MCQs with One Cormet Answer Dinitrogen is a robust compound, but reacts at high altitude to form oxides, The oxide of nitrogen that can damage plant leaves and retard photosynthesis is @ NO) NO; @ NO, White phosphorus reacts with thionyl chloride to give {Main July 28,2022 (DD) (@) PCls.S0,andS,Cl, (6) PCl,,$0,andS,Cl, (©) PCI, SO,andCl, (4) PCIs,80, and Cl, Which oxoacid of phosphorous has the highest number cof oxygen atoms present in its chemical formula? {Main July 27,2022] (@)_Pyrophosphorous ac (6) Hypophosphoric acid (©) Phosphoric acid (@) Pyrophosphoric acid 73K eat 809K A244 Red phosphors — te ed by heating “A” at S73 K, by heating at 803 K under Red phosphorus is obta and can be converted to pressure ‘Aand B, respectively, are [Main June 30,2022) (@) B-black phosphorus and white phosphorus. (6) white phosphorus and f-black phosphorus. (©) acblack phosphorus and white phosphorus. (@) white phosphorus and a-black phosphorus. ‘The oxoacid of phosphorus that is easily obtained from a reaction ofalkali and white phosphorus and has two P-H bonds, is [Main June 29, 2022 (@) Phosphonic acid (b) Phosphinic acid (6) Pyrophosphorus acid (4) Hypophosphoric acid ‘Nitrogen gas is obtained by thermal decomposition of [Main June 28,2022 (D) (a) Ba(NO,), (6) Ba(N,), (©) NaNO, (@) NaNO, 9, 13. 14, Heating white phosphors wih cme: NAOH sy gives mainly ig (a) NaPand H,0 ©) POs, (©) P(OH), and NaHPO, (3) PH, and Natieo The most stable trihalide of nitrogen is iM ( NCL, (©) NBr, Samson @o — &2 @1 @3 |. ‘The oxidation states of nitrogen in NO, NO, NO; arein the order of {Main March 18,2021 (1); Similar. (a) NO,>NO;>NO>N,0 (b) NO;>NO, SNoN (0 N,0>NO,>NO>NO; (4) NO>NO,>N,0>, Thereation of NO withN,0, 2250 K gis. : ay @NO ONO, ONO, (Xo, ‘The number of pentagons in C,. and trigons(iang)a white phosphorous, respectively, ae: [Main (@) 20and3 (b) ands (©) Iand3 (@) 2and4 ‘The number of P—O bonds in PO, is [Main Online i @9 ws @2z wR ‘The number of P-OH bonds and the oxidation sate phosphorus atom in pyrophosphoric acid (1120 respectively are: [Main Online Aprl9, 20178 mv (@) four and four () fiveand four (©) fiveand five (@) four and five . The order ofthe oxidation state ofthe phosphowsstom® H,PO,, H,PO, H,PO, and H,P,0,is @) HPO,>Hi,P0,> H,PO,>H'P.0, (b) H,PO,>H,PO, > H,P0,> H.P,0, (©) H,PO,>H,P,0,>H,P0,>H,?0, (@ H,PO,>H,PO,> H,?,0,> 11,0,Elements (Group 15, 16, 17 & 1) in which phosphorus atoms have ei 8 formal ne pat gute iMaln 26 ston eporous and hypophosphorie acide. 6) Oe phous an! ryTophosphoic aid . piso and nyrophophoros acids oneroxthorous and hypophosphoric acids (@ RT be flowing conpotnd has a =P hn 2 (Main Online April 11-2018) 5147205 9 HPO (©) HPO, Hypo, Uy neo he Flowing dos Ht havea panda [Main Online Ay ‘ s a ‘Online Aprit 1, 2014 TEI ANO (HNN ACH), Si j SO MORE MOL posphorous iS Ady. 2014) ot © So, (@ Poh (eeniated nitric acid, ypon long standing uns yellow feown ducto te formation of [Ady 2013] @N ON ONO NO, She reaction of white phosphorus with aqueous NaOH tines phosphine along with another phosphorus fine Ting compound. The reaction type; the oxidation Sires of phosphorus in phosphine and the other product are respectively 120t2] {@) redox reaction; ~3.and—S {b) redox reaction: +3 and +5 {@) disproportionation reaction; ~3.and +5 {@) cisproportionation reaction; ~3 and +3 Which ordering of compounds is according to the decreasing order of the oxidation state of