla we;'
(4) NO(g) iy O2(g) m%udK jeäùfï keUqre;djhla we;'
(5) m%;sls%hdj iu;=,s;j mj;sk fyhska ix>glj, idkaøK fjkiaùfï keUqr ejla ke;'

28. my; l=uk wjia:dfõ§ pH>7 jk ødjK ,nd foao@

A). 0.1moldm-3HCl ødjK 25cm3 la yd 0.2moldm-3NaOH ødjK 25cm3 la ñY% lsÍfï§'
B). 0.2moldm-3NaOH ødjK 25cm3 la yd 0.1moldm-3 CH3COOH ødjK 25cm3 ñY% lsÍfï§'
C). 0.1moldm-3NH3 ødjK 25cm3 la iy 0.1moldm-3CH3COOH ødjK 50cm3 ñY% lsÍfï§'
(1) A muKhs' (2) B muKhs' (3) C yd D muKhs'
(4) A yd B muKhs' (5) B yd D muKhs'

29. CHCl3 yd H2O wñY% øj 2 w;r A kï øjHhla jHdma;j iu;=,s;j mj;S' T1 WIaK;ajfha§ CHCl3 yd H2O w;r jHdma;s

A H 2O
ix.=Klh K1 o T2 kï by< WIaK;ajfha § tu w.h K2 o fõ' jHdma;s ix.=Klh =
A CHCl3 f,i w¾: olajd we;'
K2 > K1 fõ' T1 WIaK;ajfha iu;=,s; moaO;shla T2 WIaK;ajhg f.k f.dia kej; iu;=,s;;djg m;a ùug bv foa'
fuu wjia:dj iïnkaOfhka my; i`oyka l=uk m%ldYh i;H fõo@
(1) CHCl3 ia:rfha A j, idkaøKh jeä fõ'
(2) ia:r foflysu A j, idkaøKh jeä fõ'
(3) A j, uq¿ m%udKh ksh; fyhska ia:r foflysu idkaøKh wvq úh fkdyel'
(4) c,Sh ia:rfha A j, ødjH m%udKh ^ujq,& wvq fõ'
(5) A ixfhda.h CHCl3 isg H2O ys Èhùu ;dmwjfYdaIl fõ'

30. A, B yd C c,Sh ixfhda. ;=k f.k bka A g" B iaj,amh ne.ska jeämqr tla lrk ,§' túg wjlafIamhka iE§ miqj th
Èhúh' C g" B iaj,amh ne.ska jeämqr tla lsÍfï§ o wjlafIa mh iE§ th Èh ù hhs' A, B, C jkafka ms<sfj<ska"
(1) CuCl2, NaOH, AlCl3 (2) CuCl2, NH4OH, AlCl3 (3) CrCl3, NaOH, AlCl3
(4) CrCl3, Ba(OH)2, Al2(SO4)3 (5) ZnCl2, Ba(OH)2, (NH4)2CO3

pß; Èidkdhl B.Sc. Engineering (Hon's)

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· m%Yak wxl 31 isg 40 f;la m%Yak j,g Wmfoia
wxl 31 isg 40 f;la jq tla tla m%Yakfha olajd we;s (a), (b), (c) iy (d) hk m%;spdr 4 w;frka tlla fyda jeä
ixLHdjla fyda ksjerÈh. ksjerÈ m%;spdrh $ m%;spdr ljf¾±hs f;dard .kak.
(a) iy (b) muKla ksjerÈ kï (1) u; o
(b) iy (c) muKla ksjerÈ kï (2) u; o
(c) iy (d) muKla ksjerÈ kï (3) u; o
(d) iy (a) muKla ksjerÈ kï (4) u; o
fjk;a m%;spdr ixLHdjla fyda ixfhdackhla fyda ksjerÈ kï (5) u; o W;a;r m;%fhys ±lafjk mßÈ ,l=Kq lrkak.

by; Wmfoia iïmsKavkh

(1) (2) (3) (4) (5)
(a) yd (b) (b) yd (c) (c) yd (d) (d) yd (a) fjk;a m%;spdr ixLHdjla fyda
muKla ksjerÈh. muKla ksjerÈh. muKla ksjerÈh. muKla ksjerÈh. ixfhdackhla fyda ksjerÈh.

