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Chemistry

Subjects Total Marks Duration No. of Questions

Chemistry 100 Marks 3 Hrs 50 Questions

Instructions

1. Total duration of test is 3 hours .

2. Total number of questions in the test is 50.
3. Total number of sections in the test is 1.
4. Section 1 is A consisting of 50 questions.

A 50 Questions: 100 Marks

Q.1 2 Marks
The ionization isomer of is :

A) B) C) D)

Q.2 2 Marks
The term which is used to indicate the anionic as the central metal atom in a coordination compound is
A) Iron B) Ferrum C) Ferrate D) Ferrous

Q.3 2 Marks
A complex compound whose central metal is in its oxidation state with coordination number two can show which isomerism?
A) Ionisation B) Hydrate C) Linkage D) Geometrical

Q.4 2 Marks
Which of the following ligands is NOT a chelating agent?
A) B) en C) Oxalate D) Pyridine

Q.5 2 Marks
The IUPAC name for the complex is:

A) Nitrito- -pentaamminecobalt‌ chloride B) Nitrito- -pentaamminecobalt chloride

C) Pentaamminenitrito- -cobalt chloride D) Pentaamminenitrito- -cobalt chloride

Q.6 2 Marks
Microcosmic salt is
A) B) C) D)

Q.7 2 Marks
Assume 100% ionisation of the following in aq. solution of
(I) (II) (III) (IV)
Increasing order of conductivity is:
A) I < II < III < IV B) III < IV < II < I C) IV < III < II < I D) equal

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Q.8 2 Marks
Which of the following is a type of addition compounds?
A) Ligands B) Double salts C) Heteroleptic complexes D) Homoleptic complexes

Q.9 2 Marks
Of the following, which ligand does not possess the name suggested by when it acts as a ligand in complex?
A) , aqua B) , ammonia C) , carbonyl D) , fluoro

Q.10 2 Marks
Select the ligand from the following which is not an ambidentate ligand:

A) B) C) D)

Q.11 2 Marks
The tetrahedral complexes have coordination number:
A) B) C) D)

Q.12 2 Marks
Which of the following is a common donor atom in ligands?
A) Nitrogen B) Oxygen C) Arsenic D) Both (a) and (b)

Q.13 2 Marks
Which has maximum EAN of the underlined atoms?

A) B) C) D)

Q.14 2 Marks
The pair of compounds having metals in their highest oxidation state is:
A) B) C) D)

Q.15 2 Marks
The IUPAC name of is

A) Hexaamminecobalt(III) tris(oxalato)chromium B) Hexaamminecobalt(III) tris(oxalato)chromate(III)

C) Hexaamminecobalt tris(oxalato)chromium(III) D) Hexaamminecobalt(III) chromium(III)oxalate

Q.16 2 Marks
Pentamminechloroplatinum (IV) chloride ionises to give :
A) Two ions B) Three ions C) Four ions D) Five ions

Q.17 2 Marks
In the compound , the term used to denote the number of molecules is?

A) Six B) Hexa C) Pentis D) Penta

Q.18 2 Marks
In which of the following complexes more than one type of structural isomerism is possible?
A) B) C) D)

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Q.19 2 Marks
Select correct statement :
A) Chelation effect is maximum for five-member rings.

B) Complex ions in which ligands can be interchanged rapidly are said to be labile C) Both are correct D) None is correct

Q.20 2 Marks
Which is correct for the following reactions?
(i) Trans number of rings in the resulting complex.

(ii) Cis number of rings in the resulting complex.

(iii) number of rings in the resulting complex.

(iv) number of rings in the resulting complex.
A) B) C) D)

Q.21 2 Marks
The coordination number in a/an ......... complex may increase to 8.
A) Cobalt B) Osmium C) Nickel D) Iron

Q.22 2 Marks
Diethylene triamine is
A) a chelating agent. B) a polydentate ligand. C) a tridentate ligand. D) all.

Q.23 2 Marks
The number of geometric isomers that can exist for square planar is ( pyridine):

A) B) C) D)

Q.24 2 Marks
Which of the following system is most stable for a chelate?
A) Two fused cyclic system B) Three fused cyclic system C) Four fused cyclic system D) Five fused cyclic system

Q.25 2 Marks
Which one of the following is not a homoleptic complex?