nitrogen? [2012] {@) HNO, NO, NH,CLNy {0) HNO,, NO, N,,NH,CL () HNO, NH,CI,NO,N, (@) NO,HNO,.NH,CIN, Extra pure N, can be obtained by heating (@) NA, with CuO (b) NINO, (9) (NH),Cr.0, (@) BatX,), |. Thereaction of P, with X leads selectively to PO, The Xis (a) DryO, [2009] {b) A mixture of Oyand Ny (0) Moist O, {@) 0, in the presence of aqueous NaOH The percentage of n-character in the orbitals forming PP ou) bonds in P, is [2007] (@) 5 (b) 33 () 0 @ 5 ‘When PbO, reacts with cone. HNO,, the gas evolved is {2005S} @No, 00, ©, WNO . Blue liquid which is obtained on reacting equimolar amounts of two gases at 30°C is? [2005S] (@) NO (b) NO, © NO, N,0s ‘Which is the most thermodynamicaly stable alltropie form ‘of phosphors? [2005S], {@) red (b) white (¢) black _(d) yellow 120038} ). For H,PO, and H,PO,, the correct choice is: (@) HPO, is dibasic and reducing. (b) H,PO, is dibasie and non-reducing (9) H,PO, istribasic and reducing (8) H,PO, is tribasic and non-reducing 0 B. uM 36. a1. 39. 40. @ aL. 2, @ 43. 349 Ammonia can be dried by (2000S) (a) cone. H,S0, (b) PO (©) Gao (d) anhydrous CaCl, The number of PO ~ P bonds in cyclic metaphosphoric acidis [2000S] (a) zero (b) two (c) three (4) four In compounds of type ECl,, where E = B, P, As or Bi, the angles Cl -E-Cl fr diferent Fare in the order [1999-2 Marks) (@) B>P=As=Bi—_(b) B>P>As>Bi (0 BeP=As (8) BeP CHCL+A A+ PCI —B. [Main July 26,2022, pacene menace om PCI, +H,0 —> A+ HCL A+H,0 —> B+HCL ‘number of ionisable protons present in the product B. [Main Jume25, 2022 (11)}850 45, Dissolving 1.24 g of white phosphorous in boiling NaOH solution in an inert atmosphere gives a gas Q, The amount of CuSO, (in g) required to completely consume the jas 20 Qis Ia [Given: Atomic mass of H= 1, 0= 16, Na=23, P=31 32,Cu=63] 46. The reaction of white phosphorus on boiling with alkali in inert atmosphere resulted in the formation of product "AY A’ with excess of AgNO, in The reaction of | mol of mol(s) of Ag med gives the Nearest Integer) /Main March 17, 2 (Round off to | Lin the Blanks the number of oxygen atoms bonded fo each. #7. InP, phosphorus atom is [1992-1 Mark} 48 The basicity of phosphorous acid (H,PO,)is. [1990 1 Mark} 0 phosphorus is reactive because of its highly strained tetrahedral structure [1987-1 Mark} The lowest possible oxidation state of nitrogen is [1980] True / False Si. Nitric oxide, though an odd electron molecule, is diamagnetic in liquid state, (1991-1 Mark] The H-N-H bond angle in NH, is greater than the H-AS-H. bond angle is Ast, [1984-1 Mark} Red phosphorus is less volatile than white phosphorus because the former has a tetrahedral structure{ 1982-1 Mark] MCQs with One or More than One Correct Answer The correct statement(s) related to oxoacids of phosphorous is(are) [Adv. 2021] (2) Upon heating, H,PO, undergoes disproportionation reaction to produce HPO, and PH, (©) While H,PO, can act as reducing agent, HPO, cannot (©) H,PO; isa monobasic acid. (@) The H atom of P-H bond in HPO, is not ionizable in water 55, Based on the compounds of group 15 elements, the correct. statement(s) is (are) [Ady 2018] (@) Bi,O, ismore basic than N,O, (b). NF, is more covalent than BiF, (©) PH, boils at lower temperature than NH, ()_TheN-Nsinglebondis stronger than the P-Psinge bond ‘56, Thecompound(s) which generate(s) N, gas upon thermal decomposition below 300 °Cis (are) [Adv. 2018] (@)_NH,NO, (b) (NH),Cr,0, (©) Ba(N,), (@) Mg,N,, 57. The nitrogen