31. yhsv%cka mrudKql j¾Kdj,sfha wkqhd; f¾Ld fY%aKs 2l m<uq f¾Ld ;=k my; rEmfha ±lafõ'

C f¾Ldj r;= mdáka Èia fõ' my; ljr m%ldYh i;H fõo@
(a) A isg E olaj d hEfï§ ixLHd;h jeä fõ'
(b) C f¾Ldfõ ixLHd;h B f¾Ldfõ ixLHd;hg jvd jeä fõ'
(c) E f¾Ldjg wkqr Em bf,lafg%dak ixl%u Kh jkafka n = 5 ® n = 3 fõ'
(d) A yd B f¾Ld w;r mr;rh E yd F f¾Ld w;r mr;rhg iudk fõ'

32. my; i|yka l=uk m%ldYh$ m%ldY lsishï jdhq ksh uhka iu. tlÕ jkafkao@
(a) WIaK;ajh ksh; úg ksh; jdhq ialkaOhl mßudj tys mSvkhg wkqf,dauj iudkqmd;sl fõ'
(b) ksh ; WIa K;ajhl§ ksh; jdhq ialkaOhl >k;ajh tys mSvkhg m%;sf,dauj iudkqmd;sl fõ'
(c) ksh; mSvkfha§ ksh; jdhq ialkaOhl mßudj tys ksrfmalaI WIaK;ajhg m%;f
s ,dauj iudkqmd;sl fõ'
(d) ksh ; mSvkfha§ ksh; jdhq ialkaOhl >k;ajh tys ksrfmalaI WIaK;ajhg m%;sf,dauj iudkqmd;sl fõ'

33. Mg2+ , Zn2+ , Pb2+ whk wvx.= c,Sh ødjKhla iïnkaOfhka my; ljr m%ldYh$m%ldY i;H fõ o@
(a) NdIañl udOHl§ H2S nqnq,kfhka ZnS muKla wjlafIam fõ'
(b) NH 4Cl iy NH4OH ñY%Khl § Mg2+ wjlafIamhla fkdfok kuq ;a NH4OH ødjKhl § idok wjlafIamh
NaOH ;=< Èh fkdfõ'
(c) ñY%Khg jeämqr Ba(OH)2 ødjKhla tl;= l<úg wjlafIamhla olakg ,efnhs'
(d) wdï,sl udOHhl§ H2S jdhq j nqnq,kh l<úg iqÿ wjlafIa mhla olakg ,efnhs'

34. wefudakshd iy wefudakshï ,jK ms<sn`oj my; i`oyka l=uk j.ka;sh $ j.ka;s wi;H fõo@
(a) wefudaksh d NdIañl jdhqjla jk w;r th c,fha uo jYfhka ødjH fõ'
(b) ´kEu wefudakshï ,jKhla m%n,laIdr iu`. r;a l< úg m%;sl%shd lr wefudaksh d msg lrhs'
(c) ish¨ wefudakshï ,jK c,fha ødjH fõ'
(d) wefudakshdj,g Tlaisldrlhla f,i l%shd l< fkdyel'

35. my; § we;s m%;sl%sh d j,ska DH, DS yd DG hk úm¾hdi ;=fkysu ,l=K iDK úh yels m%;sl%shdj $ m%;sl%s hd jkafka"
(a) Ba(OH)2(aq) + H2SO4(aq) ® BaSO4(s) + 2H2O(l)
(b) 4Na(s) + O2(g) ® 2Na2O(s)
-
(c) NaCl(s)® Na+(g) + Cl(g)
(d) 2H2O(l) ® 2H2(g) + O2(g)

pß; Èidkdhl B.Sc. Engineering (Hon's)

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36. HIn kï tla;rd wdï,sl o¾Ylhl ú>gk m%udKh 50% la jk úg ødjKfha pH w.h 2 ls' tu ødjKfha tu
WIaK;ajfha §u pH w.h 2.4 la jk úg o¾Ylh iys; iu;=,s; moaO;sh ;=< my; ljr wjia:d $ wjia:djla mj;S o@
(a) o¾Ylfha whkSlrKhg ,la jQ m%fNaofha m%;sY;h 71.5% muK fõ'
(b) o¾Ylfha [In–] / [HIn] wkqmd;h 0.4 la fõ'
(c) o¾Ylfha whkslrKhg ,la fkdjQ m%fNaofha m%;sY;h 71.5% muK fõ'
(d) o¾Ylfha [In-] / [HIn] wkqmd;h 2.51 la fõ'

