NIFA CLASSES Kanpur

Electro

Subjects Total Marks Duration No. of Questions

Chemistry 30 Marks 3 Hrs 30 Questions

Instructions

1. Total duration of test is 3 hours .

2. Total number of questions in the test is 30.
3. Total number of sections in the test is 1.
4. Section 1 is A consisting of 30 questions.

A 30 Questions: 30 Marks

Q.1 2 Marks

at for the cell is The equilibrium constant at is

A) B) C) D)

Q.2 2 Marks
The calomel electrode is reversible with respect to:

A) B) C) D)

Q.3 2 Marks
In fuel cell the reaction occuring at cathode is:

A) B) C) D)

Q.4 2 Marks
Which of the following reaction occur at anode in lead-storage battery when battery is in use?

A) B)

C) D)

Q.5 2 Marks
The equivalent conductances of , and at infinite dilution are 91,426 and respectively at
. The equivalent conductance of solution is . The of solution is
A) B) C) D)

Q.6 2 Marks
The number of metals which can liberate from dilute is: .

Q.7 2 Marks
Calculate the magnitude of of the cell (up to two places of decimals) of .

and . Take

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Q.8 2 Marks
Calculate of acetic acid if its solution has equivalent conductance of at . If your
answer is then is :

Q.9 2 Marks
The specific conductance at of a saturated solution of in water is If is equal to
find out the solubility of in water in

Q.10 2 Marks
How many of the following species conduct electricity?
Fused (solid), aqueous solution, aqueous urea solution, diamond, graphite, , aqueous glucose solution, (solid),
metal

Q.11 2 Marks
The solubility product of Agl is (scientific notation) and the standard reduction potential . It was found that the
reduction potential is . Then the value of
is

Q.12 2 Marks
Consider the cell at

The fraction of total iron present as ion at the cell potential of is . The value of is ______. (Nearest integer)

Q.13 2 Marks
Kolbe discovered the method of preparation of hydrocarbon in which sodium salt of carboxylic acid is electrolysed. If aqueous solution of
is electrolysed by a current of passed for second and total volume of gas collected at anode and cathode is
at S.T.P, then value of is

Q.14 2 Marks
An electrochemical cell is made by placing a zinc electrode in of solution and a copper electrode in of
solution.
Calculate the final concentration of in this cell if it is allowed to produce an average current of for . Given that,
cell
.
Answer correct up to two places of decimals.

Q.15 2 Marks
An aqueous solution of solution is filled in a long capillary tube of internal radius The solution was found to
have a specific conductance of The current in when a potential of is applied across the capillary tube is
, then the value of reported to two decimal places is:

Q.16 2 Marks
An aqueous solution of is electrolysed using direct current. The electrodes are inert and time dependence of current is represented as

The mass (in ) of deposited at cathode is [Given ]

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Q.17 2 Marks
Using the standard electrode potentials given below, predict if the reaction between the following is feasible.

o is Y. Then find the value of Y.

Fe3+(aq) and Cu(s) If the value of Ecell

Q.18 2 Marks
For the given reactions

the electrode potentials are ; and . The magnitude of standard electrode

potential for i.e. is____ (Nearest integer)

Q.19 2 Marks
Calculate the equilibrium constant for the following reaction at :

The standard EMF of the corresponding voltaic cell is .

Answer correct up to three places of decimals.

Q.20 2 Marks
For the cells

The potential for the reaction, is assigned as zero. Determine the potential for the following electrodes in V.

Q.21 2 Marks
A saturated solution in and has conductivity of . Limiting molar
conductivity of and are and respectively. If the limiting molar conductivity of is in
Find out the value of

Q.22 2 Marks
The standard reduction potential of the electrode is . Calculate at if Nernst equation takes
the form . If , report after rounding-off up to two places of decimals.

Q.23 2 Marks
How many of these metals can displace easily from acids.
Fe, Mg, Al, Cu, Ag, Au, Zn

Q.24 2 Marks
Calculate emf of electrode immersed in at . .
(mention the answer upto three decimal places after rounding off)

Q.25 2 Marks
Electrolysis of aqueous solution of is carried out in two separate electrolytic cells using same amount of charge.
In cell is used as electrodes. In cell is used as anode while is used as cathode.
A greenish yellow gas is evolved with colourless paramagnetic gas in molar ratio at anode in cell
while only greenish yellow gas is evolved at anode in cell Determine ratio of total volumes of gases evolved in cells to during the
entire electrolysis.

Q.26 2 Marks
Which of the following are electrical insulators?

A) Glass B) Diamond C) Rubber D) All of the above

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Q.27 2 Marks
Which of the following are true for a standard hydrogen electrode?
A) The temperature is maintained at . B) The hydrogen ion concentration is .
C) The pressure of hydrogen gas is maintained at . D) It contains platinum metal that is used in adsorbing the hydrogen gas.

Q.28 2 Marks
Which is/are correct about corrosion?
A) Due to corrosion formed B) Due to corrosion formed
C) Presence of air and moisture increases the rate of corrosion D) Magnesium is used as sacrificial anode

Q.29 2 Marks
Which of the following statements are correct about cell?
A) It consists of a cadmium electrode (as anode) and a metal grid containing nickel (IV) oxide (as cathode) immersed in solution.
B)

C) D) The potential of each cell is approximately .

Q.30 2 Marks
Given .
Which of the following statements is/are correct.
A) can be stored in copper vessel B) can be stored in copper vessel C) can be stored in silver vessel
D) can be stored in copper vessel

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