containing compound produced in the reaction of HINO, with P,O,, 1Ach. 2016) (@) can also be prepared by reaction of P, and HNO, (b) isdiamagnetic - (©) contains one N-N bond (@) reacts with Na metal producing a brown gas 58, Thenitrogen oxide(s) that contain(s) N-N bond{s)is(are) 2009} @ No, @NO ©) NO, © No, Chem ‘Asolution of colourless salt H on boiling with excexy vocluces a non-flammable gas. The gas evolution olution, the gas evolution restarts, The colourless (6) His (are) {2} NINO, (©) NHNO, (©) NH, ‘Ammonia, en reaction with hypoch! (a) NO) NHCI_ (©) NH, White phosphorus (P,) has (a) six P-P single bonds (b)_ four P-P single bonds (6) four lone pairs of electrons (d)_ PPPangle of 60° Sodium nitrate decomposes above 800° C to give (@ Ny (©) NO, Nitrogen(I) oxide is produced by: * (1989-1, (@) thermal decomposition of ammonium nitrate ()_disproportionation of N,O, (6). thermal decomposition of ammonium nitrite (@)_ interaction ofhydroxylamine and nitrous acid. 2 6. (Q) i Match the Following 64. Match List-Iwith List-II: [Main Mareh 16,2021, List Name of oxoacid Oxidation state of P (A) Hypophosphorous acid (1) +5 (B) Orthophosphoric acid. (I) +4 (© Hypophosphoric acid (I) +3 (D) Orthophosphorous acid (IV) +2 (W) + ‘Choose the correct answer from the options given bel (a) (AMIV), (BYV), (CHM), (DMD) () (ACV), (B)-1V), (1D, (D)-CHID) (©) (AHV), (BHD, (CHI), (DUD) @) (A)1V), B-(, (CHAD, (DAM), 65, Match the following, choosing one item from column, ‘and the appropriate item from column \ .|19§3- Mia Xx y @ Haber (@) Activation energy (i) Graham (0) Diffusion of gases ii) Arthenius (©) Octetrule (iv) Lewis (d)_ Ammonia synthesis 5 Comprehension/Passage Based Questions There are some deposits of nitrates and phosphates in earth rust. Nitrates are more soluble in water. Nitrates are difficult ions. Hybridization easily: ‘explains the ease of sigma donation ‘capability of NH, and PH,, Phosphine is a flammable gas andi Prepared from white phosphorous, pe 66, Among the following, the correct statement is (a) Phosphates have no biological significance in h (b) Between nitrates and phosphates, phosphates less abundant in earth’s crust (©) Between nitrates and phosphates, nitrates are abundant in earth’s crust (©) Oxidation of nitrates is possible in soil852 aM S) (Ci) Elemental phosphorus reacts with cone, HNO, 10 ive phosphoric acid [1991-1 Marky () Nitrogen is obtained in the reaction of aqu ammonia with potassium permanganate. [1991-1 Mark} ©) Sodium nitrite is produced by absorbing the oxides of nitrogen in aqueous solution of washing soda, [1991-1 Mark} (i) Aqueous solution of sodium nitrate is heated with ine dust and caustic soda solution, [1990-1 Mark (vi Write balanced equations for the preparation of | ammonium sulphate from gypsum, ammonia and carbon dioxide, [1990-1 Mark} (vi Write balanced equations for the preparation of phosphine from CaO and white phosphorus. [1990 -2 Marks} (és). Hypophosphorous acid is heated. [1989-1 Mark (Phosphorus reaets with nitric acid to give equimolar ratio ofnitric oxide and nitrogen dioxide. [1988-1 Mark] (xi) Dilute nitric acd is slowty reacted with metallic tin [1987-1 Mark] 1 MCQs with One Correct Answer Which ofthe following oxoacids of sulphur contains “S" in {wo different oxidation states? (Main June 28, 2022 (11), @ HS,0, ©) HS,0, © HS,0, @ H.S,0, ‘The number of S=O bonds present in Sulphurous acid, peroxodisulphuric acid and