37. fm%dmhska (CH3 C º CH) iïnkaOfhka i;H m%ldYh $ m%ldY jkafka"

(a) HgSO4 W;afm%arl yuqfõ ;kql H2SO4 iu`. r;a lsÍfuka fm%dmfkdaka (CH3COCH3) ,nd.; yels h'
(b) ,skaâ,¾ W;afm%arlh yuqfõ yhsv%ckSlrKfhka fm%dfmaka ,nd.; yelsh'
(c) wefudakSh is,a j¾ khsfÜ%Ü iu`. ߧ levm;la ,nd foa'
(d) úh,s B;¾ udOHfha CH3MgBr iu`. CH4 jdhq j ,nd foa'

38. ødjH;d .=Ks;h iïnkaOj ksjerÈj m%ldY $ m%ldYh f;darkak'

(Ksp - AgCl = 1 x 10-10 mol2dm-6 / Ksp- PbCl2 = 1 x 10-5 mol3dm-9
(a) AgCl j, ødjH;djh 0.5 x 10-10 moldm-3 fõ'
(b) 0.1moldm-3 NaCl ødjKhl AgCl ys ødjH;djh 1x 10-9 moldm-3 fõ'
(c) 0.2moldm-3 HCl ødjKhl Mg(OH)2 j, ødjH;djh C1 o 0.2moldm-3 NaOH ødjKhl Mg(OH)2 ys ødjH;djh
C2 o c,fha ødjH;djh C3 o kï C1, C2 yd C3 w;r iïnkaOh C2 < C3 < C1 fõ'
(d) idkaøKh 0.1moldm-3 jQ AgNO3 yd Pb(NO3)2 ødjKhlg NaCl fifuka tlalrk úg m<uqj wjlafIam
jkafka AgCl fõ'

39. m%;l
s %shdjl pd,l ridhkh wOHhkfha§ my; f;dr;=re ,nd .ekqks'
m%;sl%shdj ( X + 2Y Z
· ksh; Y idkaøKhla hgf;a X ys idka øKh w¾Ohla olaj d wvq l< úg iS>%;dj 0.5R úh'
(R = wdrïNl iS>%;djh)
· 250C ys§ m%;sl%shl foflysu idkaøK ksh; fkdjk úg m%;sl%shdfõ iS>%;d ksh;h 1.2 ´ 10-4 dm6mol-2s-1 úh'
fuu m%;sl%shdj ms<sn`o t<ôh yels ks.ukh $ ks.uk jkafka"
(a) fuh fojk fm< m%;sl% shdjls'
(b) fuh ;ks mshjr hka;%Khla Tiafia isÿ úh hq;=h'
(c) Y wkqnoaOfhka m<uq fm< m%;sl%h s djls'
(d) 250C ys§ X yd Y idkaøK 0.1moldm-3 úg m%;sl%shd iS>%;dj 1.2 ´ 10-7moldm-3s-1 fõ'

40.

hk m%;sl%shdj iïnkaOfhka i;H j.ka;sh jkafka"

(a) fuh bf,lafg%da*s,sl wdl,k m%;sl%shdjla jk w;r hka;%Kfha mshjr folla we;'

(b) m%Odk M,h fõ'

(c) m%;sl%shd hdka;%Kfha§ iEfok m%Odk ldnksl w;rueÈh jkafka"

(d) iEfok m%Odk M,h m%;srEm wjhj iudjhúl;dj fmkajhs'

pß; Èidkdhl B.Sc. Engineering (Hon's)