A) B) C) D)

Q.26 2 Marks
In the coordination compound, , the oxidation state of nickel is

A) -1 B) 0 C) +1 D) +2

Q.27 2 Marks
Value of in potash alum,

is
A) B) C) D) None of these

Q.28 2 Marks

Co-ordination number of platinum in ion is:

A) B) C) D)

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Q.29 2 Marks

The oxidation state of in its oxo-complex species is

A) B) C) D)

Q.30 2 Marks
For an octahedral complex, a transition metal, and are the monodentate achiral ligands), the correct statement, among the
following, is
A) has geometrical isomers, one of which is chiral. B) has geometrical isomers, both of which are achiral.
C) has geometrical isomers, all of which are achiral. D) has geometrical isomers, two of which are chiral.

Q.31 2 Marks
When of is treated with an excess of , of are obtained. The conductivity of the solution
will correspond to which of the following rations?
A) 1 : 3 electrolyte B) 1 : 2 electrolyte C) 1 : 1 electrolyte D) 3 : 1 electrolyte

Q.32 2 Marks
Which of the following statements is correct?

A) In , the ligand has satisfied both primary and secondary valencies of ferric ion.

B) In the ligand has satisfied only the secondary valency of copper.

C) In the ligand has satisfied only the secondary valency of ferric ion. D) Both (b) and (c).

Q.33 2 Marks
How many ions are produced from the complex in solution?

A) B) C) D)

Q.34 2 Marks
An imperfect complex of a complex compound is ionized; the compound is called
A) acid salt. B) complex salt. C) double salt. D) normal salt.

Q.35 2 Marks
Which of the following does not have optical isomer?

A) B) C) D)

Q.36 2 Marks
Oxidation state of iron and the charge on the ligand in are

A) and respectively B) and C) and respectively D) and respectively

Q.37 2 Marks
The two compounds pentamminesulphatocobalt ( ) bromide and pentamminesulphatocobalt ( ) chloride represent
A) linkage isomerism. B) ionisation isomerism. C) coordination isomerism. D) no isomerism.

Q.38 2 Marks
Coordination isomerism is caused by interchange of ligands between the
A) Complex cation and complex anion B) Inner sphere and outer sphere C) Low oxidation and higher oxidation states

D) and structure

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Q.39 2 Marks
Which of the following is the correct statement?
A) The bond between metal and carbonyl. Carbon reduces the bond length of in carbon monoxide

B) orbital of central metal atom/ion is used in hybridization C) is a acid ligand

D) All negative ligands are stronger than neutral ligands

Q.40 2 Marks
In complex compounds, the ligand is named as
A) nitrato B) nitrito C) nitro D) none of these

Q.41 2 Marks
Which of the following is not correctly matched?
A) - Bidentate ligand B) Ethylenediamine - Bidentate ligand C) - Monodentate ligand D) - Monodentate ligand

Q.42 2 Marks
Some salts, although containing two different metallic elements, give test for one of them in solution. Such salts are
A) double salts. B) complex salts. C) normal salts. D) none of these.

Q.43 2 Marks
Primary and secondary valency of in are
A) B) C) D)

Q.44 2 Marks
Which of the following 0.1 M complex compound solutions will have the minimum electrical conductivity?
A) Hexammine platinum (IV) chloride B) Chloropenta ammine platinum (IV) chloride C) Dichloro tetrammine platinum (IV) chloride

D) Trichloro triammine platinum (IV) chloride

Q.45 2 Marks
Which of the following complexes exhibit optical isomerism?
A) Trans-tetraamminedithiocyanatochromium (III) ion B) Cis-diamminedicarbonatocobaltate (III) ion

C) Trans-diamminedicarbonatocobaltate (III) ion D) Cis-bis (glycinato) platinum (II)

Q.46 2 Marks
The IUPAC name of the coordination complex is
A) potassium pentachloridoazidoosmate . B) potassium pentachloridoazoosmate .
C) potassium pentachloridonitridoosmate . D) potassium nitroosmate .

Q.47 2 Marks
The correct structure of ethylenediaminetetraacetic acid (EDTA) is

A) B) C) D)

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Q.48 2 Marks
A solution containing of is passed through a cation exchanger. The chloride
ions obtained in the solution were treated with an excess of to give of . The formula
of the complex is:
Hint:molesof of

mole of contains anions

A) B) C) D)

Q.49 2 Marks
A chelating agent has two or more than two donor atoms to bind to a single metal ion. Which of the following is not a chelating agent?
A) thiosulphato B) oxalato C) glycinato D) Ethane-1,2-diamine

Q.50 2 Marks
Which of the following statement is incorrect for ligand-metal complex
A) Larger the donor atom of the ligand, the more stable is the metal-ligand bond B) Highly charged ligand forms strong bond

C) Larger the permanent dipole moment of ligand, the more stable is the bond

D) Greater the ionization potential of central metal, the stronger is the bond

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