pyrosulphuric acid, respectively ae: [Main Aug, 31, 2021 (I); Similar April 8,2017] (@ 2,3and4 () 1,4and3 (© 2,4and3 (@) 1,4and4 Reaction ofan inorganic sulphite X with dilute H,SO, gen- erates compound Y. Reaction of Y with NaOH gives X. Further, the reaction of X with Y and water affords com- poundZ. Yand2, respectively are: [Main Sep. 06, 2020 (I)] {@) SO, andNa,S0, _(b) SO, and NaHISO, (c) SO, and NaH1SO, (@ SandNa,SO, The oxoacid of sulphur that does not contain bond between sulphur atoms is: {Main April 10,2019 ()] (@) H.S,0, (b) H,,0, (© H,S,0, (@) HS,0, In KO,, the nature of oxygen species and the oxidation state af cape taentnretrereaen [Main Online April 15,2018 (1D) (a) Superoxideand-1(b) Superoxideand—1/2 (©) Peroxideand-1/2_(d) Oxide and-2 The correct sequence of decreasing number of -bonds in the structures of H,SO,, H,SO, and H,S,0, is [Main Online Apri 9, 2017] (a) H,SO,>H,S0,>H,,0, (b) H,SO, > H,8,0,>H,SO, (©) H.S,0,>H,SO,>H,S0, (d) H,S,0, > H,S0, > H,S0, Topic-2: Group-16 Elements (Oxygen Family) Chemi (vif) White phosphorous (P,) is boiled with a si solution of sodium hydroxide in an inert atmos 11982/87— 1 yy 83. Givereasons forthe following (0 Theexperimentally determined N ~F bond len NB; is greater than the sum of the single bond radii of Nand F (i) Ammonium chloride solvent (iv) H,PO, isa dibasic acid. [1989-1 (0). Orthophosphorus acid is not tribasic acid [1987-1 (vi) A bottle of liquor ammonia should be cooled opening the stopper: 1983-1 (vi) Orthophosphoric acid, H,PO,, is tribas phosphorous acid, H,PO,, is dibasic. (1982-1 Give structural formula forthe following : (i Phosphorous acid, H,PO, li98i-1 (ii). Pyrophosphorie acid, H, 1981-1 7. Identify the incorrect statement: [Main Online April 10, (©) S,isparamagnetic like oxygen (@) S,ring has. crown shape. 8, In the following reaction sequence in aqueous sok the species X, Yand Z, respectively, are | Aa. Oe) ea hs car white solution precipitate vith ime D ; mateotisg (@) [Aa(S,0)4).A8,8,0,,42,8 0) [ARtS,0))]AESO, Ag, (©) [Ag(S0,)}*49,8,0, Ag (@) [Ax60))-1Ag:S0, Ag 9, Aqueous solution ofNa,S,0, on reaction with Clg (@) NaS,0, (b) NaHSO, [21 © ma (@) NaOH 10. Which of the following is not oxidized by O,? (2 (@) KI (b) FeSO, (c) KMnO, (d) K,Mn0, 11, Theacid having O—O bond is I @) HS,0, () H,S,0, (©) H,5,0, (6) HS. 12, Thenumber of S —S bonds in sulphur trioxide trimer (S¥ is (@) three (b) two (©) one 13, Sodium thiosulphate is prepared by (@)_ reducing Na,SO, solution with H,S (6) boiling Na,SO, solution with Sin alkaline mei (©) neutralising H.S,O, solution with NaOH (@ boiling Na,SO; solution with S in acidic mediumpBlock Elements (Group 15, 16, 17 & 18) The js of one mole of peroxodisulphuric acid produces =» 1 two moles of sulphuric acid [1996-1Markj ‘«&) 5 Comprefeng two moles of peroxomonosulphuric acid (c) one mole of sulphuric acid and one mole of Upon heating KCI, Tat peroxomonosulphuric acid P 4 £08 Wis Rane _ @ one mole of sulphuric acid, one mole of Phosphorus to give ¥. Th peroxomonosulphuric acid andone mole ofhydrogen Yan Z. ia peroxide. 