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— m%Yak wxl 41 isg 50 f;la m%Yak j,g Wmfoia
wxl 41 isg 50 f;la jQ tla tla m%Yakh i|yd m%ldY fol ne.ska bÈßm;a lr we;' tu m%ldY hq.<hg fyd¢ka u
.e<fmkqfha my; j.=fjys ±lafjk (1) , (2) , (3) , (4) iy (5) hk m%;spdrj,ska ljr m%;p
s drh ±hs f;dard W;a;r m;%fhys
WÑ; f,i ,l=Kq lrka k'

m%;spdrh m<uqjeks m%ldYh fojeks m%ldYh

(1) i;H h' i;H jk w;r" m<uq jekak ksjerÈ j myod fohs'
(2) i;H h' i;H jk kuq;a m<uqjekak ksjerÈ j myod fkdfohs'
(3) i;H h' wi;H h'
(4) wi;H h' i;H h'
(5) wi;H h' wi;H h'

m<uqjeks m%ldYh fojeks m%ldYh

41. 1-Butene j,g Br2 tl;= l<úg ,efnk ixfhda.h wiuñ;sl C mrudKqjla mj;sk ´kEu ldnksl ixfhda.hla
m%ldY iudjhúl;dj olajhs' m%ldY iudjhúl;dj olajhs'

42. ;kql HCl j,ska wdï,sl lrk ,o ødjKhlg H2S hejQ Mn2+(aq) yd Co2+(aq) laf,da rhsv whk iu. ixlS¾K idohs'
úg Co2+ iy Mn2+ i,a*hsv f,i wjlafIam fõ'

43. NaOH ødjKh yuq fõ yd w;r ksh q l a , s f hd*s , s l wdfoa Y m% ;s l s %h dj,g jeä
keUqrejla olajhs'
is ÿj k m% ;s ls % h dfj ka m % O dk M,h f, i

iEfoa'

44. tlu WIaK;ajfha§ H2(g) yd D2(g) ys j¾. uOHkH wKql jdhQ kays j¾. uOHkH fõ.hka WIaK;ajh u; muKla r|d
fõ.hka ms< s f j,s k a C1 yd C 2 f,i ie<l= úg mj;S'
C1>C2fõ'

45. Fe3+, whk ødjKhlg ;kql wefudakshd ødjKhla jeämqr wefudakshd ;=, Èhùhk ÿUqremdg wjlafIamhla Fe3+
fh§fuka wjlafIamhla we;sl< yel' ødjK u.ska ,nd.; yel'

46. fid,afõ l%ufha § wg¿j, WIaK;ajh wvqlsÍu uÕska Na2CO3 ksIamdokfha § m<uq wg¿j ;=,ska by,ska msßisÿ
NaHCO3 ys ødjH;djh wvq flf¾' l< n%hska o my,ska NH3 jdhq j;a hjñka m%;sm%jdy l%u hg
ødjKh NH3 j,ska ix;Dma; flf¾'

47. O%eùh nkaOk iys; iEu wKqjlu oaúO%ej >Q¾Khla oaúO%ej >Q¾Kh" nkaOkj, wjldYSh úys§u u; r|d mj;S'
olakg ,efí'

48. c,Sh Co2+ whk ødjKhlg idkaø NH3 jeämqr tl;= c,Sh ødjKj,§ H2O2 u.ska Co2+ whk" Co 3+ njg
l< úg ly ÿUqre mdg [Co(NH3)6]2+ixlS¾Kh iEfok TZlrKh jk w;r TZlrK wxlh fjkia jk úg
w;r thg H2O2 iaj,amhla tl;= l< úg" ;eô,s ÿUqre ixlS¾Kfha j¾Kh fjkia fõ'
mdg [Co(NH3)6]3+ ixlS¾Kh njg m;afõ'

pß; Èidkdhl B.Sc. Engineering (Hon's)

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49. ixfhda.hla c,fha Èhùug tys ødjK tka;e,a msh whksl ixfhda.hl iïu; ødjK tka;e,amsh iïu; ±,sia
(dissolution enthalpy) wksjd¾hfhkau (–) w.hla úh tka;e,amsfha (lattice enthalpy) yd ix>gl whk j, iïu;
hq;=h' ic,k tka;e,amsj, (hydration enthalpy) tl;=jg iudk
fõ'

50. ksh; WIaK;ajfha§ m%;sl%shdjla isÿjk ixjD; moaO;shl ksh; WIaK;ajfha§ m%;sl%shdjla isÿjk moaO;shl mßudj wvq
mßudj wvq lsÍfuka m%;sl%shd iS>%;djh jeäl< yel' l< úg tall ld,hl§ tall mßudjla ;=< isÿjk iM,
ix>Ügk m%udKh jeä fõ'

pß; Èidkdhl B.Sc. Engineering (Hon's)