26. WandX 15. HSO, cannot be used to prepare HBr from NaBras it : (A) : [1995 Oo (a) reacts slowly with NaBr (b) oxidises HBr 27. Yand Zare, respect (c)_ reduces HBr ; ; (d)_disproportionates HBr (A) N,O, and H,P 16. The compound which gives off oxygen on moderate (© _N,0, and HPC heatingis: [1986 - 1 Mark] i (a) cupric oxide (b) mercuric oxide The reactions of Cl (©) zinc oxide (d) aluminium oxide NaOH in wat 17. A gas that cannot be collected over water is : @ N. (&) 0, [1985-1 Mark] © 80 @ PH, phosphorus tc 18. Which of the following is coloured {1980} oxoacid of phosp r @ NO (b) NO ©) SO, (d) None 28. PandQ,re: (a) Hypoc! @) 2 Integer Value Answer chlorus and y 1 : (b)Hypochlorus a 19. The total number of compounds Bene at iol oe (0) Chloricand sie a. ong the molecules given be! (d)_ Chlorie and hypo Haare a erO, P.Oy HuP,Os HsPOw yo, R Sand Pepe is N,O3, N,O5, P05 Pulp» Sataisr os ae and F HS,0, 1150, 8 0 eat V3, aos (b) $0,C PCI, ane . i ») Soc, PCI, and H, a a cl S sort, PCIcand 2 a oacids. @ Ss U, Consider te following sulphure Pas Sy yj Awsrtion and Rew H,$O,, H,S,0x and H)5,07- ; th Jitrogen and Bey 2 oe aceazy the number of BOSE TN) sertion Ni Amongst t xa ae iy [Main July 29. ane (i jin the atmosphe! peroxo(0-O) ra F eraliotropic formsiof sulphate nitrog 2»), Among the following 2 forms, which will s! Reas0 number OE a4 {Main Feb-24 2021 (01 ae iste eee sh we arama (B) B-sulphur_ (C) Sor dation of | Both AN ig sup OS imeeineneediinig)inthoOT ind... (c) Both asState with balanced equations what happens yy." oe : 2 prepared from its hexahydrated salt by treating with RHE GREER a creicionctions.” sulphur is precip gen 2,2 dimethoxypropane, Discs al this using ba with sodium bisulphite solution Thoth chemical equations. [1998-6 43. Giverreasons forthe following an atin B Sulphur dioxide isa more powerful re Sea nS aaa eR a cae et [1991 -2 Marks} i [1903 47. Write the wo resonance structures oforone which saity (i) Valency of oxygen is generally two wherea ut the ett rule shows valency ottwo fourand a isan on Suphurdediegns arr sopourandararcpasedover (i) Sulphur melsto acter mabietguida i Sulphar dios anal ies. 1Morig further heating above 160°C, it becomes vg heated sodium chlo 11981 1 Mary i [1991 Tople-S: Group-17 Elements (Halogen Family) ee _. ape Ec bond energies in descending order: CCC — Be. (QZ) | MOQ with One Conmvet Answer ; . (Main Jan. oR, 1. Concentrated HNO, reacts with Iodine to give j a i wae! [Main Juty 28, 2022 (I) (a) eo ge eS 1 @) HINO, andH,0 (6) HIO,,N,O and H,0 her eaaeon cS (©) HIO;,NO, and H,O (d) HIO,,N,Oand H,O () C_Cl>C-Br>C-I>C-F A colorless aqueous solution contains nitrates oft90 my als, Xand ¥. When it was added to:an aqueous solutions, ‘NaCl, a white precipitate was formed. This precipitate ya, 2 The intechalogen compound formed from the reaction of bromine with excess of fluorine isa: Main July 25, 2022 (1) (@) hypohalite () hralate (©) perhalate (@ halite found to be partly soluble in hot water to give a reside p 3. On the surface of polar stratospheric clouds, hydrolysis and a solution Q. The residue P was soluble in aq, Nit of chlorine nitrate gives A and B while its reaction with and also in excess sodium thiosulfate. The hot solution HCI produces Band C. A, Band Care, respectively gave a yellow precipitate with KI. The metals X and y_ [Main June 27, 2022(11)] respectively, are {Adv.2020) (@) HOCI,HNO;,Cl, —_(b) Cl,, HNO,, HOCL (@) Agand Pb (b) Agand Cd (©) HCIO,,HNO,,HOCI (a) HOCI HNO,,C1,0 ©) Cdand Pb) o)pCtand Zn The reaction of HCIO, with HCl givesaparamagneticgas, °: lodine reacts with concentrated FINO, to yield Y along 5 s Sm ge with other products. The oxidation state of iodine in Ys which upon reaction with O, produces. [Ad 2022] [Main Jan. 12.201940) @ C0 0) CO, © CL @ CL0, @ 5 ) 7 © 3 @i Which one of the following correctly represents the order 19, ‘The products obtained when chlorine, ‘gas reacts with cold of stability of oxides, X,O; (X =halogen) ? and dilute aqueous NaOH are (2017) [Main Aug. 31, 2021 (1)] (a) ClO-and Clo; (b) ClO; and ClO; @) Br>Ci>I (b) Br>I>cl (©) Chand Clo- (@) Chand cio; (©) CI>I>Br (@) I>Cl>Br 11. The non-metal that does not exhibit positive oxidation Number of Cl=0 bonds in chlorous acid, chloric acid and state is : [Main Online April 9, 2016] (@) Chlorine (b) Todine (c) Fluorine (d) Oxygen perchloric acid respectively are: {Main July 27, 2021 (I1)] (@) 3,1and1 (b) 4, 1and0 12. Which among the following is the most reactive? (c) 1,land3 (@ 1,2and3 {Main 2015] ®@, oC Oa @B,cements (Group 35; 16,37 & 18) nierhalogen compounds are stated 27, of cortain hem isnot correctly stated? one o The number of halogens) fo ich [Main Online April 11,2014] 9g The number of Cl= 0 bonds iny al bipyramid Bg we 29. Chlorine reacts with hot and ea Produces o dimeric -ompounds (X) and @ 1 in enthay with negative sign of furine isles white precipitate with sve 4 Bret of chine duet: {Main Online April 9, 2013] average bond order between ( hat nization enthalpy of fluorine eee (@) Hieh er size of chlorine atom 6 . Siaersize of luorine atom Q) + Fillinthe Blanks () pigaesize of 2p orbital of uorine 30. Solubility of iodine in water is (0 fre ofthe following speciesisnota pseudohaide? addition of iodide ions because 1B [1997-1 Mark] ENO (b) RCO” (6) OCN—(d) NNW 31 aid BiVES HYPO ne heer combines with HF to form KHF,. ie compound (hydrobromic, hypobromous, per! contains the species. }6- | Mark] O KF andi () KY.FandHE 32. The increase in the solubility (9 Koad [HF (4) [KHF}* and F- solution of potassium iodide i |. Which of the following statements is correct for CsBr,? @) Ttis.a covalent compound. [1996-1 Mark] 33+ = is a weak acid. (HF, K {b) Itcontains Cs** and Br° ions. 34. Todine reacts with hot NaOH s (9 Itcontains Cs" and Br, ions Naland (@) Itcontains Cs*, and Br’ and lattice Br, molecule @ 5 Bromine can be liberated from potassium bromide solution Gl: ta by the action of {1987-1 Mark] 35: HBr is a stronger.acid than (@) Iodine solution (b) Chlorine water bonding. 36. Inaqueous solution, chlorine is than fluorine. Dil. HC! oxidizes metallic Feto (a) dryair e moisture 6 MCQS with One or More (6) sunlight (a) pure oxygen Seen tobypochirie ch HBrand Hi reduce sulphuric acid, HCl can redueeKMnO, ” eas hecomrea atement(s and HF can reduce (1981-1 Mark] (a) Thehypochlorite ion sth a) H,SO, (b) KMnO, (b) The molecular shape of (© K,Cr,0, (@) none of the above enced by the lone pair of AA solution of KBr is treated with each of the igen (©) Thehypochlorite and chl Which one would liberate bromine to give rise to identical st HI () (@ SO, (4) The hypochlorite ion oxit @qa (@ Theby Which of the following is most Stable toheat [1980] 49. The colour of the X, molect (© HBr = @) HI changes gradually from yello” This is due to er Va (a) Thephysical state of X,2 : roduces an oxide of chlorine, Theaverage from gas 0 solid down meee! lorineinthis oxideis__. |Adv. 2021] (6) Decrease in ionization ¢ mec ‘with Na,CO,in aqueous solution gives (6) Decrease in x*-o* ap Reaction of Bes “Tr dium bromate with evolution of (@ Decrease in HOMO-LU sodium bromide a7 of sodium bromide molecules 4, The correct statement(s) abe gas. The MH Ted chemical equation is (2011) HCIO, (are) wed in the ba (@)Thecentralstom inbothH () HCIO, is more acidic resonance stabilization ne Coed inthe! (©) Sodium chloride (4) Potassium iodide Chlorine acts as a bleaching agent only in presence of [1983 - 1 Mark]‘and bleach solution are produced on a large Jin several household products. The effectiveness soften measured by iodometry. (201.2 1) fe Theat that nei i BO (0) CHO, td) CLO, shuld sic eure wih S0mLo00M OmL oN a aa nthe tin ofthe bert 48 mL. of 0.25 N Na,S,O, was used to reach the end paint The mean the Mose Wench sation (9) 048M (D) OOM WO) OD4M a) ODEN @ 9) Asertion and Rewon Statement Type Questions: Each question contains STATEMENT-1 (Assertion) and STATEMENT: (Reason). Each question has 4 chotoes (a, (0), (6) and (d) ut of which ONLY ONE iscorreet. Mark your answer as (@) If both Statement -1 and Statement -2 are correct, and Smtement-2 isthe correct explanation ofthe Statement-2 (©) [both Statement -1 and Statement -2 are correct, but Statement 2 isnot the correct explanation of the Statement 1 (©) 1fStatement-1 is correct but Statement -2is incorrect (@) _1fStatement-1 is incorrect but Statement -2is correct. 44 Given below are two statements: one is labelled as Assertion A and the other is labelled as Reason R. Assertion A : Flourine forms one oxoacid. eavon ft» Flourine has smallest size amongstall halogens andi highly electronegative. [Main June 27, 2022 (ID) 45. Statement: Fatom has ess electron affinity than Cl atom Statement-2: Additional electrons are repelled more effectively by 3p electrons in Cl atom than by 2p electrons inFatom, [1998-2 Marks} ZB) Subjective Problems 46, Givean example of oxidation of one halide by another halogen. Explain the feasibility ofthe reaction. [2000-2 Marks} 47. Complete the following chemical equations : (@) KiCh > (b) KCIO; +1, > Justify the formation of the products in the above reactions, [1996-2 Marks} 48. Gradual addition of KI solution to Bi(NO,), solution initially produces a dark brown precipitate which dissolves in excess of KI to give a clear yellow solution. Write chemical equations for the above reactions. 1996-2 Marks} fom ee." 4 salt of an oxoacid as one of a Bi MEQ with One Comeet Answer ONT 1. Match List-I with List-II: [Main July 25, 2022 (11) List- List- (Molecule) (hybridization; shape) (A) Xe0, (sp°d; linear @) XeF, (sp; pyramidal (© Xe0r, (UD). sp°d?sdistorted octahedral (D) XeF, (V) sp* sqaure pyramidal Die ° so, si 52. 53, 54, Chem Completeand balance the following chemical ry (ii) NH, + N¥OC1 {1993 ns Mention the products formed in the folowing ; | ary (0) Chlorine gas is bubbled through a sluts or bromide 119g (W oaine i added toa solution of stannous cy tac Arrange the following in (9 HOCI, HOCIO,; HOCIO,, HOCI in increas, acest Vth (ii) increasing bond strength trope. Mang HC, HBr, HF HI Man State with balanced equations what happens whey (9) Sodium iodate 8 add toa statin bisulphite. 1190-1 ya (id, Sodium chlorate reacts wth sulphur dog sulphuric acid medium (1989-1 ya (uy Som bom eats with Sucrin my alka 1985 1a (G)Todate on reacts with bisulphite onto liberate 1988-1 via (Sodium iodate is treated with sodium bsy solution (1982-1 Mary Give reasons for the following (0 Bond dissociation energy of F, is less than the a 1192-1 Mar (i) Fluorine cannot be prepared from fuorise. chemical oxidation, [1985-1 Mar (ili) Anhydrous HCI is a bad conductor of clectsey but aqueous HCI is a good conductor [1985-1 var (i) In the preparation of hydrogen iodide fom sa iodides, phosphoric acid is preferred to sulphuricasd 1982-1 Mar Write balanced equation involved inthe preparatng (Anhydrous aluminium chloride from alumina (a) Bleaching powder from slaked lime. (ii) Tin metal from cassiterite (iv) Chlorine from sodium chloride. Account for the following, Limit your answer to two enes (Hydrogen bromide cannot be prepared by actions concentrated sulphuric acid or sodium bromide (#) Whena blue litmus paper is dipped into a solutions hypochlorous acid, it first tums red and then late gets decolourised. 1199 Topic-4; Group-18 Elements (Noble Gases) ‘Choose the correct answer from the options given teow (a) AdI,B-L,CAV,D-I (b)A-1,B-IV, C-lll, DI (© AAV,BALCHILDI ATV, BA,C-D-ll The reaction in which the hybridisation of the underline! atom is affected is : [Main Sep. 04, 202000] @_H,PO, —Pisproponionation_, () H,S0, +Nacl—22k_, © x (@) Xek, + SbF, —>ments (GTOUP 15, 16, 17 & 18) esis ta does NOT occur inthe atmosphere g A [Main Ay Main Apri 1, 2019 O) ot 0 on ee ‘the number of bond pair(s), x-bond\) mo Rn ters id(s) and tone [Main Online Aprit 15, ine A, 2018 ay oe @ 44,0 Ds, ‘on partial hydrolysis with water produces a sand ‘X°. The same compound *X” is formed when Ser reacts vith sili. Thecompound ig a [Main Ontine April 9, 2017) se @ x ee (9 XP, ees intermolecular force is most responsible in allowing enon gas toliquefy? [Main Online April9, 2016) {@) Instantaneous dipole-induced dipole () [on-dipole (0) Tonic {@ Dipole— \ PSO,+ 0, + other product Q. Na $,0,+1,0—> 24 NaHlSO, + other product a 8 XeF,—2> Xe+ other product, 4 Ch, Codes FAGORLER: 8 (yin i, 1 OR eae + cn eee 3 eo. oe 17, All'the compounds listed in Column | react with water. ‘Match the result of the respective reactions with the appropriate options listed in Column Ih {2010 Column Colurnn-tt (a) CH) SiC, (p) Hydrogen halide formation ® Xe, (@)_ Redox reaction oa (©) Reacts with glass @) Va, (s)_ Polymerization (1) 0, formationuse of ts 2007) nt of metal ? An ——— e reactions of the folly a in (2002-5 Mang (ii) BF, (iv) NCI, (wy) XeF, Draw the molecular structures of XeF ,XeF, and Xeq idicating the location of lone pair(s) of electrons, indi ae (2000-3 May Topic-1 : Group-15 Elements (Nitrogen Family) GC Fo 3@ 40 50 6% 7@ &@ %8 10 12 2 ne uO Bo co melo B®) 2.6 tO 2 2 (@) 24.) 25. 26.) 27, &) 28. © . (@) 30. () a © 32.) asin ch aN OEE Oe @ 37.) 38 @) 39% @) 40. io) fu. ©, 2 4 BM @ 4. AH) as 4%, (Rout) 4B. (CO) 49. (ohitevelgy) Ge (3) St. True 52, True 53 Fale 54, G@bAOSS (abe) se be), SE GA 58 HOS. wy ea © 61. (aca) 62. ad) 64. (©) 65. (i) @) Gi) ©) (iil) @ (i) © 66. ©) 67. +) 69. @ 70. Group-16 Elements (Oxygen Family) ©@ 2@ 32060 40 50 606 2@ &@ 2% 06 1 © 2@ BO © Bo 60) 17.0 8% @ 6 2.4) 21. (1) 22. Q88) 23, Nitricoxide [NO] 24. (@cd)28. (acd) 26. (6) 27. ) 28. (@) 29. @) 30. (ce) - Topic-3 : Group-17 Elements (Halogen Family) 1 2s 3. @) 40 53@ 6@ 72@ &@ 2%@ © un. ‘S 2 i 1B. a 14. (©) 15. (b) 16 (©) 17. ©) «18. ) 19.) 20.) | 21. (@) 22 @ «23. ©) 4. 5) 25. GB) 26. 4) 27. GB) 28. GB) 28. (1.67) | 30. 1; complex ion 31. Hypobromous; bromite 32. Kl, 33. HF 34. NalO, 35. False36. False 37. True 38. (a,b,d) 39. (cd) 40. (abd)41. (ad) 42. @ 8. © 44, (a) 45. (0) Topic-4 : Group nts (Noble Gases) L@ 20 3@ 4@ 5&0 6@ 20 &@ 46 00 i. (d) 12. (b) 13. (3) 14, (19) 15, (19) 16, @ 17. AHP. (BO). (0.01. DH. 18. @) 19. (©) 20. @